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RESEARCH PAPER · Coordination Chemistry Reviews · 2020

Metal-organic frameworks as a versatile platform for radionuclide management

Kangwoo Jin, Byeongchan Lee, Jinhee Park

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Metal-organic frameworks as a versatile platform for radionuclide managementOriginalEfficient Sr-90 removal from highly alkaline solution by an ultrastable crystalline zirconium phosphonate29Hydrangea-like architectures composed of Zr-based metal–organic framework nanosheets with enhanced iodine capture6Metal–organic architectures designed from a triphenyl-pentacarboxylate linker: hydrothermal assembly, structural multiplicity, and catalytic Knoevenagel condensation19Recent advances in luminescent metal–organic frameworks (LMOFs) based fluorescent sensors for antibiotics216A Green Metal–Organic Framework‐Cyclodextrin MOF: A Novel Multifunctional Material Based Triboelectric Nanogenerator for Highly Efficient Mechanical Energy Harvesting158Remediation of Metal/Metalloid-Polluted Soils: A Short Review158An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Designable Assembly of Aluminum Molecular Rings for Sequential Confinement of Iodine Molecules92Designable Assembly of Aluminum Molecular Rings for Sequential Confinement of Iodine Molecules12Coordination Polymers Driven by Carboxy Functionalized Picolinate Linkers: Hydrothermal Assembly, Structural Multiplicity, and Catalytic Features19Metal-organic frameworks as superior porous adsorbents for radionuclide sequestration: Current status and perspectives52Impact of Structural Functionalization, Pore Size, and Presence of Extra-Framework Ions on the Capture of Gaseous I2 by MOF Materials13Application of carbon dots and their composite materials for the detection and removal of radioactive ions: A review133Constructing Cationic Metal–Organic Framework Materials Based on Pyrimidyl as a Functional Group for Perrhenate/Pertechnetate Sorption44High Sorption and Selective Extraction of Actinides from Aqueous Solutions12Water-stable metal–organic framework–based nanomaterials for removal of heavy metal ions and radionuclides4Post‐synthesis metal‐organic framework for turn‐on ratiometric fluorescence sensing of UO22+11UoC-3: A Metal–Organic Framework with an Anionic Framework Based on Uranyl UO22+ Nodes and Partly Fluorinated Benzene-1,3,5-Tribenzoate Linkers22Evaluation on migration and transformation of trace nuclides in thermal degradation for low-level radioactive waste17Adsorption of iodine in metal–organic framework materials557Enhanced Xe/Kr separation via the pore size confinement effect of a microporous thorium-based metal–organic framework9Multi-functional metal–organic frameworks for detection and removal of water pollutions69Precise Regulation of Active Sites of Mofs for Capture of Iodine19Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters50Structural investigation of the efficient capture of Cs + and Sr 2+ by a microporous Cd–Sn–Se ion exchanger constructed from mono-lacunary supertetrahedral clusters28Triptycene-based and imine linked porous uniform microspheres for efficient and reversible scavenging of iodine from various media: a systematic study24Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs+ Ions※1Hydrogen‐Bonded Metal–Nucleobase Frameworks for Efficient Separation of Xenon and Krypton18Hydrogen‐Bonded Metal–Nucleobase Frameworks for Efficient Separation of Xenon and Krypton89Efficient adsorption of cesium using a novel composite inorganic ion-exchanger based on metal organic framework (Ni[(BDC)(TED)]) modified matal hexacyanoferrate11Highly Efficient Uptake of Cs + by Robust Layered Metal–Organic Frameworks with a Distinctive Ion Exchange Mechanism49Organic porous solid as promising iodine capture materials41Rapid and highly selective Sr2+ uptake by 3D microporous rare earth oxalates with the facile synthesis, high water stability and radiation resistance31Capture of Gaseous Iodine in Isoreticular Zirconium‐Based UiO‐n Metal‐Organic Frameworks: Influence of Amino Functionalization, DFT Calculations, Raman and EPR Spectroscopic Investigation59pH‐Controlled Switch over Coadsorption and Separation for Mixed Cs + and Sr 2+ by an Acid‐Resistant Potassium Thioantimonate55Environmental Restoration of Metal-Contaminated Soils15A Multifunctional Porous Uranyl Phosphonate Framework for Cyclic Utilization: Salvages, Uranyl Leaking Prevention, and Fluorescent Sensing44A Cu2I2-Based Coordination Framework as the Selective Sensor for Ag+ and the Effective Adsorbent for I248Hydrolytically Stable Zr-Based Metal–Organic Framework as a Highly Sensitive and Selective Luminescent Sensor of Radionuclides34Magnetically separable h-Fe3O4@phosphate/polydopamine nanospheres for U(VI) removal from wastewater and soil14Fast Room‐Temperature Synthesis of an Extremely Alkaline‐Resistant Cationic Metal–Organic Framework for Sequestering TcO4− with Exceptional Selectivity77Synthesis and characterization of a novel nanocomposite ([(SBA-15)-(Cu(BTC)]-[KZn(Fe(CN)6)]) for cesium removal from aqueous media and optimization condition using central composite design4Mapping the Porous and Chemical Structure–Function Relationships of Trace CH3I Capture by Metal–Organic Frameworks using Machine Learning20Preparation and applications of metal–organic frameworks composed of sulfonic acid67Post-synthetic modification of zirconium terephthalate sorbents and their application for sorption of selected toxic elements from water0Waste PET-MOF-Cleanwater3Cu(II)-Based Molecular Hexagons Forming Honeycomb-like Networks Exhibit High Electrical Conductivity4Highly Sensitive Adsorption and Detection of Iodide in Aqueous Solution by a Post-Synthesized Zirconium-Organic Framework17Giant Polyoxoniobate‐Based Inorganic Molecular Tweezers: Metal Recognitions, Ion‐Exchange Interactions and Mechanism Studies24Giant Polyoxoniobate‐Based Inorganic Molecular Tweezers: Metal Recognitions, Ion‐Exchange Interactions and Mechanism Studies4Selective Sequestration of Perrhenate by Cationic Polymeric Networks Based on Elongated Pyridyl Ligands28MOF-Based Sorbents Used for the Removal of Hg2+ from Aqueous Solutions via a Sorption-Assisted Microfiltration9Multiscale structural control of thiostannate chalcogels with two-dimensional crystalline constituents24Hollow structure molecularly imprinted ratiometric fluorescence sensor for the selective and sensitive detection of dopamine12The Capture Performance of An-Mof for Fission Gases: Insight from Dft and Aimd Calculations0Efficient Iodine Removal by Porous Biochar-Confined Nano-Cu2O/Cu0: Rapid and Selective Adsorption of Iodide and Iodate Ions19Advanced porous adsorbents for radionuclides elimination207A Promising 1,3,5-Triazine-Based Anion Exchanger for Perrhenate Binding: Crystal Structures of Its Chloride, Nitrate and Perrhenate Salts3Crystallochemical Role of Benzoate and Phenylacetate Ions in Structures of Coordination 3d-Metal Compounds2Crystallochemical Role of Benzoate and Phenylacetate Ions in Structures of Coordination 3d-Metal Compounds0A review on the clean-up technologies for heavy metal ions contaminated soil samples45Facile synthesis of imidazolium cationic organic polymer with ultrafast ReO4−/99TcO4− removal under highly alkaline conditions28From Supramolecular Organic Cages to Porous Covalent Organic Frameworks for Enhancing Iodine Adsorption Capability by Fully Exposed Nitrogen‐Rich Sites118Efficient radioactive gas detection by scintillating porous metal–organic frameworks104Rationally designing imidazole-based coordination polymers with high adsorption capacity for removing iodine67Spent Catalyst‐Derived Mo‐MOF: Triboelectric Nanogenerators and Energy Harvesting25Open-framework hybrid zinc/tin selenide as an ultrafast adsorbent for Cs+, Ba2+, Co2+, and Ni2+29Adenosine/β-Cyclodextrin-Based Metal–Organic Frameworks as a Potential Material for Cancer Therapy28Estimation of radionuclides migration mechanism in thermal decomposition of spent ion exchange resin in nuclear power plant22Solid-State Structural Transformation in Zn(II) Metal–Organic Frameworks in a Single-Crystal-to-Single-Crystal Fashion5Nonporous amorphous superadsorbents for highly effective and selective adsorption of iodine in water216The capture performance of An-MOF for fission gases: Insight from DFT and AIMD calculations6Enhancing Uranium Removal with a Titanium-Incorporated Zirconium-Based Metal–Organic Framework9Test Bench Development and Application to a Parametric Experimental Study on the Dynamic Adsorption Capacity of Noble Gases (Kr, Xe) in the Metal–Organic Framework HKUST-13Luminescent metal organic frameworks and their fluorescence sensing application10Highly efficient iodine uptake and iodate selective probe in a 3D honeycomb-like copper–organic framework based on in situ ligand transformation2The migration behavior of cesium during plasma gasification melting process of spent radioactive resins by thermodynamic calculation4A Chromium-Incorporated All-Inorganic Polyoxoniobate Framework Material: Good Chemical Stability and Selective Ion Exchange Capability0A Mixed Polynuclear Clusters-Based Y-Mof with an Unprecedented (12, 12, 18)-C Topology: Highly Efficient Propylene/Ethylene Separation and Iodine Adsorption0Exploration of iodine adsorption performance of pyrene-based two-dimensional covalent organic frameworks15Novel nitrogen-rich conjugated microporous polymers for efficient capture of iodine and methyl iodide31Nuclear Waste Management8Remediation approaches for heavy metals contaminated soils0Structural polymorphism and luminescence properties of zinc( ii ) and cobalt( ii ) MOFs with rigid and flexible ligands5Designing External Pores of Aluminum Oxo Polyhedrons for Efficient Iodine Capture15Adsorption of molecular iodine and alkyl iodides from spent-nuclear-fuel-reprocessing off-gas using reduced silver mordenite47Incorporating Two Crown Ether Struts into the Backbone of Robust Zirconium‐Based Metal–Organic Frameworks as Custom‐Designed Efficient Collectors for Radioactive Metal Ions36Selective Sr2+ capture in an In3+-based anionic metal-organic framework31Magnetic CNT-based electrode for efficient electro-adsorption of uranium26Recent advances in functionalized porous adsorbents for radioactive waste water decontamination: Current status, research gap and future outlook34Optimizing Iodine Enrichment through Induced‐Fit Transformations in a Flexible Ag(I)‐Organic Framework: From Accelerated Adsorption Kinetics to Record‐High Storage Density16Recent Development of Metal–Organic Frameworks for Water Purification43Recent progress in separation of technetium-99 from spent nuclear fuel and radioactive waste. Challenges and prospects55Carbon Dots in Environmental Remediation: Removal of Inorganic Compounds and Many Other Complex Compounds4Simple surface modification of PVDF membrane via a quaternization of NM88B for efficient oil/water separation22UoC‐7: A Bimetallic K‐Zn‐MOF with an Anionic Framework Based on Fluorinated Trimesate Ligands Exhibiting a Large CO2 Uptake1Radiation resistant metal–organic frameworks for the production of high specific activity 51Cr by the Szilard-Chalmers effect9Unraveling the role of coordinated water in the capture of americium and toxic gases by an ultrastable uranyl phosphonate framework12A chromium-incorporated all-inorganic polyoxoniobate framework material: Good chemical stability and selective ion exchange capability1N-Heteroatom Engineered Nonporous Amorphous Self-Assembled Coordination Cages for Capture and Storage of Iodine14Nitrogen-rich and core-sheath polyamide/polyethyleneimine@Zr-MOF for iodine adsorption and nerve agent simulant degradation43Construction of nitrogen-rich groups @ zirconium-based metal-organic frameworks for efficient iodine capture9Recent progress of radionuclides separation by porous materials265Optimizing iodine adsorption in functionalized metal-organic frameworks via an unprecedented positional isomerism strategy30Synthesis and characterization of non-porous amorphous polymers for enhanced iodine adsorption5Rapid adsorption of iodine from water and reversible capture of iodine vapor using stilbene-crosslinked porous organic polymers13In-situ synthesis of layered double hydroxides with tunable basal spacing for efficient iodide over iodate adsorption selectivity19Observing Anion Binding in Single Charge-Neutral Metal–Organic Frameworks through C–H Hydrogen-Bonding Interactions0Positional Isomerism: A Novel Paradigm for Enhancing Iodine Adsorption in Functionalized Metal–Organic Frameworks15Fe/Cu Bimetallic Nanozyme Co‐Assembled with 177Lu and Tanshinone for Quadruple‐Synergistic Tumor‐Specific Therapy8Efficient capture of gaseous, aqueous iodine, near-sunlight white light emission and iodine sensing in 12-connected and [Pb6]-cluster based MOFs14Advances in Porous Materials for Transuranic Element Separation5Bell-shaped magnetic hollow porous carbon: an efficient and sustainably recycled iodine absorbent in aqueous solution1Extreme Water Swelling Induced Pore-Reconfiguration of Hydrospongel for Ultrafast and Selective Trapping of Reo4− / 99tco4− from Nuclear Wastewater0Highly efficient and selective Sr 2+ capture using robust two-dimensional MOF nanosheets decorated with cage-like cavities13Metal–organic frameworks as advanced platforms for radionuclide detection22Robust copper-based cationic metal–organic frameworks for efficient sequestration of perrhenate/pertechnetate4Advancements in radionuclide adsorption for wastewater treatment using metal-organic frameworks and cellulose composites12Aluminum Cluster Molecular Ring-Based Heterometallic Framework Materials for Iodine Capture8Metal-free porphyrin porous organic cage for efficient iodine capture24Moldable SnS2/polyimide aerogel as fixed-bed adsorbent: efficient immobilization of radioiodine vapor with resistance to high-temperature and high-humidity conditions6Efficient iodine adsorption from water using tailored multi-heteroatom porous metal–organic framework by dual-ligand strategy21Formation of the Most Iodine‐Rich Polyiodide [I13]− in Pore‐Partitioned Metal‐Organic Frameworks for Efficient Iodine Capture9Advances on constructing functional reticular materials for efficient determination of radionuclides6Increasing Tc retention during nuclear waste vitrification: Effect of alumina source on the rate of rhenium incorporation into glass4The emerging applications of nanoscale hierarchically porous metal–organic frameworks8Dual Capture of Iodine and Methyl Iodide Using Nonporous Nitrogen-Enriched Palladium(II) Assemblies13Ultrahigh molybdenum adsorption capacity of hierarchical MXene@UiO-66 composites for potential application in the 99Mo/99mTc generator2Aqueous Adsorption of Lead Ions Using Copper-Based MOFs Immobilized Nanofibers0Self‐Assembled Pd(II) Nano‐Adsorbents for Iodine and Methyl Iodide Capture in Vapor and Aqueous Phases30Detection of radioactive ions: current status of nanomaterial-based sensors5Extreme water swelling induced pore-reconfiguration of hydrospongel for ultrafast and selective trapping of ReO4−/99TcO4− from nuclear wastewater0Permeable Layered Tin Sulfide Ion Exchanger for Rapid Elimination of Cs + and Sr 2+4Targeted Selenite Adsorption Using Defective Fe‐BTC: Effective in Acidic and Alkaline Conditions3Synthesis and efficient iodine capture of novel imine-based covalent organic skeleton material1Metal-organic frameworks with oxygen-rich adsorption sites for efficient capture of uranium and thorium in acidic environments20Adsorption of volatile radionuclides in covalent organic frameworks: Mechanisms, optimization strategies, and prospects5SuFEx-derived macrocyclic polysulfates for efficient dual capture of methyl iodide and iodine6MOFs and COFs for Radionuclide and Nuclear‐Waste Treatment35Scalable Ambient Synthesis of Hydroxyl-Rich Cyclodextrin Potassium Metal–Organic Frameworks for High-Efficiency Iodine Capture10Tetratopic zirconium-based metal-organic frameworks: Synthesis and application in environmental remediation via adsorption and catalysis9Thermal degradation of spent cation exchange resin with fixatives or metal ion catalysts: Insights from experiments, thermodynamics and kinetics4Crystal Chemical Role of Naphtalenecarboxylate and Anthracenecarboxylate Ions in the Structures of 3d Metal Coordination Compounds0Highlighting the Advancement of Nuclear Waste Water Treatment with Modular Porous Scaffolds15Porous Noncovalent Organic Frameworks as Emerging Adsorbents for Radionuclide Decontamination8Study on the modification of silica for enhancing the structural stability and thorium ion adsorption capacity of metal-organic frameworks2Recent progress in zeolite-based separation of radioactive nuclides: a comprehensive review12Metal-organic frameworks for clean water21Framework materials for nuclear waste treatment19Molecular engineering of pyridinium-functionalized metal–organic cages for iodine capture in multiple phase media1

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  34. Capture of Gaseous Iodine in Isoreticular Zirconium‐Based UiO‐n Metal‐Organic Frameworks: Influence of Amino Functionalization, DFT Calculations, Raman and EPR Spectroscopic Investigation

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