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RESEARCH PAPER · Inorganic Chemistry · 2018

Two-Dimensional Deep-Ultraviolet Beryllium-Free KBe2BO3F2 Family Nonlinear-Optical Monolayer

Guoyu Yang, Kechen Wu

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Two-Dimensional Deep-Ultraviolet Beryllium-Free KBe2BO3F2 Family Nonlinear-Optical MonolayerOriginalThe linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation26Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals26Two-dimensional nonlinear optical materials predicted by network visualization14NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14A new barium-containing alkali metal silicate fluoride NaBa3Si2O7F with deep-UV optical property12Discovery of a New Family of Polyoxometalate-Based Hybrids with Improved Catalytic Performances for Selective Sulfoxidation: The Synergy between Classic Heptamolybdate Anions and Complex Cations24RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence37Strategies for designing two-dimensional nonlinear optical layers from KBBF and BBO crystals20Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge31Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 117SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences11Two deep-ultraviolet nonlinear optical monolayers obtained by a template-optimized design strategy2Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence37Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB18Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges12Cd4InO(BO3)3: A New Nonlinear Optical Crystal Exhibiting Strong Second Harmonic Generation Effect and Moderate Birefringence2Noncentrosymmetric Rare-Earth Borate Fluoride La2B5O9F3: A New Ultraviolet Nonlinear Optical Crystal with Enhanced Linear and Nonlinear Performance48Decentering the Symmetry via Docking B and F in the KBe2BO3F2-Family Structure0Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units18Stereochemically Active Tin(II)‐Induced Enhancement of Birefringence in SnIISnIV(PO4)2 and SrSn(PO4)PO2(OH)23Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups8Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence9K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0Design of deep-ultraviolet zero-order waveplate materials using LiB3O5 as the template8Theoretical Prediction of Monolayer BeP 2 O 4 H 4 with Excellent Nonlinear‐Optical Properties in Deep‐Ultraviolet Range6From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence2Li 2 CeRbB 18 O 30 and Li 2 Cs 2 SrB 18 O 30 : promising low-birefringence materials for UV and deep UV zero-order waveplates4Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+2Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response2

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  1. The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation

    Optik · 2018-10-25

    Qiaoqiao Zhang, Hahaer Mushahali, Haiming Duan, Ming‐Hsien Lee, Qun Jing

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  2. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  3. From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals

    Inorganic Chemistry Frontiers · 2019-01-01

    Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Hualiang Yu, Shilie Pan

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  4. Two-dimensional nonlinear optical materials predicted by network visualization

    Molecular Systems Design & Engineering · 2019-01-01

    Guoyu Yang, Kechen Wu

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  5. NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates

    Inorganic Chemistry · 2019-03-04

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Sujuan Yu, Shilie Pan

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  6. A new barium-containing alkali metal silicate fluoride NaBa3Si2O7F with deep-UV optical property

    Science China Materials · 2019-07-03

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Tushagu Abudouwufu, Shilie Pan

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  7. Discovery of a New Family of Polyoxometalate-Based Hybrids with Improved Catalytic Performances for Selective Sulfoxidation: The Synergy between Classic Heptamolybdate Anions and Complex Cations

    Inorganic Chemistry · 2019-10-22

    Yin Zhang, Wei‐Dong Yu, Bin Li, Zhengfan Chen, Jun Yan

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  8. RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence

    Chemical Communications · 2020-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  9. Strategies for designing two-dimensional nonlinear optical layers from KBBF and BBO crystals

    Molecular Systems Design & Engineering · 2020-01-01

    Guo-Yu Yang

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  10. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

    Journal of Solid State Chemistry · 2020-07-18

    Wenfeng Zhou, Xiaohui Li, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  11. Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge

    Inorganic Chemistry Frontiers · 2020-10-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  12. Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 11

    Dalton Transactions · 2021-01-01

    Kaitong Liu, Jian Wei Han, Shilie Pan

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  13. SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences

    RSC Advances · 2021-01-01

    Kaitong Liu, Jian Wei Han, Junben Huang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  14. Two deep-ultraviolet nonlinear optical monolayers obtained by a template-optimized design strategy

    Inorganic Chemistry Frontiers · 2021-01-01

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  15. Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence

    Inorganic Chemistry · 2021-01-12

    Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  16. Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB

    Inorganic Chemistry Frontiers · 2022-01-01

    Feixiang Wang, Yun Mo Yang, Congcong Jin, Shilie Pan

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  17. Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges

    New Journal of Chemistry · 2022-01-01

    Jianbang Chen, Jie Zhang, Aixin Zhu, Xuchu Huang

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  18. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Zhikang Chen, Kewang Zhang, Bei Zhang, Jun Zhang

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  19. MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2022-02-02

    Zhikang Chen, Kewang Zhang, Zi‐Jian Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  20. Cd4InO(BO3)3: A New Nonlinear Optical Crystal Exhibiting Strong Second Harmonic Generation Effect and Moderate Birefringence

    Crystals · 2022-02-15

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  21. Noncentrosymmetric Rare-Earth Borate Fluoride La2B5O9F3: A New Ultraviolet Nonlinear Optical Crystal with Enhanced Linear and Nonlinear Performance

    ACS Applied Materials & Interfaces · 2022-04-13

    Xuping Shi, Abudukadi Tudi, Meng Cheng, Fangfang Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  22. Decentering the Symmetry via Docking B and F in the KBe2BO3F2-Family Structure

    Inorganic Chemistry · 2022-10-25

    Qiang Bian, Xueli Zuo, Zhikang Chen, Bingbing Zhang, Feng Peng, Tao Tao

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  23. Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge

    New Journal of Chemistry · 2023-01-01

    Zhiyuan Zhang, Lihan Deng, Die Xu, Mei Ying Hu, Zhencheng Wu, Xin Su, Yineng Huang

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  24. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

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  25. Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units

    Inorganic Chemistry · 2023-02-16

    Mei Hu, Nuerbiye Tuerhong, Zhaohui Chen, Qun Jing, Ming‐Hsien Lee

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  26. Stereochemically Active Tin(II)‐Induced Enhancement of Birefringence in SnIISnIV(PO4)2 and SrSn(PO4)PO2(OH)2

    Chemistry - A European Journal · 2023-05-03

    Lihan Deng, Ruonan Zhang, Jie Zhang, Wenlong Xie, Chunyan Bai, Zhihua Yang, Xueling Hou, Shujuan Han, Shilie Pan

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  27. Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups

    ACS Omega · 2023-06-02

    Yu Dang, Jingdong Yan, Xueling Hou, Hongsheng Shi

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  28. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-09-04

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Zhihua Yang, Xifa Long, Yun Mo Yang

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  29. Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2023-09-08

    Yunjie Bai, Xinyue Wang, Hongbo Huang, Danyang Dou, Cheng Chen, Bingbing Zhang, Ying Wang

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  30. K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response

    New Journal of Chemistry · 2024-01-01

    Aihaimaitijiang Ababaikeri, Xueting Pan, Xueling Hou, Jian Wei Han

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  31. Design of deep-ultraviolet zero-order waveplate materials using LiB3O5 as the template

    Science China Materials · 2024-01-31

    Zhiyuan Zhang, Die Xu, Abudukadi Tudi, Zhihua Yang, Shujuan Han, Shilie Pan

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  32. Theoretical Prediction of Monolayer BeP 2 O 4 H 4 with Excellent Nonlinear‐Optical Properties in Deep‐Ultraviolet Range

    Small · 2024-06-10

    Xin Liu, Li‐Ming Wu, Lei Kang, Zheshuai Lin, Ling Chen

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  33. From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence

    Journal of Alloys and Compounds · 2024-11-26

    Yin-Jie Peng, Yanbo Li, Jun Li, Chao-Qian Li, Baichuan Wang, Zhi Gang Fang, Meihong Duan

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  34. Li 2 CeRbB 18 O 30 and Li 2 Cs 2 SrB 18 O 30 : promising low-birefringence materials for UV and deep UV zero-order waveplates

    Dalton Transactions · 2025-01-01

    Xiao-Ming Wang, Zhiyuan Zhang, Juanjuan Lu, Feng Zhang, Shilie Pan

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  35. Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+

    Journal of Materials Chemistry C · 2025-01-01

    Xintong Cai, Kaitong Liu, Yanhui Zhang

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  36. Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships

    Coordination Chemistry Reviews · 2025-04-06

    Junben Huang, Chenglong Zhang, Siying Chen, Ailijiang Abudurusuli

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  37. LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-12-11

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