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RESEARCH PAPER · Advanced Optical Materials · 2019

Cr 3+ ‐Doped Broadband NIR Garnet Phosphor with Enhanced Luminescence and its Application in NIR Spectroscopy

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Cr 3+ ‐Doped Broadband NIR Garnet Phosphor with Enhanced Luminescence and its Application in NIR SpectroscopyOriginalSol-gel processing of Eu3+ doped Li6CaLa2Nb2O12 garnet for efficient and thermally stable red luminescence under near-ultraviolet/blue light excitation75Two-Site Occupation for Exploring Ultra-Broadband Near-Infrared Phosphor—Double-Perovskite La 2 MgZrO 6 :Cr 3+559Broad band emission near-infrared material Mg3Ga2GeO8:Cr3+: Substitution of Ga-In, structural modification, luminescence property and application for high efficiency LED98Heavy Mn2+ Doped MgAl2O4 Phosphor for High‐Efficient Near‐Infrared Light‐Emitting Diode and the Night‐Vision Application268Highly efficient and thermally stable Cr3+-activated silicate phosphors for broadband near-infrared LED applications385Ultra-Broadband Phosphors Converted Near-Infrared Light Emitting Diode with Efficient Radiant Power for Spectroscopy Applications104Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes660[INVITED] Near-infrared phosphors and their full potential: A review on practical applications and future perspectives196Broadband near-infrared (NIR) emission realized by the crystal-field engineering of Y 3−x Ca x Al 5−x Si x O 12 :Cr 3+ ( x = 0–2.0) garnet phosphors263Structural, luminescence and EPR properties of deep red emitting MgY2Al4SiO12:Cr3+ garnet phosphor51A solid-state colorimetric fluorescence Pb 2+ -sensing scheme: mechanically-driven CsPbBr 3 nanocrystallization in glass33Broadband near-infrared emission of La 3 Ga 5 GeO 14 :Tb 3+ ,Cr 3+ phosphors: energy transfer, persistent luminescence and application in NIR light-emitting diodes66Disentangling site occupancy, cation regulation, and oxidation state regulation of the broadband near infrared emission in a chromium-doped SrGa 4 O 7 phosphor72Electron–phonon coupling mechanisms of broadband near-infrared emissions from Cr 3+ in the Ca 3 Sc 2 Si 3 O 12 garnet71Luminescence properties and energy transfer of novel Bi 3+ and Mn 2+ -co-activated Y 3 Ga 5 O 12 single-component white light-emitting phosphor54Two-site Cr 3+ occupation in the MgTa 2 O 6 :Cr 3+ phosphor toward broad-band near-infrared emission for vessel visualization215Ultra-broadband near-infrared emission CuInS 2 /ZnS quantum dots with high power efficiency and stability for the theranostic applications of mini light-emitting diodes35Review—Mn 4+ vs Cr 3+ : A Comparative Study as Activator Ions in Red and Deep Red-Emitting Phosphors50Efficient Super Broadband NIR Ca 2 LuZr 2 Al 3 O 12 :Cr 3+ ,Yb 3+ Garnet Phosphor for pc‐LED Light Source toward NIR Spectroscopy Applications308Eu2+-doped ultra-broadband VIS-NIR emitting phosphor126An Ultraviolet–Visible and Near‐Infrared‐Responded Broadband NIR Phosphor and Its NIR Spectroscopy Application285Enhancing Near-Infrared Photoluminescence Intensity and Spectral Properties in Yb 3+ Codoped LiScP 2 O 7 :Cr 3+345Broadband near‐infrared emission enhancement in K 2 Ga 2 Sn 6 O 16 :Cr 3+ phosphor by electron‐lattice coupling regulation87Design of a Broadband NIR Phosphor for Security-Monitoring LEDs: Tunable Photoluminescence Properties and Enhanced Thermal Stability140Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources743Near-Infrared Persistent Luminescence in a Cr3+-Doped Perovskite for Low-Irradiance Imaging113Identification of Dy 3 + / Dy 2 + as Electron Trap in Persistent Phosphors100Broadband infrared LEDs based on europium-to-terbium charge transfer luminescence152Design and control of the luminescence in Cr3+-doped NIR phosphors via crystal field engineering105Broadband Cr3+-sensitized upconversion luminescence of LiScSi2O6:Cr3+/Er3+33Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation106Broadband Near-Infrared Emitting Ca2LuScGa2Ge2O12:Cr3+ Phosphors: Luminescence Properties and Application in Light-Emitting Diodes202Solid‐State Thin‐Film Broadband Short‐Wave Infrared Light Emitters53Enticing applications of near‐infrared phosphors: Review and future perspectives44Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications242Lead‐Free Halide Double Perovskites: Structure, Luminescence, and Applications131A highly efficient and thermally stable broadband Cr 3+ -activated double borate phosphor for near-infrared light-emitting diodes236A dual-excited and dual near-infrared emission phosphor Mg 14 Ge 5 O 24 :Cr 3+ ,Cr 4+ with a super broad band for biological detection70Emerging high-power NIR-emitting phosphor-converted LEDs4Cr,Yb-codoped Ca 2 LaHf 2 Al 3 O 12 garnet phosphor: electronic structure, broadband NIR emission and energy transfer properties63Cr 3+ ‐Doped Sc‐Based Fluoride Enabling Highly Efficient Near Infrared Luminescence: A Case Study of K 2 NaScF 6 :Cr 3+259A broadband near-infrared phosphor BaZrGe 3 O 9 :Cr 3+ : luminescence and application for light-emitting diodes73A near infrared-II broad emission material with multi-spectral excitation and long persistent luminescence properties21A novel Cr 3+ -doped Lu 2 CaMg 2 Si 3 O 12 garnet phosphor with broadband emission for near-infrared applications136A single luminescence center ultra-broadband near-infrared LiScGeO 4 :Cr phosphor for biological tissue penetration49Ab initio two-sites occupancy and broadband near-infrared emission of Cr 3+ in Li 2 MgZrO 482Achieving the potential multifunctional near-infrared materials Ca 3 In 2−x Ga x Ge 3 O 12 :Cr 3+ using a solid state method59Broadband near-infrared BaMSi 3 O 9 :Cr 3+ (M = Zr, Sn, Hf) phosphors for light-emitting diode applications38Cr 3+ -activated Na 3 X 2 Li 3 F 12 (X = Al, Ga, or In) garnet phosphors with broadband NIR emission and high luminescence efficiency for potential biomedical application124Distorted octahedral site occupation-induced high-efficiency broadband near-infrared emission in LiScGe 2 O 6 :Cr 3+ phosphor65Enhancing and tuning broadband near-infrared (NIR) photoluminescence properties in Cr 3+ -doped Ca 2 YHf 2 Al 3 O 12 garnet phosphors via Ce 3+ /Yb 3+ -codoping for LED applications101Highly Efficient and Thermally Stable Far-Red-Emitting Phosphors for Plant-Growth Lighting44Highly thermally stable Cr 3+ and Yb 3+ codoped Gd 2 GaSbO 7 phosphors for broadband near-infrared applications54Long-lived emission beyond 1000 nm: control of excited-state dynamics in a dinuclear Tb( iii )–Nd( iii ) complex7Site engineering strategy toward enhanced luminescence thermostability of a Cr 3+ -doped broadband NIR phosphor and its application107Synthesis and luminescence properties of a broadband near-infrared emitting non-gallate persistent luminescence Mg 1.4 Zn 0.6 SnO 4 :Cr 3+ phosphor25Tuning luminescence from NIR-I to NIR-II in Cr 3+ -doped olivine phosphors for nondestructive analysis175A broadband near-infrared phosphor Ca3Y2Ge3O12:Cr3+ with garnet structure136Review—Photoluminescence Properties of Cr3+-Activated Fluoride Phosphors45Disorder-Induced Broadband Near-Infrared Persistent and Photostimulated Luminescence in Mg2SnO4:Cr3+47Review—Photoluminescence Properties of Cr3+-Activated Oxide Phosphors106A High Efficiency Trivalent Chromium-Doped Near-Infrared-Emitting Phosphor and Its NIR Spectroscopy Application166Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodes143Broadband near-infrared emission of K3ScF6:Cr3+ phosphors for night vision imaging system sources189Effect of R+ (R = Li, Na and K) codoping on the luminescence enhancement of broadband NIR BaZrGe3O9:Cr3+ phosphors for NIR LED26Simultaneous Broadening and Enhancement of Cr 3+ Photoluminescence in LiIn 2 SbO 6 by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications325Simultaneous Broadening and Enhancement of Cr3+Photoluminescence in LiIn2SbO6by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications5Trivalent Chromium Ions Doped Fluorides with Both Broad Emission Bandwidth and Excellent Luminescence Thermal Stability269Efficient near‐infrared pyroxene phosphor LiInGe 2 O 6 :Cr 3+ for NIR spectroscopy application144Temperature-dependent luminescent properties of Cr3+ doped ZnGa2O4 far-red emitting phosphor36The hydrothermally synthesis of K 3 AlF 6 :Cr 3+ NIR phosphor and its performance optimization based on phase control33Structural Confinement for Cr 3+ Activators toward Efficient Near-Infrared Phosphors with Suppressed Concentration Quenching216Achievement of broadband near-infrared phosphor Ca3Y2Ge3O12:Cr3+, Ce3+ via energy transfer for food analysis34Research on a new type of near-infrared phosphor Li2MgZrO4:Cr3+- synthesis, crystal structure, photoluminescence and thermal stability18Thermally Stable CaLu 2 Mg 2 Si 3 O 12 :Cr 3+ Phosphors for NIR LEDs145Multi-site occupation of Cr3+ toward developing broadband near-infrared phosphors59A General Ammonium Salt Assisted Synthesis Strategy for Cr3+‐Doped Hexafluorides with Highly Efficient Near Infrared Emissions212Sb 3+ ‐Doping in Cesium Zinc Halides Single Crystals Enabling High‐Efficiency Near‐Infrared Emission370Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Ytterbium-Doped CsPbCl 3 Quantum Cutters for Near-Infrared Light-Emitting Diodes94Broadband Short-Wave Infrared Light-Emitting Diodes Based on Cr 3+ -Doped LiScGeO 4 Phosphor147Cr 3+ Activated Garnet Phosphor with Efficient Blue to Far‐Red Conversion for pc‐LED175A highly efficient and suitable spectral profile Cr3+-doped garnet near-infrared emitting phosphor for regulating photomorphogenesis of plants278Visible and Near-Infrared Emission in Ba 3 Sc 4 O 9 :Bi Phosphor: An Investigation on Bismuth Valence Modification32Multi spectral responsive near infrared-II broad emission material and its LED device and imaging research12Controlling Cr3+/Cr4+ concentration in single-phase host toward tailored super-broad near-infrared luminescence for multifunctional applications99LiBAlF6:Cr3+ (B = Ca, Sr) fluoride phosphors with ultra-broad near-infrared emission for NIR pc-LEDs76Enhanced self-activated far-red photoluminescence from Sr3LiSbO6 phosphors by Gd3+ doping for plant growth20Efficient broadband near-infrared phosphor Sr2ScSbO6:Cr3+ for solar-like lighting146Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230Efficient and Broadband LiGaP2O7:Cr3+ Phosphors for Smart Near‐Infrared Light‐Emitting Diodes231The synthesis and luminescent properties of Eu3+ doped Li5La3Ta2O12 garnet phosphor with enhanced red emission and thermally stable12Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP2O7: Cr3+, Yb3+ phosphor80Near-Infrared Emitting Phosphor LaMg 0.5 (SnGe) 0.5 O 3 :Cr 3+ for Plant Growth Applications: Crystal Structure, Luminescence, and Thermal Stability80Near-Infrared Inorganic Nanomaterials for Precise Diagnosis and Therapy26An Extra‐Broadband VIS‐NIR Emitting Phosphor toward Multifunctional LED Applications153Trade‐off Lattice Site Occupancy Engineering Strategy for Near‐Infrared Phosphors with Ultrabroad and Tunable Emission98Luminescence and energy transfer of color-tunable Tb3+/Sm3+co-doped BaZn2(PO4)2 glass-ceramic phosphors17Efficient Ultra‐Broadband Ga 4 GeO 8 :Cr 3+ Phosphors with Tunable Peak Wavelengths from 835 to 980 nm for NIR pc‐LED Application134Multifunctional Near-Infrared (NIR) Phosphors with NIR I and NIR II Luminescence for Biological Detection29A high thermal stability Cr 3+ -doped gallate far red phosphor for plant lighting: structure, luminescence enhancement and application prospect51A Highly Efficient and Broadband Near-Infrared-Emitting Garnet Phosphor for Plant Lighting Realized by Cation Co-Substitution in Lutetium Aluminum Garnet41A mini review of machine learning in inorganic phosphors10A simple and generic post-treatment strategy for highly efficient Cr 3+ -activated broadband NIR emitting phosphors for high-power NIR light sources45Achievement of high efficiency and thermally stable near-infrared phosphors by designing a chromium crystallographic environment for nondestructive testing and night vision15Achieving a tunable and ultra-broadband near-infrared emission in the Ga 2−2 x Zn x Ge x O 3 :Cr 3+ phosphor16Afterglow-intensity-ratio-based temperature sensing using a persistent phosphor23Chemical unit co-substitution enabling broadband and tunable near-infrared emission in garnet-type Lu3Sc2Ga3O12:Cr3+ phosphors22Consequence of optimal bonding on cation ordering and enhanced near-infrared luminescence in Cr 3+ -doped pyroxene oxides49Cr 3+ -Doped double perovskite antimonates: efficient and tunable phosphors from NIR-I to NIR-II78Cr3+ and Eu3+ Co-Activated Al2w3o12 Phosphor for Ratiometric Temperature Sensing0Design and synthesis of a novel blue-emitting CaNaSb 2 O 6 F:Bi 3+ phosphor for optical temperature sensing22Design and tuning Cr 3+ -doped near-infrared phosphors for multifunctional applications via crystal field engineering26Efficient and thermally stable broadband near-infrared emission from near zero thermal expansion AlP 3 O 9 :Cr 3+ phosphors67Efficient and thermally stable broadband near-infrared emission in a garnet Gd 3 In 2 Ga 3 O 12 :Cr 3+ phosphor44Efficient broadband near-infrared emission induced by Nb 5+ substitution for Ta 5+ in GaTa 1− y Nb y O 4 :Cr 3+ phosphor50Efficient Cr 3+ -activated NaInP 2 O 7 phosphor for broadband near-infrared LED applications21Manipulating trap distribution and density by chemical unit cosubstitution for near-infrared persistent luminescent Zn 1−2 x Li x Ga 2+ x O 4 :Cr 3+ solid solutions22Modular high power plant lighting sources based on phosphor–sapphire composites with high thermal conductivity6Synthesis of broadband NIR garnet phosphor Ca 4 ZrGe 3 O 12 : Cr 3+ , Yb 3+ for NIR pc-LED applications148Ultra-Broadband Near-Infrared Gd3mgscga2sio12: Cr, Yb Phosphors: Photoluminescence Properties and Led Applications73Eu2+‐Doped Layered Double Borate Phosphor with Ultrawide Near‐Infrared Spectral Distribution in Response to Ultraviolet–Blue Light Excitation110A broadband near‐infrared Sc 1 − x (PO 3 ) 3 : X Cr 3+ phosphor with enhanced thermal stability and quantum yield by Yb 3+ codoping28Anisometric Ln(III) Complexes with Efficient Near-IR Luminescence2Structural Rigidity Control toward Cr3+-Based Broadband Near-Infrared Luminescence with Enhanced Thermal Stability243Glass‐Crystallized Luminescence Translucent Ceramics toward High‐Performance Broadband NIR LEDs120Novel broadband near-infrared emitting phosphor LiGe2(PO4)3:Cr3+ with tuning and enhancement of NIR emission by codoping Sb5+49Spectral design in Cr3+-doped NIR phosphors via crystal field modulation20Cr3+ and Nd3+ co-activated garnet phosphor for NIR super broadband pc-LED application25Ultra-Broadband and high efficiency Near-Infrared Gd3Zn Ga5-2Ge O12:Cr3+ (x = 0–2.0) garnet phosphors via crystal field engineering222Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP 2 O 7 :Cr 3+ Phosphor for Nondestructive Examination191Broadband NIR-emitting Te cluster-doped glass for smart light source towards night-vision and NIR spectroscopy applications23Luminescence properties and thermal stability of Dy3+/Eu3+co-doped single-component BaZn2(PO4)2 glass-ceramic phosphors32Broadband near-infrared emitting Sr3Sc4O9: Cr3+ phosphors: Luminescence properties and application in light-emitting diodes46Design of a Novel Near-Infrared Luminescence Material Li2Mg3TiO6:Cr3+ with an Ultrawide Tuning Range Applied to Near-Infrared Light-Emitting Diodes111Luminescence properties of Cr3+-doped Al6Ge2O13 broadband near-infrared phosphor21Novel one-dimensional Ga2O3:Cr3+ nanofibers with broadband emission for near infrared LED sources13A near-infrared phosphor doped with Cr3+ towards zero-thermal-quenching for high-power LEDs56Ultra‐Efficient GAGG:Cr 3+ Ceramic Phosphor‐Converted Laser Diode: A Promising High‐Power Compact Near‐Infrared Light Source Enabling Clear Imaging109Luminescence Spectroscopy of 3d 3 (Mn 4+ , Cr 3+ ) Ions in Multiple Octahedral-Site Phosphors20Highly Efficient and Stable Near‐Infrared Broadband Garnet Phosphor for Multifunctional Phosphor‐Converted Light‐Emitting Diodes118Rapid Nondestructive Detection Enabled by an Ultra‐Broadband NIR pc‐LED137Broadband near-infrared emission in the NaInP2O7:Cr3+ phosphor for light-emitting-diode applications50Structural induced tunable NIR luminescence of (Y,Lu)3(Mg,Al)2(Al,Si)3O12: Cr3+ phosphors37Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis251Temperature quenching of Cr3+ in ASc(Si1-xGex)2O6 (A=Li/Na) solid solutions14Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors30Efficient, Stable, and Ultra‐Broadband Near‐Infrared Garnet Phosphors for Miniaturized Optical Applications89Efficient Broadband Near-Infrared CaMgGe 2 O 6 :Cr 3+ Phosphor for pc-LED85Modulation of Thermally Stable Photoluminescence in Cr 3+ -Based Near-Infrared Phosphors201

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  2. Two-Site Occupation for Exploring Ultra-Broadband Near-Infrared Phosphor—Double-Perovskite La 2 MgZrO 6 :Cr 3+

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  3. Broad band emission near-infrared material Mg3Ga2GeO8:Cr3+: Substitution of Ga-In, structural modification, luminescence property and application for high efficiency LED

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  4. Heavy Mn2+ Doped MgAl2O4 Phosphor for High‐Efficient Near‐Infrared Light‐Emitting Diode and the Night‐Vision Application

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  5. Highly efficient and thermally stable Cr3+-activated silicate phosphors for broadband near-infrared LED applications

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  7. Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes

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  8. [INVITED] Near-infrared phosphors and their full potential: A review on practical applications and future perspectives

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  9. Broadband near-infrared (NIR) emission realized by the crystal-field engineering of Y 3−x Ca x Al 5−x Si x O 12 :Cr 3+ ( x = 0–2.0) garnet phosphors

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  10. Structural, luminescence and EPR properties of deep red emitting MgY2Al4SiO12:Cr3+ garnet phosphor

    Journal of Luminescence · 2019-12-17

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  29. Design and control of the luminescence in Cr3+-doped NIR phosphors via crystal field engineering

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  30. Broadband Cr3+-sensitized upconversion luminescence of LiScSi2O6:Cr3+/Er3+

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  31. Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation

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  32. Broadband Near-Infrared Emitting Ca2LuScGa2Ge2O12:Cr3+ Phosphors: Luminescence Properties and Application in Light-Emitting Diodes

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  33. Solid‐State Thin‐Film Broadband Short‐Wave Infrared Light Emitters

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  34. Enticing applications of near‐infrared phosphors: Review and future perspectives

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  35. Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications

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  36. Lead‐Free Halide Double Perovskites: Structure, Luminescence, and Applications

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  37. A highly efficient and thermally stable broadband Cr 3+ -activated double borate phosphor for near-infrared light-emitting diodes

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