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RESEARCH PAPER · Chemistry of Materials · 2004

Syntheses, Structures, Second-Harmonic Generating, and Ferroelectric Properties of Tungsten Bronzes: A6M2M‘8O30 (A = Sr2+, Ba2+, or Pb2+; M = Ti4+, Zr4+, or Hf4+; M‘ = Nb5+ or Ta5+)

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Syntheses, Structures, Second-Harmonic Generating, and Ferroelectric Properties of Tungsten Bronzes: A6M2M‘8O30 (A = Sr2+, Ba2+, or Pb2+; M = Ti4+, Zr4+, or Hf4+; M‘ = Nb5+ or Ta5+)OriginalSyntheses, Structures, Second‐Harmonic Generating, and Ferroelectric Properties of Tungsten Bronzes: A6M2M′8O30 (A: Sr2+, Ba2+, or Pb2+; M: Ti4+, Zr4+, or Hf4+; M′: Nb5+ or Ta5+).720 New compounds and structures in the solid state5New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O125Distribution, structures and nonlinear properties of noncentrosymmetric niobates and tantalates29Distribution, structures and nonlinear properties of noncentrosymmetric titanates15Phase Transition in Ba 6−3 x (Sm 1− y La y ) 6+2 x Ti 18 O 54 ( x =0.5) Ceramics7Structural and Spectroscopic Properties of Pure and Doped Ba6Ti2Nb8O30 Tungsten Bronze19Tungsten Bronzes Framework as a Glasslike Host for Transition Cations: The Case of Ba6Zr2Ta8O3011Nonlinear Optical Properties of Ln2Ti2O7 (Ln = La, Pr, Nd) Oxides2Nonlinear optical effects in nano-sized ferroelectrics Sr6Ti2Nb(Ta)8O3012Deuteration Effect of Ferroelectricity and Permittivity on Homochiral Zinc Coordination Compound47(NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties88Polar Hexagonal Tungsten Bronze-Type Oxides: KNbW2O9, RbNbW2O9, and KTaW2O973Synthetic Approaches for Noncentrosymmetric Molybdates59Zur Kristallchemie der Oxometallate des Hafniums4B-cation effects in relaxor and ferroelectric tetragonal tungsten bronzes62Structural and electrical properties of Na2Pb2Eu2W2Ti4X4O30 (X=Nb, Ta) ferroelectric ceramics70Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)306Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6112A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Noncentrosymmetry in New Templated Gallium Fluorophosphates34Structural and optical properties of (100−x)Li2B4O7·x(Ba5Li2Ti2Nb8O30) glasses and glass nanocrystal composites17Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8Interrelationship of Micro- and Macrostructure with Nonlinear Optical Properties of Simple and Binary Acentric Niobate Crystals7Anisotropic Polarization Switching in Tungsten Bronze Ferroelectrics in Binary (Bi1/2Na1/2)Nb2O6–BaNb2O6 System2Dielectric and magnetic properties of Ba5BiNiNb9O30 ceramics3Origin and stability of the dipolar response in a family of tetragonal tungsten bronze relaxors52Phase Separation and Phase Transitions in Multiferroic K0.58FeF3 with the Tetragonal Tungsten Bronze Structure15New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Picosecond nonlinear optical features of ferroelectric large sized nanocrystallites26Effect of structural packing on the luminescence properties in tungsten bronze compounds M2KNb5O15 (M=Ca, Sr, Ba)32Deriving the magnitude of niobium off-center displacement in ferroelectric niobates from infrared spectroscopy18Phase Relationships in the BaO–Ga2O3–Ta2O5System and the Structure of Ba6Ga21TaO4011Complex impedance properties of LiSr2Nb5O15 ceramic43Structural Evolving Sequence and Porous Ba 6 Zr 2 Nb 8 O 30 Ferroelectric Ceramics with Ultrahigh Breakdown Field and Zero Strain18Chemistry of Polar Transition-Metal Oxides1Pseudo-Symmetry in Tungsten Bronze Type Sr3TiNb4O151Nanorods of Potassium Tantalum Niobate Tetragonal Tungsten Bronze Phase Grown by Pulsed Laser Deposition15Relaxor nature in lead-free Sr5LaTi3Nb7O30 tetragonal tungsten bronze ceramics29Defect Structure, Phase Separation, and Electrical Properties of Nonstoichiometric Tetragonal Tungsten Bronze Ba0.5–xTaO3–x17Optical properties of epitaxial (Ba0.39Sr0.61)6Ti2Nb8O30 thin films grown by pulsed laser deposition1A-site size effect in a family of unfilled ferroelectric tetragonal tungsten bronzes: Ba 4 R 0.67 Nb 10 O 30 (R = La, Nd, Sm, Gd, Dy and Y)77Ferroelectric Transition and Low‐Temperature Dielectric Relaxations in Filled Tungsten Bronzes98Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Ferroelectric and optical properties of Ba5Li2Ti2Nb8O30 ceramics potential for memory applications10(MMgBO3)n (n = 1, M = Li, Na, K, Rb and n = 4, M = Cs): An investigation on the structure transition and optical properties8Synthesis and X-ray powder diffraction data of Ba 2.64 Ta 11.25 O 30.811Structural investigation of tungsten bronze-type relaxor ferroelectrics in the Ba x Sr 3− x TiNb 4 O 15 system3Engineering the A- and B-sites for upconversion luminescence in Ho- and Yb-codoped filled tetragonal tungsten bronze oxides23Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Vogel–Fulcher analysis of relaxor dielectrics with the tetragonal tungsten bronze structure: Ba6MNb9O30 (M = Ga, Sc, In)29Modifying optical, electric and magnetic properties of multifunctional Gd3+-doped Ba4La0.95Er0.05TiNb9O30 ceramics4Structure and upconversion analyses of Er3+-doped Ba6Ti2Nb8O30–Sr6Ti2Nb8O30 solid solutions4Nonstoichiometric Control of Tunnel-Filling Order, Thermal Expansion, and Dielectric Relaxation in Tetragonal Tungsten Bronzes Ba0.5–xTaO3–x7Superconductivity and crystal structural origins of the metal-insulator transition in Ba6−xSrxNb10O30 tetragonal tungsten bronzes22New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7Thermal Expansion Anomaly in TTB Ferroelectrics: The Interplay between Framework Structure and Electric Polarization13Crystal structure, ferroelectricity and polar order in a Ba 4 R 2 Zr 4 Nb 6 O 30 (R = La, Nd, Sm) tetragonal tungsten bronze new system55Layered Perovskite Pb2Bi4Ti5O18 for Excellent Visible Light-Driven Photocatalytic NO Removal33Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals16Electric field and aging effects of uniaxial ferroelectrics Sr x Ba1−x Nb2O6 probed by Brillouin scattering19Novel insight into the structure and properties of lead-free dielectric Sr 3 TiNb 4 O 156Synthesis, Luminescence Property and Thermal Quenching Investigation of Niobate Phosphors Ba3ZrNb4O15:Eu3+under Multiple Excitations4Novel red-emitting phosphor Ba3ZrNb4O15:Pr3+: The structure, characteristic photoluminescence property and thermal quenching behaviour investigation23Effects of B site ions on the relaxor to normal ferroelectric transition crossover in Ba4Sm2Zr4(NbxTa1-x)6O30 tungsten bronze ceramics34An algebraic approach to cooperative rotations in networks of interconnected rigid units34Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure245Simultaneously enhanced ferroelectric and magnetic properties in Fe-substituted Ba4Sm2Fe Ti4-2Nb6+O30 ceramics6Sodium titanium oxide bronze nanoparticles synthesized via concurrent reduction and Na + -doping into TiO 2 (B)10Aging effect and metastable ferroelectric state in Ba4Eu2(Ti0.9Zr0.1)4Ta6O30 tetragonal tungsten bronze ceramic5The structure and thermoelectric properties of tungsten bronze Ba6Ti2Nb8O3016Synthesis, structure and dielectric properties of the Sr 3 Ti 1−x Zr x Nb 4 O 15 , (0 ≤ x ≤ 1), series of tungsten bronze type compounds3The structure of the metastable K 18 Ta 5 Zr 5 F 63 phase4Second harmonic generation in ferroelectric Ba2EuFeNb4O15-based epitaxial thin films2Strong Second Harmonic Generation in a Tungsten Bronze Oxide by Enhancing Local Structural Distortion48Structure and Conductivity of Li3/8Sr7/16−xAxZr1/4Nb3/4O3 (A = Ca, Ba) Li-ion Solid Electrolytes16Sr2Nb6O13F8·4H2O and Sr3Nb2O2F12·2H2O: A Variant of Three-Dimensional Tungsten Bronze and a Polar Molecular Oxide Fluoride17Structure and relaxor ferroelectric behavior of the novel tungsten bronze type ceramic Sr5BiTi3Nb7O308Lead-Free Piezoelectric Ceramics6Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates112Small Changes, Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B‐Site26Band shifting triggered ·OH evolution and charge separation enhanced H2O2 generation in piezo-photocatalysis of Silleń-Aurivillius-structured Bi4W0.5Ti0.5O8Cl81Tungsten Bronze-Type Ceramics for Temperature-Stable Energy Storage Properties: A Feasibility Study9Structure, Lithium-Ion Conductivity Coupled with Second-Order Jahn–Teller Effect, and Electrochemical Stability of Sr-Based Perovskite-Type Solid Electrolytes6Enhancing structural, optical, magnetic, dielectric and impedance properties of Ba0.95Sr0.05Ca5Ti2-xFexNb8O30 tungsten bronze ferroelectric ceramic through Fe/Ti ratio on optimization for the advanced device applications13The effect of cation size on structure and properties of Ba-based tetragonal tungsten bronzes Ba 4 M 2 Nb 10 O 30 (M = Na, K or Rb) and Ba 4 M 2 Nb 8 Ti 2 O 30 (M = Ca or Sr)8Influence of Boron Doping on the Dielectric Characteristics of Eu3+-Doped β-SrTa2O6 and Eu3+-Doped BaTa2O6 Tungsten Bronze-Type Ceramics10An investigation of structural, magnetic and electrical properties of Ca dominant A-site tungsten bronze ferroelectric ceramic2Simultaneous broadening and enhancement of Cr 3+ photoluminescence in Ba 3 ZrTa 4 O 15 by chemical unit co-substitution1

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  1. Syntheses, Structures, Second‐Harmonic Generating, and Ferroelectric Properties of Tungsten Bronzes: A6M2M′8O30 (A: Sr2+, Ba2+, or Pb2+; M: Ti4+, Zr4+, or Hf4+; M′: Nb5+ or Ta5+).

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  2. 20 New compounds and structures in the solid state

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  3. New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O

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  4. Distribution, structures and nonlinear properties of noncentrosymmetric niobates and tantalates

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  5. Distribution, structures and nonlinear properties of noncentrosymmetric titanates

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  6. Phase Transition in Ba 6−3 x (Sm 1− y La y ) 6+2 x Ti 18 O 54 ( x =0.5) Ceramics

    Journal of the American Ceramic Society · 2006-06-13

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  7. Structural and Spectroscopic Properties of Pure and Doped Ba6Ti2Nb8O30 Tungsten Bronze

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  8. Tungsten Bronzes Framework as a Glasslike Host for Transition Cations: The Case of Ba6Zr2Ta8O30

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  9. Nonlinear Optical Properties of Ln2Ti2O7 (Ln = La, Pr, Nd) Oxides

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  10. Nonlinear optical effects in nano-sized ferroelectrics Sr6Ti2Nb(Ta)8O30

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  11. Deuteration Effect of Ferroelectricity and Permittivity on Homochiral Zinc Coordination Compound

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  12. (NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties

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  13. Polar Hexagonal Tungsten Bronze-Type Oxides: KNbW2O9, RbNbW2O9, and KTaW2O9

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  14. Synthetic Approaches for Noncentrosymmetric Molybdates

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  15. Zur Kristallchemie der Oxometallate des Hafniums

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  16. B-cation effects in relaxor and ferroelectric tetragonal tungsten bronzes

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  17. Structural and electrical properties of Na2Pb2Eu2W2Ti4X4O30 (X=Nb, Ta) ferroelectric ceramics

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  18. Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)

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  19. Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6

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  20. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

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  22. Structural and optical properties of (100−x)Li2B4O7·x(Ba5Li2Ti2Nb8O30) glasses and glass nanocrystal composites

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  23. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

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  24. Interrelationship of Micro- and Macrostructure with Nonlinear Optical Properties of Simple and Binary Acentric Niobate Crystals

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  25. Anisotropic Polarization Switching in Tungsten Bronze Ferroelectrics in Binary (Bi1/2Na1/2)Nb2O6–BaNb2O6 System

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  27. Origin and stability of the dipolar response in a family of tetragonal tungsten bronze relaxors

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  29. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

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  30. Picosecond nonlinear optical features of ferroelectric large sized nanocrystallites

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  31. Effect of structural packing on the luminescence properties in tungsten bronze compounds M2KNb5O15 (M=Ca, Sr, Ba)

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  32. Deriving the magnitude of niobium off-center displacement in ferroelectric niobates from infrared spectroscopy

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  33. Phase Relationships in the BaO–Ga2O3–Ta2O5System and the Structure of Ba6Ga21TaO40

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  34. Complex impedance properties of LiSr2Nb5O15 ceramic

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  35. Structural Evolving Sequence and Porous Ba 6 Zr 2 Nb 8 O 30 Ferroelectric Ceramics with Ultrahigh Breakdown Field and Zero Strain

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  36. Chemistry of Polar Transition-Metal Oxides

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  37. Pseudo-Symmetry in Tungsten Bronze Type Sr3TiNb4O15

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  38. Nanorods of Potassium Tantalum Niobate Tetragonal Tungsten Bronze Phase Grown by Pulsed Laser Deposition

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  39. Relaxor nature in lead-free Sr5LaTi3Nb7O30 tetragonal tungsten bronze ceramics

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  40. Defect Structure, Phase Separation, and Electrical Properties of Nonstoichiometric Tetragonal Tungsten Bronze Ba0.5–xTaO3–x

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  41. Optical properties of epitaxial (Ba0.39Sr0.61)6Ti2Nb8O30 thin films grown by pulsed laser deposition

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  42. A-site size effect in a family of unfilled ferroelectric tetragonal tungsten bronzes: Ba 4 R 0.67 Nb 10 O 30 (R = La, Nd, Sm, Gd, Dy and Y)

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  43. Ferroelectric Transition and Low‐Temperature Dielectric Relaxations in Filled Tungsten Bronzes

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  44. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

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  45. Ferroelectric and optical properties of Ba5Li2Ti2Nb8O30 ceramics potential for memory applications

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  47. Synthesis and X-ray powder diffraction data of Ba 2.64 Ta 11.25 O 30.81

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  48. Structural investigation of tungsten bronze-type relaxor ferroelectrics in the Ba x Sr 3− x TiNb 4 O 15 system

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  49. Engineering the A- and B-sites for upconversion luminescence in Ho- and Yb-codoped filled tetragonal tungsten bronze oxides

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  50. Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 6

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