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RESEARCH PAPER · IUCrJ · 2021

Structural chemistry of layered lead halide perovskites containing single octahedral layers

Jason A. McNulty, Philip Lightfoot

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Structural chemistry of layered lead halide perovskites containing single octahedral layersOriginalStructural Features in Some Layered Hybrid Copper Chloride Perovskites: ACuCl4 or A2CuCl427Structural diversity in hybrid lead halides templated by 4-methylimidazolium16Relationships between Distortions of Inorganic Framework and Band Gap of Layered Hybrid Halide Perovskites68Perovskite-derived structure modulation in the iron sulfate family0Photophysics of Two-Dimensional Semiconducting Organic–Inorganic Metal-Halide Perovskites46Polar Ferromagnet Induced by Fluorine Positioning in Isomeric Layered Copper Halide Perovskites20Polarity and Ferromagnetism in Two-Dimensional Hybrid Copper Perovskites with Chlorinated Aromatic Spacers48Hybrid Layered Double Perovskite Halides of Transition Metals66Anomalous and colossal thermal expansion, photoluminescence, and dielectric properties in lead halide-layered perovskites with cyclohexylammonium and cyclopentylammonium cations5Crystal Structures of the Perovskite‐Related System A/Rb/Cu(II)/Br (A=BA, Gu, PEA, 5‐AVA, H2en) with Winners, Losers and Compromises – Versatility from 0D to 3D on Different Levels6The chemistry and physics of organic—inorganic hybrid perovskite quantum wells10[Methylhydrazinium] 2 PbCl 4 , a Two-Dimensional Perovskite with Polar and Modulated Phases46Layered Hybrid iron Fluorides2Broadband emission originating from the stereochemical expression of 6s 2 lone pairs in two-dimensional lead bromide perovskites11Broadband yellow and white emission from large octahedral tilting in (110)-oriented layered perovskites: imidazolium-methylhydrazinium lead halides24Pressure driven rotational isomerism in 2D hybrid perovskites50Emergence of Rashba-/Dresselhaus effects in Ruddlesden–Popper halide perovskites with octahedral rotations22Controlled Assembly and Anomalous Thermal Expansion of Ultrathin Cesium Lead Bromide Nanoplatelets42Structural Insights into Layered Tetrahalocuprates(II) Based on Small Unsaturated and Cyclic Primary Ammonium Cations3Investigation of cubic K2NaXBr6(X=Sc, Y) double perovskites for optical and thermoelectric devices60Understanding structural distortions in hybrid layered perovskites with the n = 1 Ruddlesden–Popper structure22Manipulation of the Structure and Optoelectronic Properties through Bromine Inclusion in a Layered Lead Bromide Perovskite10Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)4Functional materials design: octahedral tilts in hybrid n = 1 Ruddlesden–Popper phases1Bulk Photovoltaic Effect in Chiral Layered Hybrid Perovskite Enables Highly Sensitive Near-Infrared Circular Polarization Photodetection33Lead-free metal halide (halogenidometallate) semiconductors for optoelectronic applications22The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX 4 (X = Cl, Br, I) perovskites17[NH 3 (CH 2 ) 4 NH 3 ]SnX 4 (X = Br, I): Dion–Jacobson type 2-D perovskites with short interlayer spacing7Influence of the even–odd effect on the crystal structure, band structure and optical properties of hybrid crystals of the [H 3 N-(CH 2 ) n -NH 3 ]PbX 4 ( n = 4–8 and X = Cl, Br, and I) type10Revisiting a (001)-oriented layered lead chloride templated by 1,2,4-triazolium: structural phase transitions, lattice dynamics and broadband photoluminescence6Phase transition at 350 K in the Ti 3 C 2 T x MXene: Possible sliding or moiré ferroelectricity4Structure Directing Forces in Hybrid Layered Double Perovskites Containing Aromatic Organic Cations5An Air-Stable and Exfoliable Ferromagnetic Two-Dimensional Perovskite, (Phenethylammonium)2CrCl413Extending the Family of Hybrid Layered Fluoride Perovskites2Symmetry relationships between hybrid lead halide perovskite-derived phases: vacancy ordering as a key classification factor7Magnetostructural Correlations in a Layered Perovskite: K2CuF4 at Large Compression0Understanding secondary order parameters in perovskites with tilted octahedra5Is There an Optimal Spacer Cation for Two-Dimensional Lead Iodide Perovskites?18The Determination of the Mechanical, Optoelectronic, Structural and Transport Attributes of Double Perovskite A2InGaBr6 (A=K, Rb, Cs) Halides for Renewable Energies: A DFT Study12Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]]0IUCrJ on passing its tenth anniversary and entering its second decade: progress, current status and prospects for the future1Constructing a photoferroelectric semiconductor by regulating non-covalent interactions through halogen substitution7Discerning two-dimensional metal halide perovskite moieties using solid-state NMR fingerprints2Relating structure, composition, and spin crossover properties in Hofmann complexes1Analysis of Ruddlesden‐Popper and Dion‐Jacobson 2D Lead Halide Perovskites Through Integrated Experimental and Computational Analysis6Advancing intercalation strategies in layered hybrid perovskites by bringing together synthesis and simulations3Synthesis, Crystal Structure, and Optical Properties of Two Lead Iodide Hybrid Compounds Based on the 4‐(Ammonioethyl)‐Tetrahydropyran Cation1Pressure-Induced Detrapping from Self-Trapped Excitons to Free Excitons toward Enhanced Emission and Piezochromism in Ruddlesden–Popper (110)-Oriented Perovskites6Raman Spectroscopic Signatures of Piezochromism in Organic‐Inorganic Hybrid Compound (p‐bromoanilinium) 2 CuCl 41Dion–Jacobson Lead Bromide Perovskites with 1,4-Butanediammonium Cations: Lattice Dynamics, Phase Transitions, Dielectric Switching, and Optical Properties10Effects of dimethylformamide intercalation on the structure and optical properties of layered perovskite comprising 2-chloroethylammonium cations0Manipulating light emission in two-dimensional 1,2,4-triazolium lead chloride perovskite by pressure-induced anisotropic compression and phase transitions0Rare 3 × 3 Layering in High‐Pressure Pseudo‐Perovskite Sr 4 Te 4 O 150Solid–Solid Phase Change Layered Hybrid Materials for Thermal Energy Storage: Impact of the Chemical Composition and Structural Topology3Mixing of Spacer Cations in 2D Halide Perovskites0Exciton Localization in Dion–Jacobson and Mixed-Spacer 2D Lead Bromide Perovskites Constructed with 1,4-Butanediammonium Cations0Quantifying hybrid lead halide perovskites from multiple viewpoints: a human-guided machine learning approach1Extremely low thermal conductivity in rigid layered hybrid perovskites1

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  1. Structural Features in Some Layered Hybrid Copper Chloride Perovskites: ACuCl4 or A2CuCl4

    Inorganic Chemistry · 2021-07-09

    Ceng Han, Alasdair J. Bradford, Alexandra M. Z. Slawin, Bela E. Bode, Edoardo Fusco, Stephen Lee, Chiu Chung Tang, Philip Lightfoot

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  2. Structural diversity in hybrid lead halides templated by 4-methylimidazolium

    Journal of Solid State Chemistry · 2021-08-02

    Clement Elliott, Jason A. McNulty, David B. Cordes, Alexandra M. Z. Slawin, Philip Lightfoot

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  3. Relationships between Distortions of Inorganic Framework and Band Gap of Layered Hybrid Halide Perovskites

    Chemistry of Materials · 2021-09-13

    Ekaterina I. Marchenko, Vadim Korolev, Sergey A. Fateev, Artem A. Mitrofanov, Nikolay N. Eremin, Eugene Alekseevich Goodilin, Alexey B. Tarasov

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  4. Perovskite-derived structure modulation in the iron sulfate family

    Chemical Communications · 2022-01-01

    Yuanqi Lan, Yan Qi, Xinyuan Zhang, Wenjiao Yao, Chenchen Wang, Chun‐Sing Lee, Philip Lightfoot, Yongbing Tang

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  5. Photophysics of Two-Dimensional Semiconducting Organic–Inorganic Metal-Halide Perovskites

    Annual Review of Physical Chemistry · 2022-02-04

    Daniel B. Straus, Cherie R. Kagan

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  6. Polar Ferromagnet Induced by Fluorine Positioning in Isomeric Layered Copper Halide Perovskites

    Inorganic Chemistry · 2022-02-09

    Ceng Han, Jason A. McNulty, Alasdair J. Bradford, Alexandra M. Z. Slawin, Finlay D. Morrison, Stephen Lee, Philip Lightfoot

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  7. Polarity and Ferromagnetism in Two-Dimensional Hybrid Copper Perovskites with Chlorinated Aromatic Spacers

    Chemistry of Materials · 2022-02-21

    Ceng Han, Alasdair J. Bradford, Jason A. McNulty, Weiguo Zhang, P. Shiv Halasyamani, Alexandra M. Z. Slawin, Finlay D. Morrison, Stephen Lee, Philip Lightfoot

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  8. Hybrid Layered Double Perovskite Halides of Transition Metals

    Journal of the American Chemical Society · 2022-04-04

    Pratap Vishnoi, Julia L. Zuo, Xiaotong Li, Devesh Chandra Binwal, Kira E. Wyckoff, Lingling Mao, Linus Kautzsch, Guang Xin Wu, Stephen D. Wilson, Mercouri G. Kanatzidis, Ram Seshadri, Anthony Kevin Cheetham

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  9. Anomalous and colossal thermal expansion, photoluminescence, and dielectric properties in lead halide-layered perovskites with cyclohexylammonium and cyclopentylammonium cations

    iScience · 2022-05-23

    Alberto Cuquejo Cid, Alberto García‐Fernández, Cătălin Popescu, Juan Manuel Bermúdez‐García, M. A. Señarı́s-Rodrı́guez, Socorro Castro‐García, D. Vázquez-García, Manuel Sánchez‐Andújar

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  10. Crystal Structures of the Perovskite‐Related System A/Rb/Cu(II)/Br (A=BA, Gu, PEA, 5‐AVA, H2en) with Winners, Losers and Compromises – Versatility from 0D to 3D on Different Levels

    European Journal of Inorganic Chemistry · 2022-06-02

    Michael Daub, Daria Natalukha, Harald Hillebrecht

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  11. The chemistry and physics of organic—inorganic hybrid perovskite quantum wells

    Science China Chemistry · 2022-09-16

    Yongping Fu

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  12. [Methylhydrazinium] 2 PbCl 4 , a Two-Dimensional Perovskite with Polar and Modulated Phases

    Inorganic Chemistry · 2022-09-21

    Katarzyna Fedoruk, Dawid Drozdowski, Mirosław Mączka, Jan K. Zaręba, Dagmara Stefańska, Anna Gągor, Adam Sieradzki

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  13. Layered Hybrid iron Fluorides

    Crystals · 2022-10-13

    Teng Li, Philip Lightfoot

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  14. Broadband emission originating from the stereochemical expression of 6s 2 lone pairs in two-dimensional lead bromide perovskites

    Dalton Transactions · 2023-01-01

    Xiaofan Jiang, Yu Tao, Jiazhen Gu, Leyang Jin, Chen Li, Wenkai Zhang, Yongping Fu

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  15. Broadband yellow and white emission from large octahedral tilting in (110)-oriented layered perovskites: imidazolium-methylhydrazinium lead halides

    Journal of Materials Chemistry C · 2023-01-01

    Dawid Drozdowski, Katarzyna Fedoruk, Adam Kabański, Mirosław Mączka, Adam Sieradzki, Anna Gągor

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  16. Pressure driven rotational isomerism in 2D hybrid perovskites

    Nature Communications · 2023-01-25

    Tingting Yin, Hejin Yan, Ibrahim Abdelwahab, Yulia Lekina, Xujie Lü, Wenge Yang, Handong Sun, Kai Leng, Yongqing Cai, Zexiang Shen, Kian Ping Loh

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  17. Emergence of Rashba-/Dresselhaus effects in Ruddlesden–Popper halide perovskites with octahedral rotations

    Journal of Physics Condensed Matter · 2023-02-17

    Sonja Krach, Nicolás Forero-Correa, Raisa-Ioana Biega, Sebastian E. Reyes‐Lillo, Linn Leppert

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  18. Controlled Assembly and Anomalous Thermal Expansion of Ultrathin Cesium Lead Bromide Nanoplatelets

    Nano Letters · 2023-03-08

    Chantalle J. Krajewska, Alexander E. K. Kaplan, Matthias Kick, David B. Berkinsky, Hua Zhu, Tara Šverko, Troy Van Voorhis, Moungi G. Bawendi

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  19. Structural Insights into Layered Tetrahalocuprates(II) Based on Small Unsaturated and Cyclic Primary Ammonium Cations

    Materials · 2023-03-10

    Edi Topić, Mirta Rubčić

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  20. Investigation of cubic K2NaXBr6(X=Sc, Y) double perovskites for optical and thermoelectric devices

    Journal of Physics and Chemistry of Solids · 2023-03-27

    Sanobar Jamshaid, Nasarullah, Shatha A. Aldaghfag, Mehwish Khalid Butt, Muhammad Shahzad Yaseen, Adil Murtaza, Mudassir Ishfaq, Hosameldin Helmy Hegazy

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  21. Understanding structural distortions in hybrid layered perovskites with the n = 1 Ruddlesden–Popper structure

    IUCrJ · 2023-04-28

    Tianyu Liu, Noah P. Holzapfel, Patrick M. Woodward

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  22. Manipulation of the Structure and Optoelectronic Properties through Bromine Inclusion in a Layered Lead Bromide Perovskite

    Chemistry of Materials · 2023-05-03

    Lin-Jie Yang, Wenye Xuan, David Webster, Lethy Krishnan Jagadamma, Teng Li, David Miller, David B. Cordes, Alexandra M. Z. Slawin, Graham A. Turnbull, Ifor D. W. Samuel, Hsin‐Yi Tiffany Chen, Philip Lightfoot, Matthew Stephen Dyer, Julia Louise Payne

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  23. Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)

    Crystal Growth & Design · 2023-05-09

    Edi Topić, Pavla Šenjug, Dario Barišić, Ivor Lončarić, Damir Pajić, Mirta Rubčić

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  24. Functional materials design: octahedral tilts in hybrid n = 1 Ruddlesden–Popper phases

    IUCrJ · 2023-06-28

    Emma E. McCabe

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  25. Bulk Photovoltaic Effect in Chiral Layered Hybrid Perovskite Enables Highly Sensitive Near-Infrared Circular Polarization Photodetection

    Chemistry of Materials · 2023-08-25

    Huang Ye, Peng Yu, Meng Wei, Xinyuan Zhang, Tingting Zhu, Qianwen Guan, Lina Li, Shuang Chen, Xitao Liu, Junhua Luo

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  26. Lead-free metal halide (halogenidometallate) semiconductors for optoelectronic applications

    Applied Physics Reviews · 2023-09-01

    Biplab Ghosh, Darrell Jun Jie Tay, Maarten B. J. Roeffaers, Nripan Mathews

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  27. The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX 4 (X = Cl, Br, I) perovskites

    Journal of Materials Chemistry C · 2023-11-27

    Dmitry Sergeevich Shtarev, Mikhail I. Balanov, A. Ju. Major, А.В. Герасименко, R. Kevorkyants, D. A. Zharovov, K. M. Bulanin, Dmitrii Vasil'evich Pankin, Aida V. Rudakova, D. A. Chaplygina, N. I. Selivanov, Alexei V. Emeline

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  28. [NH 3 (CH 2 ) 4 NH 3 ]SnX 4 (X = Br, I): Dion–Jacobson type 2-D perovskites with short interlayer spacing

    Dalton Transactions · 2024-01-01

    Nagale S. Vishwajith, Mridul Krishna Sharma, Isha Jain, Pratap Vishnoi

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  29. Influence of the even–odd effect on the crystal structure, band structure and optical properties of hybrid crystals of the [H 3 N-(CH 2 ) n -NH 3 ]PbX 4 ( n = 4–8 and X = Cl, Br, and I) type

    Dalton Transactions · 2024-01-01

    Mikhail I. Balanov, Alexei V. Emeline, Dmitry Sergeevich Shtarev

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  30. Revisiting a (001)-oriented layered lead chloride templated by 1,2,4-triazolium: structural phase transitions, lattice dynamics and broadband photoluminescence

    Dalton Transactions · 2024-01-01

    Mirosław Mączka, Szymon Sobczak, Maciej Ptak, Szymon Smółka, Katarzyna Fedoruk, Filip Dybała, Artur P. Herman, Waldeci Paraguassu, Jan K. Zaręba, R. Kudrawiec, Adam Sieradzki, Andrzej Katrusiak

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  31. Phase transition at 350 K in the Ti 3 C 2 T x MXene: Possible sliding or moiré ferroelectricity

    Physical review. B./Physical review. B · 2024-01-18

    F. Cordero, Hanna Pazniak, T. Ouisse, Jesús González‐Julián, Aldo Di Carlo, Viktor Soprunyuk, W. Schranz

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  32. Structure Directing Forces in Hybrid Layered Double Perovskites Containing Aromatic Organic Cations

    Crystal Growth & Design · 2024-01-24

    Joseph T. Race, Tianyu Liu, Patrick M. Woodward

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  33. An Air-Stable and Exfoliable Ferromagnetic Two-Dimensional Perovskite, (Phenethylammonium)2CrCl4

    Chemistry of Materials · 2024-02-01

    R. Smith, Kelly M. Walsh, Qianni Jiang, Jiun‐Haw Chu, Daniel R. Gamelin

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  34. Extending the Family of Hybrid Layered Fluoride Perovskites

    Chemistry of Materials · 2024-05-09

    Teng Li, Alasdair J. Bradford, Stephen Lee, Philip Lightfoot

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  35. Symmetry relationships between hybrid lead halide perovskite-derived phases: vacancy ordering as a key classification factor

    Mendeleev Communications · 2024-09-01

    Ekaterina I. Marchenko, E. A. Kobeleva, Nikolay N. Eremin, Eugene Alekseevich Goodilin, Alexey B. Tarasov

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  36. Magnetostructural Correlations in a Layered Perovskite: K2CuF4 at Large Compression

    The Journal of Physical Chemistry C · 2024-10-02

    Sharad Babu Pillai, Deepak Upadhyay, Jakub Drapała, Zoran Mazej, Dominik Kurzydłowski

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  37. Understanding secondary order parameters in perovskites with tilted octahedra

    Journal of Applied Crystallography · 2024-10-03

    Ekaterina G. Trotsenko, Mikhail V. Talanov

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  38. Is There an Optimal Spacer Cation for Two-Dimensional Lead Iodide Perovskites?

    ACS Materials Au · 2024-11-26

    Jiazhen Gu, Yongping Fu

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  39. The Determination of the Mechanical, Optoelectronic, Structural and Transport Attributes of Double Perovskite A2InGaBr6 (A=K, Rb, Cs) Halides for Renewable Energies: A DFT Study

    ChemPhysChem · 2024-11-26

    Masoofa Akhtar, Junaid Munir, Junaid Munir, Quratul Ain, Abdullah Saleh Aldwayyan, Hamid M. Ghaithan, Abdullah Ahmed Ali Ahmed, Saif M. H. Qaid, Saif M. H. Qaid

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  40. Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]]

    Acta Crystallographica Section E Crystallographic Communications · 2024-12-13

    Olesia I. Kucheriv, Mircea-Odin Apostu, Olena Prysiazhna, Vadim A. Potaskalov, Sergey O. Malinkin

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  41. IUCrJ on passing its tenth anniversary and entering its second decade: progress, current status and prospects for the future

    IUCrJ · 2024-12-20

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  42. Constructing a photoferroelectric semiconductor by regulating non-covalent interactions through halogen substitution

    Chemical Science · 2025-01-01

    Yueyue He, Shufang Wu, Xiaofei Li, Qi Wang, Ruifang Zhao, Lin Pan, Chengbing Qin, Xian‐Ming Zhang, Dongying Fu

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  43. Discerning two-dimensional metal halide perovskite moieties using solid-state NMR fingerprints

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  44. Relating structure, composition, and spin crossover properties in Hofmann complexes

    Dalton Transactions · 2025-01-01

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  45. Analysis of Ruddlesden‐Popper and Dion‐Jacobson 2D Lead Halide Perovskites Through Integrated Experimental and Computational Analysis

    Battery energy · 2025-02-17

    Basir Akbar, Kil To Chong, Hilal Tayara

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  46. Advancing intercalation strategies in layered hybrid perovskites by bringing together synthesis and simulations

    Nature Communications · 2025-07-01

    Lin-Jie Yang, Wenye Xuan, Sara Henda, Shaoyang Wang, Sai Kiran Rajendran, David B. Cordes, David Miller, Alexandra M. Z. Slawin, Lethy Krishnan Jagadamma, Hamid Ohadi, Hsin‐Yi Tiffany Chen, Matthew Stephen Dyer, Julia Louise Payne

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  47. Synthesis, Crystal Structure, and Optical Properties of Two Lead Iodide Hybrid Compounds Based on the 4‐(Ammonioethyl)‐Tetrahydropyran Cation

    Zeitschrift für anorganische und allgemeine Chemie · 2025-07-07

    Yang Meng, Xinqi Wang, Johanna Heine

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  48. Pressure-Induced Detrapping from Self-Trapped Excitons to Free Excitons toward Enhanced Emission and Piezochromism in Ruddlesden–Popper (110)-Oriented Perovskites

    ACS Applied Materials & Interfaces · 2025-10-09

    Mirosław Mączka, Szymon Sobczak, Kinga Roszak, Daniel M. L. Vasconcelos, Filip Dybała, Artur P. Herman, R. Kudrawiec, Andrzej Katrusiak, Paulo Freire

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  49. Raman Spectroscopic Signatures of Piezochromism in Organic‐Inorganic Hybrid Compound (p‐bromoanilinium) 2 CuCl 4

    Chemistry - A European Journal · 2025-11-10

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  50. Dion–Jacobson Lead Bromide Perovskites with 1,4-Butanediammonium Cations: Lattice Dynamics, Phase Transitions, Dielectric Switching, and Optical Properties

    Inorganic Chemistry · 2025-12-09

    Mirosław Mączka, Dagmara Stefańska, Maciej Ptak, Anna Gągor, Katarzyna Fedoruk, Szymon Smółka, Jan K. Zaręba, Adam Sieradzki

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