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RESEARCH PAPER · Journal of Materials Chemistry A · 2018

Thermally driven in situ exsolution of Ni nanoparticles from (Ni, Gd)CeO 2 for high-performance solid oxide fuel cells

Jeiwan Tan, Daehee Lee, Jihoon Ahn, Bokyung Kim, Joosun Kim, Jooho Moon

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Thermally driven in situ exsolution of Ni nanoparticles from (Ni, Gd)CeO 2 for high-performance solid oxide fuel cellsOriginalNanostructured Materials and Interfaces for Advanced Ionic Electronic Conducting Oxides51Formation and Properties of Ni–Ce–La–O Catalysts of Reforming14In situ exsolution of PdO nanoparticles from non-stoichiometric LaFePd0.05O3+δ electrode for impedancemetric NO2 sensor33CeO2 nanorods supported M–Co bimetallic oxides (M = Fe, Ni, Cu) for catalytic CO and C3H8 oxidation69A highly active Ni/Ce 0.8 Sm 0.2 O 1.9 anode catalyst with a three-dimensionally ordered macroporous structure for solid oxide fuel cells21Progress and Opportunities for Exsolution in Electrochemistry26In situ embedding of CoFe nanocatalysts into Sr3FeMoO7 matrix as high-performance anode materials for solid oxide fuel cells53In Situ Exsolved Metal Nanoparticles: A Smart Approach for Optimization of Catalysts163GENESIS AND STRUCTURAL PROPERTIES OF (Ce1–xMx0.8Ni0.2Oy (M = La, Mg) OXIDES9Surface decorated La0.43Ca0.37Ni0.06Ti0.94O3−d as an anode functional layer for solid oxide fuel cell applications6Nanoparticle Ex-solution for Supported Catalysts: Materials Design, Mechanism and Future Perspectives181Emergence and Future of Exsolved Materials214Degradation Mechanisms of Metal-Supported Solid Oxide Cells and Countermeasures: A Review67Fast Solution Synthesis of NiO-Gd0.1Ce0.9O1.95 Nanocomposite via Different Approach: Influence of Processing Parameters and Characterizations11In-situ generation of platinum nanoparticles on LaCoO3 matrix for soot oxidation28Probing into the In-Situ Exsolution Mechanism of Metal Nanoparticles from Doped Ceria Host6Enhancement of hydrogen production using Ni catalysts supported by Gd-doped ceria15Enhanced Ionic Conductivity and Durability of Novel Solid Oxide Fuel Cells by Constructing a Heterojunction Based on Transition and Rare Earth Metal Co-doped Ceria22Doped ceria with exsolved Fe 0 nanoparticles as a Sr-free cathode for CO 2 electrolysis in SOECs at reduced temperatures38In Situ Precipitated Nico Nanoparticles Synergize with Metaborate to Promote Hydrogen Evolution and Couple with Urea Oxidation to Reduce Overall Water Splitting Potential13Slightly ruthenium doping enables better alloy nanoparticle exsolution of perovskite anode for high-performance direct-ammonia solid oxide fuel cells81Recent progress in design and fabrication of SOFC cathodes for efficient catalytic oxygen reduction95Ultrafast Ambient-Air Exsolution on Metal Oxide via Momentary Photothermal Effect36Ni-doped CeO2 nanoparticles to promote and restore the performance of Ni/YSZ cathodes for CO2 electroreduction25Oxide nanoparticle exsolution in Lu-doped (Ba,La)CoO 38Catalytic Activity of Ni Based Materials Prepared by Different Methods for Hydrogen Production via the Water Gas Shift Reaction11Exsolved materials for CO2 reduction in high-temperature electrolysis cells32Operando X-ray Diffraction Study of Mn–Ce Catalysts for CO Oxidation0OPERANDO X-Ray Diffraction Study of Mn–Ce Catalysts for CO Oxidation0Achieve a high electrochemical oxidation activity by a self-assembled cermet composite anode with low Ni content for solid oxide fuel cells1Facile Construction of Nanostructured Cermet Anodes with Strong Metal–Oxide Interaction for Efficient and Durable Solid Oxide Fuel Cells30Nanotechnologies in ceramic electrochemical cells84New trends in nanoparticle exsolution45Phase Relationship and Ni Solubility in Nanoparticles of Ce 0.9 Zr 0.1 O 22Dielectric Barrier Plasma Discharge Exsolution of Nanoparticles at Room Temperature and Atmospheric Pressure13In situ ex-solution of CoFeRu solid solution nanoparticles from non-stoichiometric (La0.8Sr0.2)0.9Co0.1Fe0.8Ru0.1O3−δ perovskite for hydrogen gas sensor3In situ reconstruction of multi-phase heterostructured anodes for efficient and durable solid oxide fuel cells10In-situ dual-exsolved nanometal anchoring on heterogeneous composite nanofiber using as SOEC cathode for direct and highly efficient CO2 electrolysis24Reviewing metal supported solid oxide fuel cells for efficient electricity generation with biofuels for mobility38Peculiarities of the formation of catalysts, based on γ-Al2O3 modified with Ca2+ and Ni2+ ions, highly active and resistant to carbonization in dry reforming of methane into syngas reaction: relationship between physical-chemical and catalytic properties0Recent advances and future prospects in exsolution technology for solid oxide cells20Nanofabrication technologies for low-temperature solid oxide cells: a comprehensive review of techniques, challenges, and future perspectives15Features of the Formation of Catalysts on the Basis of γ-Al2O3 Modified with Ca2+ and Ni2+ Ions Highly Active and Resistant to Carbonization in the Dry Reforming of Methane into Synthesis Gas: Relationship between Physicochemical and Catalytic Properties0Concurrent enhancement of electron and mass transport through microstructural engineering for SOC fuel electrodes0Unraveling Sulfur Tolerance Mechanisms in Samarium-Doped Ceria-NiRh Catalysts for Solid Oxide Fuel Cells1Oxygen vacancies regulation via in situ dual-exsolution: Constructing self-assembled Fe-based perovskite cathodes0Electro-chemo-mechanically Driven Ni Exsolution from (Pr,Ce,Ni)O 2−δ : Controlled Nucleation Density and Enhanced Electrode Kinetics0Phase-tunable exsolution approaches to energy-functional nanostructured metal-based hybrid materials: synthesis, application, and perspective3Advances in Ceria‐Based Fuel Electrodes for Solid Oxide Cells: Reaction Mechanisms, Performance, Stability, and Future Directions With Focus on Nickel–Gadolinium‐Doped Ceria1

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  2. Formation and Properties of Ni–Ce–La–O Catalysts of Reforming

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  3. In situ exsolution of PdO nanoparticles from non-stoichiometric LaFePd0.05O3+δ electrode for impedancemetric NO2 sensor

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  4. CeO2 nanorods supported M–Co bimetallic oxides (M = Fe, Ni, Cu) for catalytic CO and C3H8 oxidation

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  5. A highly active Ni/Ce 0.8 Sm 0.2 O 1.9 anode catalyst with a three-dimensionally ordered macroporous structure for solid oxide fuel cells

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  6. Progress and Opportunities for Exsolution in Electrochemistry

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  7. In situ embedding of CoFe nanocatalysts into Sr3FeMoO7 matrix as high-performance anode materials for solid oxide fuel cells

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  9. GENESIS AND STRUCTURAL PROPERTIES OF (Ce1–xMx0.8Ni0.2Oy (M = La, Mg) OXIDES

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  10. Surface decorated La0.43Ca0.37Ni0.06Ti0.94O3−d as an anode functional layer for solid oxide fuel cell applications

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  12. Emergence and Future of Exsolved Materials

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  13. Degradation Mechanisms of Metal-Supported Solid Oxide Cells and Countermeasures: A Review

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  14. Fast Solution Synthesis of NiO-Gd0.1Ce0.9O1.95 Nanocomposite via Different Approach: Influence of Processing Parameters and Characterizations

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  15. In-situ generation of platinum nanoparticles on LaCoO3 matrix for soot oxidation

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  16. Probing into the In-Situ Exsolution Mechanism of Metal Nanoparticles from Doped Ceria Host

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  17. Enhancement of hydrogen production using Ni catalysts supported by Gd-doped ceria

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  19. Doped ceria with exsolved Fe 0 nanoparticles as a Sr-free cathode for CO 2 electrolysis in SOECs at reduced temperatures

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  21. Slightly ruthenium doping enables better alloy nanoparticle exsolution of perovskite anode for high-performance direct-ammonia solid oxide fuel cells

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