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RESEARCH PAPER · Inorganic Chemistry · 2022

Organic Cation Modulation Triggered Second Harmonic Response in Manganese Halides with Bright Fluorescence

Yue Guo, Jiajing Wu, Wenlong Liu, Sheng‐Ping Guo

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Organic Cation Modulation Triggered Second Harmonic Response in Manganese Halides with Bright FluorescenceOriginalMultiple Light Source-Excited Organic Manganese Halides for Water-Jet Rewritable Luminescent Paper and Anti-Counterfeiting68Two organic-inorganic manganese(II) halide hybrids containing protonated N,N’-dialkylthioureas with efficient green-emission13Quasi-linear CuX 2 (X = Cl, Br) motif-built hybrid copper halides realizing encouraging nonlinear optical activities28Ultrahigh Photoluminescence Quantum Yield Organic Manganese Halide Scintillator for X-ray Imaging28[C(NH2)2NHNO2][C(NH2)3](NO3)2: A Mixed Organic Cationic Hybrid Nitrate with an Unprecedented Nonlinear-Optical-Active Unit30Unveiling the Superior Optical Properties of Novel Melamine‐Based Nonlinear Optical Material with Strong Second‐Harmonic Generation and Giant Optical Anisotropy74Two Organic–Inorganic Manganese(II) Halide Hybrids Showing Compelling Photo- and Mechanoluminescence as well as Rewritable Anticounterfeiting Printing32α- and β-(C4H5N2O)(IO3)·HIO3: Two SHG Materials Based on Organic–Inorganic Hybrid Iodates14Optical and scintillation properties of hybrid manganese(II) halides with formamidinium and acetamidinium cations1A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials150High-quality white photoluminescence of zero-dimensional hybrid metal halides with multiple optical polyhedral units8Synthesis, crystal structure, optical properties and bactericidal activity of a new organic-inorganic hybrid: Benzyl triethylaminium tetrachloromanganate(II)1Optical and scintillation properties of hybrid manganese( ii ) bromides with formamidinium and acetamidinium cations5Tellurium(IV) Halide Achieving Effective Nonlinear-Optical Activity: The Role of Chiral Ligands and Lattice Distortion17(C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance31SHG-active luminescent thermometers based on chiral cyclometalated dicyanidoiridate( iii ) complexes4Temperature/water triggered reversible emission transition in a one-dimensional Mn( ii )-based metal halide11Three types of promising functional building units for designing metal halide nonlinear optical crystals20Nonlinear Optical Effects of Hybrid Antimony(III) Halides Induced by Stereoactive 5s 2 Lone Pairs and Trimethylammonium Cations23Photoluminescence-Tunable organic phosphine cuprous halides clusters for X-ray scintillators and white light emitting diodes35Bright insights: Examining fluorescence behavior using 5,7‐dibromo‐8‐hydroxyquinoline in organic–inorganic hybrid materials1Near Ultraviolet‐Excitable Cyan‐Emissive Hybrid Copper(I) Halides Nonlinear Optical Crystals with Near‐Unity Photoluminescence Quantum Yield and High‐Efficiency X‐ray Scintillation84Near Ultraviolet‐Excitable Cyan‐Emissive Hybrid Copper(I) Halides Nonlinear Optical Crystals with Near‐Unity Photoluminescence Quantum Yield and High‐Efficiency X‐ray Scintillation14Unlocking the Potential of Organic‐Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications171l -Homoproline-Directed Synthesis of Organic–Inorganic Metal Iodides for Second Harmonic Generation14Chirality and Solvent Coassist the Structural Evolution of Hybrid Manganese Chlorides with Second-Harmonic-Generation Response7Polar Thiazole Derivative-Induced Second Harmonic Response in Hybrid Bismuth Chlorate with Reversible Photochromism9Structural Design of Hybrid Manganese(II) Halides for High Quantum Efficiency and Specific Response to Methanol23Enhancements of the first and second hyperpolarizability of a GMP coordination polymer: crystal structure and computational studies20Near-unity and narrow green emission from a manganese( ii ) bromide for efficient WLEDs and 3D X-ray imaging14Structural and thermal photobehaviour characterizations of (DPA) 2 MnBr 4 : an environmentally friendly organic–inorganic hybrid metal halide perovskite with reversible emission colour switching for anti-counterfeiting and solvent vapour photosensing4Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering39Tunable Luminescence in Mn(II) Hybrid Halides Triggered by Stacking Mode Variation of Organic Moieties6Narrow‐Band Green‐Emitting Manganese (II) Hybrids Single Crystal with Record External Quantum Efficiency Under Blue Light Excitation2Highly Luminescent Hybrid Europium(II) Bromide for Electrically Driven Light‐Emitting Diodes1High‐Degree Organic–Inorganic Disorder Enables Near‐Unity Photoluminescence Quantum Yield and Robust High‐Pressure Luminescence in Manganese Halides1Double Organic‐Ligand Enabled Narrow‐Band Manganese Halides Toward Wide Gamut Displays, Flexible X‐Ray Detection, and 3D Printing Applications10Centimeter-scale chiral zero-dimensional manganese halide hybrids with green emission and second-harmonic generation0Phosphonium tetrachloromanganate( ii ) for efficient information encryption0Halide‐Dependent Photoluminescence and Heavy‐Atom Effects in Low‐Melting Organic–Inorganic Manganese Halides5Engineering Multiple Hydrogen‐Bond Sites With D‐π‐A Motifs for Strong Optical Nonlinearity and Giant Birefringence in Organic‐Inorganic Halides4Engineering Multiple Hydrogen‐Bond Sites With D‐π‐A Motifs for Strong Optical Nonlinearity and Giant Birefringence in Organic‐Inorganic Halides1Lead‐Free Hybrid Halide Perovskite for Piezoelectric Energy Harvesting0Amino Acid-Directed Synthesis of Chiral Manganese Chlorides with One-Dimensional Helical Structures0Lighting Hidden Traces: Rapid Green Synthesis of Zero‐Dimensional Manganese Halide Perovskite for X‐Ray and Fingerprint Imaging0Enhanced Ambient-Air, Thermal, and Photostability of Green-Emitting (PPIP)2MnCl4 for White LEDs and X-ray Imaging0

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    ACS Applied Materials & Interfaces · 2022-12-05

    Chen Sun, Hao Lü, Cheng‐Yang Yue, Honghan Fei, Shaofan Wu, Shuai‐Hua Wang, Xiao‐Wu Lei

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  2. Two organic-inorganic manganese(II) halide hybrids containing protonated N,N’-dialkylthioureas with efficient green-emission

    Journal of Molecular Structure · 2022-12-23

    Nicolay N. Golovnev, Marina A. Gerasimova, Ivan A. Ostapenko, Andrey Zolotov, Мaxim S. Моlokeev

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  3. Quasi-linear CuX 2 (X = Cl, Br) motif-built hybrid copper halides realizing encouraging nonlinear optical activities

    Inorganic Chemistry Frontiers · 2023-01-01

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  4. Ultrahigh Photoluminescence Quantum Yield Organic Manganese Halide Scintillator for X-ray Imaging

    ACS Applied Optical Materials · 2023-02-06

    Sijun Cao, Chen Li, Peng He, Jun’an Lai, Kang An, Miao Zhou, Miao Zhou, Peng Feng, Mi Zhou, Mi Zhou, Xiaosheng Tang

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  5. [C(NH2)2NHNO2][C(NH2)3](NO3)2: A Mixed Organic Cationic Hybrid Nitrate with an Unprecedented Nonlinear-Optical-Active Unit

    Inorganic Chemistry · 2023-03-14

    Dong Yan, Meng-Meng Ren, Qian Liu, Fei‐Fei Mao, Yu Ma, Ru‐Ling Tang, Hongbo Huang, Bingbing Zhang, Xiu‐Du Zhang, Shu‐Fang Li

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  6. Unveiling the Superior Optical Properties of Novel Melamine‐Based Nonlinear Optical Material with Strong Second‐Harmonic Generation and Giant Optical Anisotropy

    Small · 2023-03-27

    Zhiyong Bai, Jihyun Lee, Heewon Kim, Chun‐Li Hu, Kang Min Ok

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  7. Two Organic–Inorganic Manganese(II) Halide Hybrids Showing Compelling Photo- and Mechanoluminescence as well as Rewritable Anticounterfeiting Printing

    Inorganic Chemistry · 2023-03-30

    Qi Yang, Meng-Qing Yu, Zi-Ang Su, Zhen Pei, Dengfeng Peng, Guo Peng, Xiao‐Ming Ren

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  8. α- and β-(C4H5N2O)(IO3)·HIO3: Two SHG Materials Based on Organic–Inorganic Hybrid Iodates

    Inorganic Chemistry · 2023-08-11

    Qianqian Chen, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

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  9. Optical and scintillation properties of hybrid manganese(II) halides with formamidinium and acetamidinium cations

    ChemRxiv · 2023-09-22

    Sergey A. Fateev, Vladislava Yu. Kozhevnikova, Kirill M. Kuznetsov, Daria E. Belikova, Victor Nikolaevich Khrustalev, Eugene Alekseevich Goodilin, Alexey B. Tarasov

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  10. A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials

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  11. High-quality white photoluminescence of zero-dimensional hybrid metal halides with multiple optical polyhedral units

    Journal of Luminescence · 2023-12-09

    Xiangyan Yun, Jingheng Nie, Hanlin Hu, Haizhe Zhong, Denghui Xu, Yumeng Shi, Henan Li

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  12. Synthesis, crystal structure, optical properties and bactericidal activity of a new organic-inorganic hybrid: Benzyl triethylaminium tetrachloromanganate(II)

    Molecular Crystals and Liquid Crystals · 2023-12-18

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  13. Optical and scintillation properties of hybrid manganese( ii ) bromides with formamidinium and acetamidinium cations

    Dalton Transactions · 2023-12-20

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  14. Tellurium(IV) Halide Achieving Effective Nonlinear-Optical Activity: The Role of Chiral Ligands and Lattice Distortion

    Inorganic Chemistry · 2023-12-28

    Shufang Yan, Yue Guo, Wenlong Liu, Sheng‐Ping Guo, Jiajing Wu

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  15. (C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance

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  16. SHG-active luminescent thermometers based on chiral cyclometalated dicyanidoiridate( iii ) complexes

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  17. Temperature/water triggered reversible emission transition in a one-dimensional Mn( ii )-based metal halide

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  18. Three types of promising functional building units for designing metal halide nonlinear optical crystals

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  19. Nonlinear Optical Effects of Hybrid Antimony(III) Halides Induced by Stereoactive 5s 2 Lone Pairs and Trimethylammonium Cations

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    Danping Chen, Zhexin Song, Can Yang, Yaoyao Wei, Guokui Liu, Lingqiang Meng, Qi Wu, Yangyang Dang

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  20. Photoluminescence-Tunable organic phosphine cuprous halides clusters for X-ray scintillators and white light emitting diodes

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  21. Bright insights: Examining fluorescence behavior using 5,7‐dibromo‐8‐hydroxyquinoline in organic–inorganic hybrid materials

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  22. Near Ultraviolet‐Excitable Cyan‐Emissive Hybrid Copper(I) Halides Nonlinear Optical Crystals with Near‐Unity Photoluminescence Quantum Yield and High‐Efficiency X‐ray Scintillation

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  24. Unlocking the Potential of Organic‐Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications

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  25. l -Homoproline-Directed Synthesis of Organic–Inorganic Metal Iodides for Second Harmonic Generation

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  26. Chirality and Solvent Coassist the Structural Evolution of Hybrid Manganese Chlorides with Second-Harmonic-Generation Response

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  27. Polar Thiazole Derivative-Induced Second Harmonic Response in Hybrid Bismuth Chlorate with Reversible Photochromism

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  28. Structural Design of Hybrid Manganese(II) Halides for High Quantum Efficiency and Specific Response to Methanol

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  29. Enhancements of the first and second hyperpolarizability of a GMP coordination polymer: crystal structure and computational studies

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  30. Near-unity and narrow green emission from a manganese( ii ) bromide for efficient WLEDs and 3D X-ray imaging

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  31. Structural and thermal photobehaviour characterizations of (DPA) 2 MnBr 4 : an environmentally friendly organic–inorganic hybrid metal halide perovskite with reversible emission colour switching for anti-counterfeiting and solvent vapour photosensing

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  32. Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering

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  35. Highly Luminescent Hybrid Europium(II) Bromide for Electrically Driven Light‐Emitting Diodes

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  37. Double Organic‐Ligand Enabled Narrow‐Band Manganese Halides Toward Wide Gamut Displays, Flexible X‐Ray Detection, and 3D Printing Applications

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  38. Centimeter-scale chiral zero-dimensional manganese halide hybrids with green emission and second-harmonic generation

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  39. Phosphonium tetrachloromanganate( ii ) for efficient information encryption

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  40. Halide‐Dependent Photoluminescence and Heavy‐Atom Effects in Low‐Melting Organic–Inorganic Manganese Halides

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