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RESEARCH PAPER · Inorganic Chemistry · 2018

Full Color Luminescence Tuning in Bi 3+ /Eu 3+ -Doped LiCa 3 MgV 3 O 12 Garnet Phosphors Based on Local Lattice Distortion and Multiple Energy Transfers

Peipei Dang, Sisi Liang, Guogang Li, Yi Wei, Ziyong Cheng, Hongzhou Lian, Mengmeng Shang, Abdulaziz Abdullah Al Kheraif, Jun Lin

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Full Color Luminescence Tuning in Bi 3+ /Eu 3+ -Doped LiCa 3 MgV 3 O 12 Garnet Phosphors Based on Local Lattice Distortion and Multiple Energy TransfersOriginalA novel Sm 3+ singly doped LiCa 3 ZnV 3 O 12 phosphor: a potential luminescent material for multifunctional applications85Photoluminescence tuning in a novel Bi 3+ /Mn 4+ co-doped La 2 ATiO 6 :(A = Mg, Zn) double perovskite structure: phase transition and energy transfer78Tunable emission of LiCa3MgV3O12:Bi3+ via energy transfer and changing excitation wavelength56Red-emitting phosphor Na2Ca2Nb4O13:Eu3+ for LEDs: Synthesis and luminescence properties53Morphology evolution of Eu 3+ -activated NaTbF 4 nanorods: a highly-efficient near-ultraviolet light-triggered red-emitting platform towards application in white light-emitting diodes93Broad-band emission and color tuning of Eu3+-doped LiCa2SrMgV3O12 phosphors for warm white light-emitting diodes18Site-Bi3+ and Eu3+ dual emissions in color-tunable Ca2Y8(SiO4)6O2:Bi3+, Eu3+ phosphors prepared via sol-gel synthesis for potentially ratiometric temperature sensing106A single-phase NaCa2Mg2V3O12:Sm3+ phosphor: Synthesis, energy transfer, and luminescence properties76Synthesis, energy transfer and multicolor luminescent property of Eu3+-doped LiCa2Mg2V3O12 phosphors for warm white light-emitting diodes31Highly bright multicolor-tunable KSrLu(PO4)2:Ce3+, Tb3+, Mn2+ phosphors via efficient energy transfer15Novel high-efficiency violet-red dual-emitting Lu2GeO5: Bi3+, Eu3+ phosphors for indoor plant growth lighting41Enhanced emission from thermally stable Eu3+ doped CaB2Si2O8 red phosphors via alkali metal modification for W-LEDs application17Realization of color-tunable emission via energy transfer in novel single-phase K3YB6O12:Bi3+, Eu3+ phosphors2Dual-functional of non-contact thermometry and field emission displays via efficient Bi3+ → Eu3+ energy transfer in emitting-color tunable GdNbO4 phosphors296A study of optical properties and site preference of Bi3+/Eu3+ co-doped CaLa4Si3O13 red-emitting phosphors for w-LED applications47Synthesis, energy transfer mechanism, and tunable emissions of novel Na3La(VO4)2:Re3+ (Re3+ = Dy3+, Eu3+, and Sm3+) vanadate phosphors for near-UV-excited white LEDs45A deep-red-emitting Bi3+/Mn4+-doped CaLi6La2Nb2O12 phosphor: Luminescence and energy transfer properties36Thermally stable Na3.6Y1.8(PO4)3:Eu3+ phosphor, luminescent properties and application in WLEDs27Color manipulation of Bi 3+ -activated CaZnOS under stress with ultra-high efficiency and low threshold for anticounterfeiting applications62Luminescence properties and energy transfer of novel Bi 3+ and Mn 2+ -co-activated Y 3 Ga 5 O 12 single-component white light-emitting phosphor54The optical properties of Bi 3+ and Sb 3+ in YNbTiO 6 analysed by means of DOS and semi-empirical calculations18Tunable photoluminescence from YTaO 4 :Bi 3+ for ultraviolet converted pc-WLED with high chromatic stability63Red emitting Ba2GdVO6:Eu3+ phosphors for blue light converted warm white LEDs43Tunable color emission in LaScO 3 :Bi 3+ ,Tb 3+ ,Eu 3+ phosphor47Mechanistic Insight into Energy‐Transfer Dynamics and Color Tunability of Na4CaSi3O9:Tb3+,Eu3+ for Warm White LEDs37Yellow Emission Obtained by Combination of Broadband Emission and Multi-Peak Emission in Garnet Structure Na2YMg2V3O12: Dy3+ Phosphor13Tunable dual emission of Bi3+ and Mn4+ co-doped LaMg0.598Nb0.402O3 double perovskite via energy transfer for plant growth lighting21A novel green-emitting Ni2+-doped Ca-Li hydroxyapatite nanopowders: structural, optical, and photoluminescence properties13Synthesis and Luminescence Properties of SrGd2O4:Eu3+ Red Phosphors8Enhancing thermometric performance via improving indicator signal in Bi3+-doped CaNb2O6:Ln3+ (Ln = Eu/Sm/Dy/Tb) phosphors143A Novel Highly Efficient Host‐Sensitized Red Emitting (Ba 2 YV 3 O 11 : Eu 3+ ) Phosphor for Hybrid White LEDs24Emission improvement and tunable emission properties of SrZrSi2O7:R (R = Sm3+ and Sm3+/Bi3+) phosphors31Recent Advances in Bismuth Ion‐Doped Phosphor Materials: Structure Design, Tunable Photoluminescence Properties, and Application in White LEDs363An orange‐emitting phosphor BaSrGa 4 O 8 :Bi 3+ ,K + with unique one‐dimensional chain structure for high index color WLEDs18Tailoring narrow-band blue emitting Ca7(Mg, Zn)2P6O24: Eu2+ phosphate phosphor via crystal lattice distortion for WLEDs12High-efficiency fully concentrated Na3Eu(VO4)2 phosphor with excellent thermal stability for white light-emitting diodes4Luminescence color tuning of Ce3+ and Tb3+ co-doped Ca2YZr2Al3O12 phosphors with high color rendering index via energy transfer20Structural, Vibrational, Optical and Improved Photoluminescence Properties of Dy3+ Doped Ca2KZn2V3O12 Phosphors16A promising blue-emitting phosphor CaYGaO 4 :Bi 3+ for near-ultraviolet (NUV) pumped white LED application and the emission improvement by Li + ions89Tunable photoemission and energy transfer of heavily Bi3+,Eu3+ co-doped Y4GeO8 phosphors40Design of white-emitting optical temperature sensor based on energy transfer in a Bi 3+ , Eu 3+ and Tb 3+ doped YBO 3 crystal44Synthesis and luminescence properties of double perovskite Bi3+/Mn4+ co-doped Ca2GdTaO6 phosphor40Luminescent properties of Na2GdMg2(VO4)3:Eu3+ red phosphors for NUV excited pc-WLEDs59A novel red-emitting Ca2GdHf2Al3O12:Eu3+ phosphor for light-emitting didoes and field emission display25Designing multi-mode optical thermometers via the thermochromic LaNbO4:Bi3+/Ln3+ (Ln = Eu, Tb, Dy, Sm) phosphors321Novel and wide-ranging color tuning photoluminescence properties of Tb3+/Eu3+ doped garnet-type Li3Lu3Te2O12 phosphor: Energy transfer and enhanced thermal stability70Tunable luminescence property and optical temperature sensing performance of Bi3+ and Sm3+ co-doped Ca2YZr2Al3O12 phosphors39Distortion and energy transfer assisted tunability in garnet phosphors62Photoluminescence properties of y at.% Eu3+-doped Gd(NbxP1-x)O4: A color-tunable orange-red phosphor3Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Artificial mimics of light-harvesting organic pigment via a double-perovskite structure (LiLa2SbO6:Bi3+, Mg2+, Mn4+) with single-composition and structure-activity relationship5A ratiometric optical thermometer based on Bi3+ and Mn4+ co-doped La2MgGeO6 phosphor with high sensitivity and signal discriminability66Luminescence properties and energy transfer mechanism of La2ZnTiO6:Mn4+/Er3+ far-red/green dual-emitting phosphors for plant lighting11Enhanced self-host blue emission of CaSrSb2O7 materials via Bi3+ ion doping for high CRI WLEDs, security inks and flexible displays19Extension of Spectral Shift Controls from Equivalent Substitution to an Energy Migration Model Based on Eu2+/Tb3+-Activated Ba4–xSrxGd3–xLuxNa3(PO4)6F2 Phosphors11Pressure-sensitive Ce 3+ photoluminescence in LiCaY 5 (BO 3 ) 6 : high internal quantum yields and energy transfer to Tb 3+13Utilizing the energy transfer mechanism to realize color tunable luminescence14Multiple energy transfer between CaNb2O6:Tb3+, Eu3+ for single-component white light-emitting phosphors6A potential red-emitting phosphor Na2.5Zr2Si1.5P1.5O12: Eu3+ for WLEDs with excellent thermal stability, color purity and high quantum efficiency41Luminescence depreciation in ScVO4:Bi3+ upon irradiation in the Bi3+-related absorption bands5Photoluminescence of Bi3+ in LiCaY5(BO3)6 and color-tunable emission through energy transfer to Eu3+/Tb3+11Color-tunable emissions in Bi3+/Eu3+ activated phosphors for multi-mode optical thermometers35High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors35Synthesis and photoluminescence properties of Eu3+-doped Na2YMg2V3O12: A novel red-emitting phosphor for WLEDs11Color‐Tunable Single‐Phase Bi 3+ /Eu 3+ ‐Activated LiCa 3 ZnV 3 O 12 Luminescence Materials Based on Energy Transfer4Color-tunable emissions realized by Tb 3+ to Eu 3+ energy transfer in ZnGdB 5 O 10 under near-UV excitation9Luminescence–structure relationships in solids doped with Bi 3+57Multi-Color Tunable Emission of Bi3+,Eu3+ Co-Doped Ca3liznv3o12 Phosphors for Warm White Light-Emitting Diodes0Recent progress in trivalent europium (Eu 3+ )-based inorganic phosphors for solid-state lighting: an overview72A three-mode optical thermometry based on thermochromic Gd2GaSbO7:Bi3+,Eu3+ phosphors57Optical thermometry based on Bi3+,Ln3+ co-doped YNbO4 (Ln = Dy, Eu) phosphors63Strategic Tuning of Photophysical Response in the Polyhedral Framework of the Garnet Structure toward White Light-Emitting Devices with Enhanced Color Rendering20Preparation and luminescence investigations of garnet-based Y2Ca2Ga3VO12:RE (RE = Eu3+, Sm3+, and Dy3+) phosphors13Dual-mode optical thermometers based on YNbO4:Bi3+,Sm3+ phosphors21A self-referenced fluorescence intensity ratio optical temperature sensing materials K3YSi2O7:Bi3+/Sm3+based on multi-strategy combination32Eu3+ doped Ca3LiZnV3O12 phosphors for four-mode optical thermometry38Multi‐color luminescence of Sm3+‐doped Na2YMg2V3O12 phosphor potentially applicable in white‐LEDs5Efficient upconversion and downshifting luminescence of CaIn2O4: Yb3+/Tm3+/RE3+ (RE=Er/Ho) phosphor: Temperature sensing performance in the visible and near-infrared range26Na 2 GdMg 2 V 3 O 12 :Sm 3+ phosphors for three‐mode optical temperature sensing40A dual-mode optical thermometer based on dual-excitation Bi3+,Sm3+ co-doped Y4GeO8 phosphors73Multi-color tunable emission of Bi3+,Eu3+ co-doped Ca3LiZnV3O12 phosphors for warm white light-emitting diodes14Luminescence properties of Bi 3+ /Sm 3+ co-doped K 3 Gd 5 (PO 4 ) 6 phosphors for self-referencing optical thermometry30SrGa 2 B 2 O 7 : Bi 3+ , M + (M = Li, Na, K), Novel Deep‐Blue Phosphors with High Quantum Yields and Negative Thermal Quenching for High‐Quality White LED22Two-Dimensional Hybrid Perovskite with High-Sensitivity Optical Thermometry Sensors7Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers3A competitive trivalent-europium-activated phosphor: Achieving highly efficient red light emission in a sodium-rich garnet host17Thermally stable and red emitting bismuth ions sensitized SrGa2O4:Eu3+ phosphors for phosphor converted WLED applications8Bi 3+ /Eu 3+ Co‐Activated Multimode Anti‐Counterfeiting Material with White Light Emission and Orange‐Yellow Persistent Luminescence37Towards White Light Emission Through Metal‐to‐Metal Charge Transfer (MMCT) Effect in Bi3+ Activated Ca2YTi2‐mZrmGa3O12 (0≤m≤2) Garnets8Near infrared emission in garnet structured LiCa3MgV3O12:Nd3+/Yb3+ phosphor13A novel palmierite-type Sr9La(VO4)7: xEu3+ phosphors with superior quantum efficiency via defect engineering11A Ca 7 Mg 1.8 Zn 0.2 Ga 6 O 18 :Bi 3+ /Mn 4+ phosphor: energy transfer enables tuneable colour emission and high sensitivity in optical thermometry3Bi 3+ -sensitized Dy 3+ emission for tunable luminescence and efficiency enhancement in LiY 6 O 5 (BO 3 ) 3 phosphors4Crystallographic site engineering of a single Bi 3+ -doped single-component Ca 5 Ga 6 O 14 :Bi 3+ phosphor for full-spectrum white light emission and highly sensitive optical thermometry10Electronic structure analysis, a large Stokes shift of Bi 3+ in BiSr 3 (YO) 3 (BO 3 ) 4 and color-tunable emissions by energy transfer to Eu 3+ dopants0Na2YMg2V3O12:Dy3+, Eu3+ wideband absorption phosphors suitable for near ultraviolet excitation4Dual-emissive Bi3+, Cr3+ Co-doped K2LiGaF6 phosphors: Achieving white and near-infrared light for innovative applications in food detection and bio-imaging10Red Color Tuning and Emission Enhancement in Thermally Stable Co‐Doped Ba 3 MoTiO 8 : Bi 3+ /Eu 3+ Phosphors for Photo‐Electronic Applications3Near-infrared luminescence and temperature sensing properties of Sc2Mo3O12:Nd3+/Yb3+/Ho3+ phosphor13Enhanced Red Emission from Bi3+ Sensitized Eu3+ Activated BaLaGa3O7 Phosphors for Solid-State Lighting Applications2Synthesis and luminescence properties of LiY(WO4)2:Bi3+ broadband yellow-emitting phosphor for high-quality NUV pumped WLEDs2Enhancing near-infrared luminescence of Cs2NaBiCl6:Yb3+/RE3+ (Er, Pr, Tm) double perovskite through codoping Cr3+ ions and bioimaging applications8Blue-light-excited broadband near-infrared garnet Ca3Zr2Ga2SiO12:Cr3+/Yb3+ phosphors for high-performance pc-LED applications4Lattice Distortion Promoting Wavelength‐Tunable Emissions in Cu(I)‐Based Halides for Thermography and Anti‐Counterfeiting29Lattice Distortion Promoting Wavelength‐Tunable Emissions in Cu(I)‐Based Halides for Thermography and Anti‐Counterfeiting0Achieving single-phase white light emission by utilizing the sensitization effect of Bi3+ to Eu3+ and Tb3+ in LiY6O5(BO3)36Recent Advances in Vanadate Phosphor Materials: Synthesis and Optoelectronic Applications: A Comprehensive Review13Excitation wavelength-dependent color-tunable emitting phosphor CaCd2ZnZrGe3O12:Sm3+ for multi-mode optical anti-counterfeiting1Enhanced red luminescence via Dy3+-mediated energy transfer in garnet-type Vanadates Na2Dy1-Eu Mg2V3O121Enhancement of Red Luminescence in Eu 3+ ‐Concentrated EuNa 2 Mg 2 V 3 O 12 Phosphor via La 3+ Co‐Doping1Bi2-xLaTiVO9:xEu3+: A highly thermally stable red phosphor for W-LED and plant growth lighting0Emitting-color-tunable Ca2YGa3Ge2O12: Bi3 +, Eu3+ garnet phosphors for high-contrast fingerprint visualization and temperature sensing0

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  1. A novel Sm 3+ singly doped LiCa 3 ZnV 3 O 12 phosphor: a potential luminescent material for multifunctional applications

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  12. Enhanced emission from thermally stable Eu3+ doped CaB2Si2O8 red phosphors via alkali metal modification for W-LEDs application

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  13. Realization of color-tunable emission via energy transfer in novel single-phase K3YB6O12:Bi3+, Eu3+ phosphors

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  14. Dual-functional of non-contact thermometry and field emission displays via efficient Bi3+ → Eu3+ energy transfer in emitting-color tunable GdNbO4 phosphors

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  15. A study of optical properties and site preference of Bi3+/Eu3+ co-doped CaLa4Si3O13 red-emitting phosphors for w-LED applications

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  16. Synthesis, energy transfer mechanism, and tunable emissions of novel Na3La(VO4)2:Re3+ (Re3+ = Dy3+, Eu3+, and Sm3+) vanadate phosphors for near-UV-excited white LEDs

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  30. Enhancing thermometric performance via improving indicator signal in Bi3+-doped CaNb2O6:Ln3+ (Ln = Eu/Sm/Dy/Tb) phosphors

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  31. A Novel Highly Efficient Host‐Sensitized Red Emitting (Ba 2 YV 3 O 11 : Eu 3+ ) Phosphor for Hybrid White LEDs

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  32. Emission improvement and tunable emission properties of SrZrSi2O7:R (R = Sm3+ and Sm3+/Bi3+) phosphors

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  33. Recent Advances in Bismuth Ion‐Doped Phosphor Materials: Structure Design, Tunable Photoluminescence Properties, and Application in White LEDs

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  34. An orange‐emitting phosphor BaSrGa 4 O 8 :Bi 3+ ,K + with unique one‐dimensional chain structure for high index color WLEDs

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  35. Tailoring narrow-band blue emitting Ca7(Mg, Zn)2P6O24: Eu2+ phosphate phosphor via crystal lattice distortion for WLEDs

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  36. High-efficiency fully concentrated Na3Eu(VO4)2 phosphor with excellent thermal stability for white light-emitting diodes

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  37. Luminescence color tuning of Ce3+ and Tb3+ co-doped Ca2YZr2Al3O12 phosphors with high color rendering index via energy transfer

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  38. Structural, Vibrational, Optical and Improved Photoluminescence Properties of Dy3+ Doped Ca2KZn2V3O12 Phosphors

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  39. A promising blue-emitting phosphor CaYGaO 4 :Bi 3+ for near-ultraviolet (NUV) pumped white LED application and the emission improvement by Li + ions

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  40. Tunable photoemission and energy transfer of heavily Bi3+,Eu3+ co-doped Y4GeO8 phosphors

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  41. Design of white-emitting optical temperature sensor based on energy transfer in a Bi 3+ , Eu 3+ and Tb 3+ doped YBO 3 crystal

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  45. Designing multi-mode optical thermometers via the thermochromic LaNbO4:Bi3+/Ln3+ (Ln = Eu, Tb, Dy, Sm) phosphors

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  46. Novel and wide-ranging color tuning photoluminescence properties of Tb3+/Eu3+ doped garnet-type Li3Lu3Te2O12 phosphor: Energy transfer and enhanced thermal stability

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  47. Tunable luminescence property and optical temperature sensing performance of Bi3+ and Sm3+ co-doped Ca2YZr2Al3O12 phosphors

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  48. Distortion and energy transfer assisted tunability in garnet phosphors

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  49. Photoluminescence properties of y at.% Eu3+-doped Gd(NbxP1-x)O4: A color-tunable orange-red phosphor

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  50. Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications

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