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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2019

Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuning

Peipei Dang, Dongjie� Liu, Guogang Li, Sisi Liang, Hongzhou Lian, Mengmeng Shang, Jun Lin

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Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuningOriginalConstructing a single-white-light emission by finely modulating the occupancy of luminescence centers in europium-doped (Ca 1−x Sr x ) 9 Bi(PO 4 ) 7 for WLEDs28Design of core–shell phosphors with tunable luminescence and improved thermal stability by coating with g-C 3 N 418Tunable Photoluminescence and Energy Transfer Efficiency in β-Ca3(PO4)2-Ca9La(PO4)7:Eu2+, Mn2+ Solid Solution Phosphors Introduced by Emptying Site and Structural Confinement Effect for Solid-State Lighting Application47Eu3+-activated Ca3Mo0.2W0.8O6 red-emitting phosphors: A near-ultraviolet and blue light excitable platform for solid-state lighting and thermometer33A dual-excited emission phosphor Eu3+/Eu2+ co-doped Ca4Si2O7F2: Lattice occupancy and luminescence characterization15A new langbeinite-type phosphate K2GdHf(PO4)3: synthesis, crystal structure, band structure and luminescence properties9The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs14Photoluminescence and energy transfer of efficient and thermally stable white-emitting Ca9La(PO4)7:Ce3+, Tb3+, Mn2+ phosphors26Eu3+ doped high-aluminum cast residue prepared EuCaAl3O7/Ca2Al2SiO7 luminescent material with 5D0→7F2/5D0→7F4 double red intense emission14A single-phase full-color phosphor Sr2Ca2La(PO4)3O:Eu2+,Tb3+,Mn2+: Photoluminescence and energy transfer16Li + Ion Induced Full Visible Emission in Single Eu 2+ ‐Doped White Emitting Phosphor: Eu 2+ Site Preference Analysis, Luminescence Properties, and WLED Applications93Theoretical Calculation of Bond Energy, Self-Reduction Phenomenon, and Photoluminescence Properties of Eu/Ce Single-Doped and Codoped Ba2CaB2Si4O14 Phosphors20Controlling Cr3+/Cr4+ concentration in single-phase host toward tailored super-broad near-infrared luminescence for multifunctional applications99Toward white light emission from plasmonic‐luminescent hybrid nanostructures5Blue-light-excitable broadband yellow-emitting CaGd2HfSc(AlO4)3:Ce3+ garnet phosphors for white light-emitting diode devices with improved color rendering index68A single-component white-light-emitting fluorescent material with high color rendering index based on resonance energy transfer11Defects in rare-earth-doped inorganic materials3Eu 2+ as the structural probe in the phase transformation of CMSA by site-selective occupancy and adjustable multimode white luminescence in Ca 2 (Mg 0.5 Al 0.5 )(Si 1.5 Al 0.5 O 7 ) akermanite based on high-aluminum blast furnace slag2Preparation and properties of Eu 2+ /Eu 3+ co-activated Ca 9 Lu(PO 4 ) 7 phosphors for multichannel photoluminescence52Research progress in cyan and blue phosphors14Regulation of Local Site Structures to Stabilize Mixed-Valence Eu2+/3+ under a Reducing Atmosphere for Multicolor Photoluminescence23Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors23Site Occupancies, Electron–Vibration Interaction and Energy Transfer of CaMgSi2O6: Eu2+, Mn2+ Phosphors for Potential Temperature‐Sensing and Anti‐counterfeiting Applications12A potential red-emitting phosphor Na2.5Zr2Si1.5P1.5O12: Eu3+ for WLEDs with excellent thermal stability, color purity and high quantum efficiency41Novel high-saturated red-emitting phosphor Sr9(Mg0.5Mn0.5)K(PO4)7: Eu2+ with great quantum efficiency enhancement by La3+ codoping for white LED application16Design of Eu 2+ ‐activated broadband orange‐emitting phosphors with excellent luminescent performance for warm WLEDs10Site-selective occupation, optical spectrum regulation and photoluminescence property investigation of Eu 2+ -activated blue light-excited yellow-orange emitting phosphors5Abnormal Eu3+ → Eu2+ Reduction in Ca9−xMnxEu(PO4)7 Phosphors: Structure and Luminescent Properties19Energy Transfer Processes in NASICON-Type Phosphates under Synchrotron Radiation Excitation6Tuning of photoluminescence by mixing valence of Eu2+/Eu3+ in Ca9Ln(PO4)7 (Ln = Y, La) phosphor for UV light-emitting diodes12Synthesis and luminescent properties of a new cyan Ca18Li6-3xYx(PO4)14:0.1Eu phosphors and PVA-based composite films for multifunctional applications11Europium Ions Self‐Reduction Benefiting from AlO4/Si(Al)O4 Network Structure for Multimode Optical Thermometry Manometry27Reversible luminescence of Bi 3+ ions by X-ray induced crystal field regulation0Unexpected Reduction of Eu3+ Ions to Eu2+ on a Nanodiamond Surface: An XPS, NMR, EPR, and Photoluminescence Study0

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  1. Constructing a single-white-light emission by finely modulating the occupancy of luminescence centers in europium-doped (Ca 1−x Sr x ) 9 Bi(PO 4 ) 7 for WLEDs

    Journal of Materials Chemistry C · 2020-01-01

    Yaxin Cao, Xicheng Wang, Jianyan Ding, Xiaopeng Zhou, Takatoshi Seto, Yuhua Wang

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  2. Design of core–shell phosphors with tunable luminescence and improved thermal stability by coating with g-C 3 N 4

    Inorganic Chemistry Frontiers · 2020-01-01

    Yingli Zhu, Xiangcheng Li, Boquan Zhu, Yujun Liang

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  3. Tunable Photoluminescence and Energy Transfer Efficiency in β-Ca3(PO4)2-Ca9La(PO4)7:Eu2+, Mn2+ Solid Solution Phosphors Introduced by Emptying Site and Structural Confinement Effect for Solid-State Lighting Application

    Inorganic Chemistry · 2020-02-27

    Shiqi Liu, Yujun Liang, Xiangjie Ma, Haoran Li, Weilun Zhang, Dong Tu, Yongjun Chen

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  4. Eu3+-activated Ca3Mo0.2W0.8O6 red-emitting phosphors: A near-ultraviolet and blue light excitable platform for solid-state lighting and thermometer

    Journal of Luminescence · 2020-03-17

    Junpeng Xue, Hyeon Mi Noh, Sung Heum Park, Byung Chun Choi, Jung Hwan Kim, Jung Hyun Jeong, Peng Du, Weiguang Ran, Mingjun Song

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  5. A dual-excited emission phosphor Eu3+/Eu2+ co-doped Ca4Si2O7F2: Lattice occupancy and luminescence characterization

    Journal of Luminescence · 2020-06-20

    Zefeng Xu, Yuhan Zhu, Pu Fan, Qi Luo, Zongjie He, Xiaoguang Liu, ling yun li

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  6. A new langbeinite-type phosphate K2GdHf(PO4)3: synthesis, crystal structure, band structure and luminescence properties

    Acta Crystallographica Section C Structural Chemistry · 2020-07-22

    Hua Nan, Li Chen, Rui-Juan Zhang, Dan Zhao

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  7. The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs

    Journal of Materials Chemistry C · 2020-12-11

    Jindi Wang, Shuai Huang, Mengmeng Shang, Peipei Dang, Hongzhou Lian, Jun Lin

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  8. Photoluminescence and energy transfer of efficient and thermally stable white-emitting Ca9La(PO4)7:Ce3+, Tb3+, Mn2+ phosphors

    Ceramics International · 2021-01-08

    Xiaoyi Fan, Jiayong Si, Mengjie Xu, Guihua Li, Jiamin Tang, Gemei Cai

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  9. Eu3+ doped high-aluminum cast residue prepared EuCaAl3O7/Ca2Al2SiO7 luminescent material with 5D0→7F2/5D0→7F4 double red intense emission

    Journal of Luminescence · 2021-01-17

    Kailong Qin, Jingbo Sun, Xudong Zhu, Fabin Cao, Weiming Liu, Xingmei Shen, Xingrong Wu, Zhaojin Wu

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  10. A single-phase full-color phosphor Sr2Ca2La(PO4)3O:Eu2+,Tb3+,Mn2+: Photoluminescence and energy transfer

    Journal of Rare Earths · 2021-01-30

    Ju Cheng, Xintian Bian, Zhangyin Zhai, Maryam Sardar, Jian Lü

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  11. Li + Ion Induced Full Visible Emission in Single Eu 2+ ‐Doped White Emitting Phosphor: Eu 2+ Site Preference Analysis, Luminescence Properties, and WLED Applications

    Advanced Optical Materials · 2021-06-17

    Dan Zhang, Xiangting Zhang, Baofeng Zheng, Qi Sun, Zhibo Zheng, Zhan Shi, Yanhua Song, Haifeng Zou

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  12. Theoretical Calculation of Bond Energy, Self-Reduction Phenomenon, and Photoluminescence Properties of Eu/Ce Single-Doped and Codoped Ba2CaB2Si4O14 Phosphors

    The Journal of Physical Chemistry C · 2021-08-09

    Pu Fan, Zefeng Xu, Qi Luo, Zongjie He, Yuhui Chen, Qiqi Miao, Cong Huang, Xiaoguang Liu, Ling Li

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  13. Controlling Cr3+/Cr4+ concentration in single-phase host toward tailored super-broad near-infrared luminescence for multifunctional applications

    Materials Today Chemistry · 2021-09-11

    Hao-Bin Cai, H. Chen, Hao Zhou, Jing Wei Zhao, Zhen Song, Quanlin Liu

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  14. Toward white light emission from plasmonic‐luminescent hybrid nanostructures

    Nanophotonics · 2021-10-16

    Pilar Gómez-Rodríguez, Esther Soria, Jin Yu, A. Caño, Irene Llorente, Alexander Cuadrado, A. Mariscal, Amanda K. Petford-Long, R. Serna, J. Gonzalo

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  15. Blue-light-excitable broadband yellow-emitting CaGd2HfSc(AlO4)3:Ce3+ garnet phosphors for white light-emitting diode devices with improved color rendering index

    Materials Today Chemistry · 2021-11-16

    Wei Li, Nan Ma, Balaji Devakumar, Xiaoyong Huang

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  16. A single-component white-light-emitting fluorescent material with high color rendering index based on resonance energy transfer

    Journal of Materials Chemistry C · 2022-01-01

    Ci’an Xie, Zekun Wang, Haojun Yu, Juyu Yang, Yangai Liu, Lefu Mei

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  17. Defects in rare-earth-doped inorganic materials

    Elsevier eBooks · 2022-01-01

    Jelena Mitrić

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  18. Eu 2+ as the structural probe in the phase transformation of CMSA by site-selective occupancy and adjustable multimode white luminescence in Ca 2 (Mg 0.5 Al 0.5 )(Si 1.5 Al 0.5 O 7 ) akermanite based on high-aluminum blast furnace slag

    Dalton Transactions · 2022-01-01

    Fabin Cao, Ying Xiong, Jian Liu, Jingwen Zhang, Kailong Qin, Jingbo Sun, Weiming Liu, Xingmei Shen, Xingrong Wu, Zhaojin Wu

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  19. Preparation and properties of Eu 2+ /Eu 3+ co-activated Ca 9 Lu(PO 4 ) 7 phosphors for multichannel photoluminescence

    Inorganic Chemistry Frontiers · 2022-01-01

    Wenke Ruan, Mubiao Xie, Qiaoli Yang, Limin Hu, Kangsheng Su

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  20. Research progress in cyan and blue phosphors

    New Journal of Chemistry · 2022-01-01

    Chang Yu, Bin Liu, Zongming Liu, Jinkai Li

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  21. Regulation of Local Site Structures to Stabilize Mixed-Valence Eu2+/3+ under a Reducing Atmosphere for Multicolor Photoluminescence

    Inorganic Chemistry · 2022-01-10

    Shuai Huang, Mengmeng Shang, Yu Yan, Peipei Dang, Jun Lin

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  22. Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors

    Inorganic Chemistry · 2022-02-08

    Ci’an Xie, Lefu Mei, Yangai Liu, Ruiyu Mi, Haojun Yu, Xiaoya Bu, Jian Chen, Juyu Yang, Danyang Liu

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  23. Site Occupancies, Electron–Vibration Interaction and Energy Transfer of CaMgSi2O6: Eu2+, Mn2+ Phosphors for Potential Temperature‐Sensing and Anti‐counterfeiting Applications

    Chemistry - A European Journal · 2022-04-13

    Fang Su, Yunlin Yang, Yiyi Ou, Weijie Zhou, Fengkai Ma, Jianhui Zhang, M.G. Brik, H. Liang

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  24. A potential red-emitting phosphor Na2.5Zr2Si1.5P1.5O12: Eu3+ for WLEDs with excellent thermal stability, color purity and high quantum efficiency

    Journal of Luminescence · 2022-04-15

    Bohuai Shao, Qingyi Lv, Xiaoxi Ma, Ying Li, Xufeng Zhou, Chuang Wang, Yue Wang

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  25. Novel high-saturated red-emitting phosphor Sr9(Mg0.5Mn0.5)K(PO4)7: Eu2+ with great quantum efficiency enhancement by La3+ codoping for white LED application

    Materials Today Chemistry · 2022-12-06

    Weiying Zhou, Jiaqi Fan, Jiabao Luo, Jiahui Wu, Rongda Zhang, Jilin Zhang, Qi Pang, Liya Zhou, Tingting Zhang, Xinguo Zhang

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  26. Design of Eu 2+ ‐activated broadband orange‐emitting phosphors with excellent luminescent performance for warm WLEDs

    Journal of the American Ceramic Society · 2022-12-14

    Wenzhi Sun, Liyan Fan, Xinxin Zhang, Denghu Wei, Mengmeng Jiao, Wenlong Xu, Hongwu Zhang

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  27. Site-selective occupation, optical spectrum regulation and photoluminescence property investigation of Eu 2+ -activated blue light-excited yellow-orange emitting phosphors

    Physical Chemistry Chemical Physics · 2023-01-01

    Wenzhi Sun, Tingting Zhao, Shuya Wang, Denghu Wei, Mengmeng Jiao, Hongwu Zhang

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  28. Abnormal Eu3+ → Eu2+ Reduction in Ca9−xMnxEu(PO4)7 Phosphors: Structure and Luminescent Properties

    Materials · 2023-02-07

    Elena V. Sipina, Dmitry A. Spassky, N. Krutyak, Vladimir A. Morozov, Evgenia S. Zhukovskaya, Alexei А. Belik, Mikhail S. Manylov, Bogdan I. Lazoryak, Dina V. Deyneko

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  29. Energy Transfer Processes in NASICON-Type Phosphates under Synchrotron Radiation Excitation

    Symmetry · 2023-03-18

    N. Krutyak, V. Nagirnyi, Ivo Romet, Dina V. Deyneko, Dmitry A. Spassky

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  30. Tuning of photoluminescence by mixing valence of Eu2+/Eu3+ in Ca9Ln(PO4)7 (Ln = Y, La) phosphor for UV light-emitting diodes

    Optical Materials · 2023-06-27

    Wenke Ruan, Kangle zhou, Huifang Lv, Zhiwei Yang, Mubiao Xie

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  31. Synthesis and luminescent properties of a new cyan Ca18Li6-3xYx(PO4)14:0.1Eu phosphors and PVA-based composite films for multifunctional applications

    Ceramics International · 2023-12-23

    Wenke Ruan, Mubiao Xie, Lanqing Hu, Jieyi Li, Jiayi Zhang, Shuli Gu

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  32. Europium Ions Self‐Reduction Benefiting from AlO4/Si(Al)O4 Network Structure for Multimode Optical Thermometry Manometry

    Laser & Photonics Review · 2024-06-14

    Ruiying Lu, Xinyao Zhang, Yuanyuan Fang, Xue Wu, Mochen Jia, Kai Wang, Jinfei Wu, Qian Li, Zhen Hui Sun

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  33. Reversible luminescence of Bi 3+ ions by X-ray induced crystal field regulation

    Journal of Materials Chemistry C · 2025-01-01

    Linglu Kuang, Zhichao Liu, Yuan Xue, Xinran Wang, Dedan Mu, Hao Song, Yichun Liu, Peng Zhang, Xuhui Xu

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  34. Unexpected Reduction of Eu3+ Ions to Eu2+ on a Nanodiamond Surface: An XPS, NMR, EPR, and Photoluminescence Study

    Nanomaterials · 2026-09-01

    Natalya Froumin, Alexander I. Shames, Anastasia S. Chizhikova, Maxim Uchaev, Alexander M. Panich

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