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RESEARCH PAPER · Inorganic Chemistry · 2020

Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material

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Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical MaterialOriginalA highly distorted HgS 4 tetrahedron-induced moderate second-harmonic generation response of EuHgGeS 462Quaternary rare-earth sulfide LaSnGa3S7: Synthesis, structure, thermal and optical properties5A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster33(Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template38Hexagonal In2Se3: A Defect Wurtzite-Type Infrared Nonlinear Optical Material with Moderate Birefringence Contributed by Unique InSe5 Unit75Volume Modulation of Nonlinear Optical Properties by Cation Substitution8Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se2014Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt39Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Nonlinear-Optical Crystal Rb3YB6O12 with Condensed B5O10 Blocks That Exhibits an Intriguing Structural Arrangement and a Short Ultraviolet Absorption Edge26Borates as promising electrode materials for rechargeable batteries92Two Mixed-Anion Units of [GeOSe3] and [GeO3S] Originating from Partial Isovalent Anion Substitution and Inducing Moderate Second Harmonic Generation Response and Large Birefringence55Investigation of the second-order nonlinear optical property of Sr6Sb6S173Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Ba 2 BS 3 Cl and Ba 5 B 2 S 8 Cl 2 : first alkaline-earth metal thioborate halides with [BS 3 ] units21Two bismuth iodate sulfates with enhanced optical anisotropy17Second-order nonlinear optical and photoelectric properties of Zn4B6O12S20Ternary rare-earth sulfides RE3GaS6 (RE = Ho, Er): Crystal chemistry, second-order nonlinear optical properties and theoretical investigation18Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence31A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance35Three-in-One Strategy Constructing a Series of Hybrid Tetrahedral Motif-Based Selenides with Balanced Second-Order Nonlinear Optical Performance12“Size or mass” which plays a role? An investigation on the optical and ultrasonic properties of chitosan-lanthanide composites10Nd2CaB10O19: A potential self-activated and self-frequency-doubling multifunctional crystal8CsCdGa3O6: A I-II-III-O (I = alkali metal, II = divalent metal, III = Al, Ga, In) type oxide featuring [Ga4O14]16− helical belts linked [Ga6O6]6+ and [Ga8O8]8+ cages11Tourmaline with ultraviolet optical nonlinearity: Emergent material discovery from mineral5Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain15Réponses optiques linéaires et non linéaires de semi-métaux chiraux multifolds0BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect32KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring10KNa 0.78 Eu 0.27 In 3.80 B 12 S 12 : a novel hexanary thioborate featuring a B 12 S 12 cluster and diverse InS x ( x = 4, 5, 6) units9Ti0.85Eu3SiS7: The rare-earth/Ti based quaternary sulfide containing two variable valence elements4Second-harmonic generation in the topological multifold semimetal RhSi24Cation Regulation to Investigate the Chalcogenide Borate RE6Nb2MgSB8O26 (RE = La–Nd) Family12Eu 2 P 2 S 6 : The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold143Eu2P2S6: The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold7Electronic Structure, Optical, and Elastic Properties of AgGaS2 Crystal: Theoretical Study5From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**22First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †28Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid2Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra17Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material27Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials28A review of structures and physical properties of rare earth chalcophosphates77Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS626KREP2Se6 (RE = Sm, Gd, Tb): The First Rare‐Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE‐ and P‐Based Motifs39Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction25Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behavior26Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance64Two Mixed-Alkali-Metal Selenates as Short-Wave Ultraviolet Nonlinear-Optical Materials10Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters7Fluorosulfide La 2+ x Sr 1– x F 4+ x S 2 with a Triple-Fluorite Layer Enabling Interstitial Fluoride-Ion Conduction20Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge17Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials20A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties1Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Chromium iodate: the structure and origin of optical second harmonic generation1Fluorosulfide La 2.7 Ba 6.3 F 8.7 S 6 with a double-layer honeycomb structure enabling fluoride-ion conduction3Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances156Anhydrous Aluminum Iodate: Strong Second Harmonic Generation Effect Contributed by Unbonded and Antibonding Orbitals3Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties4Modulating Electron Density of Boron–Oxygen Groups in Borate via Metal Electronegativity for Propane Oxidative Dehydrogenation5Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy26Structure and optical properties of alkali rare-earth double phosphates of M3RE(PO4)2 (M = K, Rb; RE = Y, La, and Lu)4Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal10Construction of a new ionic Co(II) coordination polymer and its composite with CNTs showing dual electrochemical sensing to AA and Fe3+23Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials10[C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence13Synthesis, structural analysis and investigation of photoluminescence properties of mixed metal cation borates12A potential UV nonlinear-optical crystal with a strong second-harmonic response: RbNa 2 Eu 2 (BO 3 ) 35Synthesis, structural characterization and comparative optoelectronic performance analysis of Al/KSrSm(BO 3)2 /Si and Al/KCaSm(BO 3)2 /Si photodiodes2Cation Equivalent Multisubstitution Realizing Structure Transformation and Balanced Nonlinear Optical Performance of Quaternary Eu-Based Chalcogenides8A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps1Fabrication and evaluation of NaSrEr(BO3)2 interlayer in Al/Si photodiode structures for photodetector applications2Synthesis, structural and electrical analysis of La and Nd-doped KCa(BO3)2 interlayers in Al/n-Si photodiode structures2From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity3Theoretical Insights into ESIPT and GSIPT in Schiff Base Cu(II)-BSSMO Complexes: Substituent Effects Explored via DFT, Molecular Docking, and Dynamics Simulations for Optoelectronic and Biomedical Applications3REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups2LiK4B(SO4)4: a potential optical crystal for deep ultraviolet zero-order waveplates1Mg Substitution in BaGa 4 Se 7 : Synthesis, Structure, and Property Modulation2Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure1New system mixed metal borates NaBaR(BO3)2 (R = La3+, Ce3+, Nd3+, Sm3+, Er3+). Synthesis, structural characterization and photoluminescence properties0From KBa 4 Ge 3 S 10 Cl to ABa 3 EuGe 3 S 11 (A = Na, K) Synthesized by Reactive Flux Assisted Metal Oxide-Boron-Chalcogen (MOBQ) Method: Effect of Cation/Anion Cosubstitution on Crystal Structure and Nonlinear Optical Properties0A newly NaCaSm(BO3)2 interfacial material doped with rare-earth ions for sensitive photo-detection in Schottky structures2K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals1Novel mixed metal borate (NaCaR(BO3)2) compounds: Synthesis, structure, and light-emitting properties0EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide0d-f synergistic effect contributing record-high second-harmonic generation response in phase-matchable Mn-based chalcogenides0A novel NaCaLa(BO3)2 interface material doped with rare-earth elements for Schottky devices in order to sensitive light detection0

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  1. A highly distorted HgS 4 tetrahedron-induced moderate second-harmonic generation response of EuHgGeS 4

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  2. Quaternary rare-earth sulfide LaSnGa3S7: Synthesis, structure, thermal and optical properties

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  3. A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster

    Inorganic Chemistry · 2020-02-24

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  4. (Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template

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  5. Hexagonal In2Se3: A Defect Wurtzite-Type Infrared Nonlinear Optical Material with Moderate Birefringence Contributed by Unique InSe5 Unit

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  6. Volume Modulation of Nonlinear Optical Properties by Cation Substitution

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  7. Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se20

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  8. Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt

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  9. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

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  10. Nonlinear-Optical Crystal Rb3YB6O12 with Condensed B5O10 Blocks That Exhibits an Intriguing Structural Arrangement and a Short Ultraviolet Absorption Edge

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  11. Borates as promising electrode materials for rechargeable batteries

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  12. Two Mixed-Anion Units of [GeOSe3] and [GeO3S] Originating from Partial Isovalent Anion Substitution and Inducing Moderate Second Harmonic Generation Response and Large Birefringence

    Inorganic Chemistry · 2020-10-26

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  13. Investigation of the second-order nonlinear optical property of Sr6Sb6S17

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  14. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

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  15. Ba 2 BS 3 Cl and Ba 5 B 2 S 8 Cl 2 : first alkaline-earth metal thioborate halides with [BS 3 ] units

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  16. Two bismuth iodate sulfates with enhanced optical anisotropy

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  17. Second-order nonlinear optical and photoelectric properties of Zn4B6O12S

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  18. Ternary rare-earth sulfides RE3GaS6 (RE = Ho, Er): Crystal chemistry, second-order nonlinear optical properties and theoretical investigation

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  19. Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence

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  20. A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance

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  21. Three-in-One Strategy Constructing a Series of Hybrid Tetrahedral Motif-Based Selenides with Balanced Second-Order Nonlinear Optical Performance

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  22. “Size or mass” which plays a role? An investigation on the optical and ultrasonic properties of chitosan-lanthanide composites

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  23. Nd2CaB10O19: A potential self-activated and self-frequency-doubling multifunctional crystal

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  24. CsCdGa3O6: A I-II-III-O (I = alkali metal, II = divalent metal, III = Al, Ga, In) type oxide featuring [Ga4O14]16− helical belts linked [Ga6O6]6+ and [Ga8O8]8+ cages

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  25. Tourmaline with ultraviolet optical nonlinearity: Emergent material discovery from mineral

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  26. Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain

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  27. Réponses optiques linéaires et non linéaires de semi-métaux chiraux multifolds

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  28. BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect

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  29. KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring

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  30. KNa 0.78 Eu 0.27 In 3.80 B 12 S 12 : a novel hexanary thioborate featuring a B 12 S 12 cluster and diverse InS x ( x = 4, 5, 6) units

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  31. Ti0.85Eu3SiS7: The rare-earth/Ti based quaternary sulfide containing two variable valence elements

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  32. Second-harmonic generation in the topological multifold semimetal RhSi

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  33. Cation Regulation to Investigate the Chalcogenide Borate RE6Nb2MgSB8O26 (RE = La–Nd) Family

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  34. Eu 2 P 2 S 6 : The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold

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  35. Eu2P2S6: The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold

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  36. Electronic Structure, Optical, and Elastic Properties of AgGaS2 Crystal: Theoretical Study

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  37. From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**

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  38. First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †

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  39. Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid

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  40. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra

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  41. Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material

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  42. Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

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  43. A review of structures and physical properties of rare earth chalcophosphates

    Coordination Chemistry Reviews · 2022-10-11

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  44. Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS6

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  45. KREP2Se6 (RE = Sm, Gd, Tb): The First Rare‐Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE‐ and P‐Based Motifs

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  46. Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction

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  47. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

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  48. The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behavior

    Chemical Communications · 2023-01-01

    Mei Yang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  49. Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance

    Small · 2023-02-12

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  50. Two Mixed-Alkali-Metal Selenates as Short-Wave Ultraviolet Nonlinear-Optical Materials

    Inorganic Chemistry · 2023-03-13

    Qian Yan, Xuehua Dong, Ling Huang, Yuqiao Zhou, Zhien Lin, Guohong Zou

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