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RESEARCH PAPER · Angewandte Chemie · 2023

Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior

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Multi‐Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching BehaviorOriginalPhotoluminescence and Nonlinear Optical Properties of Two Terpyridine-Based Hybrid Zn/Cd Halides25(C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance31Thermally Activated Delayed Fluorescent Binuclear Copper(I) Alkynyl Complexes with Cuprophilic Interactions8Three types of promising functional building units for designing metal halide nonlinear optical crystals20Photoluminescent Cu(I) Assemblies with High‐Temperature Solid‐State Transitions as a New Class of Thermic History Tracers9Remarkable Second Harmonic Generation Response in (C 5 H 6 NO) + (CH 3 SO 3 ) − : Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch50Remarkable Second Harmonic Generation Response in (C5H6NO)+(CH3SO3)−: Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch10Oriented Growth of Highly Emissive Manganese Halide Microrods for Dual‐Mode Low‐Loss Optical Waveguides18Oriented Growth of Highly Emissive Manganese Halide Microrods for Dual‐Mode Low‐Loss Optical Waveguides2Identifying Practical DFT Functionals for Predicting 0D and 1D Organic Metal-Halide Hybrids3Megamerger of porphyrin (phthalocyanine) with azulene-based graphene nanosheets for high-performance nonlinear optical materials5Designing Polar Covalent Hybrid Cadmium‐Based Chalcohalides Ultraviolet Nonlinear Optical Crystal with Strong Optical Anisotropy via Double‐Site Dual FBUs Tailoring25(C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption23Structural Diversity and Tunable Emission in Hybrid Organic–Inorganic Copper(I) Bromides8An ultrastable Cu( i ) cluster exhibiting TADF for ppm-level oxygen detection0Water‐Stable 3D Cu 4 I 4 Framework With Near‐Unity Photoluminescence From Cluster‐Centered Self‐Trapped Excitons1Broad-temperature-range thermoresponse of Cu(I)-based organic-inorganic hybrid metal halides with multimode dynamic luminescence0Water‐Triggered Domino‐Like Phase Transition in a Molecular Ferroelectric1Ratiometric Luminescent Thermo‐Hygrometry, Metal‐Dependent Second Harmonic Generation, and Humidity‐Variable Magnetic Relaxation in a Manganese(II)‐Doped Zinc(II) Molecular Halide0

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  1. Photoluminescence and Nonlinear Optical Properties of Two Terpyridine-Based Hybrid Zn/Cd Halides

    Inorganic Chemistry · 2023-12-12

    Sihan Wang, Zhengli Liang, Xinluan Song, Xin Huang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  2. (C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance

    Inorganic Chemistry Frontiers · 2024-01-01

    Jiajing Wu, Yifan Fu, Wenlong Liu, Sheng‐Ping Guo

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  3. Thermally Activated Delayed Fluorescent Binuclear Copper(I) Alkynyl Complexes with Cuprophilic Interactions

    Chemistry - A European Journal · 2024-02-27

    Xi Zhang, Jia‐Xi Song, Xiaoyong Chang, Kai Li, Yong Chen

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  4. Three types of promising functional building units for designing metal halide nonlinear optical crystals

    Chinese Journal of Structural Chemistry · 2024-04-01

    Jiajing Wu, Ru‐Ling Tang, Sheng‐Ping Guo

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  5. Photoluminescent Cu(I) Assemblies with High‐Temperature Solid‐State Transitions as a New Class of Thermic History Tracers

    Advanced Optical Materials · 2024-06-10

    Adrien Schlachter, Florent Moutier, Raquel Utrera‐Melero, Jana Schiller, Ali Moustafa Khalil, Guillaume Calvez, Manfred Scheer, Karine Costuas, Christophe Lescop

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  6. Remarkable Second Harmonic Generation Response in (C 5 H 6 NO) + (CH 3 SO 3 ) − : Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch

    Angewandte Chemie International Edition · 2024-06-10

    Zi‐Peng Zhang, Xin Liu, Rui‐Xi Wang, Shuang Zhao, Wen‐Jie He, Hongyu Chen, Xue‐Bin Deng, Li‐Ming Wu, Zhengyang Zhou, Ling Chen

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  7. Remarkable Second Harmonic Generation Response in (C5H6NO)+(CH3SO3)−: Unraveling the Role of Hydrogen Bond in Thermal Driven Nonlinear Optical Switch

    Angewandte Chemie · 2024-06-11

    Zi‐Peng Zhang, Xin Liu, Rui‐Xi Wang, Shuang Zhao, Wen‐Jie He, Hongyu Chen, Xue‐Bin Deng, Li‐Ming Wu, Zhengyang Zhou, Ling Chen

    Read original paper ↗ ·
  8. Oriented Growth of Highly Emissive Manganese Halide Microrods for Dual‐Mode Low‐Loss Optical Waveguides

    Angewandte Chemie International Edition · 2024-10-08

    Jin‐Feng Liao, Zhipeng Zhang, Gang Wang, Lei Zhou, Ningbo Yi, Zikang Tang, Guichuan Xing

    Read original paper ↗ ·
  9. Oriented Growth of Highly Emissive Manganese Halide Microrods for Dual‐Mode Low‐Loss Optical Waveguides

    Angewandte Chemie · 2024-10-08

    Jin‐Feng Liao, Zhipeng Zhang, Gang Wang, Lei Zhou, Ningbo Yi, Zikang Tang, Guichuan Xing

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  10. Identifying Practical DFT Functionals for Predicting 0D and 1D Organic Metal-Halide Hybrids

    The Journal of Physical Chemistry C · 2024-10-15

    Yufang He, Md. Sazedul Islam, Jarek Viera, Hanwei Gao, Jianwei Sun, Biwu Ma, Bin Ouyang

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  11. Megamerger of porphyrin (phthalocyanine) with azulene-based graphene nanosheets for high-performance nonlinear optical materials

    Materials Chemistry Frontiers · 2025-01-01

    Ya Qing Zhang, Cuicui Yang, Li Li, Wei Quan Tian

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  12. Designing Polar Covalent Hybrid Cadmium‐Based Chalcohalides Ultraviolet Nonlinear Optical Crystal with Strong Optical Anisotropy via Double‐Site Dual FBUs Tailoring

    Small · 2025-01-26

    Yi‐Fan Fu, Wen‐Dong Yao, Jiajing Wu, Qiao‐Feng Huang, Yumei Zhang, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  13. (C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption

    Chemical Engineering Journal · 2025-03-09

    Chuanying Shen, Chenyi Zhang, Chenyi Zhang, Qiwei Xing, Defu Sun, Kui Wu, Bingbing Zhang, Jiyang Wang, Jiyang Wang, Duanliang Wang

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  14. Structural Diversity and Tunable Emission in Hybrid Organic–Inorganic Copper(I) Bromides

    Inorganic Chemistry · 2025-12-08

    Tamanna Pinky, Kanika Parashar, Dilruba A. Popy, Kowsik Ghosh, Aleksandra D. Valueva, Mario F. Borunda, Svilen Bobev, Bayrammurad Saparov

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  15. An ultrastable Cu( i ) cluster exhibiting TADF for ppm-level oxygen detection

    Chemical Communications · 2026-01-01

    Li-Li Tan, Zong‐Ren Chen, Zhen-Jie Lin, Hong-Jin Zhang, Zhen‐Yu Liang, Xinyi Wu, Wan-Tao Chen, Ling Chen, Jia‐Wen Ye

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  16. Water‐Stable 3D Cu 4 I 4 Framework With Near‐Unity Photoluminescence From Cluster‐Centered Self‐Trapped Excitons

    Advanced Optical Materials · 2026-02-28

    Amarjith V. Dev, Andrzej Sławek, G. S. Suresh Kumar, Ranjith Padinjarepattathodi, Asla Farhana Kovval, Aiswarya Lakshmi, Agnieszka Podborska, Tomasz Mazur, Łukasz Orzeł, Grażyna Stochel, Subrata Das, Konrad T. Szacilowski, Chakkooth Vijayakumar

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  17. Broad-temperature-range thermoresponse of Cu(I)-based organic-inorganic hybrid metal halides with multimode dynamic luminescence

    Science China Materials · 2026-04-01

    Jiaman He, Liwen Kang, Weigang Zeng, Wanxin Shi, Qidan Ling, Qidan Ling

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  18. Water‐Triggered Domino‐Like Phase Transition in a Molecular Ferroelectric

    Advanced Materials · 2026-06-18

    Chen‐Kai Yang, Yong Ai, Xian‐Jiang Song, Huan‐Huan Chen, Xiao‐Gang Chen, Yuan‐Yuan Tang, Yao Zhang, Juanxia Wu, Bing Han, Liming Xie, Ren‐Gen Xiong

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  19. Ratiometric Luminescent Thermo‐Hygrometry, Metal‐Dependent Second Harmonic Generation, and Humidity‐Variable Magnetic Relaxation in a Manganese(II)‐Doped Zinc(II) Molecular Halide

    Angewandte Chemie · 2026-09-22

    Aleksander Hoffman, Jakub J. Zakrzewski, Mikołaj Żychowicz, Sebastian Baś, Shin‐ichi Ohkoshi, Szymon Chorąży

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