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RESEARCH PAPER · ACS Applied Energy Materials · 2020

La0.6Sr0.4Cr0.8Co0.2O3Perovskite Decorated with Exsolved Co Nanoparticles for Stable CO2Splitting and Syngas Production

Alfonso J. Carrillo, Kun Joong Kim, Zachary David Hood, Alexander H. Bork, Jennifer L. M. Rupp

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La0.6Sr0.4Cr0.8Co0.2O3Perovskite Decorated with Exsolved Co Nanoparticles for Stable CO2Splitting and Syngas ProductionOriginalLow temperature methane conversion with perovskite-supported exo / endo -particles42CO2-free conversion of CH4 to syngas using chemical looping79Toward Controlling Filament Size and Location for Resistive Switches via Nanoparticle Exsolution at Oxide Interfaces44Chlorine-promoted perovskite nanocomposite as a high-performance oxygen transfer agent for chemical looping methane-assisted CO2 splitting6Recent advances during CH4 dry reforming for syngas production: A mini review165Nanoparticle Ex-solution for Supported Catalysts: Materials Design, Mechanism and Future Perspectives181A -site deficient chromite with in situ Ni exsolution as a fuel electrode for solid oxide cells (SOCs)51Defect engineering of oxide perovskites for catalysis and energy storage: synthesis of chemistry and materials science335Evaluating the Redox Behavior of Doped Ceria for Thermochemical CO 2 Splitting Using Time-Resolved Raman Spectroscopy34Progress of Exsolved Metal Nanoparticles on Oxides as High Performance (Electro)Catalysts for the Conversion of Small Molecules120Intensification of Chemical Looping Processes by Catalyst Assistance and Combination14Emergence and Future of Exsolved Materials214Chemical looping-A perspective on the next-gen technology for efficient fossil fuel utilization106Exploring the Stability of Fe–Ni Alloy Nanoparticles Exsolved from Double-Layered Perovskites for Dry Reforming of Methane46Ca- and Ga-Doped LaMnO3 for Solar Thermochemical CO2 Splitting with High Fuel Yield and Cycle Stability35Enhanced performance of CH4 dry reforming over La0.9Sr0.1FeO3/YSZ under chemical looping conditions43Synthesis of stimuli responsive nanoparticles for electrocatalysis0Highly Active and Anticoke Ni/CeO2 with Ultralow Ni Loading in Chemical Looping Dry Reforming via the Strong Metal–Support Interaction84High-throughput oxygen chemical potential engineering of perovskite oxides for chemical looping applications110Ru-promoted perovskites as effective redox catalysts for CO 2 splitting and methane partial oxidation in a cyclic redox scheme9In Situ Exsolution Catalyst: An Innovative Approach to Develop Highly Selective and Sensitive Gas Sensors19Promoting Ex‐Solution from Metal–Organic‐Framework‐Mediated Oxide Scaffolds for Highly Active and Robust Catalysts39Highly active and stable catalyst with exsolved PtRu alloy nanoparticles for hydrogen production via commercial diesel reforming51Review of chemical looping process for carbonaceous feedstock Conversion: Rational design of oxygen carriers27Redox-manipulated RhOx nanoclusters uniformly anchored on Sr2Fe1.45Rh0.05Mo0.5O6–δ perovskite for CO2 electrolysis13Redox Cycles, Active Materials, and Reactors Applied to Water and Carbon Dioxide Splitting for Solar Thermochemical Fuel Production: A Review45Tuning Ternary Alloyed Nanoparticle Composition and Morphology by Exsolution in Double Perovskite Electrodes for CO 2 Electrolysis48Oxide nanoparticle exsolution in Lu-doped (Ba,La)CoO 38Recent advances in exsolved perovskite oxide construction: exsolution theory, modulation, challenges, and prospects86Tuning reduction conditions to understand and control Ni exsolution from Sr 0.8 La 0.1 Ca 0.1 Ti 0.94 Ni 0.06 O 3− δ14Chemical looping-based energy transformation via lattice oxygen modulated selective oxidation144Impact of lattice properties on the CO2 splitting kinetics of lanthanide-doped cerium oxides for chemical looping syngas production9Roadmap on exsolution for energy applications71Perovskite Catalysts for Biomass Valorization62Influence of Sr-Site Deficiency, Ca/Ba/La Doping on the Exsolution of Ni from SrTiO339Effect of low-loading of Ni on the activity of La0.9Sr0.1FeO3 perovskites for chemical looping dry reforming of methane30Co nanoparticles decorated with in-situ exsolved oxygen-storage CeO2 for an efficient and stable electrolysis of pure CO28Exsolution-enhanced reverse water-gas shift chemical looping activity of Sr2FeMo0.6Ni0.4O6-δ double perovskite39The Potential of Chemical Looping Solutions for Direct Methane Conversion1Solar-driven thermochemical conversion of H2O and CO2 into sustainable fuels35Thermochemical splitting of CO2 on perovskites for CO production: A review20New trends in nanoparticle exsolution45Understanding the evolution of ternary alloyed nanoparticles during reversible exsolution from double perovskite oxides17Effects of lanthanide doping on the electrode properties and exsolution behavior of A-site deficient Sr1.9Fe1.3Ni0.2Mo0.5O6-δ double perovskites14Concurrent Amorphization and Nanocatalyst Formation in Cu‐Substituted Perovskite Oxide Surface: Effects on Oxygen Reduction Reaction at Elevated Temperatures15Boosted Solar Thermochemical Low‐Temperature CO 2 Splitting On Pt/CeO 2 by Interface Catalysis1Squeezing Out Nanoparticles from Perovskites: Controlling Exsolution with Pressure21Experimental investigation of La0.6Sr0.4FeO3- pellets as oxygen carriers in a counter-current packed-bed reactor for efficient chemical looping CO2 splitting15Critical assessment of the exsolution process in Cu-doped SrTiO 3 by a combined spectroscopic approach11Evaluating oxide nanoparticle exsolution on A-site deficient PrBaCo2O6-δ electrodes7Tailoring oxide nanoparticle exsolution in La0.5Ba0.5-yCo1-xFexO3-δ2Advances in perovskite membranes for carbon capture & utilization: A sustainable approach to CO2 emissions reduction – A review12Surface reconstruction of versatile perovskites via in situ nanoparticle engineering for solid oxide cells4Dry Reforming of Methane over Nickel‐Based Catalyst on Mg‐Stabilized Zirconia Support: A Pathway to Sustainable Syngas Production3Mechanistic elucidation of cascade CO2 hydrogenation enabled by Cu–Fe interfaces and oxygen vacancies2Unveiling new, unique structural and transport effects in Cu-doped (La0.2Sr0.8)1-xTiO3 system1LaFe1-xMnxO3−δ as effective redox catalysts for CO2 splitting and methane partial oxidation in a cyclic redox scheme4Enhanced syngas production from CH4-CO2 chemical looping over A-site Ce3+-modified brownmillerite oxygen carriers4Synergistic A/B-site engineering of brownmillerite Ca2Fe2O5 oxygen carriers for high-purity syngas production via chemical looping reforming5In situ exsolved Fe-Ni nanoparticles on Pr0.8La0.2Fe Ni1-O3- perovskite as high-performance anode for solid oxide fuel cells3Ni-exsolved nanoparticles from a titanium-based perovskite as efficient active sites for the OER in alkaline media0Proton and O vacancy hopping, dopant clustering, and octahedral tilt transitions in exsolved BaCe0.7Zr0.1Y0.15Ni0.05O3−δ2Sr2Fe1.5Mo0.5O6-δ double perovskite for chemical-looping hydrogen production from water splitting1Chemical Looping Reforming of Methane Coupled with CO2 Splitting Using a Sol–Gel-Derived LaFe0.4Co0.6O3 Oxygen Carrier0

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  4. Chlorine-promoted perovskite nanocomposite as a high-performance oxygen transfer agent for chemical looping methane-assisted CO2 splitting

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  5. Recent advances during CH4 dry reforming for syngas production: A mini review

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  9. Evaluating the Redox Behavior of Doped Ceria for Thermochemical CO 2 Splitting Using Time-Resolved Raman Spectroscopy

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  15. Ca- and Ga-Doped LaMnO3 for Solar Thermochemical CO2 Splitting with High Fuel Yield and Cycle Stability

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  17. Synthesis of stimuli responsive nanoparticles for electrocatalysis

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  18. Highly Active and Anticoke Ni/CeO2 with Ultralow Ni Loading in Chemical Looping Dry Reforming via the Strong Metal–Support Interaction

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  48. Experimental investigation of La0.6Sr0.4FeO3- pellets as oxygen carriers in a counter-current packed-bed reactor for efficient chemical looping CO2 splitting

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  50. Evaluating oxide nanoparticle exsolution on A-site deficient PrBaCo2O6-δ electrodes

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