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RESEARCH PAPER · Journal of Materials Chemistry C · 2019

Luminescence color tuning and energy transfer properties in (Sr,Ba) 2 LaGaO 5 :Bi 3+ ,Eu 3+ solid solution phosphors: realization of single-phased white emission for WLEDs

Dongjie� Liu, Peipei Dang, Xiaohan Yun, Guogang Li, Hongzhou Lian, Jun Lin

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Luminescence color tuning and energy transfer properties in (Sr,Ba) 2 LaGaO 5 :Bi 3+ ,Eu 3+ solid solution phosphors: realization of single-phased white emission for WLEDsOriginalWhite-light/tunable emissions in single-phased BaLa2Si3O10:Eu3+, Bi3+ phosphor for the simultaneous applications in white light-emitting diodes and luminous cement9Energy transfer, multi-colour emission and high thermal stability behaviour of K 2 Tb 1−x Eu x Hf(PO 4 ) 3 with langbeinite-type structure7Luminescence properties and energy transfer of novel Bi 3+ and Mn 2+ -co-activated Y 3 Ga 5 O 12 single-component white light-emitting phosphor54Mechanistic Insight into Energy‐Transfer Dynamics and Color Tunability of Na4CaSi3O9:Tb3+,Eu3+ for Warm White LEDs37Yellow/Orange-Emitting ABZn 2 Ga 2 O 7 :Bi 3+ (A = Ca, Sr; B = Ba, Sr) Phosphors: Optical Temperature Sensing and White Light-Emitting Diode Applications256Eu3+-activated Ca3Mo0.2W0.8O6 red-emitting phosphors: A near-ultraviolet and blue light excitable platform for solid-state lighting and thermometer33Synthesis and photoluminescent properties of Ba2+ ions doped europium formate phosphors for white light-emitting diodes8Recent Advances in Bismuth Ion‐Doped Phosphor Materials: Structure Design, Tunable Photoluminescence Properties, and Application in White LEDs363Delayed Concentration Quenching of Luminescence Caused by Eu3+-Induced Phase Transition in LaSc3(BO3)4114Ultraviolet-A Persistent Luminescence of a Bi3+-Activated LiScGeO4 Material80Enhanced Cyan Emission and Optical Tuning of Ca 3 Ga 4 O 9 :Bi 3+ for High‐Quality Full‐Spectrum White Light‐Emitting Diodes139Excellent photoluminescence and cathodoluminescence properties in Eu3+-activated Sr2LaNbO6 materials for multifunctional applications216Design of a Bismuth-Activated Narrow-Band Cyan Phosphor for Use in White Light Emitting Diodes and Field Emission Displays100The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs14A solid-solution modulation strategy in trivalent bismuth-doped gallate phosphors for single substrate tunable emission5Efficient Bi 3+ to Eu 3+ energy transfer and color tunable emissions in K 7 CaY 2 (B 5 O 10 ) 3 -based phosphors22Enhanced luminescence and tunable color in [Eu 2+ , Si 4+ ]/Mn 2+ doped K 2 BaCa(PO 4 ) 2 based on charge compensation and energy transfer5Improvement of thermal stability and photoluminescence in Mg 2 Y 2 Al 2 Si 2 O 12 :Ce 3+ by the cation substitution of Ca 2+ , Sr 2+ and Ba 2+ ions14Keggin-type polyoxometalate 1 : 1 complexes of Pb( ii ) and Bi( iii ): experimental, theoretical and luminescence studies8Realization of high-quality white light emission in single-phased α-Sr2P2O7: Dy3+, Tm3+ phosphor7Realization of warm white light emitting in single phase Gd(P V1)O4:y at% Sm3+,1 at% Bi3+ phosphor23Spontaneous-reduction and photoluminescence tuning in singly-doped Ba5-Ca (PO4)3Cl:Eu2+/Eu3+ phosphors23Simultaneous Broadening and Enhancement of Cr 3+ Photoluminescence in LiIn 2 SbO 6 by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications325Full-visible-spectrum emission with high color rendering index and low correlated color temperature enabled by a single-phased phosphor of α-Sr2V1.98P0.02O7: 0.5% Eu3+19Simultaneous Broadening and Enhancement of Cr3+Photoluminescence in LiIn2SbO6by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications5Double-excited states of charge transfer band and 4f-4f in single-phase K3Gd(VO4)2:Tb3+/Sm3+ phosphors with superior sensing sensitivity for potential luminescent thermometers29Multi-color emitting luminescence in an Eu3+/Tb3+ co-doping borate-phosphate system CsNa2Tb2-(BO3)(PO4)2:xEu3+10Tuning Emission from Greenish to Blue via Chemical Composition Modulation in Solid Solutions (Sr 1– y Ca y ) 2 Sb 2 O 7 :Bi 3+ under near-UV Light Excitation63Novel Ba3Lu4O9:Bi3+,Eu3+ phosphors for white LEDs: Efficient energy transfer, broad near-UV excitation band and green-yellow-orange-red color tunable emissions13Thermally Stable Tb3+/Eu3+-Codoped K0.3Bi0.7F2.4 Nanoparticles with Multicolor Luminescence for White-Light-Emitting Diodes39Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Enhanced up-conversion luminescence and temperature sensing property of Ba3-xSrxLu4O9:Tm3+/Yb3+ phosphors42Achievement of high-efficiency sunlight-like emission in Rb2CaP2O7: Ce3+, Eu2+ phosphors16High thermal stability pyroxene type CaScAlSiO6:Tb3+/Sm3+ ceramics with excellent cryogenic optical thermometry performance21Eu3+ and Tb3+ doped LiCaY5(BO3)6: Efficient red and green phosphors under UV or NUV excitations26Single-component white emitting phosphor Mg2Y2Al2Si2O12:Tb3+, Eu3+, Tm3+ for white LEDs40Green-emitting Bi3+-doped La2SrSc2O7 phosphor for pc-WLED lighting: Luminescent properties and energy transfer strategy50(3+1)-Dimensional Modulated Structure and Tb3+-Doped Luminescence for Vanadate Na3La(VO4)27Bi 3+ /Mn 4+ co‐doped dual‐emission phosphors for potential plant lighting50Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors30Energy transfer mediated single-phased white light emission in Bi3+-Eu3+ codoped Ba3YGa2O7.5 for WLED33High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors35Self‐Activated Tungstate Phosphor for Near‐Infrared Light‐Emitting Diodes58High quality germanate phosphor La(2-x-y)Ge2O7: Tb3+, Eu3+for WLED applications21Design of novel cyan phosphor Ca7NaLu(PO4)6:Eu2+ for full-visible-spectrum white LED: enhanced thermal stability and tuned emission by neighbor cation effect30Highly efficient and tunable broadband UV excitable Ba9Lu2Si6O24:Eu2+, Mn2+ single-phase white-light-emitting phosphors21Study on luminescence properties of Bi3+ doped Ba2YAlO5：A wide-band yellow emitting phosphor with excellent thermal stability20A multi-centre activated single-phase white light phosphor with high efficiency for near-UV based WLEDs69Ba 3 LuGa 2 O 7.5 :Bi 3+ phosphors with potential application in full-spectrum WLEDs and temperature sensing73Energy transfer and tunable emission in BaSrGd 4 O 8 :Bi 3+ ,Eu 3+ phosphors for warm WLED9Energy Transfer from Bi3+ to Eu3+ in Liy6(Bo3)3o5 Phosphors for Non-Contact Optical Thermometry Sensors and White Light-Emitting Diodes of Bifunctional Applications0Exclusive confinement of Bi 3+ -activators in the triangular prism enabling efficient and thermally stable green emission in the tridymite-type phosphor CaBaGa 4 O 8 :Bi 3+13Mechanistic insights for regulating the site occupancy, valence states and optical transitions of Mn ions in yttrium–aluminum garnets via codoping5Multicolor tunable Bi 3+ ,Sm 3+ co-doped Sr 2 GdGaO 5 phosphor and its application in optical thermometry47A three-mode optical thermometry based on thermochromic Gd2GaSbO7:Bi3+,Eu3+ phosphors57Tunable emission color and anti-thermal-quenching behaviors in niobates for high-sensitive optical thermometry53Bi3+-activated dual-wavelength emitting phosphors toward effective optical thermometry45Synthesis, Photoluminescent Characteristics and Eu3+-Induced Phase Transitions in Sr3Zr2O7:Eu3+ Red Phosphors13Designing multicolor luminescence in Tb3+/Eu3+-codoped KGd2F7 nanoparticles through energy transfer engineering for warm white light-emitting diode5Optical and DFT study of a novel blue-emitting Gd7O6(BO3) (PO4)2: Bi3+ phosphor5Structural and luminescence characterization of red-emitting Li6SrLa2Nb2O12:Eu3+ phosphors with excellent thermal stability17Energy transfer in Bi3+-Sm3+ co-doped phosphors for temperature sensing and imaging39A potential cyan phosphor for full spectrum light-emitting diodes: Bi3+ activated SrBaGdGaO5 phosphor20Energy transfer of Eu2+→Eu3+ improves the photoluminescence properties of orange-red phosphor La2O2S:Eu27Synthesis, bright red-emitting and low thermal quenching behavior of europium(Ⅲ)-activated sodium borophosphate phosphor2Regulation of the luminescence of Bi3+-activated Ca5Ga6O14 phosphors by varying doping concentration and composition design5Exploring Optically Stable Reddish-Orange Fluorescent Magnetic Pigment (0.90)Y2O3:(0.10-x)Eu3+:(x)Bi3+ for Anti-counterfeiting Applications6Synthesis of Bi3+ and Eu3+ co-doped Na4CaSi3O9 blue-red light tunable emission phosphors for inducing plant growth43Electronic structure, colour-tunable emission and energy transfer in Li 3 Ba 2 Y 3 (WO 4 ) 8 :Bi 3+ ,Eu 3+ phosphors for white light-emitting diodes14Fluorescence properties of novel deep-red phosphor LiMg 4 SbO 7 :Mn 4+ with excellent quantum efficiency and color purity for warm white LEDs15Structure, luminescence properties, and valence-induced spectral behavior of a bismuth-activated garnet phosphor9Unraveling the origin of broadband yellow emission in Bi 3+ -doped LuXnGaO 4 (Xn = Mg, Zn) phosphors9Dual-emitting Dy3+/Eu3+ co-doped SrLaGaO4 phosphor: Tunable luminescence, energy transfer and ratiometric temperature sensing58Tunable broadband luminescence of Bi‐ion‐doped glasses via Gd 2 O 3 co‐doping0Broadband yellow-emitting LuMgGaO4:Bi3+ phosphor utilizing Bi3+ pairs for full-spectrum WLEDs26Superior Quantum Efficiency Blue‐Emitting Phosphors with High Thermal Stability toward Multipurpose LED Applications57Zero-thermal-quenching broadband yellow-emitting Bi3+-activated phosphors based on metal to metal charge transfer27Bi3+/Mn4+ co-doped Y2MgTiO6 dual-emitting phosphors for plant growth lighting and temperature sensor27Energy transfer in dual-emission LiY6(BO3)3O5: Bi3+, Eu3+ phosphors for temperature sensing applications20Adjustable emission and energy transfer in perovskite structure La2MgSnO6: Eu3+, Bi3+ phosphors for multifunctional applications29Enhanced color rendering index and thermal stability of Ca2GdNbO6: Dy3+ phosphors by co-doping Sm3+ ions28Photoluminescence Tuning of Stable CaYGaO4: Bi/Eu via Compositional Modulation and Crystallographic Site Engineering for nUV wLEDs27Band-gap engineering enabled emission switch in solid-solution phosphors LiIn1-xScxGeO4:Bi3+ for spectral-temporal anti-counterfeiting8Broadband red emission in disordered Sr2LaGaO5:Eu2+ phosphors7Electronic structure analysis, a large Stokes shift of Bi 3+ in BiSr 3 (YO) 3 (BO 3 ) 4 and color-tunable emissions by energy transfer to Eu 3+ dopants0Enhanced optical properties and optical temperature sensing performance of SrGa 4 O 7 :Bi 3+ co-doped with K + and Cr 3+ via charge compensation and energy transfer4Insight into temperature dependence of the photoluminescence properties of bright orange-red BaAl 4 Sb 2 O 12 :Bi 3+ phosphors for fluorescence thermometry2Unlocking the multifunctional applications of a novel bismuth-activated high-brightness orange-emitting phosphor through lattice engineering12Cationic substitution induces multicolor emission in YBaZn3-yMgyGaO7: Bi3+ phosphors for WLEDs and information encryption13High-brightness Bi3+ activated Gd2GeO5 blue phosphor for white light-emitting diodes: Synthesis, characterization, and thermal stability2Bi3+-induced dual-color luminescence in Eu3+ substituted Y2WO6 magnetic nanophosphors for anti-counterfeiting applications5Enhanced quantum efficiency and thermal stability of cyan-green emitting BaLu2Al3ScGeO12: Ce3+, Si4+ phosphor via cation substitution for WLEDs13Novel phosphor K3YSi2O7:Bi3+/ Eu3+ for dual-mode optical thermometry and multicolor anti-counterfeiting13Efficient Tuning of Blue-to-Cyan-Green Emission in Bismuth(III)-Doped Alkaline-Earth Aluminates via Crystal Site Engineering2Site-selected emission and excitation of Bi3+-activated scandium silicate used for multi-mode fluorescent anti-counterfeiting and WLEDs4Solvent-free synthesis of rare-earth-doped zirconia ceramic nanofiber films with enhanced luminescence for anti-counterfeiting and warm white lighting1Emission spectrum Matched-degree approaching 99.4 % sunlight-like full-spectrum white-light phosphors3Lanthanide-activated single-phosphor white light emission via Bi3+ → Eu3+ energy transfer in Ca₂Ga₂GeO₇ for next-generation LEDs1Doping-induced phase transition and tunable luminescence of Sr9Tm(VO4)7:Eu3+ phosphor for multifunctional applications0Sb5+-Nb5+ substitution driven structural tuning and luminescence enhancement of Mn4+-activated double perovskite phosphors1Multi-sites induced multicolor emissions of Bi3+-Activated aluminate with excellent thermal and chemical stability used for dynamic fluorescent anti-counterfeiting1Multisite-selective occupancy enabled luminescence tuning in aluminate-gallate solid solutions for solid-state lighting0All biogenic phosphors: Albumen, chlorophylls, silk fibroin toward biohybrid white light-emitting diodes0Enhanced and tunable white luminescence in NaGdGeO₄: Bi3+, Dy3+ phosphors featuring anomalous thermal quenching0Bi2-xLaTiVO9:xEu3+: A highly thermally stable red phosphor for W-LED and plant growth lighting0Evolution of lighting technologies: The central role of rare-earth-doped materials in advancing modern illumination0Advancing health-oriented LED illumination using an excellent broadband cyan-emitting Ba2MgGe2O7:Bi3 + phosphor0

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  41. Energy transfer mediated single-phased white light emission in Bi3+-Eu3+ codoped Ba3YGa2O7.5 for WLED

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