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RESEARCH PAPER · Electrochimica Acta · 2018

Exploration of Co-Fe alloy precipitation and electrochemical behavior hysteresis using Lanthanum and Cobalt co-substituted SrFeO3-δ SOFC anode

Xiaoyang Chen, Weijie Ni, Juan Wang, Qin Zhong, Minfang Han, Tenglong Zhu

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Exploration of Co-Fe alloy precipitation and electrochemical behavior hysteresis using Lanthanum and Cobalt co-substituted SrFeO3-δ SOFC anodeOriginalCu–Fe–Ni nano alloy particles obtained by exsolution from Cu(Ni)Fe 2 O 4 as active anode for SOFCs27In situ exsolved FeNi 3 nanoparticles on nickel doped Sr 2 Fe 1.5 Mo 0.5 O 6−δ perovskite for efficient electrochemical CO 2 reduction reaction273A-Site Ordered Double Perovskite with in Situ Exsolved Core–Shell Nanoparticles as Anode for Solid Oxide Fuel Cells97Exsolution and electrochemistry in perovskite solid oxide fuel cell anodes: Role of stoichiometry in Sr(Ti,Fe,Ni)O383The effect of calcination temperature on the properties of Ni-SDC cermet anode25Structural and electrochemical property evolutions of perovskite SOFC anodes: Role of fuel atmosphere in (La0.4Sr0.6)1-Co0.2Fe0.7Nb0.1O3-δ24Enhanced Anode Performance and Coking Resistance by In Situ Exsolved Multiple-Twinned Co–Fe Nanoparticles for Solid Oxide Fuel Cells59Direct-methane solid oxide fuel cells with an in situ formed Ni–Fe alloy composite catalyst layer over Ni–YSZ anodes56An FeNbO4-based oxide anode for a solid oxide fuel cell (SOFC)28Cobalt and Titanium substituted SrFeO3 based perovskite as efficient symmetrical electrode for solid oxide fuel cell34Modifying the Surface Structure of Perovskite-Based Catalysts by Nanoparticle Exsolution50Review of cell performance in solid oxide fuel cells97Progress and Opportunities for Exsolution in Electrochemistry26Effect of Fe, Ni and Zn dopants in La0·9Sr0·1CoO3 on the electrochemical performance of single-component solid oxide fuel cell26In-situ exsolution of nanoparticles from Ni substituted Sr2Fe1.5Mo0.5O6 perovskite oxides with different Ni doping contents111Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La 0.4 Sr 0.6 Co 0.2 Fe 0.7 Mo 0.1 O 3− δ with Efficient CO 2 Electrolysis185Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La0.4Sr0.6Co0.2Fe0.7Mo0.1O3−δ with Efficient CO2 Electrolysis6In Situ Exsolved Metal Nanoparticles: A Smart Approach for Optimization of Catalysts163Prepation of perovskite oxides/(CoFe)P2 heterointerfaces to improve oxygen evolution activity of La0.8Sr1.2Co0.2Fe0.8O4+δ layered perovskite oxide26Construction of Multifunctional Nanoarchitectures in One Step on a Composite Fuel Catalyst through In Situ Exsolution of La0.5Sr0.5Fe0.8Ni0.1Nb0.1O3−δ41Efficient Ferrite-Based Perovskite Anode for Solid Oxide Fuel Cells with A-Site and B-Site Co-exsolution27Exsolved Alloy Nanoparticles Decorated Ruddlesden–Popper Perovskite as Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells55Exsolution manipulated local surface cobalt/iron alloying and dealloying conversion in La0·95Fe0·8Co0·2O3 perovskite for oxygen evolution reaction36Ternary Ni–Co–Fe Exsolved Nanoparticles/Perovskite System for Energy Applications: Nanostructure Characterization and Electrochemical Activity23Organic Photochemistry-Assisted Nanoparticle Segregation on Perovskites14Ca-doped rare earth perovskite materials for tailored exsolution of metal nanoparticles24Sr(Ti,Fe)O 3− δ Based Intermediate Temperature Solid Oxide Fuel Cell Anode with Self-precipitated (Ni,Fe) and Gd 0.1 Ce 0.9 O 2− δ Nano Particles2Metal Exsolution to Enhance the Catalytic Activity of Electrodes in Solid Oxide Fuel Cells55Stability and activity controls of Cu nanoparticles for high-performance solid oxide fuel cells66Nanoparticle Ex-solution for Supported Catalysts: Materials Design, Mechanism and Future Perspectives181Iron-based electrode materials for solid oxide fuel cells and electrolysers129Minimized thermal expansion mismatch of cobalt-based perovskite air electrodes for solid oxide cells25Trends and Prospects of Bimetallic Exsolution67Coupling decreased polarization resistance Sr0.95Ti0.3Fe0.6Ni0.1O3-δ cathode with efficient metal supported Solid Oxide Fuel Cell31Progress of Exsolved Metal Nanoparticles on Oxides as High Performance (Electro)Catalysts for the Conversion of Small Molecules120Nanoparticle exsolution in perovskite oxide and its sustainable electrochemical energy systems43Improving the performance of Pr0.4Sr0.6Co0.2Fe0.7Nb0.1O3-δ-based single-component fuel cell and reversible single-component cells by manufacturing A-site deficiency38Problems, Challenges, and Removing Methods of Micro Plastics from Water0Enhancing the Catalytic Activity and Coking Tolerance of the Perovskite Anode for Solid Oxide Fuel Cells through In Situ Exsolution of Co-Fe Nanoparticles56Boosting the stability of perovskites with exsolved nanoparticles by B-site supplement mechanism125The influence of calcination temperature on crystallographic and chemical characteristics of NiO-CeO2 powder for PCFC anodes4Preparation of SOFC Anodes at Lower Temperature with Boosted Electrochemical Performance11Exsolved materials for CO2 reduction in high-temperature electrolysis cells32Roadmap on exsolution for energy applications71B-Site Super-Excess Design Sr2V0.4Fe0.9Mo0.7O6−δ-Ni0.4 as a Highly Active and Redox-Stable Solid Oxide Fuel Cell Anode21Enhanced Stability of Iridium Nanocatalysts via Exsolution for the CO2 Reforming of Methane7Nanotechnologies in ceramic electrochemical cells84In situ investigation of ruthenium doped lanthanum nickel titanium double perovskite and its exsolution behaviour4The ex situ exsolved Ni–Ru alloy from nickel–ruthenium co-doped SrFeO 3− δ perovskite as a potential catalyst for CC and CO hydrogenation11In Situ Exsolved CoFe Alloy Nanoparticles on Gd2SrCo0.8Fe1.2O7−δ for Direct Hydrocarbon Fuel Solid Oxide Fuel Cells10Multifunctional perovskite oxide Sr2Ti1-Ni FeO6– (x=0.1, 0.2, 0.3) as symmetrical electrode for solid oxide cells9Advances in Advanced In Situ Assembled Composite Electrode Materials for Enhanced Solid Oxide Cell Performance33The effects of nano-socketed metal particles over perovskite surfaces on the electrochemical synthesis of high-value fuels13Promoting bifunctional electrocatalytic activity and redox kinetics of praseodymium-based perovskite ceramic for electrochemical energy conversion and storage4In-situ exsolution super-excess Ni metal anchoring on Ba2V0.4Fe0.9Mo0.7O6−δ using as high catalytic activity solid oxide fuel cell composite anode6Effect of Sr doping on the potential cathode of Ba0.875Fe0.875Zr0.125O3 for proton-conducting fuel cells3Ni-doped cobalt-free perovskite as the cathode for proton ceramic fuel cells1Design high-performance symmetrical electrode of stable double perovskite oxides with in situ exsolved nanoparticles for solid oxide cells3In‐Situ Exsolved Metal Nanoparticles for Solid Oxide Fuel Cell Anode: Mechanism, Design Strategies and Application9Modified perovskite surface structure through in situ exsolution of CoFe alloy nanoparticles for efficient oxygen evolution reaction2Direct methane fuel Cells: Developments, challenges, and prospects6Anchored PtSn nanoalloys via in situ exsolution for enhanced solid oxide cell performance5Exsolution‐enhanced performance for energy conversion and storage5Cerium-Doped Strontium Ferrate Perovskite Oxides: Sustainable Materials to Face Energy and Environmental Challenges3Ultrathin defective Fe 2 O 3− x skins on exsolved nanoparticles from a perovskite cathode enable highly active and sulfur-tolerant CO 2 electroreduction2Cobalt doping-induced band modulation and proton hydration enhancement: realization for proton ceramic fuel cell cathode0

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  1. Cu–Fe–Ni nano alloy particles obtained by exsolution from Cu(Ni)Fe 2 O 4 as active anode for SOFCs

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  2. In situ exsolved FeNi 3 nanoparticles on nickel doped Sr 2 Fe 1.5 Mo 0.5 O 6−δ perovskite for efficient electrochemical CO 2 reduction reaction

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  3. A-Site Ordered Double Perovskite with in Situ Exsolved Core–Shell Nanoparticles as Anode for Solid Oxide Fuel Cells

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  4. Exsolution and electrochemistry in perovskite solid oxide fuel cell anodes: Role of stoichiometry in Sr(Ti,Fe,Ni)O3

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  5. The effect of calcination temperature on the properties of Ni-SDC cermet anode

    Ceramics International · 2019-09-30

    Muhammad Ahsan, Muneeb Irshad, Pei Fang Fu, Khurram Siraj, Rizwan Raza, Fayyaz Javed

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  6. Structural and electrochemical property evolutions of perovskite SOFC anodes: Role of fuel atmosphere in (La0.4Sr0.6)1-Co0.2Fe0.7Nb0.1O3-δ

    International Journal of Hydrogen Energy · 2019-10-25

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  7. Enhanced Anode Performance and Coking Resistance by In Situ Exsolved Multiple-Twinned Co–Fe Nanoparticles for Solid Oxide Fuel Cells

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  8. Direct-methane solid oxide fuel cells with an in situ formed Ni–Fe alloy composite catalyst layer over Ni–YSZ anodes

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  9. An FeNbO4-based oxide anode for a solid oxide fuel cell (SOFC)

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  10. Cobalt and Titanium substituted SrFeO3 based perovskite as efficient symmetrical electrode for solid oxide fuel cell

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  11. Modifying the Surface Structure of Perovskite-Based Catalysts by Nanoparticle Exsolution

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  12. Review of cell performance in solid oxide fuel cells

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  13. Progress and Opportunities for Exsolution in Electrochemistry

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  14. Effect of Fe, Ni and Zn dopants in La0·9Sr0·1CoO3 on the electrochemical performance of single-component solid oxide fuel cell

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  15. In-situ exsolution of nanoparticles from Ni substituted Sr2Fe1.5Mo0.5O6 perovskite oxides with different Ni doping contents

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  16. Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La 0.4 Sr 0.6 Co 0.2 Fe 0.7 Mo 0.1 O 3− δ with Efficient CO 2 Electrolysis

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  17. Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La0.4Sr0.6Co0.2Fe0.7Mo0.1O3−δ with Efficient CO2 Electrolysis

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  18. In Situ Exsolved Metal Nanoparticles: A Smart Approach for Optimization of Catalysts

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  19. Prepation of perovskite oxides/(CoFe)P2 heterointerfaces to improve oxygen evolution activity of La0.8Sr1.2Co0.2Fe0.8O4+δ layered perovskite oxide

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  20. Construction of Multifunctional Nanoarchitectures in One Step on a Composite Fuel Catalyst through In Situ Exsolution of La0.5Sr0.5Fe0.8Ni0.1Nb0.1O3−δ

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  21. Efficient Ferrite-Based Perovskite Anode for Solid Oxide Fuel Cells with A-Site and B-Site Co-exsolution

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  22. Exsolved Alloy Nanoparticles Decorated Ruddlesden–Popper Perovskite as Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells

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  23. Exsolution manipulated local surface cobalt/iron alloying and dealloying conversion in La0·95Fe0·8Co0·2O3 perovskite for oxygen evolution reaction

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  24. Ternary Ni–Co–Fe Exsolved Nanoparticles/Perovskite System for Energy Applications: Nanostructure Characterization and Electrochemical Activity

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  26. Ca-doped rare earth perovskite materials for tailored exsolution of metal nanoparticles

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  27. Sr(Ti,Fe)O 3− δ Based Intermediate Temperature Solid Oxide Fuel Cell Anode with Self-precipitated (Ni,Fe) and Gd 0.1 Ce 0.9 O 2− δ Nano Particles

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  28. Metal Exsolution to Enhance the Catalytic Activity of Electrodes in Solid Oxide Fuel Cells

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  29. Stability and activity controls of Cu nanoparticles for high-performance solid oxide fuel cells

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  32. Minimized thermal expansion mismatch of cobalt-based perovskite air electrodes for solid oxide cells

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  33. Trends and Prospects of Bimetallic Exsolution

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  34. Coupling decreased polarization resistance Sr0.95Ti0.3Fe0.6Ni0.1O3-δ cathode with efficient metal supported Solid Oxide Fuel Cell

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  36. Nanoparticle exsolution in perovskite oxide and its sustainable electrochemical energy systems

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  38. Problems, Challenges, and Removing Methods of Micro Plastics from Water

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  39. Enhancing the Catalytic Activity and Coking Tolerance of the Perovskite Anode for Solid Oxide Fuel Cells through In Situ Exsolution of Co-Fe Nanoparticles

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  40. Boosting the stability of perovskites with exsolved nanoparticles by B-site supplement mechanism

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  41. The influence of calcination temperature on crystallographic and chemical characteristics of NiO-CeO2 powder for PCFC anodes

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  42. Preparation of SOFC Anodes at Lower Temperature with Boosted Electrochemical Performance

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  45. B-Site Super-Excess Design Sr2V0.4Fe0.9Mo0.7O6−δ-Ni0.4 as a Highly Active and Redox-Stable Solid Oxide Fuel Cell Anode

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  49. The ex situ exsolved Ni–Ru alloy from nickel–ruthenium co-doped SrFeO 3− δ perovskite as a potential catalyst for CC and CO hydrogenation

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