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RESEARCH PAPER · Inorganic Chemistry · 2018

A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions

Meiying Qie, Jian Hung Lin, Fang Kong, Mark A. Silver, Zenghui Yue, Xiaomei Wang, Linjuan Zhang, Hongliang Bao, Thomas E. Albrecht‐Schmitt, Jian‐Qiang Wang

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A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional ReductionsOriginalIn Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect16Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties19Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation23The structural evolution and tunable photoluminescence of f-element bearing coordination polymers of the 2,4,6-tri-α-pyridyl-1,3,5-triazine ligand22[Ln6O8] Cluster‐Encapsulating Polyplumbites as New Polyoxometalate Members and Record Inorganic Anion‐Exchange Materials for ReO4− Sequestration21REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Structural Complexity and Magnetic Orderings in a Large Family of 3d–4f Heterobimetallic Sulfates10In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Two bismuth iodate sulfates with enhanced optical anisotropy17Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant0The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures2Advances and perspectives of actinide chemistry from ex situ high pressure and high temperature chemical studies10Hydrothermal Synthesis of New Mixed-Oxoanion Materials: Rare Earth Iodate Sulfates Sm(Io3)(So4) and Ln2(Io3)3(So4)Oh•3h2o (Ln = Sm, EU, Dy)5Towards a relationship between photoluminescence emissions and photocatalytic activity of Ag 2 SeO 4 : combining experimental data and theoretical insights10RE(OH) 2 NO 3 (RE = Tb, Dy, Ho, and Er): Synthesis and Nonlinear Optical Properties of Water-Resistant Lanthanide Hydroxide Nitrates15[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence8A survey of stereoactive oxysalts for linear and nonlinear optical applications40Anisotropic Thermal Expansion of Structurally Related Lanthanide–Mercury(II) Cyanide Coordination Polymers1The crystal structure of samarium sulfate pentahydrate, Sm2(SO4)3(H2O)50Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate6Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials0

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  1. In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect

    Inorganic Chemistry · 2018-05-24

    Jian Hung Lin, Zenghui Yue, Mark A. Silver, Meiying Qie, Xiaomei Wang, Wei Liu, Xiao Lin, Hongliang Bao, Linjuan Zhang, Shuao Wang, Jian‐Qiang Wang

    Read original paper ↗ ·

  2. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  3. Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties

    Dalton Transactions · 2019-01-01

    Jian Hung Lin, Qi Liu, Zenghui Yue, Kariem Diefenbach, Liwei Cheng, Yue‐Jian Lin, Jian‐Qiang Wang

    Read original paper ↗ ·

  4. Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation

    Dalton Transactions · 2019-01-01

    Huangjie Lu, Xiao-Jing Guo, Yaxing Wang, Kariem Diefenbach, Lanhua Chen, Jian‐Qiang Wang, Jian Hung Lin, Shuao Wang

    Read original paper ↗ ·

  5. The structural evolution and tunable photoluminescence of f-element bearing coordination polymers of the 2,4,6-tri-α-pyridyl-1,3,5-triazine ligand

    CrystEngComm · 2019-01-01

    Zenghui Yue, Huangjie Lu, Zi‐Jian Li, Shangyao Guo, Junze Song, Yiming Ren, Yuying Huang, Jian Hung Lin, Jian‐Qiang Wang

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  6. [Ln6O8] Cluster‐Encapsulating Polyplumbites as New Polyoxometalate Members and Record Inorganic Anion‐Exchange Materials for ReO4− Sequestration

    Advanced Science · 2019-06-17

    Jian Hung Lin, Lin Hong Zhu, Zenghui Yue, Chuang Yang, Wei Liu, Thomas E. Albrecht‐Schmitt, Jian‐Qiang Wang, Shuao Wang

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  7. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie International Edition · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiao‐Han Zhang, Jiang‐Gao Mao

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  8. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiaohan Zhang, Jiang‐Gao Mao

    Read original paper ↗ ·

  9. Structural Complexity and Magnetic Orderings in a Large Family of 3d–4f Heterobimetallic Sulfates

    Inorganic Chemistry · 2020-07-29

    Huangjie Lu, Kariem Diefenbach, Zi‐Jian Li, Hongliang Bao, Xiaofeng Guo, Jian‐Qiang Wang, Thomas E. Albrecht‐Schmitt, Jian Hung Lin

    Read original paper ↗ ·

  10. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  11. Two bismuth iodate sulfates with enhanced optical anisotropy

    Dalton Transactions · 2021-01-01

    Yilin Li, Chun‐Li Hu, Jin Chen, Jiang‐Gao Mao

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  12. Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant

    Polyhedron · 2021-04-18

    Colin N. Reedy, Eric M. Villa

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  13. The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures

    Crystals · 2021-08-16

    Gabriel L. Murphy, Philip Kegler, Eike M. Langer, Evgeny V. Alekseev

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  14. Advances and perspectives of actinide chemistry from ex situ high pressure and high temperature chemical studies

    Dalton Transactions · 2022-01-01

    Gabriel L. Murphy, Philip Kegler, Evgeny V. Alekseev

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  15. Hydrothermal Synthesis of New Mixed-Oxoanion Materials: Rare Earth Iodate Sulfates Sm(Io3)(So4) and Ln2(Io3)3(So4)Oh•3h2o (Ln = Sm, EU, Dy)

    Solid State Sciences · 2022-01-01

    Ceren Kütahyalı Aslani, Vladislav V. Klepov, Hans‐Conrad zur Loye

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  16. Towards a relationship between photoluminescence emissions and photocatalytic activity of Ag 2 SeO 4 : combining experimental data and theoretical insights

    Dalton Transactions · 2022-01-01

    Ivo M. Pinatti, Ana C. M. Tello, Paula F. S. Pereira, Aline B. Trench, Marcio Daldin Teodoro, Ieda L. V. Rosa, Albérico B. F. da Silva, E. Longo, Juán Andrés, Alexandre Zirpoli Simoes

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  17. RE(OH) 2 NO 3 (RE = Tb, Dy, Ho, and Er): Synthesis and Nonlinear Optical Properties of Water-Resistant Lanthanide Hydroxide Nitrates

    Inorganic Chemistry · 2022-11-01

    Min Chen, Zhengli Liang, Xiaoxiao Wang, Jiehua Li, Xingguo Chen, Xingxing Jiang, Zheshuai Lin, Zhen Ma, Hongming Liu

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  18. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  19. Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence

    Journal of Materials Chemistry C · 2023-01-01

    Wen Dong Song, Jinxuan Ren, Jinwen Tan, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

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  20. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  21. Anisotropic Thermal Expansion of Structurally Related Lanthanide–Mercury(II) Cyanide Coordination Polymers

    Inorganic Chemistry · 2023-12-25

    Thomas E. Karpiuk, Daniel B. Leznoff

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  22. The crystal structure of samarium sulfate pentahydrate, Sm2(SO4)3(H2O)5

    Zeitschrift für Kristallographie - New Crystal Structures · 2024-02-06

    Ming Li, Xiaofei Wang, Chunyan Mao

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  23. Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates

    Chemistry of Materials · 2024-10-04

    Zhenhua Li, Yi Shui, Zhengli Liang, Lehui Liu, Jiahao Wan, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  24. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

    Dalton Transactions · 2025-01-01

    Shihua Ma, Lei Geng, Baozhu Zhu, Changyu Meng

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  25. A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate

    Journal of Molecular Structure · 2025-07-01

    Chunxiang Wu, Y. X. Li, Zhengli Liang, Xiao Mei Jiang, Xiao Jiang, Hui Fang, Lixiang Qin, Xingyuan Bai, Lehui Liu, Lehui Liu, Xingxing Jiang, Xingxing Jiang, Hongming Liu, Hongming Liu

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  26. Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials

    Journal of Alloys and Compounds · 2025-12-31

    Yinglei Han, Tongqing Sun, Hongde Liu, Dahuai Zheng, Shiguo Liu, Yongfa Kong, Jingjun Xu

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