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RESEARCH PAPER · Chemistry of Materials · 2017

Tunable Optical Properties and Increased Thermal Quenching in the Blue-Emitting Phosphor Series: Ba2(Y1–xLux)5B5O17:Ce3+ (x = 0–1)

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Tunable Optical Properties and Increased Thermal Quenching in the Blue-Emitting Phosphor Series: Ba2(Y1–xLux)5B5O17:Ce3+ (x = 0–1)OriginalTunable luminescence of K2MgSi3O8:Ce3+, Tb3+ phosphors through energy transfer24Structure Transformation and Cerium-Substituted Optical Response across the Carbonitridosilicate Solid Solution (LaδY1−δ)2Si4N6C (δ = 0–0.5)1A strategy for realizing tunable luminescence and full-color emission in Sr 3 Gd 2 (Si 3 O 9 ) 2 :Eu phosphors by introducing dual functional Mn 2+18An efficient green phosphor of Ce 3+ and Tb 3+ -codoped Ba 2 Lu 5 B 5 O 17 and a model for elucidating the high thermal stability of the green emission53Broad color tuning of Bi 3+ /Eu 3+ -doped (Ba,Sr) 3 Sc 4 O 9 solid solution compounds via crystal field modulation and energy transfer107Controllable two-dimensional luminescence tuning in Eu 2+ ,Mn 2+ doped (Ca,Sr) 9 Sc(PO 4 ) 7 based on crystal field regulation and energy transfer61Enhanced near infrared persistent luminescence of Zn 2 Ga 2.98 Ge 0.75 O 8 :Cr 0.02 3+ nanoparticles by partial substitution of Ge 4+ by Sn 4+23Synthesis and characterization of Ca 3 Lu(GaO) 3 (BO 3 ) 4 :Ce 3+ ,Tb 3+ phosphors: tunable-color emissions, energy transfer, and thermal stability16Understanding the Interactions between Vibrational Modes and Excited State Relaxation in Y3–xCexAl5O12: Design Principles for Phosphors Based on 5d–4f Transitions72An efficient blue phosphor Ba 2 Lu 5 B 5 O 17 :Ce 3+ stabilized by La 2 O 3 : Photoluminescence properties and potential use in white LEDs43Effects of the deep traps on the thermal‐stability property of CaAl 2 O 4 : Eu 2+ phosphor49Ba3Y2B6O15:Ce3+—A High Symmetry, Narrow-Emitting Blue Phosphor for Wide-Gamut White Lighting188Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics495Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics67White Light Emitting Phosphors for Solid State Lighting0Ligand-Mediated Control of Dopant Oxidation State and X-ray Excited Optical Luminescence in Eu-Doped LaOCl18Ca3Lu(GaO)3(BO3)4:Eu3+: A novel high-brightness and thermal-stable red-emitting phosphor for white LEDs44Crystallographic-site induced multi-color emission with high efficiency in Ca3(SiO3)3:Ce3+ phosphor19Photoluminescence properties and site-preferable distribution of Ce3+ in Na2Ca1-Sr Si2O6 (x = 0–1) blue-emitting phosphors7Efficient Blue-emitting Phosphor SrLu2O4:Ce3+ with High Thermal Stability for Near Ultraviolet (~400 nm) LED-Chip based White LEDs67Eu 2+ Site Preferences in the Mixed Cation K 2 BaCa(PO 4 ) 2 and Thermally Stable Luminescence577Full Color Luminescence Tuning in Bi 3+ /Eu 3+ -Doped LiCa 3 MgV 3 O 12 Garnet Phosphors Based on Local Lattice Distortion and Multiple Energy Transfers112Synthesis and photoluminescent properties of high-efficient color-tunable Ba3Y2B6O15: Ce3+, Tb3+ phosphors20Synthesis and Luminescence Properties of Bi3+-Activated K2MgGeO4: A Promising High-Brightness Orange-Emitting Phosphor for WLEDs Conversion190Pechini sol-gel synthesis of La2CaB8O16:Eu3+ red phosphor and its photoluminescence spectral properties21High-efficiency cubic-phased blue-emitting Ba3Lu2B6O15:Ce3+ phosphors for ultraviolet-excited white-light-emitting diodes69Identifying an efficient, thermally robust inorganic phosphor host via machine learning362Novel highly efficient blue-emitting SrHfSi2O7:Eu2+ phosphor: A potential color converter for WLEDs and FEDs25Understanding the blue-emitting orthoborate phosphor NaBaBO 3 :Ce 3+ through experiment and computation49Cyan-Green Phosphor (Lu2M)(Al4Si)O12:Ce3+ for High-Quality LED Lamp: Tunable Photoluminescence Properties and Enhanced Thermal Stability150A strategy for developing thermal-quenching-resistant emission and super-long persistent luminescence in BaGa 2 O 4 :Bi 3+62Density-functional theory calculations, luminescence properties and fluorescence ratiometric thermo-sensitivity for a novel borate based red phosphor: NaBaSc(BO 3 ) 2 :Ce 3+ ,Mn 2+58Enhanced photoluminescence and thermal stability in solid solution Ca 1−x Sr x Sc 2 O 4 :Ce 3+ ( x = 0–1) via crystal field regulation and site-preferential occupation49Luminescence color tuning and energy transfer properties in (Sr,Ba) 2 LaGaO 5 :Bi 3+ ,Eu 3+ solid solution phosphors: realization of single-phased white emission for WLEDs107Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuning34Tuning the Bi 3+ -photoemission color over the entire visible region by manipulating secondary cations modulation in the ScV x P 1−x O 4 :Bi 3+ (0 ≤ x ≤ 1) solid solution67Structural Micromodulation on Bi3+-Doped Ba2Ga2GeO7 Phosphor with Considerable Tunability of the Defect-Oriented Optical Properties93Structure refinement and thermal properties of novel cubic borate Lu2Ba3B6O1513Co-existence phenomenon of Ce3+/Ce4+ and Tb3+ in Ce/Tb co-doped Zn2(BO3)(OH)0.75F0.25 phosphor: Luminescence and energy transfer24Investigation of site occupancy and photoluminescence of Ce3+ in cubic borate Ba3Y2(B2O5)3 and Ce3+ → Tb3+ energy transfer behavior16First-principles calculations, structure research and luminescence properties for a novel apatite blue/green phosphor Ca6Y4(SiO4)2(PO4)4O2:Eu2+/Tb3+5Red-emitting phosphor series: Ca9Y(PO4)7(1-x)(VO4)7x:Eu3+ (x = 0 − 1) with improved luminescence thermal stability by anionic polyhedron substitution22Local Structure Modulation Induced Highly Efficient Far-Red Luminescence of La 1– x Lu x AlO 3 :Mn 4+ for Plant Cultivation89Sr2LiScB4O10:Ce3+/Tb3+: A Green-Emitting Phosphor with High Energy Transfer Efficiency and Stability for LEDs and FEDs107Activating persistent luminescence and thermal stability of K2Ba7Si16O40: Eu2+ via traps modulation9A promising thermally robust blue-green Li-α-sialon:Ce3+ for ultraviolet LED-driven white LEDs19The novel borate Lu5Ba6B9O27with a new structure type: synthesis, disordered crystal structure and negative linear thermal expansion14A novel thermally stable Ba3Bi2(BO3)4:Eu3+ red phosphor for solid state lighting application31Site occupation and 4f → 5d transitions of Ce3+ ions at mixed Ca2+/Y3+ sites in CaYAlO4: Insights from first-principles calculations13Site occupancy and tunable photoluminescence properties of Eu2+-Activated Ba3Sc(BO3)3 phosphors for white light emitting diodes33Studying crystal-field splitting difference of Eu3+ ions from orthorhombic to cubic Ca4Al6SO166Enhanced photoluminescence emission and thermal stability in diamond-like framework contained K(Sr, Ba)BP2O8:Eu3+ red phosphors via composition modification29A broadband cyan-emitting Ca 2 LuZr 2 (AlO 4 ) 3 :Ce 3+ garnet phosphor for near-ultraviolet-pumped warm-white light-emitting diodes with an improved color rendering index245Full-visible-spectrum lighting enabled by an excellent cyan-emitting garnet phosphor284Super stable (Ba,Sr)LuAl 2 Si 2 O 2 N 5 :Ce 3+ ,Eu 2+ phosphors30Highly Efficient Green‐to‐Yellowish‐Orange Emitting Eu2+‐Doped Pyrophosphate Phosphors with Superior Thermal Quenching Resistance for w‐LEDs99Multisite-Occupancy-Driven Intense Narrow-Band Blue Emission from Sr 5 SiO 4 Cl 6 :Eu 2+ Phosphor with Excellent Stability and Color Performance69Discovery of blue-emitting Eu2+-activated sodium aluminate phosphor with high thermal stability via phase segregation40The effect of rare-earth substitution on the Debye temperature of inorganic phosphors27Pyrophosphate Phosphor Solid Solution with High Quantum Efficiency and Thermal Stability for Efficient LED Lighting34Site Occupation and Luminescence of Novel Orange-Red Ca3M2Ge3O12:Mn2+,Mn4+ (M = Al, Ga) Phosphors106Novel color tunable garnet phosphor of Tb3+ and Eu3+ co-doped Ca2YZr2Al3O12 with high thermal stability via energy transfer74Simultaneous Enhancement and Modulation of Upconversion by Thermal Stimulation in Sc 2 Mo 3 O 12 Crystals152A novel wide-excitation and narrow-band blue-emitting phosphor with hafnium silicon multiple rings structure for photoluminescence and cathodoluminescence20Quantum Dots for Display Applications318Quantum Dots for Display Applications90Novel 4ZnO⋅B2O3⋅H2O:Ln3+/HTC (where Ln = Eu or Tb) phosphors: Synthesis, morphology and luminescence properties6Achieving full-visible-spectrum LED lighting via employing an efficient Ce3+-activated cyan phosphor115Highly Robust Oxynitride Phosphor against Thermal Oxidization and Hydrolysis36Synthesis and photoluminescence properties of near-UV-excitable cyan-emitting Ca2YHf2Ga3O12:Ce3+ garnet phosphors16Ternary solid solution phosphors Ca1--Li Al1--Si1++N3-O :Ce3+ with enhanced thermal stability for high-power laser lighting67Red phosphors A2GdNbO6: Mn4+ (A = Ca, Sr, Ba) for plant growth LEDs with Emerson enhancement effect39Enhancement of blue emission in Ce3+, Eu2+ activated BaSiF6 downconversion phosphor by energy transfer mechanism: A photochromic phosphor62Improving thermal stability and quantum efficiency through solid solution for Ce3+-activated (Ba1-Sr )3Y2(BO3)4 phosphors16Hetero-valent substitution strategy toward orange-red luminescence in Bi3+ doped layered perovskite oxide phosphors for high color rendering index white light-emitting diodes105Discovery of a new phosphor via aliovalent cation substitution: DFT predictions, phase transition and luminescence properties for lighting and anti-counterfeiting applications22Investigation on the photoluminescence and thermoluminescence of BaGa 2 O 4 :Bi 3+ at extremely low temperatures32A highly sensitive ratiometric optical cryothermometer using a new broadband emitting trivalent bismuth singly activated Ba 2 ZnSc(BO 3 ) 3 microcrystal10Bi 3+ photoluminescence in Y 1− x Bi x Ca 3 (GaO) 3 (BO 3 ) 4 and energy transfer to Eu 3+ and Tb 3+ in co-doped phosphors9Construction of a novel mechanoluminescent phosphor Li 2 MgGeO 4 : x Mn 2+ by defect control32Improvement of thermal stability and photoluminescence in Mg 2 Y 2 Al 2 Si 2 O 12 :Ce 3+ by the cation substitution of Ca 2+ , Sr 2+ and Ba 2+ ions14Intrinsic and extrinsic defects build a novel mechanoluminescent phosphor Na 2 MgGeO 4 :Mn 2+52Luminescence and energy transfer of warm white-emitting phosphor Mg 2 Y 2 Al 2 Si 2 O 12 :Dy 3+ ,Eu 3+ for white LEDs28The influence of Sc substitution on the crystal structure and scintillation properties of LuBO 3 :Ce 3+ based on a combinatorial materials chip and high-throughput XRD4Improving the thermal stability and luminescent efficiency of (Ba,Sr)3SiO5:Eu2+ phosphors by structure, bandgap engineering and soft chemistry synthesis method98Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors11A novel red-emitting Ca2GdHf2Al3O12:Eu3+ phosphor for light-emitting didoes and field emission display25Rare-Earth-Free Barium Borostannate with Deep-Blue Light Emission16Near-ultraviolet excited broadband orange-yellow emitting Sr8MgIn(PO4)7:Eu2+ phosphors for WLEDs with high color rendering index10A novel blue-emitting phosphors (CsBaYB6O12:Ce3+): Potential applications in w-LEDs and X-ray phosphors34Achieving high quantum efficiency independent on luminescence center through sub-lattice cage engineering10Controllable structural ordering via chemical substitution to the efficient and thermally stable luminescence in NASICON-type phosphor Series: Na1+Hf2−Sc (PO4)3:Eu12Bismuth activated blue phosphor with high absorption efficiency for white LEDs55Realization of non-rare earth doped blue-emitting phosphor Ba2Y5B5O17: Sb by selective site excitation, and its application in n-UV excited wLEDs3Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction12Highly efficient and zero-thermal-quenching blue-emitting Eu2+-activated K-beta-alumina phosphors72Effect of Partial Ca2+ Substitution with Ln3+ (Ln = Y, La) on Luminescence Enhancement of Ca18.62Zn2(PO4)14:0.38Dy3+ White-Emitting Phosphor for White Light-Emitting Diodes32Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230Site occupancies, photoluminescence, and temperature sensing properties of a K7ZnSc2B15O30:Ce3+, Tb3+ phosphor3Highly efficient and thermally stable Eu3+ activated phosphate based phosphors for wLEDs: An experimental and DFT study53Blue-light-excitable broadband yellow-emitting CaGd2HfSc(AlO4)3:Ce3+ garnet phosphors for white light-emitting diode devices with improved color rendering index68From β‐Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic‐Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra10Chemical unit co-substitution for a new far-red-emitting phosphor Ca3-6(NaLu)3LiSbO6:Mn4+ to achieve high quantum efficiency and superb thermal stability12Spectral Design of Phosphor-Converted LED Lighting Guided by Color Theory26The high thermal stability of white emitting phosphor Mg2Y2Al2Si2O12:Dy3+,Eu3+,La3+/Lu3+ for white light emitting diodes1(INVITED)KRbAl2B2O7: Eu2+: A new blue-emitting luminescent material with good thermal stability0A novel red-emitting phosphor K 2 MgGeO 4 :Eu 3+ for WLEDs: zero-thermal quenching induced by heterovalent substitution27Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba 1− x Sr x ScO 2 F:Eu 2+12Oxygen vacancy content drives self-reduction and anti-thermal quenching40Research progress in cyan and blue phosphors14Tunable concentration/excitation-dependent deep-red and white light emission in single-phase Eu 2+ -activated Sc-based oxide phosphors for blue/UV-LEDs32Tuning of the thermal quenching performance of Bi 3+ -doped scheelite Ca(Mo/W)O 4 solid solution phosphors13How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Tailoring the Luminescent Properties of SrS:Ce3+ by Sr-Deficiency and Na+ Doping15Preparation of M2B5O9Cl:Eu2+ (M=Sr, Ca) blue phosphors by a facile low-temperature self-reduction method and their enhanced luminescent properties25Effect of ionic couple substitution on the enhanced photoluminescence properties of (BaMg)1-x(KxAl10+x)O17:Eu2+ phosphor for white LEDs application7Green-emitting Bi3+-doped La2SrSc2O7 phosphor for pc-WLED lighting: Luminescent properties and energy transfer strategy50Synthesis, crystal structure, and anti‐thermal quenching performance of Lu 2 Sr (1− x ) Al 4 SiO 12 : x Eu 2+ phosphors9Excellent enhancement of thermal stability and quantum efficiency for Na2BaCa(PO4)2:Eu2+ phosphor based on Sr doping into Ca30Disorder–Order Conversion‐Induced Enhancement of Thermal Stability of Pyroxene Near‐Infrared Phosphors for Light‐Emitting Diodes140Disorder–Order Conversion‐Induced Enhancement of Thermal Stability of Pyroxene Near‐Infrared Phosphors for Light‐Emitting Diodes50Facile Microwave Synthesis of a Narrow-Band Green-Emitting Phosphor Cs3MnBr5 and the Effect of Anion Substitution on Its Luminescence Properties17Investigation on Ba2(Y1-x, Lux)5B5O17: y at.% Bi as a new type of N-UV excited high efficient blue phosphor for wLED6Photoluminescence properties and energy transfer in the Sm3+ and Eu3+ co-doped Ca3Bi(PO4)3 red phosphor17A super stable Near-Infrared garnet phosphor resistant to thermal Quenching, thermal degradation and hydrolysis57Li+ doping induced zero-thermal quenching in Cs3Zn6––B9O21:xEu3+,yLi+ (0 ≤ x ≤ 0.10, 0.06 ≤ y ≤ 0.16)10Photoluminescence of Bi3+ in LiCaY5(BO3)6 and color-tunable emission through energy transfer to Eu3+/Tb3+11Luminescent properties of thermally stable and high efficiency green-emitting Ce3+/Tb3+ ions co-doped NaBaB9O15 phosphor2Luminescence in the solid state7Probing the crystal chemistry, photoluminescence and Judd–Ofelt investigation of Tb3+-activated Ba2Y5B5O17 phosphors10Neutron detection properties of thermoluminescent Sr2B2O5:Eu ceramics12Synthesis and characterizations of a color tunable single-phased warm white phosphor Sr3Lu(BO3)3: Bi3+, Eu3+23A broadband near-infrared Cr 3+ -doped phosphor applied to near-infrared light-emitting diodes: enhanced luminescence and thermal stability by annealing20A metal-to-metal charge transfer induced green-yellow phosphor CsAlGe 2 O 6 :Bi 3+ for full-spectrum LED devices13Cation-defect-induced self-reduction towards efficient mechanoluminescence in Mn 2+ -activated perovskites57Design of anti-thermal quenching Pr 3+ -doped niobate phosphors based on a charge transfer and intervalence charge transfer band excitation-driven strategy18Eu 2+ luminescence in CaYGaO 4 olivine: a new efficient red phosphor for warm illumination47Influence of framework disordering on the luminescence performance of Cr 3+ -doped near-infrared phosphors: a case study of A 3 B 6 O 14 -type hosts8Quantifying rigidity for thermally stable Cr 3+ phosphors9Pr3+ doped Y3GaO6 luminescent thermometer for high temperature conditions15Adjustment of Bi 3+ Luminescence and Thermal Quenching Properties by B′-Site Ion Substitution Strategy in Double Perovskite CaLaMgSb/TaO 6 :Bi 3+ Phosphor33Cation substitution induced highly symmetric crystal structure in cyan-green-emitting Ca2La1-xLuxHf2Al3O12:Ce3+ solid-solution phosphors with enhanced photoluminescence emission and thermal stability: Toward full-visible-spectrum white LEDs41Blue light emitting Sr2MgSi2O7:Eu2+ nanophosphor for latent fingerprint, anti-counterfeiting and near UV-LED applications45Improved Thermal and Chemical Stability of Oxynitride Phosphor from Facile Chemical Synthesis for Vehicle Cornering Lights50Improved Thermal and Chemical Stability of Oxynitride Phosphor from Facile Chemical Synthesis for Vehicle Cornering Lights2Thermal Expansion of Ba3Lu(BO3)3 Borate0Developing Thermally Stable Defect-Assisted Phosphors of BaSc2Ge3O10:Bi3+ for Pc-UV-LEDs Applications20Efficient blue-light-excited cyan-emitting CaLu2HfScAl3O12:Ce3+ phosphors for full-visible-spectrum warm-white LEDs13Novel “Anti-Zeolite” Ba3Sr3B4O12: Eu3+ Phosphors: Crystal Structure, Optical Properties, and Photoluminescence2Concentration-dependent tunable luminescence and highly thermal stability of Tb3+-activated KSrBP2O8 phosphor9

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  2. Structure Transformation and Cerium-Substituted Optical Response across the Carbonitridosilicate Solid Solution (LaδY1−δ)2Si4N6C (δ = 0–0.5)

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  3. A strategy for realizing tunable luminescence and full-color emission in Sr 3 Gd 2 (Si 3 O 9 ) 2 :Eu phosphors by introducing dual functional Mn 2+

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  5. Broad color tuning of Bi 3+ /Eu 3+ -doped (Ba,Sr) 3 Sc 4 O 9 solid solution compounds via crystal field modulation and energy transfer

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