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RESEARCH PAPER · Journal of the American Ceramic Society · 2014

Ferroelectric Transition and Low‐Temperature Dielectric Relaxations in Filled Tungsten Bronzes

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Ferroelectric Transition and Low‐Temperature Dielectric Relaxations in Filled Tungsten BronzesOriginalOriginal Crystal-Chemical Behaviors in (Ba,Sr)2Ln(Fe,Nb,Ta)5O15 Tetragonal Tungsten Bronze: Anion-Driven Properties Evidenced by Cationic Substitutions17Relaxor Behavior and Large Room‐Temperature Polarization of Ferroelectric Sr 4 CaBiTi 3 Nb 7 O 30 Ceramics50Local structure and dielectric behavior of tetragonal tungsten bronzes β-SrTa2O6 and β′-SrTa2O614Incommensurate and commensurate modulations of Ba5RTi3Nb7O30 (R = La, Nd) tungsten bronzes and the ferroelectric domain structures19A Crystal-Chemical Framework for Relaxor versus Normal Ferroelectric Behavior in Tetragonal Tungsten Bronzes195Dielectric and relaxor ferroelectric properties of Sr4CaLaTi3Nb7O30 tetragonal tungsten bronze ceramics21Sr4Nd2Ti4Nb6O30 tungsten bronze thick films prepared by electrophoretic deposition as a temperature-stable dielectric6Unusual Strong Incommensurate Modulation in a Tungsten-Bronze-Type Relaxor PbBiNb5O1543Structural, dielectric and magnetic properties of Ba3SrLn2Fe2Nb8O30 (Ln = La, Nd, Sm) filled tungsten bronze ceramics27Structural and relaxor-like dielectric properties of unfilled tungsten bronzes Ba5−5xSm5xTi5xNb10−5xO308Ferroelectric properties and polarization dynamics in Ba4Sm2Ti4Ta6O30 tungsten bronze ceramics16Dielectric relaxation and ferroelectric phase transition in Sr4BiRTi4Nb6O30 (R = Sm, Eu) ceramics9Lead-free relaxor ferroelectric ceramics Sr4+x Ca1−x BiTi3Nb7O30 with tunable transition temperature5Effect of Li + ion occupancy on microstructure and dielectric characteristics in KSr 2 Nb 5 O 15 tungsten bronze ceramics9Variation of electrical properties with structural vacancies in ferroelectric niobates (Sr0.53Ba0.47)2.5−0.5Na Nb5O15 ceramics33Relaxor-to-Ferroelectric Crossover and Disruption of Polar Order in “Empty” Tetragonal Tungsten Bronzes57Dielectric and ferroelectric characteristics of Ba 4 Pr 2 Fe 2 Nb 8 O 30 tungsten bronze ceramics21Relaxor behavior and ferroelectric properties of a new Ba 4 SmFe 0.5 Nb 9.5 O 30 tungsten bronze ceramic13Thermal Expansion Anomaly in TTB Ferroelectrics: The Interplay between Framework Structure and Electric Polarization13Manipulation of polar order in the “empty” tetragonal tungsten bronzes: Ba4-xSrxDy0.67□1.33Nb10O30, x = 0, 0.25, 0.5, 1, 2, 328Crystal structure, ferroelectricity and polar order in a Ba 4 R 2 Zr 4 Nb 6 O 30 (R = La, Nd, Sm) tetragonal tungsten bronze new system55Effects of oxygen-deficiency on crystal structure, dielectric and ferroelectric properties in Sr 5 SmTi 3+2x Nb 7−2x O 30−x with tungsten bronze structure26Role of Lone Pair Cations in Ferroelectric Tungsten Bronzes29Relaxor ceramic with a high relative permittivity and low dielectric loss in Cr doped Ca0.67La0.22TiO37Enhanced electrical properties and strong red light‐emitting in Eu 3+ ‐doped Sr 1.90 Ca 0.15 Na 0.9 Nb 5 O 15 ceramics26Tungsten bronze Li+ conductor Li Sr1−0.5Ta2O6 (0 < x ≤ 0.31) prepared by solid state ion exchange2Insight into the dynamics of low temperature dielectric relaxation of ordinary perovskite ferroelectrics10Relaxor nature in Ba 5 RZr 3 Nb 7 O 30 (R = La, Nd, Sm) tetragonal tungsten bronze new system36Core-shell structured CsxWO3@ZnO with excellent stability and high performance on near-infrared shielding66Effect of annealing atmosphere on the structure and dielectric properties of unfilled tungsten bronze ceramics Ba4PrFe0.5Nb9.5O3017Microstructure, dielectric anomaly and pinched hysteresis loops of grain-oriented KSr2Nb5O15 ferroelectric ceramics6Structural and dielectric characteristics of Ba3Ln3Ti5Nb5O30 (Ln = La, Nd, Sm) filled tungsten bronze ceramics4Electric-field-induced phase transition and pinched P–E hysteresis loops in Pb-free ferroelectrics with a tungsten bronze structure59Recent Topics in the Field of Ferroelectric Materials for BME‐MLCCs0Effects of B site ions on the relaxor to normal ferroelectric transition crossover in Ba4Sm2Zr4(NbxTa1-x)6O30 tungsten bronze ceramics34High-temperature dielectric relaxation mechanism in Ba4SmFe0.5Nb9.5O30 tungsten bronze ceramics5Oxygen-deficient tungsten bronze Sr4Sm2Ti4+2Nb6–2O30- as a temperature-stable dielectric2Oxygen-vacancy-induced reversible control of ferroelectric polarization in Ba4Eu2Fe2Nb8O30 ceramics14Eu‐substitution‐induced commensurate phase with enhanced ferroelectric property in Ba 4 (Eu x La 1− x ) 2 Fe 2 Nb 8 O 30 multiferroics10Ferroelectric transitions and relaxor behavior in Ba4Sm2(Ti1-xZrx)4Ta6O30 tungsten bronze ceramics11Property-structure relationship in lead-free relaxors Ba5RSn3Nb7O30 with tungsten bronze structure12Energy storage properties in Ba 5 LaTi 3 Ta 7 O 30 tungsten bronze ceramics22Magnetoelectric effect in Sm-substituted tungsten bronze structure Ba4(Sm La1-)2Fe2Nb8O30 ceramics13Ba 4 R 2 Sn 4 Nb 6 O 30 (R = La, Nd, Sm) lead‐free relaxors with filled tungsten bronze structure16Aging effect and metastable ferroelectric state in Ba4Eu2(Ti0.9Zr0.1)4Ta6O30 tetragonal tungsten bronze ceramic5Improved electrical properties and good thermal luminescent stability of Sm3+-doped Sr1.90Ca0.15Na0.90Nb5O15 multifunctional ceramics8Pinched P-E hysteresis loops in Ba4Sm2Fe0.5Ti3Nb6.5O30 ceramic with tungsten bronze structure8Low-temperature dielectric anomalies in KSr2Nb5O15 ceramics with tetragonal tungsten bronze structure: The effect of microstructure17Tunnel structure of tetragonal tungsten bronzes BaTa2O6, Ba0.8Ta2O5.8, and Ba0.5Ta2O5.5 studied using synchrotron X-ray and neutron diffraction4Développement de couches minces ferroélectriques sans plomb et intégration dans des antennes miniatures reconfigurables0Nuevas aproximaciones al estudio de la dinámica de la relajación dieléctrica en ferroeléctricos ordinarios y relajadores0Structural, dielectric and impedance spectroscopy analysis of Ba 5 CaTi 1.94 Zn 0.06 Nb 8 O 30 ferroelectric ceramic107Effects of Bi substitution on the structures, electrical properties, and transparency of Sr2Na1−3Bi Nb5O15 ceramics13Structural and electrical effects of Ag substitution in tungsten bronze Sr2Ag Na1−Nb5O15 ceramics27Improved ferromagnetism and magnetodielectric properties of relaxor ferroelectric Ba4-Ca Nd2Fe1.5Co0.5Nb8O30 ceramics with tungsten bronze structure6Composition‐dependent microstructure and electrical property of (1− x )SBN‐ x BNBT solid solutions11Local Structure and Order–Disorder Transitions in “Empty” Ferroelectric Tetragonal Tungsten Bronzes13Relaxor Nature and Energy Storage Properties of Sr2– x M x NaNb5– x Ti x O15 (M = La3+ and Ho3+) Tungsten Bronze Ceramics61Na2Nb8O21 microcrystalline and ceramics prepared by molten salt synthesis0Microstructure and bidirectional dielectric tunability behaviour of Nd3+-doped KSr2Nb5O15 lead-free ceramics15Pinched P–E hysteresis loops of KSr2Nb5O15 ferroelectric ceramics8Influence of Sm3+ doping on the relaxation behaviors of KSr2Nb5O15 ferroelectric ceramics and the luminescence modulation effect by polarization engineering9Polarization Mechanism in Filled Tungsten Bronze Ba4Eu2Ti4Nb6O30 with Pinched P – E Hysteresis Loops7Structural, dielectric and energy storage properties of Neodymium niobate with tetragonal tungsten bronze structure24Preparation and dielectric properties of co-contained unfilled tungsten bronze ceramics Ba4RCo0.5Nb9.5O307Spontaneous polarization and DC resistivity investigations in Ba[1.6-(3x/2)]Sr2.4ErxNa1.4Li0.6Nb10O30 tungsten bronze structured nano-phased relaxor ferroelectrics0Relaxor-normal ferroelectric transition in (1−x)Sr0.75Ba0.25Nb2O6–xNaNbO3 ceramics10Enhanced ferroelectric relaxation behaviors of KSr2Nb5O15-based ceramics by A-site entropy-engineering3Microstructural design of textured KSr 2 Nb 5 O 15 ceramics by a phase‐field simulation and lamination technique4Enhancing Energy Storage Performance in Lead-Free Bismuth Sodium Niobate-Based Tungsten Bronze Ceramics through Relaxor Tuning38Phase‐structure evolution and electrocaloric effect in Sr 2 NaNb 4.3 Ta 0.7 O 15 ‐based filled tungsten bronze ceramics9Crystal structure and dielectric properties of Ba6−xCaxTi2Nb8O30 tungsten bronze ceramics1Grain-orientation-engineered multilayer NaSr2Nb5O15 ferroelectric ceramics via templated grain growth4Synthesis and characterization of (Ba (1.6-3/2X) Sr2.4Na2Nb10O30: xHo3+) ferroelectric nanomaterials by solid state reaction routes for device applications2Molten salt synthesis of A-site disordered niobate microcrystals with tetragonal tungsten bronze structure5Simultaneously achieving large energy storage density and high efficiency in the optimized Sr2NaNb5O15 system with excellent temperature stability at a low electric field25Ultrahigh Energy Storage in Tungsten Bronze Dielectric Ceramics Through a Weakly Coupled Relaxor Design97The effect of cation size on structure and properties of Ba-based tetragonal tungsten bronzes Ba 4 M 2 Nb 10 O 30 (M = Na, K or Rb) and Ba 4 M 2 Nb 8 Ti 2 O 30 (M = Ca or Sr)8Excellent Energy Storage Capability in Sr0.6ba0.4nb2o6-Based Ceramics Via Incommensurate Modulation and Grain Boundary Reinforcement0Excellent Energy Storage Capability in Sr0.6ba0.4nb2o6-Based Ceramics Via Incommensurate Modulation and Grain Boundary Reinforcement4Impact of B-site Substitution of Transition Metal (Fe and Mn) on the Structural, Electrical, and Magnetic Properties of Tungsten Bronze Ferroelectric Ceramic2Structural and electrical properties of tetragonal tungsten bronze K4Bi2Nb10O30-Ba4Na2Nb10O30 solid solutions across two proximate phase transitions7Photocatalytic water splitting over K6M10.8O30 (M = Ta, Nb) with a partially filled tetragonal tungsten bronze structure2Role of Incommensurate Modulation in Ba4(Sm1–xLax)2Ti4Nb6O30 Tetragonal Tungsten Bronzes6Outstanding energy density and charge-discharge performances in Sr2KNb5O15-based tungsten bronze ceramics for dielectric capacitor applications18Optimizing high-temperature energy storage in tungsten bronze-structured ceramics via high-entropy strategy and bandgap engineering128Excellent energy storage capability in Sr0.6Ba0.4Nb2O6-based ceramics via incommensurate modulation and grain boundary reinforcement5Photocatalytic water splitting over K3Li2Ta5O15 with a C-site-filled tungsten bronze structure and influence of metal cations at C-site on photocatalytic properties1Effects of A-site configuration entropy on the dielectric properties in tetragonal tungsten bronze ceramics2Enhancing energy storage performance in tungsten bronze ceramics utilizing site engineering17Materials and underlying principles in vat photopolymerization-based additive manufacturing of electronic ceramics16Dielectric anomalies in solid solutions of tetragonal tungsten bronze barium sodium niobate‒potassium bismuth niobate0Evolution of re-entrant relaxor and diffuse phase transition behaviors in Sr4Sm2Ti4(Nb1-xTax)6O30 ceramics0Structural study and evaluation of dielectric, electrical, optical and energy storage properties of Sr5CaTi2-xZnxNb8O30 ceramics5A multiple collaborative optimization strategy for enhanced energy storage and ultrafast discharge performance in tungsten bronze ceramics1Tungsten bronze oxide ceramics for energy storage: Characterization, synthesis, and performance39High-entropy designed filled tungsten bronze structure ferroelectrics with high Curie temperature and enhanced piezoelectricity0Low-melting glass-assisted sintering of PSBNT glass-ceramics: densification, microstructure evolution and dielectric properties0

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  1. Original Crystal-Chemical Behaviors in (Ba,Sr)2Ln(Fe,Nb,Ta)5O15 Tetragonal Tungsten Bronze: Anion-Driven Properties Evidenced by Cationic Substitutions

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  2. Relaxor Behavior and Large Room‐Temperature Polarization of Ferroelectric Sr 4 CaBiTi 3 Nb 7 O 30 Ceramics

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  3. Local structure and dielectric behavior of tetragonal tungsten bronzes β-SrTa2O6 and β′-SrTa2O6

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  4. Incommensurate and commensurate modulations of Ba5RTi3Nb7O30 (R = La, Nd) tungsten bronzes and the ferroelectric domain structures

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  5. A Crystal-Chemical Framework for Relaxor versus Normal Ferroelectric Behavior in Tetragonal Tungsten Bronzes

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  6. Dielectric and relaxor ferroelectric properties of Sr4CaLaTi3Nb7O30 tetragonal tungsten bronze ceramics

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  7. Sr4Nd2Ti4Nb6O30 tungsten bronze thick films prepared by electrophoretic deposition as a temperature-stable dielectric

    Journal of the European Ceramic Society · 2015-07-08

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  8. Unusual Strong Incommensurate Modulation in a Tungsten-Bronze-Type Relaxor PbBiNb5O15

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  9. Structural, dielectric and magnetic properties of Ba3SrLn2Fe2Nb8O30 (Ln = La, Nd, Sm) filled tungsten bronze ceramics

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  10. Structural and relaxor-like dielectric properties of unfilled tungsten bronzes Ba5−5xSm5xTi5xNb10−5xO30

    Journal of Applied Physics · 2016-03-28

    Tong Wei, Z. Dong, Chuan‐Zhen Zhao, Yipeng Guo, Qingjun Zhou, Z.P. Li

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  11. Ferroelectric properties and polarization dynamics in Ba4Sm2Ti4Ta6O30 tungsten bronze ceramics

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  12. Dielectric relaxation and ferroelectric phase transition in Sr4BiRTi4Nb6O30 (R = Sm, Eu) ceramics

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  13. Lead-free relaxor ferroelectric ceramics Sr4+x Ca1−x BiTi3Nb7O30 with tunable transition temperature

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  14. Effect of Li + ion occupancy on microstructure and dielectric characteristics in KSr 2 Nb 5 O 15 tungsten bronze ceramics

    Materials Science and Engineering B · 2016-05-18

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  15. Variation of electrical properties with structural vacancies in ferroelectric niobates (Sr0.53Ba0.47)2.5−0.5Na Nb5O15 ceramics

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  16. Relaxor-to-Ferroelectric Crossover and Disruption of Polar Order in “Empty” Tetragonal Tungsten Bronzes

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  17. Dielectric and ferroelectric characteristics of Ba 4 Pr 2 Fe 2 Nb 8 O 30 tungsten bronze ceramics

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  18. Relaxor behavior and ferroelectric properties of a new Ba 4 SmFe 0.5 Nb 9.5 O 30 tungsten bronze ceramic

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  19. Thermal Expansion Anomaly in TTB Ferroelectrics: The Interplay between Framework Structure and Electric Polarization

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  20. Manipulation of polar order in the “empty” tetragonal tungsten bronzes: Ba4-xSrxDy0.67□1.33Nb10O30, x = 0, 0.25, 0.5, 1, 2, 3

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  21. Crystal structure, ferroelectricity and polar order in a Ba 4 R 2 Zr 4 Nb 6 O 30 (R = La, Nd, Sm) tetragonal tungsten bronze new system

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  22. Effects of oxygen-deficiency on crystal structure, dielectric and ferroelectric properties in Sr 5 SmTi 3+2x Nb 7−2x O 30−x with tungsten bronze structure

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  23. Role of Lone Pair Cations in Ferroelectric Tungsten Bronzes

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  25. Enhanced electrical properties and strong red light‐emitting in Eu 3+ ‐doped Sr 1.90 Ca 0.15 Na 0.9 Nb 5 O 15 ceramics

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  26. Tungsten bronze Li+ conductor Li Sr1−0.5Ta2O6 (0 < x ≤ 0.31) prepared by solid state ion exchange

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  28. Relaxor nature in Ba 5 RZr 3 Nb 7 O 30 (R = La, Nd, Sm) tetragonal tungsten bronze new system

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  29. Core-shell structured CsxWO3@ZnO with excellent stability and high performance on near-infrared shielding

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  30. Effect of annealing atmosphere on the structure and dielectric properties of unfilled tungsten bronze ceramics Ba4PrFe0.5Nb9.5O30

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  31. Microstructure, dielectric anomaly and pinched hysteresis loops of grain-oriented KSr2Nb5O15 ferroelectric ceramics

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  32. Structural and dielectric characteristics of Ba3Ln3Ti5Nb5O30 (Ln = La, Nd, Sm) filled tungsten bronze ceramics

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  33. Electric-field-induced phase transition and pinched P–E hysteresis loops in Pb-free ferroelectrics with a tungsten bronze structure

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  34. Recent Topics in the Field of Ferroelectric Materials for BME‐MLCCs

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  35. Effects of B site ions on the relaxor to normal ferroelectric transition crossover in Ba4Sm2Zr4(NbxTa1-x)6O30 tungsten bronze ceramics

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  36. High-temperature dielectric relaxation mechanism in Ba4SmFe0.5Nb9.5O30 tungsten bronze ceramics

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  37. Oxygen-deficient tungsten bronze Sr4Sm2Ti4+2Nb6–2O30- as a temperature-stable dielectric

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  38. Oxygen-vacancy-induced reversible control of ferroelectric polarization in Ba4Eu2Fe2Nb8O30 ceramics

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  39. Eu‐substitution‐induced commensurate phase with enhanced ferroelectric property in Ba 4 (Eu x La 1− x ) 2 Fe 2 Nb 8 O 30 multiferroics

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  40. Ferroelectric transitions and relaxor behavior in Ba4Sm2(Ti1-xZrx)4Ta6O30 tungsten bronze ceramics

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  41. Property-structure relationship in lead-free relaxors Ba5RSn3Nb7O30 with tungsten bronze structure

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  42. Energy storage properties in Ba 5 LaTi 3 Ta 7 O 30 tungsten bronze ceramics

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  43. Magnetoelectric effect in Sm-substituted tungsten bronze structure Ba4(Sm La1-)2Fe2Nb8O30 ceramics

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  44. Ba 4 R 2 Sn 4 Nb 6 O 30 (R = La, Nd, Sm) lead‐free relaxors with filled tungsten bronze structure

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  45. Aging effect and metastable ferroelectric state in Ba4Eu2(Ti0.9Zr0.1)4Ta6O30 tetragonal tungsten bronze ceramic

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  46. Improved electrical properties and good thermal luminescent stability of Sm3+-doped Sr1.90Ca0.15Na0.90Nb5O15 multifunctional ceramics

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  47. Pinched P-E hysteresis loops in Ba4Sm2Fe0.5Ti3Nb6.5O30 ceramic with tungsten bronze structure

    Applied Physics Letters · 2019-08-19

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  48. Low-temperature dielectric anomalies in KSr2Nb5O15 ceramics with tetragonal tungsten bronze structure: The effect of microstructure

    Journal of Alloys and Compounds · 2019-09-22

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  49. Tunnel structure of tetragonal tungsten bronzes BaTa2O6, Ba0.8Ta2O5.8, and Ba0.5Ta2O5.5 studied using synchrotron X-ray and neutron diffraction

    Journal of Alloys and Compounds · 2019-09-24

    Nam Gil Kim, Maxim Avdeev, Young‐Il Kim

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  50. Développement de couches minces ferroélectriques sans plomb et intégration dans des antennes miniatures reconfigurables

    Unknown journal · 2019-10-08

    Barthélemy Aspe

    Read original paper ↗ ·
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