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RESEARCH PAPER · Angewandte Chemie International Edition · 2025

Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

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Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase MatchingOriginalMultifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates0A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate6CsICl 2 : A Record-Birefringent Inorganic Crystal with Ultrawide Infrared Transparency Enabled by Linear Interhalogen ICl 2 – Units38Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs8Multifactorial directed regulation of anionic units in praseodymium-contained iodates1From (C12H9N2)2TeBr6·2H2O to (C12H9N2)2TeBr6: Dehydration-Driven Crystal Reorganization for Birefringence Optimization6Hydrogen-bond-driven noncentrosymmetric structure formation in π-conjugated (C3H7N6)(IO3): achieving both strong SHG response and wide bandgap5Maximizing the second-harmonic generation response via coordination-induced localization of nonbonding electrons12K2HGa(IO3)6: A new member of iodate families with [M(IO3)6] building blocks0Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure1[ICl 4 ] − : A large anisotropic planar anion group produces giant birefringence2Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy0Solving the long-standing hygroscopicity and thermal stability issues of the nonlinear optical crystal α-LiIO 3 via homogeneous cation exchange0Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence19(C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence0A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials1Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking1Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs0A Pyrazinamide–Iodic Acid Cocrystal Exhibiting Strong Second Harmonic Generation for Nonlinear Optics0

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  1. Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates

    SSRN Electronic Journal · 2025-01-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  2. A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate

    Journal of Molecular Structure · 2025-07-01

    Chunxiang Wu, Y. X. Li, Zhengli Liang, Xiao Mei Jiang, Xiao Jiang, Hui Fang, Lixiang Qin, Xingyuan Bai, Lehui Liu, Lehui Liu, Xingxing Jiang, Xingxing Jiang, Hongming Liu, Hongming Liu

    Read original paper ↗ ·
  3. CsICl 2 : A Record-Birefringent Inorganic Crystal with Ultrawide Infrared Transparency Enabled by Linear Interhalogen ICl 2 – Units

    Journal of the American Chemical Society · 2025-07-21

    Chong‐An Chen, Yang Li, Congcong Jin, Kang Min Ok

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  4. Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs

    European Journal of Inorganic Chemistry · 2025-08-26

    Xuehua Dong, Ling Huang, Guohong Zou

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  5. Multifactorial directed regulation of anionic units in praseodymium-contained iodates

    Journal of Molecular Structure · 2025-09-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Lehui Liu, Xingxing Jiang, Hongming Liu, Hongming Liu

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  6. From (C12H9N2)2TeBr6·2H2O to (C12H9N2)2TeBr6: Dehydration-Driven Crystal Reorganization for Birefringence Optimization

    Inorganic Chemistry · 2025-09-25

    Shiyi Wang, Yingzi Zhang, Yu Yan, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  7. Hydrogen-bond-driven noncentrosymmetric structure formation in π-conjugated (C3H7N6)(IO3): achieving both strong SHG response and wide bandgap

    Science China Chemistry · 2025-10-21

    Yu-Wei Kang, Chun‐Li Hu, Jiang‐Gao Mao

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  8. Maximizing the second-harmonic generation response via coordination-induced localization of nonbonding electrons

    Chemical Science · 2025-11-17

    Jia-Xiang Zhang, A-Lan Xu, Yang Chi, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  9. K2HGa(IO3)6: A new member of iodate families with [M(IO3)6] building blocks

    Journal of Molecular Structure · 2025-11-30

    Runqing Liu, Yuntian Zhao, Huaifeng Wang, Jiming Huang, Shibo Guan, Senlin Leng

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  10. Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure

    Physical review. B./Physical review. B · 2025-12-16

    F. Bodo, E. Kraka, A. Erba

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  11. [ICl 4 ] − : A large anisotropic planar anion group produces giant birefringence

    Chemical Communications · 2026-01-01

    Yi-Chen Liu, Ming‐Zhi Zhang, Chun‐Li Hu, Jiang‐Gao Mao

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  12. Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy

    Dalton Transactions · 2026-01-01

    Meng-Fan Duan, Jiang‐Gao Mao, Bing‐Ping Yang

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  13. Solving the long-standing hygroscopicity and thermal stability issues of the nonlinear optical crystal α-LiIO 3 via homogeneous cation exchange

    Inorganic Chemistry Frontiers · 2026-01-01

    Jiahao Wan, Zhengli Liang, Xiuying Zhang, Hongming Liu, Le Yang, Ping Wang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Qi Wu

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  14. Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence

    Science China Chemistry · 2026-01-04

    Chunmei Huang, Xuan Pang, Fuming M. Li, Shumei Cao, Shilie Pan, Miriding Mutailipu

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  15. (C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence

    Inorganic Chemistry · 2026-01-26

    Zeqiao Yin, Yue Zhang, Yongpan Lin, Xuehua Dong, Yuqiao Zhou, Daojiang Gao, Ling Huang, Liling Cao

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  16. A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials

    Inorganic Chemistry · 2026-03-17

    Jiahang Liu, Miao Zhang, Shizheng Li, Ziyang Wang, Yang Zhao, NianRui Qu, Weiwei Cao, Jianmin Gu, Tianhui Wu

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  17. Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking

    Small · 2026-06-24

    Ying Guo, Guo‐Qiang Wang, Yan Guo, Xiao‐Ming Jiang, B C Liu, Guo‐Cong Guo

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  18. Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs

    Chinese Journal of Chemistry · 2026-08-03

    Linsen Wang, Qianzhen Zhang, Ran An, Zhihua Yang, Yun Yang, Xueyan Wu

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  19. A Pyrazinamide–Iodic Acid Cocrystal Exhibiting Strong Second Harmonic Generation for Nonlinear Optics

    Advanced Optical Materials · 2026-08-31

    Meng‐Fan Duan, Chun‐Li Hu, Jiang‐Gao Mao, Bing‐Ping Yang

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