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RESEARCH PAPER · Journal of Alloys and Compounds · 2021

Single-phase far-red-emitting ZnAl2O4:Cr3+ phosphor for application in plant growth LEDs

Manh Trung Tran, Đỗ Quang Trung, Nguyen Tu, D.D. Anh, L.T.H. Thu, N. V. Du, N. V. Quang, N.T. Huyen, Nguyen Duc Trung Kien, Dao Xuan Viet, Nguyễn Duy Hùng, Phạm Thành Huy

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Single-phase far-red-emitting ZnAl2O4:Cr3+ phosphor for application in plant growth LEDsOriginalEmission-tunable Mn-doped ZnS/ZnO heterostructure nanobelts for UV-pump WLEDs22Citrate Assisted Synthesis of co-Doped ZnAl2O4 with La3+ and Pb2+ Ions and Applications; Adsorption-Photocatalysis1Effect of triethanolamine chelating agent on crystallinities, phase purities, and optical properties of zinc aluminate spinel synthesized by thermal decomposition11Conduction Mechanisms and Summerfield Scaling Model at High Temperatures in Znal1.95cr0.05o4 Nanocrystal Spinels0Design, luminescence properties and applications of Cr 3+ -doped ScTaO 4 : a broadband near-infrared phosphor18High thermal stability phosphors with a rigid structure similar to the benzene ring and application in plant growth21The Near-Infrared Luminescence Properties and Applications of Ca3lu2ge3o12: Cr3+ Phosphor29Ultra-Broadband Near-Infrared Gd3mgscga2sio12: Cr, Yb Phosphors: Photoluminescence Properties and Led Applications73Cr3+ and Nd3+ co-activated garnet phosphor for NIR super broadband pc-LED application25A novel blue-light excitable Pr3+ doped (Sr,Ba)LaMgTaO6 phosphor for plant growth lighting59Review—Temperature Dependence of Luminescence Intensity and Decay Time in Cr 3+ -Activated Oxide and Fluoride Phosphors17Greatly enhanced deep-red luminescence performance of Ca2InSbO6:Mn4+ phosphor via multiple optimization strategies34Luminescence properties of MgCaAl10O17:RE3+ (RE3+ = Sm3+,Dy3+) phosphor for eco‐friendly solid‐state lighting applications29Efficient ultraviolet to far‐red spectral conversion: Tb 3+ , Cr 3+ co‐doped Zn 0.5 Mg 0.5 Al 2 O 4 phosphors and their application4Tuneable blue to orange phosphor from Sm3+ doped ZnAl2O4 nanomaterials8Far-red-emitting Cr3+-doped CaAl12O19 phosphors with excellent color purity and good quantum efficiency for plant growth LEDs22Oxide-Based Red Emitting Phosphors with High Color Purity and Their Versatile Applications: Synthesis, Structure, and Luminescence Properties23Double-perovskite Ca2LaNbO6:Mn4+ deep red phosphors used to improve the color rendering index properties of WLED8Bi3+/Mn4+ co-activated phosphors for indoor plant growth and temperature sensing21A novel far-red phosphors Li2ZnTi3O8:Cr3+ for indoor plant cultivation:Synthesis and luminescence properties55ẢNH HƯỞNG CỦA NỒNG ĐỘ ION Eu3+ LÊN CẤU TRÚC VÀ TÍNH CHẤT QUANG CỦA VẬT LIỆU SrTiO30Synthesis and novel emission properties of Bi3+‐doped Ca2BO3Cl phosphor for plant cultivation9Improving the luminescence performance of far-red-emitting Sr2ScSbO6:Mn4+ phosphor with charge compensation and its application in plant growth LEDs54A far-red-emitting ZnAl 1.95 Cr 0.05 O 4 phosphor for plant growth LED applications24A Highly Efficient Y3-Xbaxal5-Xsixo12:Cr3+ Near Infrared Phosphor for Plant Lighting0A Highly Efficient Y3-Xbaxal5-Xsixo12:Cr3+ Near Infrared Phosphor for Plant Lighting0High quantum efficiency and excellent color purity of red-emitting Eu 3+ -heavily doped Gd(BO 2 ) 3 -Y 3 BO 6 -GdBO 3 phosphors for NUV-pumped WLED applications24Highly efficient green-emitting ZnO:Cu 2+ phosphors for NUV-pumped white-emitting diodes8Novel broadband NIR phosphors Y 2 Mg 2 Ga 2 Si 2 O 12 : x Cr 3+ for NIR LED applications30Optical Characterization and Defect-Induced Behavior in Znal₁.₉₉₉Ho₀.₀₀₁O₄ Spinel: Unraveling Novel Insights into Structure, Morphology, and Spectroscopic Features0Summerfield scaling model and electrical conductivity study for understanding transport mechanisms of a Cr 3+ substituted ZnAl 2 O 4 ceramic39Understanding native defect induced photoluminescence in Zn 2 SnO 48Anti-thermal-quenching in Zn1-Li Ga2O4-δ:Cr3+ phosphor for plant cultivation and optical thermometer based on defect engineering30Synthesis and luminescence characteristics of an efficient broadband NIR phosphor: Cr3+ activated GaTa0.5Nb0.5O420Enhancement of the self-luminescent intensity of LaSrGaO4 by Cr3+ doping for the absorption of far infrared plant PFR phytochrome7Spectroscopic Characterization and Luminescence Study of Zinc Aluminate Nanocrystals Prepared by Microwave Combustion Method using Natural Black Pepper as Combustion Agent9Design of a narrow-band blue-emitting Rb2Ba3(P2O7)2:Eu2+ phosphor with low thermal quenching for plant growth LEDs22Developing Broadband Cr3+-Substituted Phosphor-Converted Near-Infrared Light Sources38Experimental determination and modeling of structural, vibrational and optical properties of the ZnAl2−Cr O4 (x = 0 and 0.05) spinels15Structure, luminescence investigation in Dy3+, Eu3+ and Ce3+, Dy3+ co-activated Sr9MgK(PO4)7 phosphors by energy transfer mechanism19Tunable Spinel Structure Phosphors: Dynamic Change in Near‐Infrared Windows and Their Applications84Breaking the balance of chemical ratio in ZnAl2O4 to regulate activators and traps for multimode luminescence – A new strategy13Efficient trivalent chromium ions doped ZnLu2Al4SiO12 garnet phosphor: Crystal structure, optical properties and application15First principles study of the electronic, optical and photocatalytic properties of Zn(Co1-xAlx)2O43How to Achieve Excellent Luminescence Properties of Cr Ion‐Doped Near‐Infrared Phosphors103UV and blue excited tunable emission of thermally stable Bi3+ sensitized Eu3+ doped calcium aluminozincate phosphor for photonic applications6A novel co-substitution strategy to enhance the luminescence performance of Zn2TiO4:Cr3+ phosphor5Structural, optical and thermoluminescence study of annealed zinc aluminate spinel nanophosphor15High Output Power and High Quantum Efficiency in Novel NIR Phosphor MgAlGa0.7B0.3O4:Cr3+ with Profound FWHM Variation143Engineering deep-red Al20B4O36:Cr3+ phosphors for photomorphogenesis9Comprehensive characterization and optoelectronic significance of Ho 3+ and Cr 3+ Co-doped ZnAl 2 O 4 spinels8Synthesis of organic and inorganic mechanoluminescent compounds0Thermal stability enhancement of an Mn 4+ -activated germanate phosphor by a cationic non-equivalent substitution strategy13Thermally stable Cr 3+ -activated silicate phosphors for plant-growth LEDs and three-mode optical thermometry8Deep Red Photoluminescence from Cr3+ in Fluorine-Doped Lithium Aluminate Host Material8Structural and optical properties of Cd2MgTeO6:Dy3+, Na+ phosphors for potential application in w-LEDs and personal identification22Solid solution structural engineering enhances the luminescence of SrMgAl10O17:Cr3+ for agricultural lighting12Dual substitution of host lattice ions to enhance the luminescence properties of Zn2TiO4:Cr3+ phosphor3Optical characterization and defect-induced behavior in ZnAl1.999Ho0.001O4 spinel: Unraveling novel insights into structure, morphology, and spectroscopic features10Spinel-Based ZnAl2O4: 0.5%Cr3+ Red Phosphor Ceramics for WLED6Broadband emitting Mg3Lu2Ge3O12:Cr3+ phosphors with garnet structure for high-performance NIR LEDs applications25Effect of annealing temperature on the properties and the chromium oxidation state of ZnAl1.94Cr0.06O4 nanoparticles prepared by coprecipitation method3Harnessing the brilliance of Cr3+ doped LaAlO3–Al2O3 phosphors with exceptional responsiveness to far-red phytochrome for plant growth LEDs31Far-red emitting Li2TiO3: Cr3+ phosphor: Synthesis, luminescence properties and potential applications0Study of the efficiency of ZnAl2O4 as green nanocatalyst2Red-emitting Mn4+-doped Li2MgSn2O6 phosphors for plant growth LED lighting34A novel fluorapatite-type deep-red CsSr3La(PO4)3F:Eu3+ phosphor with intense 5D0-7F4 transition for temperature sensors, plant growth lighting, and w-LEDs11A novel far-red and near-infrared adjustable phosphor Sr9Al(PO4)7:Cr3+: structure and luminescence properties4Synthesis and thermoluminescence study of Dy3+ doped ZnAl2O4 phosphor for high-dose dosimetry application11A novel orange-red emitting K5Y(MoO4)4:Sm3+ phosphor with excellent color purity for temperature sensing and high CRI WLEDs19Promising deep‐red emitting Cr3+‐doped SrAl12O19 phosphors for plant growth LEDs9Simultaneously Possessing High Quantum Efficiency and Thermal Robustness in a Near‐Infrared Emitting ZnAlB(1‐x)GaxO4:Cr3+ Phosphor33Influence of carbon dots integrated in Pr3+ doped gahnite nanophosphor for thermal sensing, data fortification and fingerprint visualization analysis through YOLOv8x deep learning embedded model29Development of Mg2TiO4:Mn4+ phosphors for enhanced red LED emission and forensic fingerprint analysis21Highly efficient Y 3-x Ba x Al 5-x Si x O 12 :Cr 3+ near-infrared phosphor for plant growth3Cr3+-doped garnet-type Ca3Al2Ge3O12 phosphors with high color purity and high quantum yield for plant growth lighting19Unveiling the mechanism for excellent thermal stability in Bi3+-doped Y2O3 phosphors for NUV-pumped WLED applications8A three-mode optical thermometer based on Cr3+ doped CaAl12O19 phosphors17Near-infrared emitting Ca2AlNbO6:Cr3+ double-perovskite phosphors for plant growth LEDs13Site occupancy of Sm3+, Pr3+, Tb3+ in Na5Y(WO4)4 and their photoluminescence spectra for application in plant growth LED and fingerprint detection7Achieving tunable ultra-broadband NIR emission originating from the two-site occupation of Cr 3+ ions in Mg 3 Ga 2 SnO 8 :Cr 3+17Broadband and high internal quantum efficiency near-infrared phosphors obtained utilizing a chemical unit co-substitution strategy for plant lighting8Highly efficient red/orange-red emitting Eu 3+ and Sm 3+ /Eu 3+ co-doped phosphors with their versatile applications13Photoluminescent materials for solar spectral conversion greenhouse films13Unlocking dual Mn 3+ /Mn 4+ emissions in garnet phosphors for WLED and plant growth lighting applications15Phonon sideband induced broadband far-red emission Li2GeTeO6:Mn4+ phosphors under blue-excitation for plant-cultivation LEDs, w-LEDs, and security ink13Recent progress in Cr3+ doped phosphors for indoor plant cultivation LEDs: A review17Synthesis and luminescence characteristics of a new Mn4+-Activated Ba6Y2Ti4O17 fluorescent material for plant growth LED9Bio fueled synthesis of Cr3+ doped V2O5 nanoparticles: Multifunctional applications in Photonics, Fingerprint visualization and Oxidative damage mitigation4Highly efficient and stable Cr3+ activated SrO-TeO2- TiO2- B2O3 glasses for LED applications6Dual green and red emitting Mn-doped MgAl2O4 phosphors for WLED and plant growth LED applications31Broadband ZnO:Eu3+ powder with enhanced quantum efficiency and thermal stability for NUV-driven warm-WLEDs7Mesoporous-silica-templated synthesis of high-performance Cr3+ ions activated gahnite nanophosphors for near-infrared mini-light-emitting diodes2Efficient and broadband near-infrared emitting Ca2YHf2Ga3O12: Cr3+ phosphor for anti-counterfeiting applications8Cr3 + -activated SrAl2B2O7 phosphors for near-infrared light-emitting diodes5Wideband near-infrared luminescence in Al5BO9: Cr3+, Ga3+ phosphor for near-infrared spectroscopy application4The great potential of inorganic phosphors in the growing field of plant cultivation: A review9High efficiency Ba2MgGe2O7:Mn4+ red phosphors for phytochrome responsive LED applications and advanced latent fingerprint visualization with quantitative contrast analysis17Enhanced Luminescence in Mn4+, Bi3+ Co‐Doped Deep‐Red SrMgGaAl9O17 Phosphors for Plant‐Cultivation Light‐Emitting Diodes0A Combined Experimental and Density Functional Theory Study of Calcination Temperature Effects on the Properties and Photocatalytic Activity of Starch-Mediated Spinel ZnAl2O46Facile green synthesis of Pr3+ doped ZnAl2O4 phosphor: Insights at low and room temperatures photoluminescence and energy storage applications2Far-red emitting NaAl5O8: Cr3+ phosphors with high thermal stability for plant cultivation applications3Effects of Al/Ga ratio and Ce3+/Cr3+ Co-doping on the structural and luminescent properties of Z(A,G)GO:Ce3+,Cr3+ phosphors1Synthesis and luminescence properties of deep-red-emitting Sc1.6Al0.4W3O12: Cr3+ phosphor for plant growth lighting1Thermally stable Ca2YAl3Ge2O12: Eu3+ deep-red emitting phosphors with anomalous intense 5D0→7F4 transition for plant growth LEDs2Sustainable Sr2MgGe2O7: Bi3+, Mn4+ phosphors as a multifunctional platform for LEDs, optical thermometers, and forensic applications1Luminescence and energy transfer behavior in Gd0.985Er0.01Sm0.005Al0.995Cr0.005O3 for plant growth LED lighting0Enhanced deep-red luminescence in Ba2-Sr GdSbO6: Mn4+ phosphors via cation substitution for plant-growth LEDs2Breaking Spin-Forbidden Transition by an Antisite Defect Strategy for Enhancing Far-Red Emission of Cr 3+ -Activated Phosphors2A-site cation engineering of Mn5+-activated ABaPO4 (A=Li, Na, K) phosphors for high-performance NIR-II luminescence and optical thermometry0High-Output-Power Broadband Near-Infrared Phosphor Suitable for Various LED Applications5Crystallization mechanism and luminescence properties of Cr3+ -doped micron-sized ZnAl2O4 devitrified glasses synthesized by cooling-induced self-crystallization0Temperature-driven structural and optical modulation in spray-deposited ZnAl2O4 thin films for blue light LED and LASER applications0Spectroscopic investigation of near-infrared luminescence and energy band structure in Cr3+-doped BaGa2O40A novel red-emitting phosphor LaTa3O9:Eu3+ for WLEDs, anti-counterfeit inks, and fingerprint analysis0Structural Confinement Engineering of Cr 3+ in Nanocrystalline Spinel Glass‐Ceramics for Efficient and Thermally Robust Deep‐Red Plant‐Growth LEDs0The Anti‐Thermal Quenching Phosphor Landscape: Mechanisms, Materials, and Applications0Realization of blue-red dual-emission via energy transfer in Ca9ZnK(PO4)7: Eu2 +, Mn2+ phosphors for plant cultivation and warm white illumination0

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  39. Experimental determination and modeling of structural, vibrational and optical properties of the ZnAl2−Cr O4 (x = 0 and 0.05) spinels

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