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RESEARCH PAPER · Dalton Transactions · 2022

Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters

Zi‐Jian Li, Xiaofeng Guo, Jie Qiu, Huangjie Lu, Jian‐Qiang Wang, Jian Hung Lin

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Recent advances in the applications of thorium-based metal–organic frameworks and molecular clustersOriginalStructural transformation of metal oxo species within UiO-66 type metal–organic frameworks9Energetic Systematics of Metal–Organic Frameworks: A Case Study of Al(III)-Trimesate MOF Isomers16Achieving High Photo/Thermocatalytic Product Selectivity and Conversion via Thorium Clusters with Switchable Functional Ligands87Synthesis of Thorium Dioxide Nanocrystals by Pyrolysis of a Thorium‐based Metal‐organic Framework4Stepwise Crystallization of Millimeter Scale Thorium Cluster Single Crystals as a Bifunctional Platform for X‐ray Detection and Shielding9A ratiometric radio-photoluminescence dosimeter based on a radical excimer for X-ray detection8A robust thorium–organic framework as a bifunctional platform for iodine adsorption and Cr( vi ) sensitization9Post-synthetic linker installation: an unprecedented strategy to enhance iodine adsorption in metal–organic frameworks17Topological control of metal–organic frameworks toward highly sensitive and selective detection of chromate and dichromate32A Tetravalent Plutonium Organic Framework Containing [ Pu2O16 ] Dimers as Secondary Building Units: Synthesis, Structure, and Radiation Stability9Multiple Stimulus Response 2D Framework Constructed by a Flexible Cyclotriphosphazene-Derived Carboxylic Acid Linker: Synthesis, Characterization, and Fluorescence Sensing to Phenolic Pollutants and Small-Molecule Drugs27Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization18Adsorption and Detection of Iodine Species by a Thorium-Based Metal–Organic Framework46Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy21Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy0Thorium Removal, Recovery and Recycling: A Membrane Challenge for Urban Mining21Combined Thermodynamic, Theoretical, and Biological Study for Investigating N-(2-Acetamido)iminodiacetic Acid as a Potential Thorium Decorporation Agent4Fine‐Tuning X‐Ray Sensitivity in Organic–Inorganic Hybrids via an Unprecedented Mixed‐Ligand Strategy12Highly sensitive and selective detection of chromate and dichromate by a luminescent thorium metal-organic framework5Friends or Foes: Fundamental Principles of Th-Organic Scaffold Chemistry Using Zr-Analogs as a Guide22Unraveling the role of coordinated water in the capture of americium and toxic gases by an ultrastable uranyl phosphonate framework12Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials18Current insights into the implementation of electrochemical sensors for comprehensive detection and analysis of radionuclides17Complexation of ThoriumIV with Fluorinated Heterocyclic β‐Diketones in Aqueous Hydrochloric Solutions3Covalency parameters for nine-coordinated thorium acylpyrazolone complexes along with their synthesis and crystal features2Constructing Functional Radiation-Resistant Thorium Clusters for Catalytic Redox Reactions31Thorium Cluster Synthesized by a Solvent-Free Flux Approach: The Richest Coordination Diversity and Application Exploration5Crystal growth, characterization and sensing studies of a new metal-organic framework of Sr(II) with phenylmalonic acid4Optimizing iodine adsorption in functionalized metal-organic frameworks via an unprecedented positional isomerism strategy30Photocatalytic and sensing studies of a new metal-organic framework of Ca(II) with phenylmalonic acid2Electronic transport properties of sandwich-type phthalocyanine Th(Pc) 25Emergence of a bismuth-based metal–organic framework as an X-ray scintillator3From separation to photothermal conversion: selective crystallization of thorium from lanthanides7Pioneering radiation dosimetry and photothermal conversion in a photochromic and radiochromic thorium cluster13Functionalized Thorium‐Based Metal‐Organic Frameworks for the Photocatalytic Oxidation of 1, 5‐Dihydroxynaphthalene1Influence of Node–Linker Connectivity on Radiolytic Stability of Thorium-Terephthalate Coordination Polymers5Organic Linker Effect on Iodine Adsorption in Thorium‐Based UiO‐66‐Type Metal Organic Frameworks4Emergence of acidity modulation as a new strategy for eliciting stable radicals in multi-stimuli-responsive metal-oxo clusters5Stable Tetravalent Metal–Organic Frameworks for Electrocatalysis and Aqueous Electrochemical Energy Storage5Electrocatalytic oxidation of methanol: role of thorium (Th) doping in MoSe 20Electrocatalytic oxygen reduction reaction on single-cluster catalyst in 2D metal-organic frameworks: A density functional theory study0A Tetranuclear Thorium-Containing Hexameric Antimonotungstate: Synthesis, Structure, and Catalysis of the Knoevenagel Condensation35Highly Water-Stable Uranyl-Cluster Based Metal–Organic Framework for Thermal Adaptive Scintillator5Triple-emission bimetallic Ln-MOF probe for smartphone-based multiplex detection of radionuclides, pesticides, and biomarkers in food safety3A One-Dimensional Thorium-Containing Arsenotungstate for the Synthesis of 2,3-Dihydroquinazolinones0Construction of an Amino-Functionalized Thorium MOF for Bifunctional Catalysis toward CO2 Cycloaddition and N-Formylation0Controlled Synthesis of High‐Nuclearity Th 38 Cluster for Efficient Photocatalytic Dehydrogenative Cross‐Coupling0Photoinduced Electronic Modulation in a Thorium Cluster: Enabling Dual Radiation Sensing and Photothermal Conversion0Adsorption Electro-Neutralization of Ionic Liquids in Thorium-MOFs for Enhanced Photocatalytic CO2 Reduction0

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  1. Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks

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    Megan C. Wasson, Haomiao Xie, Xingjie Wang, Joshua S. Duncan, Omar K. Farha

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  2. Energetic Systematics of Metal–Organic Frameworks: A Case Study of Al(III)-Trimesate MOF Isomers

    Inorganic Chemistry · 2022-09-13

    Jiahong Li, Vitaliy G. Goncharov, Andrew Strzelecki, Hongwu Xu, Xiaofeng Guo, Qiang Zhang

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  3. Achieving High Photo/Thermocatalytic Product Selectivity and Conversion via Thorium Clusters with Switchable Functional Ligands

    Journal of the American Chemical Society · 2022-10-03

    Qian Niu, Qing Huang, Tao‐Yuan Yu, Jiang Liu, Jingwen Shi, Long‐Zhang Dong, Shun‐Li Li, Ya‐Qian Lan

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  4. Synthesis of Thorium Dioxide Nanocrystals by Pyrolysis of a Thorium‐based Metal‐organic Framework

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    Ting Yu, Zhenghua Qian, Lin Li, Zonghui Lu, Bin Li, Qiang Zhang, Xiaofeng Liu, Hui He, Yanbo Qiao, Ye Guoan

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  5. Stepwise Crystallization of Millimeter Scale Thorium Cluster Single Crystals as a Bifunctional Platform for X‐ray Detection and Shielding

    Small · 2022-12-19

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  6. A ratiometric radio-photoluminescence dosimeter based on a radical excimer for X-ray detection

    Chemical Communications · 2023-01-01

    Huangjie Lu, Jingqi Ma, Junpu Yang, Huiliang Hou, Jiacheng Lu, Jian‐Qiang Wang, Yaxing Wang, Jian Hung Lin

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  7. A robust thorium–organic framework as a bifunctional platform for iodine adsorption and Cr( vi ) sensitization

    Dalton Transactions · 2023-01-01

    Yiran Fu, Xue Wang, Yu Ju, Zhaofa Zheng, Jie Jian, Zi‐Jian Li, Chan Ho Jin, Jian‐Qiang Wang, Jian Hung Lin

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  8. Post-synthetic linker installation: an unprecedented strategy to enhance iodine adsorption in metal–organic frameworks

    Chemical Communications · 2023-01-01

    Zi‐Jian Li, Yu Ju, Jie Qiu, Zhi‐Hui Zhang, Linjuan Zhang, Ming‐Yang He, Jian‐Qiang Wang, Jian Hung Lin

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  9. Topological control of metal–organic frameworks toward highly sensitive and selective detection of chromate and dichromate

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    Zi‐Jian Li, Yu Ju, Xiaoling Wu, Xiaoyun Li, Jie Qiu, Yongxin Li, Zhi‐Hui Zhang, Ming‐Yang He, Linjuan Zhang, Jian‐Qiang Wang, Jian Hung Lin

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  10. A Tetravalent Plutonium Organic Framework Containing [ Pu2O16 ] Dimers as Secondary Building Units: Synthesis, Structure, and Radiation Stability

    Chinese Journal of Chemistry · 2023-03-02

    Yugang Zhang, Yingzhe Du, Lili Li, Ye Tao, Kai Li, Hailong Zhang, Yanlong Wang, Lanhua Chen, Yaxing Wang, Zhifang Chai, Shuao Wang

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  11. Multiple Stimulus Response 2D Framework Constructed by a Flexible Cyclotriphosphazene-Derived Carboxylic Acid Linker: Synthesis, Characterization, and Fluorescence Sensing to Phenolic Pollutants and Small-Molecule Drugs

    Inorganic Chemistry · 2023-03-24

    Meng Wang, Jinlong Li, Xiao Yu Tang, Qing Lin Guan, Feng‐Ying Bai, Yong‐Heng Xing, Yu Fei Wang

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  12. Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization

    Inorganic Chemistry · 2023-03-24

    Shujing Hou, Fusheng Liu, Haomiao Xie, Sylvia L. Hanna, Karam B. Idrees, Chenghui Zhang, Xingjie Wang, Yongwei Chen, Peng Li, Omar K. Farha

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  13. Adsorption and Detection of Iodine Species by a Thorium-Based Metal–Organic Framework

    Inorganic Chemistry · 2023-05-15

    Yu Ju, Zi‐Jian Li, Jie Qiu, Xiaoyun Li, Junpu Yang, Zhi‐Hui Zhang, Ming‐Yang He, Jian‐Qiang Wang, Jian Hung Lin

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  14. Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy

    Angewandte Chemie International Edition · 2023-05-22

    Sen Mei, Lixi Chen, Hailong Zhang, Zhiwei Li, Liwei Cheng, Junhao Lu, Xiaoqi Li, Qian Yang, Yanlong Wang, Zhiyong Liu, Zhifang Chai, Shuao Wang

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  15. Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy

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  16. Thorium Removal, Recovery and Recycling: A Membrane Challenge for Urban Mining

    Membranes · 2023-08-29

    Geani Teodor Man, Paul Constantin Albu, Aurelia Cristina Nechifor, Alexandra Raluca Grosu, Szidonia-Katalin Tanczos, Vlad-Alexandru Grosu, Mihail-Răzvan Ioan, Gheorghe Nechifor

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  17. Combined Thermodynamic, Theoretical, and Biological Study for Investigating N-(2-Acetamido)iminodiacetic Acid as a Potential Thorium Decorporation Agent

    Inorganic Chemistry · 2023-11-03

    S.D. Sharma, Manjoor Ali, Amit Kumar, Neetika Rawat

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  18. Fine‐Tuning X‐Ray Sensitivity in Organic–Inorganic Hybrids via an Unprecedented Mixed‐Ligand Strategy

    Advanced Science · 2023-11-08

    Huangjie Lu, Zhaofa Zheng, Huiliang Hou, Yaoyao Bai, Jie Qiu, Jian‐Qiang Wang, Jian Hung Lin

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  19. Highly sensitive and selective detection of chromate and dichromate by a luminescent thorium metal-organic framework

    Inorganica Chimica Acta · 2023-11-20

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  20. Friends or Foes: Fundamental Principles of Th-Organic Scaffold Chemistry Using Zr-Analogs as a Guide

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  21. Unraveling the role of coordinated water in the capture of americium and toxic gases by an ultrastable uranyl phosphonate framework

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  22. Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials

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  23. Current insights into the implementation of electrochemical sensors for comprehensive detection and analysis of radionuclides

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  24. Complexation of ThoriumIV with Fluorinated Heterocyclic β‐Diketones in Aqueous Hydrochloric Solutions

    European Journal of Inorganic Chemistry · 2024-07-10

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  25. Covalency parameters for nine-coordinated thorium acylpyrazolone complexes along with their synthesis and crystal features

    Journal of Molecular Structure · 2024-07-14

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  26. Constructing Functional Radiation-Resistant Thorium Clusters for Catalytic Redox Reactions

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  27. Thorium Cluster Synthesized by a Solvent-Free Flux Approach: The Richest Coordination Diversity and Application Exploration

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  28. Crystal growth, characterization and sensing studies of a new metal-organic framework of Sr(II) with phenylmalonic acid

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  29. Optimizing iodine adsorption in functionalized metal-organic frameworks via an unprecedented positional isomerism strategy

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  30. Photocatalytic and sensing studies of a new metal-organic framework of Ca(II) with phenylmalonic acid

    Journal of the Indian Chemical Society · 2024-11-07

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  31. Electronic transport properties of sandwich-type phthalocyanine Th(Pc) 2

    Journal of Materials Chemistry C · 2025-01-01

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  32. Emergence of a bismuth-based metal–organic framework as an X-ray scintillator

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  33. From separation to photothermal conversion: selective crystallization of thorium from lanthanides

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  34. Pioneering radiation dosimetry and photothermal conversion in a photochromic and radiochromic thorium cluster

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  35. Functionalized Thorium‐Based Metal‐Organic Frameworks for the Photocatalytic Oxidation of 1, 5‐Dihydroxynaphthalene

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  36. Influence of Node–Linker Connectivity on Radiolytic Stability of Thorium-Terephthalate Coordination Polymers

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  37. Organic Linker Effect on Iodine Adsorption in Thorium‐Based UiO‐66‐Type Metal Organic Frameworks

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  38. Emergence of acidity modulation as a new strategy for eliciting stable radicals in multi-stimuli-responsive metal-oxo clusters

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  39. Stable Tetravalent Metal–Organic Frameworks for Electrocatalysis and Aqueous Electrochemical Energy Storage

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  40. Electrocatalytic oxidation of methanol: role of thorium (Th) doping in MoSe 2

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  41. Electrocatalytic oxygen reduction reaction on single-cluster catalyst in 2D metal-organic frameworks: A density functional theory study

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  42. A Tetranuclear Thorium-Containing Hexameric Antimonotungstate: Synthesis, Structure, and Catalysis of the Knoevenagel Condensation

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  43. Highly Water-Stable Uranyl-Cluster Based Metal–Organic Framework for Thermal Adaptive Scintillator

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  45. A One-Dimensional Thorium-Containing Arsenotungstate for the Synthesis of 2,3-Dihydroquinazolinones

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  46. Construction of an Amino-Functionalized Thorium MOF for Bifunctional Catalysis toward CO2 Cycloaddition and N-Formylation

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  48. Photoinduced Electronic Modulation in a Thorium Cluster: Enabling Dual Radiation Sensing and Photothermal Conversion

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