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RESEARCH PAPER · Advanced Functional Materials · 2018

Structural Confinement toward Giant Enhancement of Red Emission in Mn2+‐Based Phosphors

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Structural Confinement toward Giant Enhancement of Red Emission in Mn2+‐Based PhosphorsOriginalPhotoluminescence tuning in a novel Bi 3+ /Mn 4+ co-doped La 2 ATiO 6 :(A = Mg, Zn) double perovskite structure: phase transition and energy transfer78Layered Structure Produced Nonconcentration Quenching in a Novel Eu3+-Doped Phosphor185Highly Eu 3+ ions doped novel red emission solid solution phosphors Ca 18 Li 3 (Bi,Eu)(PO 4 ) 14 : structure design, characteristic luminescence and abnormal thermal quenching behavior investigation97(INVITED) A review on the Eu2+ doped β-Ca3(PO4)2-type phosphors and the sites occupancy for photoluminescence tuning17A novel Na 3 La(PO 4 ) 2 /LaPO 4 :Eu blue-red dual-emitting phosphor with high thermal stability for plant growth lighting67A novel red-emitting La 2 CaHfO 6 :Mn 4+ phosphor based on double perovskite structure for pc-WLEDs lighting27Coexistence of self-reduction from Mn 4+ to Mn 2+ and elastico-mechanoluminescence in diphase KZn(PO 3 ) 3 :Mn 2+73Density-functional theory calculations, luminescence properties and fluorescence ratiometric thermo-sensitivity for a novel borate based red phosphor: NaBaSc(BO 3 ) 2 :Ce 3+ ,Mn 2+58Dopant preferential site occupation and high efficiency white emission in K 2 BaCa(PO 4 ) 2 :Eu 2+ ,Mn 2+ phosphors for high quality white LED applications87Intense red photoluminescence and mechanoluminescence from Mn 2+ -activated SrZnSO with a layered structure59Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuning34Multichannel photoluminescence tuning in Eu-doped apatite phosphors via coexisting cation substitution, energy transfer and valence mixing54Non-stoichiometric defect-controlled reduction toward mixed-valence Mn-doped hexaaluminates and their optical applications47Photoluminescence properties and energy transfer in a novel Sr 8 ZnY(PO 4 ) 7 :Tb 3+ ,Eu 3+ phosphor with high thermal stability and its great potential for application in warm white light emitting diodes128Structural Micromodulation on Bi3+-Doped Ba2Ga2GeO7 Phosphor with Considerable Tunability of the Defect-Oriented Optical Properties93Enhance the luminescence properties of Ca14Al10Zn6O35:Ti4+ phosphor via cation vacancies engineering of Ca2+ and Zn2+26Photoluminescence investigation of color-tunable Ca3La6(SiO4)6:Eu2+/Mn2+ phosphors3Luminescence of K2BaCa(PO4)2: Ce3+, Tb3+ dual-emitting phosphor and its application as ratiometric optical thermometer73Tuning of the Compositions and Multiple Activator Sites toward Single-Phased White Emission in (Ca 9– x Sr x )MgK(PO 4 ) 7 :Eu 2+ Phosphors for Solid-State Lighting115A novel orange–red emitting phosphor Sr2LuTaO6:Sm3+ for WLEDs20Detection of Cell Viability via Fluorescence Labeling of Silicate Phosphor with a Low-Temperature Superlong Persistent Luminescence8Effect of Dy3+ and Eu3+ 4f Band Gap States on Luminescence and Energy Transfer in Monoclinic Lutetium Tungstate33Polyhedron Transformation toward Stable Narrow‐Band Green Phosphors for Wide‐Color‐Gamut Liquid Crystal Display201High brightness and precise adjustment of multicolor-tunable luminescence of Lu2GeO5:Tb3+, Eu3+ phosphors for white LEDs14Crystal structure insight aided design of SrGa2Si2O8:Mn2+ with multi-band and thermally stable emission for high-power LED applications43Tunable multicolor luminescent properties of Ca8ZnLa(PO4)7:Ce3+, Mn2+ phosphor via efficient energy transfer37In Situ Inkjet Printing Strategy for Fabricating Perovskite Quantum Dot Patterns255Novel orange–red emitting phosphor Ba2ScNbO6:Eu3+ for WLEDs: synthesis and luminescence properties10Engineering of K3YSi2O7To Tune Photoluminescence with Selected Activators and Site Occupancy117Giant Photoluminescence Improvement and Controllable Emission Adjustment in Bi3+-Activated Ca4ZrGe3O12 Phosphors for High-Quality White Light-Emitting Diodes42Realizing efficient Mn2+ red emission via synergistic sensitization of Eu2+ and Tb3+ for white light-emitting diodes13Tb3+→Eu3+ energy transfer processes in eulytite A3Tb(PO4)3 (A=Sr, Ba) and silico-carnotite Ca3Tb2Z3O12 (Z=Si, Ge) materials doped with Eu3+11Zero‐Thermal Quenching of Mn2+ Red Luminescence via Efficient Energy Transfer from Eu2+ in BaMgP2O7113Heavy Mn2+ Doped MgAl2O4 Phosphor for High‐Efficient Near‐Infrared Light‐Emitting Diode and the Night‐Vision Application268Ca3La6Si6O24:Eu3+ orange-red-emitting phosphor: Synthesis, structure and luminescence properties104Photoluminescence properties of near ultraviolet excited Ca8La2(PO4)6O2:Sm3+ red orange phosphor8Mn4+activated Al2O3red-emitting ceramic phosphor with excellent thermal conductivity38Optical properties of undoped, Eu 3+ doped and Li + co-doped Y 2 Hf 2 O 7 nanoparticles and polymer nanocomposite films66Crystal structure refinement, photoluminescence properties and energy transfer of multicolor tunable Ca2Al2SiO7:Tm3+, Dy3+ for NUV white-light-emitting diodes20A deep-red-emitting Bi3+/Mn4+-doped CaLi6La2Nb2O12 phosphor: Luminescence and energy transfer properties36Thermally stable Na3.6Y1.8(PO4)3:Eu3+ phosphor, luminescent properties and application in WLEDs27A novel efficient single-phase dual-emission phosphor with high resemblance to the photosynthetic spectrum of chlorophyll A and B61A single-phase full-visible-spectrum phosphor for white light-emitting diodes with ultra-high color rendering18Interstitial oxygen defect induced mechanoluminescence in KCa(PO 3 ) 3 :Mn 2+53Investigation of the thermal quenching of two emission centers in Sr 9 MnLi(PO 4 ) 7 :Eu 2+ using time-resolved technique5EPR and Optical Properties of Green Emitting Mn Activated Sr2ZnSi2O7 Phosphors Prepared by Sol–Gel Method5Realizing near-UV light excitation of Mn2+ via efficient energy transfer from Eu2+ for white LEDs12Enhancing Luminescence and Controlling the Mn Valence State of Gd 3 Ga 5– x –δ Al x – y +δ O 12 : y Mn Phosphors by the Design of the Garnet Structure88An Ultraviolet–Visible and Near‐Infrared‐Responded Broadband NIR Phosphor and Its NIR Spectroscopy Application285Tunable Photoluminescence and Energy Transfer Efficiency in β-Ca3(PO4)2-Ca9La(PO4)7:Eu2+, Mn2+ Solid Solution Phosphors Introduced by Emptying Site and Structural Confinement Effect for Solid-State Lighting Application47A novel green-emitting Ni2+-doped Ca-Li hydroxyapatite nanopowders: structural, optical, and photoluminescence properties13Orange-red-emitting CaTi4(PO4)6:Eu3+ phosphor for white LEDs: synthesis and luminescence properties35Tunable Emission Properties of CaTiSiO5:Ce3+, Mn2+ Phosphor via Efficient Energy Transfer15A novel Mn4+-activated Li3CsGe8O18 red phosphor and cation substitution induced photoluminescence improvement11Emission improvement and tunable emission properties of SrZrSi2O7:R (R = Sm3+ and Sm3+/Bi3+) phosphors31Recent Advances in Bismuth Ion‐Doped Phosphor Materials: Structure Design, Tunable Photoluminescence Properties, and Application in White LEDs363Unraveling the Eu2+ → Mn2+ Energy Transfer Mechanism in w-LED Phosphors72Role of energy band structure on the luminescence performance of double perovskite La2LiMO6:Eu3+ (M=Sb, Ta, Nb) red emitting phosphors16Unraveling the Near-Unity Narrow-Band Green Emission in Zero-Dimensional Mn 2+ -Based Metal Halides: A Case Study of (C 10 H 16 N) 2 Zn 1– x Mn x Br 4 Solid Solutions285Photoluminescence properties and thermal stability of Eu3+-activated La7Ta3W4O30 red-emitting phosphors for near-UV-excited w-LEDs14Energy-transfer-induced enhancement of Mn2+-based narrow-band green emission in Sr2(Mg,Mn)Al22O36 phosphor by Eu2+ alloying9Far-red emitting Mg2La3NbO9:Mn4+ powder phosphor: Synthesis and luminescence properties37Thermally Robust and Color-Tunable Blue-Green-Emitting BaMgSi 4 O 10 :Eu 2+ ,Mn 2+ Phosphor for Warm-White LEDs44Photoluminescence and Color-Tunable Properties of Na4Ca4Mg21(PO4)18:Eu2+,Tb3+/Mn2+ Phosphors for Applications in White LEDs29Ultrahigh-Energy-Transfer Efficiency and Efficient Mn2+ Red Emission Realized by Structural Confinement in Ca9LiMn(PO4)7:Eu2+,Tb3+ Phosphor40ZnGa2–yAlyO4:Mn2+,Mn4+ Thermochromic Phosphors: Valence State Control and Optical Temperature Sensing83Multifunctional BaMnLuGdF7: Yb/Er/Ho nanoparticles for in vivo tri-modal imaging6Anti‐Thermal‐Quenching Bi 3+ Luminescence in a Cyan‐Emitting Ba 2 ZnGe 2 O 7 :Bi Phosphor Based on Zinc Vacancy162Hetero-valent substitution strategy toward orange-red luminescence in Bi3+ doped layered perovskite oxide phosphors for high color rendering index white light-emitting diodes105Centella asiatica mediated solution combustion synthesis of a novel Pr3+ doped Lanthanum Oxyfluoride for display and visualization of latent fingerprints and anticounterfeiting applications16Phase-transformation synthesis of Li codoped ZrO2: Eu3+ nanomaterials: Characterization, photocatalytic, luminescent behaviour and latent fingerprint development38Mn 2+ ‐Doped Metal Halide Perovskites: Structure, Photoluminescence, and Application319Structure evolution and tunable magneto‐optical multifunctional property study of novel Ca 18 K 3 Sc 1‐x Sm x (PO 4 ) 14 phosphors7Recent progress of zero-dimensional luminescent metal halides873Research on the quantum confinement effect and enhanced luminescence of red-emitting P 5+ -doped CaAl 12 O 19 :Mn 4+ ,Mg 2+ phosphors17Room temperature synthesis of Tb3+-activated BiF3 green-emitting nanoparticles with high thermal stability for near-ultraviolet white light-emitting didoes5Unveiling the impurity-modulated photoluminescence from Mn 2+ -containing metal chalcogenide semiconductors via Fe 2+ doping10Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146Synthesis, luminescent properties and ab initio study of yellow-emitting Sr8MgGa(PO4)7:Eu2+phosphors for white light-emitting diodes19Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor21Bright and thermal-stable RGB emission realized by Eu2+-Tb3+/Mn2+ energy transfer in Na3SrMg11(PO4)99Photon energy conversion and management in SrAl12O19: Mn2+, Gd3+ for rewritable optical information storage26Structural Confinement for Cr 3+ Activators toward Efficient Near-Infrared Phosphors with Suppressed Concentration Quenching216Lattices selective occupation, optical spectra regulation, and photoluminescence properties of Eu2+ activated Ca9La(PO4)7 phosphor19Design principles for achieving red emission in Eu2+/Eu3+ doped inorganic solids83Bi3+ occupancy rearrangement in K2-xAxMgGeO4 phosphor to achieve ultra-broad-band white emission based on alkali metal substitution engineering38Defect‐Induced Self‐Reduction and Anti‐Thermal Quenching in NaZn(PO3)3:Mn2+ Red Phosphor135In‐doped LiCa 2.98 MgV 3 O 12 rare‐earth‐free phosphor with a high photoluminescence quantum yield of 67.4%9Review on deep red-emitting rare-earth free germanates and their efficiency as well as adaptability for various applications27Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Artificial mimics of light-harvesting organic pigment via a double-perovskite structure (LiLa2SbO6:Bi3+, Mg2+, Mn4+) with single-composition and structure-activity relationship5Improved Photoluminescence Properties of Bi 3+ , Mn 4+ -Codoped Orthorhombic LaGaO 3 Perovskite Phosphor1Charge compensating effect of alkali metal ions R+ (R = Li, Na, K) on the luminescence enhancement of CaAl11.9P0.1O19.1:Mn4+ red-emitting phosphor16Structural Confinement toward Controlling Energy Transfer Path for Enhancing Near-Infrared Luminescence77An Extra‐Broadband VIS‐NIR Emitting Phosphor toward Multifunctional LED Applications153Designing a Polyphosphate Polymorph of CsMg(PO3)3 as Host Lattice for Preparing Single Mn2+-Oxidation Doped Phosphor in the Open Environment18The role of anionic heterovalent [PO 4 ] 3− → [GeO 4 ] 4− substitution on the luminescence properties of inorganic phosphors with the β-Ca 3 (PO 4 ) 2 -type structure: new data based on accurate crystal structure refinement6Multifunctional Ca9NaZn1-Mg (PO4)7:Eu2+ phosphor for full-spectrum lighting, optical thermometry and pressure sensor applications112Variation from Zero to Negative Thermal Quenching of Phosphor with Assistance of Defect States45A novel single-phased white light emitting phosphor with single Eu2+ doped whitlockite structure24A crystal defect led zero thermal quenching β-NaYF 4 : Eu 3+ ,Dy 3+ red emitting phosphor14Achieving highly thermostable red emission in singly Mn 2+ -doped BaXP 2 O 7 (X = Mg/Zn) via self-reduction36Enhancing the luminescence performance of an LED-pumped Mn 4+ -activated highly efficient double perovskite phosphor with A-site defects via local lattice tuning26NUV-pumped red-emitting Ca 9 MnK(PO 4 ) 7 phosphor: energy transfer and charge compensation3Sensitization of Mn2+ Luminescence by Eu2+: A Combined Study Using Optical Spectroscopy and Luminescence Dynamics Simulations12Pressure-driven Eu2+-doped K3Sc(PO4)2: A broad cyan-green emitting phosphor for closing the cyan cavity in solid-state lighting and applying in optical pressure sensor18Luminescence and interstitial-defect-related self-reduction in Mn2+ activated Ba3BP3O12 phosphor13Structural Confinement and Energetic Matching Synergistic Effect toward a High-Energy Transfer Efficiency and a Significant Red Emission Enhancement in a Eu2+,Ln3+ Co-doped Sr9LiMn(PO4)7 Whitlockite Phosphor14Customization of novel double-perovskite (Ca,Sr)2InNbO6:Mn4+ red-emitting phosphors for luminescence lifetime thermometers with good relative sensing sensitivity43Luminescence Enhancement of Red‐Emitting Sr9MnK(PO4)7 Phosphor via Energy Transfer and Charge Compensation3All‐Inorganic Functional Phosphor–Glass Composites by Light Curing Induced 3D Printing for Next‐Generation Modular Lighting Devices18Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489Modulation strategy of manganese valence state in yttrium gallium garnet8Design of a superb Eu 2+ –Mn 2+ co‐doped narrow‐band green phosphor via nearly 100% energy transfer efficiency22Highly efficient Mn–Mn dimer activated phosphors for high-power near-infrared LED application274f → 3d sensitization: a luminescent Eu II –Mn II heteronuclear complex with a near-unity quantum yield12Highly Efficient Narrow‐Band Green Emission in LaZn 1 ‐ x Mn x Al 11 O 19 Magnetoplumbite Phosphors toward White LED Application and Optical Thermometer46Broadband-excited and green-red tunable emission in Eu 2+ -sensitized Ca 8 MnTb(PO 4 ) 7 phosphors induced by structural-confined cascade energy transfer5Highly Efficiency Blue Emissive from Bi3+ Ion Highly Efficiency Blue Emissive from Bi3+ Ions Inzero-Dimensional Organic Bismuth Halide for White Led Applicationfor White Led Application0Single-component full-color emitting Ca 6 Y 2 Na 2 (PO 4 ) 6 F 2 :Eu 2+ ,Tb 3+ ,Mn 2+ phosphors with superior performance: color-tunable and energy transfer study4Temperature dependent luminescence properties of Mn2+ ions for site preference of NaCa2GeO4F: Mn2+, Fe3+ phosphor9A nitriding garnet structure cyan emitting phosphor Ca2(Y, Ce)Hf2(Al, Si)3(O, N)12 with high efficiency and excellent thermal stability10Facile Synthesis of Highly Efficient and Thermally Stable BaAl 4 Sb 2 O 12 :Eu 2+ Phosphor in Air72Structure and luminescence of a high-efficient blue-red-emitting Na2BaMg(PO4)2: Eu2+, Mn2+ phosphor for plant growth LEDs20Unique Self‐Reduction of Transitional Metal Ion in a Borate with Planar [BO3]3− Groups12Synthesis and photoluminescence properties of a novel double perovskite NaGdMgTeO6:Sm3+ red-emitting phosphor for plant growth LEDs and w-LEDs40Unlocking long-lasting green luminescence in manganese-doped magnesium gallate6Intervalence charge transfer of Cr3+-Cr3+ aggregation for NIR-II luminescence165Moderate Trap Engineering for Enhanced Thermal Stability and High Efficiency in a Bi3+-Doped Phosphor45Structural Confinement Induced Near‐Unity Quantum Yield for Single‐Band Ratiometric Thermometry36Zero thermal quenching and suppressed concentration quenching in a highly efficient structure‐confined fluoride near-infrared phosphor20High-temperature preparation of a new Mn2+ phosphor in the open air with red emitting properties4Highly efficiency blue emissive from Bi3+ ions in zero-dimensional organic bismuth halide for white LED applications11Highly efficient blue-green dual-narrow-emission in RbAl 11 O 17 :Eu 2+ ,Mn 2+ toward wide-color-gamut human-centric backlights7Luminescence analysis of heavily Mn 2+ -doped LaMgAl 11 O 19 phosphors: crystallographic site occupation and the formation of Mn 2+ –Mn 2+ dimers18Luminescence center modulation for the synthesis of a narrow-band green phosphor: mechanism and backlighting display application4Near-unity PLQY and high anti-thermal quenching red luminescence from one-dimensional hybrid manganese chloride for efficient and stable white light-emitting diodes23Realizing a broad-scope and high-sensitivity optical thermometer based on dual-emission centers with structure confinement effect-related energy transfer7Structural confinement helps achieve more accurate energy transfer: studies on garnet structural NYGlG:Tb 3+ ,Eu 3+ phosphors17Phosphate phosphors with anti-thermal quenching properties for urban ecological lighting15Efficient and abnormal thermal quenching Sm3+ activated perovskites-type niobate phosphor for plant growth lamp and WLEDs61Resolving multiple emissions of zero-dimensional heterometallic halide hybrid via pressure-triggered antenna effect12Cs2MnCl4:Eu2+: A Near-Violet Light-Triggered Single-Component White Light Emitter20NIR‐II Luminescence With A Recorded 76% EQE Through Energy Extraction From Dark Cr3+40Achieving High Luminescence Thermal Stability in Sm3+-Doped Sc(NbO4)x(TaO4)1–x Orange-Reddish Phosphors by Cosubstitution Component Regulation8BaGa12O19:Cr3+/Mn2+ phosphors for optical thermometry and plant growth lighting applications8Great improvement in intensity and thermal stability of Ca9Ga(XO4)7: Cr3+ near-infrared photoluminescence by next nearest coordination substitution6Recent progress of inorganic phosphors in artificial plant cultivation LEDs46Mn–Mn Dimers Induced Multimode Emitters in Mn2+-Activated AZn4(PO4)3 (A = K, Rb, and Cs) with Unique [Zn4PO12] Chains and [ZnOn] Groups3Mn4+ co-doped double perovskite CaSrLaSbO6: Bi3+ phosphors with multiple luminescent centers for optical temperature sensing and indoor plant cultivation films9

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  1. Photoluminescence tuning in a novel Bi 3+ /Mn 4+ co-doped La 2 ATiO 6 :(A = Mg, Zn) double perovskite structure: phase transition and energy transfer

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  2. Layered Structure Produced Nonconcentration Quenching in a Novel Eu3+-Doped Phosphor

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  3. Highly Eu 3+ ions doped novel red emission solid solution phosphors Ca 18 Li 3 (Bi,Eu)(PO 4 ) 14 : structure design, characteristic luminescence and abnormal thermal quenching behavior investigation

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  4. (INVITED) A review on the Eu2+ doped β-Ca3(PO4)2-type phosphors and the sites occupancy for photoluminescence tuning

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  5. A novel Na 3 La(PO 4 ) 2 /LaPO 4 :Eu blue-red dual-emitting phosphor with high thermal stability for plant growth lighting

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  11. Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuning

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  12. Multichannel photoluminescence tuning in Eu-doped apatite phosphors via coexisting cation substitution, energy transfer and valence mixing

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  13. Non-stoichiometric defect-controlled reduction toward mixed-valence Mn-doped hexaaluminates and their optical applications

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  14. Photoluminescence properties and energy transfer in a novel Sr 8 ZnY(PO 4 ) 7 :Tb 3+ ,Eu 3+ phosphor with high thermal stability and its great potential for application in warm white light emitting diodes

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  15. Structural Micromodulation on Bi3+-Doped Ba2Ga2GeO7 Phosphor with Considerable Tunability of the Defect-Oriented Optical Properties

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  19. Tuning of the Compositions and Multiple Activator Sites toward Single-Phased White Emission in (Ca 9– x Sr x )MgK(PO 4 ) 7 :Eu 2+ Phosphors for Solid-State Lighting

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  21. Detection of Cell Viability via Fluorescence Labeling of Silicate Phosphor with a Low-Temperature Superlong Persistent Luminescence

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  28. Novel orange–red emitting phosphor Ba2ScNbO6:Eu3+ for WLEDs: synthesis and luminescence properties

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  29. Engineering of K3YSi2O7To Tune Photoluminescence with Selected Activators and Site Occupancy

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  30. Giant Photoluminescence Improvement and Controllable Emission Adjustment in Bi3+-Activated Ca4ZrGe3O12 Phosphors for High-Quality White Light-Emitting Diodes

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  32. Tb3+→Eu3+ energy transfer processes in eulytite A3Tb(PO4)3 (A=Sr, Ba) and silico-carnotite Ca3Tb2Z3O12 (Z=Si, Ge) materials doped with Eu3+

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  34. Heavy Mn2+ Doped MgAl2O4 Phosphor for High‐Efficient Near‐Infrared Light‐Emitting Diode and the Night‐Vision Application

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  38. Optical properties of undoped, Eu 3+ doped and Li + co-doped Y 2 Hf 2 O 7 nanoparticles and polymer nanocomposite films

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  42. A novel efficient single-phase dual-emission phosphor with high resemblance to the photosynthetic spectrum of chlorophyll A and B

    Journal of Materials Chemistry C · 2020-01-01

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  43. A single-phase full-visible-spectrum phosphor for white light-emitting diodes with ultra-high color rendering

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  44. Interstitial oxygen defect induced mechanoluminescence in KCa(PO 3 ) 3 :Mn 2+

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