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RESEARCH PAPER · Chemistry - A European Journal · 2018

K3B6O9F3: A New Fluorooxoborate with Four Different Anionic Units

Guopeng Han, Guoqiang Q. Shi, Ying Wang, Bingbing Zhang, Shujuan Han, Fangfang Zhang, Zhihua Yang, Shilie Pan

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K3B6O9F3: A New Fluorooxoborate with Four Different Anionic UnitsOriginalBa 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block19From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry33K 3 Bi 2 Cl 5 O 2 (SO 4 ) 2 : A Novel Pentanary Chloride Oxide Sulfate4Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials102Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges16Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11Na 3 B 7 O 11 F 2 : a new sodium-rich fluorooxoborate with a unique [B 14 O 24 F 4 ] ring and a short ultraviolet absorption edge27Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66Ba 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement17BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge38β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units8Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 1219Ba(B 2 OF 3 (OH) 2 ) 2 with well-ordered OH/F anions and a unique B 2 OF 3 (OH) 2 dimer30Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways5Prediction of ternary fluorooxoborates with coplanar triangular units [BO x F 3−x ] x− from first-principles13Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation14Enhanced nonlinear optical functionality in birefringence and refractive index dispersion of the deep-ultraviolet fluorooxoborates123Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method19Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge31Borates: A Rich Source for Optical Materials1089NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers10NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate7From β‐Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic‐Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra10CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy28Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge8MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges12Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence30Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge14Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure6Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27A deep-ultraviolet nonlinear-optical material with a wide bandgap and large static dielectric polarizability coefficient: Na 6 Si 3 F 181From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy4Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation0

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  1. Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations

    Inorganic Chemistry Frontiers · 2018-01-01

    Yanna Chen, Min Zhang, Cong Hu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  2. K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block

    Dalton Transactions · 2018-01-01

    Dequan Jiang, Ying Wang, Bingbing Zhang, Guopeng Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  3. From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry

    Chemistry - A European Journal · 2018-06-04

    Shujuan Han, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  4. K 3 Bi 2 Cl 5 O 2 (SO 4 ) 2 : A Novel Pentanary Chloride Oxide Sulfate

    ChemistrySelect · 2018-07-10

    Zhen‐Tao Lu, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·

  5. Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials

    Chemistry - A European Journal · 2018-07-19

    Guopeng Han, Ying Wang, Bingbing Zhang, Shilie Pan

    Read original paper ↗ ·

  6. Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O

    Inorganic Chemistry · 2018-07-19

    Yahui Li, Hongping Wu, Bingbing Zhang, Zhihua Yang, Guopeng Han, Shilie Pan

    Read original paper ↗ ·

  7. The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges

    Chemistry - A European Journal · 2018-08-07

    Ruru Ma, Yun Mo Yang, Cong Hu, Zhihua Yang, Shilie Pan

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  8. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

    Chemistry - A European Journal · 2018-09-19

    Yanna Chen, Min Zhang, Cong Hu, Hongping Wu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  9. Na 3 B 7 O 11 F 2 : a new sodium-rich fluorooxoborate with a unique [B 14 O 24 F 4 ] ring and a short ultraviolet absorption edge

    Dalton Transactions · 2018-10-18

    Changcheng Tang, Xingxing Jiang, Wenlong Yin, Lijuan Liu, Mingjun Xia, Qian Huang, Gaomin Song, Xiaoyang Wang, Zheshuai Lin, Chuangtian Chen

    Read original paper ↗ ·

  10. Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response

    Chemistry - A European Journal · 2018-11-08

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Zhihua Yang, Shilie Pan

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  11. Ba 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement

    Chemical Communications · 2019-01-01

    Yahui Li, Hongwei Yu, Guopeng Han, Hao Li, Zhihua Yang, Shilie Pan

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  12. BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge

    Chemistry - A European Journal · 2019-04-01

    Chunmei Huang, Fangfang Zhang, Hao Li, Zhihua Yang, Haohai Yu, Shilie Pan

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  13. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

    Chemistry - A European Journal · 2019-06-18

    Shujuan Han, Chunmei Huang, Abudukadi Tudi, Shuaishuai Hu, Zhihua Yang, Shilie Pan

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  14. Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units

    Inorganic Chemistry Frontiers · 2019-10-09

    Xiaobo Pan, Hongping Wu, Shichao Cheng, Zhengping Wang

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  15. Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 12

    Dalton Transactions · 2019-12-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  16. Ba(B 2 OF 3 (OH) 2 ) 2 with well-ordered OH/F anions and a unique B 2 OF 3 (OH) 2 dimer

    Chemical Communications · 2020-01-01

    Minqiang Gai, Ying Wang, Tinghao Tong, Liying Wang, Zhihua Yang, Xin Hua Zhou, Shilie Pan

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  17. Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways

    Dalton Transactions · 2020-01-01

    Mengmeng Ding, Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  18. Prediction of ternary fluorooxoborates with coplanar triangular units [BO x F 3−x ] x− from first-principles

    Dalton Transactions · 2020-01-01

    Zhonglei Wei, Wenyao Zhang, Hao Zeng, Hao Li, Zhihua Yang, Shilie Pan

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  19. Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 19

    New Journal of Chemistry · 2020-01-01

    Xiaowen Niu, Li Wang

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  20. A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation

    Chemistry - A European Journal · 2020-01-16

    Shichao Cheng, Miriding Mutailipu, Zhihua Yang, Shilie Pan

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  21. Enhanced nonlinear optical functionality in birefringence and refractive index dispersion of the deep-ultraviolet fluorooxoborates

    Science China Materials · 2020-03-20

    Zhihua Yang, Abudukadi Tudi, Bing‐Hua Lei, Shilie Pan

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  22. Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method

    Chemistry - A European Journal · 2020-09-25

    Chunmei Huang, Fangfang Zhang, Shichao Cheng, Zhihua Yang, Hao Li, Shilie Pan

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  23. Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge

    Inorganic Chemistry Frontiers · 2020-10-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  24. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  25. NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers

    New Journal of Chemistry · 2021-01-01

    Zilong Chen, Junwei Feng, Bin Dai, Feng Yu

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  26. NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate

    Chemistry - An Asian Journal · 2021-08-20

    Rui Zhang, Jie Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  27. From β‐Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic‐Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra

    Chemistry - A European Journal · 2021-11-24

    Jiahao Jiao, Wenqi Jin, Min Zhang, Zhiyong Guo, Zhihua Yang, Shilie Pan

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  28. CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy

    Journal of Materials Chemistry C · 2022-01-01

    Yuchen Yan, Jiahao Jiao, Chenchen Tu, Min Zhang, Zhihua Yang, Shilie Pan

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  29. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Zhikang Chen, Kewang Zhang, Bei Zhang, Jun Zhang

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  30. Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Jianlong Huang, Chengfa Wu, Jianbang Chen, Zhiyong Guo, Wenjuan Ma, Feng Yu, Bin Dai

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  31. MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2022-02-02

    Zhikang Chen, Kewang Zhang, Zi‐Jian Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  32. Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence

    Advanced Optical Materials · 2022-11-17

    Ziting Yan, Dongdong Chu, Min Zhang, Zhihua Yang, Shilie Pan

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  33. Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation

    Materials Today Chemistry · 2023-01-01

    Huanhuan Cheng, Z. Li, Fromenteze Zhang, Zhihua Yang, Shilie Pan

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  34. BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-01-04

    Jinbin Fan, Mengfan Wu, Bingliang Cheng, Jian Wei Han

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  35. Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-03

    Hongkang Su, Ziting Yan, Xueling Hou, Min Zhang

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  36. Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge

    Science China Chemistry · 2023-02-23

    Huan Pei, Xuefei Wang, Jie Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  37. Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure

    Inorganic Chemistry · 2023-05-09

    Shuzhao Huang, Liang Zhu, Ivan A. Kruglov, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  38. Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures

    Chemistry of Materials · 2023-07-07

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Fangfang Zhang, Zilong Chen, Xueling Hou, Zhihua Yang, Shilie Pan

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  39. A deep-ultraviolet nonlinear-optical material with a wide bandgap and large static dielectric polarizability coefficient: Na 6 Si 3 F 18

    Materials Advances · 2024-01-01

    Changcheng Tang, Xingxing Jiang, Xiuyu Wu, Yuechen Gong, Chao Yang, Ruixin Guo, Panpan Wang, Yongming Huang, Dayu Zhou, H Chen, Zheshuai Lin

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  40. From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

    Inorganic Chemistry · 2024-11-06

    Ruyi Niu, Qing‐Yu Liu, Minqiang Gai, Zhihua Yang, Shujuan Han, Shilie Pan

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  41. Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)

    Chemistry of Materials · 2024-11-25

    Huan Pei, Luyong Zhang, Huanhuan Cheng, Shi‐Bin Wang, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  42. Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation

    Coordination Chemistry Reviews · 2026-05-20

    Wenqing Sun, Congwei Xie, Xueling Hou, Zhihua Yang, Shilie Pan

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