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RESEARCH PAPER · Inorganic Chemistry · 2020

Tunable Photoluminescence and Energy Transfer Efficiency in β-Ca3(PO4)2-Ca9La(PO4)7:Eu2+, Mn2+ Solid Solution Phosphors Introduced by Emptying Site and Structural Confinement Effect for Solid-State Lighting Application

Shiqi Liu, Yujun Liang, Xiangjie Ma, Haoran Li, Weilun Zhang, Dong Tu, Yongjun Chen

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Tunable Photoluminescence and Energy Transfer Efficiency in β-Ca3(PO4)2-Ca9La(PO4)7:Eu2+, Mn2+ Solid Solution Phosphors Introduced by Emptying Site and Structural Confinement Effect for Solid-State Lighting ApplicationOriginalA single-phase full-visible-spectrum phosphor for white light-emitting diodes with ultra-high color rendering18Two‐Step Sol–Gel Synthetic Strategy for Highly Dispersed Eu2+ Luminescence Centers for Tuning Emission5Site Occupation and Spectral Assignment in Eu 2+ -Activated β-Ca 3 (PO 4 ) 2 -Type Phosphors: Insights from First-Principles Calculations21The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs14Two-Site Occupancy Induced a Broad-Band Emission in Phosphor K2YZr(PO4)3:Eu2+ for White-Light-Emitting Diode Applications47Color tunable Ca 8 ZnM(PO 4 ) 7 (M = Lu/Tb, Lu/Eu, Tb/Eu) phosphors: luminescence, energy transfer and thermal stability studies for n-UV white LEDs11Photoluminescence and energy transfer of efficient and thermally stable white-emitting Ca9La(PO4)7:Ce3+, Tb3+, Mn2+ phosphors26Synthesis and luminescent properties of new green Li2Mg1-xSiO4:xMn2+ phosphors16Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146Bright and thermal-stable RGB emission realized by Eu2+-Tb3+/Mn2+ energy transfer in Na3SrMg11(PO4)99Structural Confinement for Cr 3+ Activators toward Efficient Near-Infrared Phosphors with Suppressed Concentration Quenching216Study on the color tunability and energy transfer mechanism in Tm3+/Dy3+ co-doped LiLaSiO4 phosphors21Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction12Regulating photoluminescence behavior by neighboring-cation-size in Sr8CaX(PO4)7: Eu2+ (X = Al and Ga) phosphors for high color rendering solid-state lighting source41The role of anionic heterovalent [PO 4 ] 3− → [GeO 4 ] 4− substitution on the luminescence properties of inorganic phosphors with the β-Ca 3 (PO 4 ) 2 -type structure: new data based on accurate crystal structure refinement6A single-component white-light-emitting fluorescent material with high color rendering index based on resonance energy transfer11Fabrication, Photoluminescence, and Applications of Rare-Earth Ions-Activated Nanophosphors0Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors23Bio-Inspired Degradable Polyethylenimine/Calcium Phosphate Micro-/Nano-Composites for Transient Ultrasound and Photoluminescence Imaging5Tin Bromido Aluminate Networks with Bright Luminescence1Correlating O-deficiency and luminescence property of Tb3+ doped SrO16Design of a narrow-band blue-emitting Rb2Ba3(P2O7)2:Eu2+ phosphor with low thermal quenching for plant growth LEDs22Single-phase white light emission Ca9NaLu0.667(PO4)7: Eu2+, Mn2+ phosphor for the application of WLED37Tuning of photoluminescence by mixing valence of Eu2+/Eu3+ in Ca9Ln(PO4)7 (Ln = Y, La) phosphor for UV light-emitting diodes12Tunable luminescence spectra of solid solution phosphors Gd3(Sb1-Ta )O7:Bi3+ for ultrahigh color rendering index full-spectrum white light-emitting diodes21Synthesis and luminescent properties of a new cyan Ca18Li6-3xYx(PO4)14:0.1Eu phosphors and PVA-based composite films for multifunctional applications11Designing of Eu2+-Activated Single-Phase White-Emitting Phosphor Through Modifying Cationic Sites for High Color Rendering Full-Spectrum Illumination0Thermodynamic modelling assisted three-stage solid state synthesis of high purity β-Ca3(PO4)29Controllable multipoint tunable luminescence of Ca8.96Al1-Gd (PO4)7:0.04Eu2+ based on crystal lattice engineering7Phosphate phosphors with anti-thermal quenching properties for urban ecological lighting15High efficiency white emission in Na3Ba2Ca(PO4)3:Eu2+, Mn2+ phosphors for urban ecological lighting11A novel far-red and near-infrared adjustable phosphor Sr9Al(PO4)7:Cr3+: structure and luminescence properties4Designing of Eu2+-activated single-phase white-emitting phosphor through modifying cationic sites for high color rendering full-spectrum illumination3Luminescent properties of near-infrared-emitting Cr3+-activated beta-Ca3(PO4)24Evaluation of Toxicity and Antibacterial Activity of Sr²⁺-Substituted β-Tricalcium Phosphate Prepared by the Polymeric Precursor Route0Investigation of the Toxicity and Antibacterial Activity of Β-Ca3(Po4)2:Sr2+ Crystals Prepared Using the Polymeric Precursor Method0Multiple Applications of Sr8znin(1- M )Lu M (Po4)7:Eu2+/Mn2+ Through Thermal Stability Adjustment, Spectral Tuning, and Resonance Energy Transfer1Innovations in phosphate phosphors: Bridging structure-property gaps for enhanced luminescence27New insights into structural and spectroscopic characteristics of Cu2+ doped β-Ca3(PO4)2: Correlation between Cu2+ concentration and material properties4Preparation of Ba9Lu2Si6O24:Sm3+ red phosphor and its application in white LEDs16A novel color-tunable β-Ca3(PO4)2-type phosphor with applications in WLEDs and anti-counterfeiting6Modeling and Scaling of Hydroxyapatite Synthesis by Combustion Reaction for Biomedical Applications0Multi-site occupancies and luminescence properties of a novel Ca9NaGd2/3(PO4)7:Eu2+, Mn2+ phosphor for WLEDs and plant growth1Site-selective occupancy-induced full-visible-spectrum emission in single-activator Ca10Na1-yLiy(PO4)7:Eu2 + phosphors for multifunctional applications0Synthesis of red phosphors by doping rare earth elements into CaS derived from flue gas desulfurization gypsum0Site engineering of single-phase β-Ca3(PO4)2-type phosphors via cation substitution for multifunctional luminescence0Multifunctional Ca9Na 1-y Li y Y2/3(PO4)7-Based Phosphors: Li+/Na+ Substitution-Regulated Site-Related Eu2+ Emission and Eu2+→Mn2+ Energy Transfer0

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  2. Two‐Step Sol–Gel Synthetic Strategy for Highly Dispersed Eu2+ Luminescence Centers for Tuning Emission

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  3. Site Occupation and Spectral Assignment in Eu 2+ -Activated β-Ca 3 (PO 4 ) 2 -Type Phosphors: Insights from First-Principles Calculations

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  4. The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs

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  5. Two-Site Occupancy Induced a Broad-Band Emission in Phosphor K2YZr(PO4)3:Eu2+ for White-Light-Emitting Diode Applications

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  6. Color tunable Ca 8 ZnM(PO 4 ) 7 (M = Lu/Tb, Lu/Eu, Tb/Eu) phosphors: luminescence, energy transfer and thermal stability studies for n-UV white LEDs

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  7. Photoluminescence and energy transfer of efficient and thermally stable white-emitting Ca9La(PO4)7:Ce3+, Tb3+, Mn2+ phosphors

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  8. Synthesis and luminescent properties of new green Li2Mg1-xSiO4:xMn2+ phosphors

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  10. Bright and thermal-stable RGB emission realized by Eu2+-Tb3+/Mn2+ energy transfer in Na3SrMg11(PO4)9

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  11. Structural Confinement for Cr 3+ Activators toward Efficient Near-Infrared Phosphors with Suppressed Concentration Quenching

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  13. Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction

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  15. The role of anionic heterovalent [PO 4 ] 3− → [GeO 4 ] 4− substitution on the luminescence properties of inorganic phosphors with the β-Ca 3 (PO 4 ) 2 -type structure: new data based on accurate crystal structure refinement

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  17. Fabrication, Photoluminescence, and Applications of Rare-Earth Ions-Activated Nanophosphors

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  18. Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors

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