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RESEARCH PAPER · Journal of Alloys and Compounds · 2020

Design and control of the luminescence in Cr3+-doped NIR phosphors via crystal field engineering

Tongyu Gao, Weidong Zhuang, Ronghui Liu, Yuanhong Liu, Xiaoxia Chen, Yuan Xue

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Design and control of the luminescence in Cr3+-doped NIR phosphors via crystal field engineeringOriginalGarnet phosphors for white-light-emitting diodes: modification and calculation63Multi-site Cr 3+ occupation-related broadband NIR luminescence in Cr 3+ -doped Li 3 Mg 2 NbO 634Structural and spectroscopic investigation of an efficient and broadband NIR phosphor InBO3: Cr3+ and its application in NIR pc-LEDs106Review—Photoluminescence Properties of Cr3+-Activated Fluoride Phosphors45Review—Photoluminescence Properties of Cr3+-Activated Oxide Phosphors106Li/Na substitution and Yb3+ co-doping enabling tunable near-infrared emission in LiIn2SbO6:Cr3+ phosphors for light-emitting diodes143Effect of R+ (R = Li, Na and K) codoping on the luminescence enhancement of broadband NIR BaZrGe3O9:Cr3+ phosphors for NIR LED26Multi-site occupation of Cr3+ toward developing broadband near-infrared phosphors59Broadband, Enhanced, and Antithermally Quenched Near-Infrared Phosphors via a Cosubstitution Approach33Explore Broadband Near-Infrared Phosphor-Perovskite LaLuO3:Cr3+2Design a rare-earth free broadband NIR phosphor and improve the photoluminescence intensity by alkali charge compensation15A facile surface passivation strategy for Na2SiF6:Mn4+,Li+ phosphors to achieve high moisture resistance and luminescent thermal stability16Cr 3+ -doped borate phosphors for broadband near-infrared LED applications68Novel broadband near-infrared emitting phosphor LiGe2(PO4)3:Cr3+ with tuning and enhancement of NIR emission by codoping Sb5+49Spectral design in Cr3+-doped NIR phosphors via crystal field modulation20Broadband near-infrared emitting Sr3Sc4O9: Cr3+ phosphors: Luminescence properties and application in light-emitting diodes46Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489Structure and tunable broadband near-infrared luminescence of Cr3+ in borophosphate glass23A novel Cr3+-doped stannate far red phosphor for plant lighting: structure evolution, broad-narrow spectrum tuning and application prospect39Dopant and compositional modulation triggered long-wavelength ultra-broadband and tunable NIR emission in MgO: Cr3+ phosphor for NIR spectroscopy applications53Far-red-emitting Cr3+-doped CaAl12O19 phosphors with excellent color purity and good quantum efficiency for plant growth LEDs22Multifunctional optical sensing applications of luminescent ions doped perovskite structured LaGaO3 phosphors in near-infrared spectroscopy50Engineering the local structure of ZnGa2O4: Cr3+ via Mg substitution to realize superior luminescence18A novel far-red phosphors Li2ZnTi3O8:Cr3+ for indoor plant cultivation:Synthesis and luminescence properties55Improvement the near-infrared luminescence properties of double perovskite phosphor La(Mg0.5Sn0.5In0.5Sc0.5)0.5O3:Cr3+ via co-doping Yb3+8A novel extra-broadband visible-NIR phosphor doped with Ce3+ and Cr3+ towards multifunctional advanced applications20Recent Advances in Chromium‐Doped Near‐Infrared Luminescent Materials: Fundamentals, Optimization Strategies, and Applications252[Zn 2+ –Ge 4+ ] co-substitutes [Ga 3+ –Ga 3+ ] to coordinately broaden the near-infrared emission of Cr 3+ in Ga 2 O 3 phosphors17Broadband emitting phosphor Sr 6 Sc 2 Al 4 O 15 :Cr 3+ for near-infrared LEDs31Broadening of the near-infrared emission band of the Mg 2 Al 4 Si 5 O 18 :Cr 3+ phosphor for illumination emission applications12Improving and broadening luminescence in Gd 2− x Al x GaSbO 7 :Cr 3+ phosphors for NIR LED applications76Quantifying rigidity for thermally stable Cr 3+ phosphors9Ultrawide near‐infrared SrHfO 3 :Cr 3+ phosphor with dual emission bands40Ion Substitution Strategy toward High-Efficiency Near-Infrared Photoluminescence of Cs2KIn1–yAlyF6:Cr3+ Solid Solutions54Deep-red to NIR emission of Mn4+ and Cr3+ doped La2MgTiO6 phosphor with multifunctional applications20Broadband near-infrared emitting Cr3+-activated InGaO3(ZnO)4 phosphor and its application in pc-LEDs10Research Progress and Development of Near-Infrared Phosphors52Effect of Ga 3+ ion doping on emission thermal stability and efficiency of MgAl 2 O 4 :Cr 3+ phosphor14Synthesis and luminescence properties of Cr2O3-CaO-GeO2 glass and glass ceramics for broadband NIR-LEDs2Efficient near-infrared luminescence in LiInO2:Cr3+ phosphor for light-emitting-diodes6Gadolinium vacancy induced photoluminescence enhancement of Cr3+-doped Gd3-Ga5O12 near-infrared garnet phosphors for plant cultivation28Broadband near-infrared luminescence in the novel Li3Cs2Sr2B3P6O24:Cr3+ phosphor for NIR pc-LED15Highly efficient and stable near-infrared broadband luminescence in SrGa4O7:Cr3+, Yb3+ phosphor13How to Achieve Excellent Luminescence Properties of Cr Ion‐Doped Near‐Infrared Phosphors103Multi-site incorporation of Cr3+ in CaAl12O1910A novel co-substitution strategy to enhance the luminescence performance of Zn2TiO4:Cr3+ phosphor5Realization of Broadband Near-Infrared Emission with High Thermal Stability in YGa 3 (BO 3 ) 4 : Cr 3+ Borate Phosphor28Achieving the performance luminescence of LaMg0.5Sn0.5O3:Cr3+ by [In3+-Sc3+] co-substitution [Mg2+-Sn4+] and its application to the biodetection and night vision lighting4A post-reduction strategy to enhance near-infrared-II emission from Li 4 SrCa(SiO 4 ) 2 :Cr 4+ phosphors11Efficient and stable near-infrared Y 2 Mg 2 Al 2 Si 2 O 12 :Cr 3+ phosphor: analysis of the luminescence source by a site elimination strategy35Enhanced NIR optical properties of a single-site-occupied ultra-broadband InNbTiO 6 :Cr 3+ phosphor at 965 nm through Ga 3+ doping7High performance NIR-I to NIR-II emission of a Cr 3+ -doped Cs 2 NaLuCl 6 phosphor with an IQE and EQE of up to 92.9% and 60.75%44Long wavelength near-infrared II emitting Na3YSi3O9:x Cr3+ silicate and spectral broadening by multi-site occupancy0Research progress on Fe 3+ -activated near-infrared phosphor18Tailoring Emission Characteristics of Na-Sc Co-Substituted Camgge2o6:Cr3+ Phosphors for Iris Acquisition0Thermal stability and quantum efficiency improvement of Cr 3+ -activated garnet phosphors via regulating A/B sites for near-infrared LED applications9Luminescence improvement of Gd3Ga5O12:Cr3+,Bi3+ NIR phosphor with superior thermal stability for plant cultivation24A highly thermal stable cubic-phase Sc(PO3)3:Cr3+ phosphor with emitting peak at 875 nm17Near-infrared thin-film electroluminescent device from ZnGa2O4:Cr3+ on silicon wafer1Dual substitution of host lattice ions to enhance the luminescence properties of Zn2TiO4:Cr3+ phosphor3Harnessing the brilliance of Cr3+ doped LaAlO3–Al2O3 phosphors with exceptional responsiveness to far-red phytochrome for plant growth LEDs31Cr3+ activated Na3RESi3O9 (RE = Y, Lu, Sc) silicate broadband near-infrared phosphors for luminescence towards NIR-II region via a multi-site occupancy strategy51Broadband near-infrared luminescence in spinel Zn4InSbO8:Cr3+ phosphor for light-emitting diodes application5A Lu3Sc2Ga3O12: Eu3+ red-emitting phosphor with excellent optical properties and thermal stability was obtained by partially replacing Lu3+ with Gd3+ / Y3+7Regulating the broadband near-infrared emission of Eu2+-doped Ca3Sc2Si3O12 phosphors through constructing defect for diversified applications56Tailoring emission characteristics of Na+-Sc3+ co-substituted CaMgGe2O6:Cr3+ phosphors for iris acquisition7Remarkable broadband NIR emission of BaCa2MgSi2O8:Cr3+ phosphors and Eu2+ co-doping modulation7Ruddlesden-Popper type Sr(La,Gd)2Al2O7:Cr3+ layered perovskite new phosphors for NIR pc-LED application7Promising deep‐red emitting Cr3+‐doped SrAl12O19 phosphors for plant growth LEDs9Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review18Broadband near-infrared luminescence in garnet Y3Ga3ZnAO12 (A = Ge, Si):Cr3+ phosphors19Long-Wavelength Broadband Near-Infrared ZrTe3O8:Cr3+, Ti4+ Phosphor of High Luminescence Quantum Yield and Excellent Thermal Stability9Luminescence enhancement of near-infrared Cr3+ doped solid solution phosphor via Al3+ substitution for light-emitting diode applications6Antithermal-Quenching Near-Infrared Emitting Lu2SrAl4SiO12:Cr3+ Garnet-Type Phosphor for High-Resolution Nonvisual Imaging38Phosphor-Converted LED for Iris Acquisition Based on Visible and Near-Infrared Phosphors6Achieving an Improved NIR Performance of Ca4–xSc2xZr1–xGe3O12:Cr3+ via [Sc3+-Sc3+]→[Ca2+-Zr4+]9Broadband photoluminescence toward the NIR II region and stable green ceramic pigments based on a novel NaBaScSi 2 O 7 : x Cr silicate phosphor10Cr 3+ -activated Ca 3 LnGa 3 B 4 O 15 (Ln = Gd, Y)—highly thermally stable NIR-emitting phosphors toward plant lighting application2Dual deep red and far red emitting Cr-doped garnet-perovskite based phosphors with excellent responsiveness to P fr for plant growth LED lighting7Far-red emitting phosphors for plant growth applications: fitted and enhanced via cation substitution of Gd 3+4Reversible luminescence of Bi 3+ ions by X-ray induced crystal field regulation0Long-wavelength broadband near-infrared luminescence of Cr3+ activated tetra-fluoride RbAlF4 and its multifunctional applications14Hydrogen bonding evolution and efficient blue light emission in a series of Zn-based organic–inorganic hybrid metal halide crystals14Effect of Chemical Composition on the Optical Properties of Cr3+ Impurity in A3B5O12 Garnets (A = Lu, Y, Gd, La; B = Al, Ga, Sc)12Structural rigidity control toward Cr3 +-based broadband near-infrared luminescence with enhanced thermal stability and luminescent intensity10Multifunctional Cr3+ Ion-Activated Sr2Sc2B4O11 Broadband Near-Infrared Phosphor with High Luminescence Thermal Stability through the Deformation Constraint6Preparation and luminescent properties of chromium ion doped aluminum borate near-infrared phosphor (Al18B4O33: Cr3+) and its application of broadband near-infrared LED17Broadband near-infrared long persistent luminescence in Cr3+-Doped CaY2Ga4GeO12 phosphors for advanced light source applications4Wideband near-infrared luminescence in Al5BO9: Cr3+, Ga3+ phosphor for near-infrared spectroscopy application4Development status of rare earth luminescence material19Structure, near-infrared broadband luminescence and long afterglow properties in CaGd2Ga4GeO12: Cr3+ garnet phosphor for multifunctional applications3Cr3 + -Cr3+ ion pair and crystal field engineering in magnetoplum type NIR-emitting phosphor for spectroscopic applications3Enhanced Luminescence Performance of Cr-Doped CaMgSi2O6 Phosphor via Alkali Metal Ion Codoping5Unveiling the Origin of Anomalous NIR Emission in Cr-Doped Sr2P2O7: A First-Principles and Experimental Study0Improved NIR luminescence in Y3-Sc Ga3MgSiO12:Cr3+ phosphor via cation substitution for multifunctional spectroscopic applications4Luminescent nano‐structured semiconductor materials via doping engineering: Functional applications toward intelligent optoelectronics and photonics6High-performance multifunctional NIR phosphor K2NaAlF6:Mn4+,Cr3+ for pc-LED and X-ray imaging via efficient energy transfer3Dual‐Strategy Enhancement of NIR Phosphors: Solid Solution Design and Flux Modulation1Recent progress of fluoride phosphors doped with Mn4+ and Cr3+: A review3Enhanced luminescence of La2LiSbO6: Cr3+ by Bi3+ and Yb3+ doping0The multi-strategy-enhanced NIR luminescence of CZGO:Cr, Ba@SiO2-GNRs nanocomposites and their potential applications0Tunable Luminescence and Energy Transfer of Eu 3+ /Tb 3+ Co‐Activated Inorganic Phosphors for Anti‐Counterfeiting and Information Encryption Applications2Review on recent trends in NIR-emitting trivalent chromium (Cr 3+ ) ion-doped phosphors for applications in pc-LEDs0Investigation of Ca3Sc2Ge3O12: Cr3+ broadband near-infrared phosphor with enhanced intensity for blue-LED-pumped NIR light sources0

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  48. Achieving the performance luminescence of LaMg0.5Sn0.5O3:Cr3+ by [In3+-Sc3+] co-substitution [Mg2+-Sn4+] and its application to the biodetection and night vision lighting

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  49. A post-reduction strategy to enhance near-infrared-II emission from Li 4 SrCa(SiO 4 ) 2 :Cr 4+ phosphors

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  50. Efficient and stable near-infrared Y 2 Mg 2 Al 2 Si 2 O 12 :Cr 3+ phosphor: analysis of the luminescence source by a site elimination strategy

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