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RESEARCH PAPER · Journal of Materials Chemistry C · 2018

Broad color tuning of Bi 3+ /Eu 3+ -doped (Ba,Sr) 3 Sc 4 O 9 solid solution compounds via crystal field modulation and energy transfer

Peipei Dang, Sisi Liang, Guogang Li, Hongzhou Lian, Mengmeng Shang, Jun Lin

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Broad color tuning of Bi 3+ /Eu 3+ -doped (Ba,Sr) 3 Sc 4 O 9 solid solution compounds via crystal field modulation and energy transferOriginalNear-ultraviolet excited Tm3+ and Dy3+ ions co-doped barium lanthanum silica oxide phosphors for white-light applications38Tunable photoluminescence properties and energy transfer of Ca5(BO3)3F: Tb3+/Eu3+ phosphors for solid state lighting27Luminescence quenching properties of Sr2Ga2GeO7: Pr3+ with and without traps participation18A narrow-band blue emitting phosphor Ca 8 Mg 7 Si 9 N 22 :Eu 2+ for pc-LEDs49A strategy for developing thermal-quenching-resistant emission and super-long persistent luminescence in BaGa 2 O 4 :Bi 3+62Luminescence color tuning and energy transfer properties in (Sr,Ba) 2 LaGaO 5 :Bi 3+ ,Eu 3+ solid solution phosphors: realization of single-phased white emission for WLEDs107Tuning the Bi 3+ -photoemission color over the entire visible region by manipulating secondary cations modulation in the ScV x P 1−x O 4 :Bi 3+ (0 ≤ x ≤ 1) solid solution67A novel red phosphor Ba2La4Y4(SiO4)6O2:Eu3+ with high quantum yield and thermal stability for warm white LEDs81High-purity upconversion output color and excellent optical thermometry performance of lanthanide-doped Ba3Y4O927An abnormal yellow emission and temperature-sensitive properties for perovskite-type Ca2MgWO6 phosphor via cation substitution and energy transfer39Giant Photoluminescence Improvement and Controllable Emission Adjustment in Bi3+-Activated Ca4ZrGe3O12 Phosphors for High-Quality White Light-Emitting Diodes42Realization of color-tunable emission via energy transfer in novel single-phase K3YB6O12:Bi3+, Eu3+ phosphors2Energy transfer and tunable photoluminescence of Sr6Gd2Na2(PO4)6F2:Tb3+, Eu3+ phosphors for near-UV white LEDs8Tunable emission of Sr3Sc(PO4)3: Tb3+, Eu3+ phosphors with efficient energy transfer and high thermal stability27Site occupancy and tunable photoluminescence properties of Eu2+-Activated Ba3Sc(BO3)3 phosphors for white light emitting diodes33Ratiometric optical thermometer based on the use of manganese(II)-doped Cs3Cu2I5 thermochromic and fluorescent halides39Synthesis, photoluminescence properties and potential applications of Eu3+ and Mn4+ activated SrLaMgNbO6 phosphors37The structures and luminescence properties of Sr 4 Gd 3 Na 3 (PO 4 ) 6 F 2 :Ce 3+ ,Tb 3+ green phosphors with zero-thermal quenching of Tb 3+ for WLEDs49Crystal structure refinement, photoluminescence properties and energy transfer of multicolor tunable Ca2Al2SiO7:Tm3+, Dy3+ for NUV white-light-emitting diodes20Bi3+ induced broad NUV-excitation band in Eu3+-doped red phosphor with scheelite-related structure19Bismuth activated high thermal stability blue-emitting phosphor Na 2 Y 2 B 2 O 7 :Bi used for near-UV white-light LEDs74Color manipulation of Bi 3+ -activated CaZnOS under stress with ultra-high efficiency and low threshold for anticounterfeiting applications62Color tuning of Bi 3+ -doped double-perovskite Ba 2 (Gd 1−x ,Lu x )NbO 6 (0 ≤ x ≤ 0.6) solid solution compounds via crystal field modulation for white LEDs9Facile solution synthesis of Bi 3+ /Yb 3+ ions co-doped Cs 2 Na 0.6 Ag 0.4 InCl 6 double perovskites with near-infrared emission32Luminescence properties and energy transfer of novel Bi 3+ and Mn 2+ -co-activated Y 3 Ga 5 O 12 single-component white light-emitting phosphor54Tunable color emission in LaScO 3 :Bi 3+ ,Tb 3+ ,Eu 3+ phosphor47Yellow/Orange-Emitting ABZn 2 Ga 2 O 7 :Bi 3+ (A = Ca, Sr; B = Ba, Sr) Phosphors: Optical Temperature Sensing and White Light-Emitting Diode Applications256Photoluminescence properties and energy transfer of high thermal stable Na2GdPO4F2:RE (RE = Sm3+, Ce3+, Tb3+) phosphor for solid-state lighting21Recent Advances in Bismuth Ion‐Doped Phosphor Materials: Structure Design, Tunable Photoluminescence Properties, and Application in White LEDs363Ultra-high color rendering warm-white light-emitting diodes based on an efficient green-emitting garnet phosphor for solid-state lighting276Enhanced Cyan Emission and Optical Tuning of Ca 3 Ga 4 O 9 :Bi 3+ for High‐Quality Full‐Spectrum White Light‐Emitting Diodes139Adjustable photoluminescence of Bi3+ and Eu3+ in solid solution constructed by isostructural end components through composition and excitation-driven strategy90A solid-solution modulation strategy in trivalent bismuth-doped gallate phosphors for single substrate tunable emission5Bi 3+ photoluminescence in Y 1− x Bi x Ca 3 (GaO) 3 (BO 3 ) 4 and energy transfer to Eu 3+ and Tb 3+ in co-doped phosphors9Complex crystal structure and photoluminescence of Bi 3+ -doped and Bi 3+ /Eu 3+ co-doped Ca 7 Mg 2 Ga 6 O 1819Design of white-emitting optical temperature sensor based on energy transfer in a Bi 3+ , Eu 3+ and Tb 3+ doped YBO 3 crystal44Preparation of zero-thermal-quenching tunable emission bismuth-containing phosphors through the topochemical design of ligand configuration31Regulating the trap distribution to achieve high-contrast mechanoluminescence with an extended saturation threshold through co-doping Nd 3+ into CaZnOS:Bi 3+ ,Li +42Sr 3 Y(BO 3 ) 3 :Bi 3+ phosphor with excellent thermal stability and color tunability for near-ultraviolet white-light LEDs84A single-phase full-color phosphor Sr2Ca2La(PO4)3O:Eu2+,Tb3+,Mn2+: Photoluminescence and energy transfer16Realization of warm white light emitting in single phase Gd(P V1)O4:y at% Sm3+,1 at% Bi3+ phosphor23First-Principles Study of Bi 3+ -Related Luminescence and Electron and Hole Traps in (Y/Lu/La)PO 456Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor21Dual emitting from Bi3+/Eu3+ co-activated Sr3La2Ge3O12 phosphor for optical thermometry34Simultaneous Broadening and Enhancement of Cr 3+ Photoluminescence in LiIn 2 SbO 6 by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications325Simultaneous Broadening and Enhancement of Cr3+Photoluminescence in LiIn2SbO6by Chemical Unit Cosubstitution: Night‐Vision and Near‐Infrared Spectroscopy Detection Applications5Utilizing energy transfer strategy to produce efficient green luminescence in Ca2LuHf2Al3O12:Ce3+,Tb3+ garnet phosphors for high-quality near-UV-pumped warm-white LEDs52Tuning Emission from Greenish to Blue via Chemical Composition Modulation in Solid Solutions (Sr 1– y Ca y ) 2 Sb 2 O 7 :Bi 3+ under near-UV Light Excitation63Bismuth activated blue phosphor with high absorption efficiency for white LEDs55Artificial mimics of light-harvesting organic pigment via a double-perovskite structure (LiLa2SbO6:Bi3+, Mg2+, Mn4+) with single-composition and structure-activity relationship5Visible and Near-Infrared Emission in Ba 3 Sc 4 O 9 :Bi Phosphor: An Investigation on Bismuth Valence Modification32Constructing a Model for Tuning the Thermal Quenching Properties of Bismuth-Doped Phosphors by Energy-Gap Modulation34Extension of Spectral Shift Controls from Equivalent Substitution to an Energy Migration Model Based on Eu2+/Tb3+-Activated Ba4–xSrxGd3–xLuxNa3(PO4)6F2 Phosphors11Crystal structure, luminescence properties and thermal stability of Lu3+ ion-substituted BaY2Si3O10: Dy3+ phosphors18The downconversion luminescence properties of Y3Al5O12: Bi3+/Sm3+ phosphors with tunable emissions11Realization of an Optical Thermometer via Structural Confinement and Energy Transfer39Broad luminescence tuning in Mn 2+ -doped Rb 2 Zn 3 (P 2 O 7 ) 2 via doping level control based on multiple synergies10Tunable concentration/excitation-dependent deep-red and white light emission in single-phase Eu 2+ -activated Sc-based oxide phosphors for blue/UV-LEDs32Ba2(Y,Sc)NbO6:Bi3+ solid solution nanocrystals: synthesis, photoluminescence properties, and white LEDs application2Tendentious multiple sites occupation towards white light emission in single-phase Ba2(1-/3)Ca(1-/3)Sr B2Si4O14:Eu2+ phosphors16Green-emitting Bi3+-doped La2SrSc2O7 phosphor for pc-WLED lighting: Luminescent properties and energy transfer strategy50Tuning of emission by effect of local symmetry in BaLaLiWO6:Dy3+/Eu3+ for WLEDs41Systematical site investigation and temperature sensing in Pr3+-doped M3RE4O9 (M = Sr and Ba; RE = Sc, Y, Lu)18High sensitivity and multicolor tunable optical thermometry in Bi3+/Eu3+ co-doped Ca2Sb2O7 phosphors64Tuning the thermal quenching properties of Ga3+-modified LiTaO3:Bi3+ phosphor through defect engineering strategy12Ba 3 LuGa 2 O 7.5 :Bi 3+ phosphors with potential application in full-spectrum WLEDs and temperature sensing73Exclusive confinement of Bi 3+ -activators in the triangular prism enabling efficient and thermally stable green emission in the tridymite-type phosphor CaBaGa 4 O 8 :Bi 3+13Luminescence–structure relationships in solids doped with Bi 3+57Modulation of Bi 3+ luminescence from broadband green to broadband deep red in Lu 2 WO 6 by Gd 3+ doping and its applications in high color rendering index white LED and near-infrared LED18Optical band gaps and spectroscopy properties of Bi m + /Eu n + /Yb 3+ co-doped ( m = 0, 2, 3; and n = 2, 3) zinc calcium silicate glasses5Site occupation and upconversion process enabled multicolor emission in a Gd 3 GaO 6 :Bi 3+ ,Er 3+ phosphor for quad-mode anti-counterfeiting23Tunable luminescence in Eu 3+ /Sm 3+ single-doped LuNbO 4 for optical thermometry and anti-counterfeiting59Screening of Broadband Near-Infrared Cr3+-Activated Phosphors Using Ce3+ as a Probe39Low temperature photo-luminescence properties of Bi3+ doped Ca3Ga4O9 phosphor6Optical memory and anti-counterfeiting application based on luminescence reversible modification and color contrast of photochromic phosphor52Enhanced Luminescence of Long-Wavelength Broadband Near-Infrared Germanate Phosphors9Tunable luminescence and efficient energy transfer investigation of a borosilicate phosphor KBSi2O6: Bi3+, Eu3+ with hypersensitive thermal quenching7Novel color tunable LaCaGaO 4 :Bi 3+ ,Eu 3+ phosphors for high color rendering warm white LEDs18Regulation of Bi3+ emission in Ca3Ga4O9 phosphors through doping concentration and solid-solution component design15Tunable luminescence and noncontact temperature sensing of oxyfluoride glass ceramics containing Na(Y1.5Na0.5)F6:Bi3+/Eu3+ nanocrystals8Energy transfer and photoluminescence properties of CaYGaO4:Bi3+,Tb3+ phosphors14White light emitting devices with high color rendering index and electrically adjustable color temperature11A new cyan phosphor NaAlO2:Bi3+ with high luminescent thermal stability5Synthesis of Bi3+ and Eu3+ co-doped Na4CaSi3O9 blue-red light tunable emission phosphors for inducing plant growth43Crystal-Site Engineering of Novel Na3kmg7(Po4)6-X(Bo3)X: Eu2+ Phosphor for Full-Spectrum Lighting0Luminescence and Optical Temperature Sensing Performance Via Efficient Tb3+-Eu3+Energy Transfer in Color-Tunable Ba9y2si6o24 Phosphors0Structure, luminescence properties, and valence-induced spectral behavior of a bismuth-activated garnet phosphor9Crystal-Site Engineering of Novel Na3KMg7(PO4)6–x(BO3)x:Eu2+ Phosphors for Full-Spectrum Lighting10Double perovskite CaSrMSbO6(M = La, Gd, Y): Bi3+ phosphors for multifunctional application9Development of highly thermal-stable blue emitting Y4Al2O9:Bi3+ phosphors for w-LEDs, fingerprint and data security applications23Electronic structure analysis, a large Stokes shift of Bi 3+ in BiSr 3 (YO) 3 (BO 3 ) 4 and color-tunable emissions by energy transfer to Eu 3+ dopants0Tunable photoluminescence and energy transfer in Dy 3+ and Eu 3+ co-doped NaCaGd(WO 4 ) 3 phosphors for pc-WLED applications9Energy transfer mediated single-component white light emission in a novel Bi3+/Eu3+ co-doped Sr2Ga2GeO7 phosphor for white LEDs20Cationic substitution induces multicolor emission in YBaZn3-yMgyGaO7: Bi3+ phosphors for WLEDs and information encryption13High-brightness Bi3+ activated Gd2GeO5 blue phosphor for white light-emitting diodes: Synthesis, characterization, and thermal stability2High-sensitivity single-band ratiometric thermometry in Bi3+/Eu3+ co-doped La2GeO5 phosphors via temperature-dependent energy transfer9Effect of Ca2+ partial substitution with Mg2+ on luminescence enhancement of Ca3Ga4O9:Bi3+ cyan-emitting phosphors for warm WLEDs4Wavelength-Tunable of Broad Red to Near-Infrared Emission in (Sr,Ba)3Sc4O9 :Eu2+ Phosphors: Crystal Field Effects and Thermal Stability6Intrinsic defects and Bi3+ luminescence in Ba3Sc4O9: a first-principles study2Efficient Tuning of Blue-to-Cyan-Green Emission in Bismuth(III)-Doped Alkaline-Earth Aluminates via Crystal Site Engineering2Orange-red emission in BaSc2O4:Sm3+ toward near-ultraviolet-LED-driven white lighting with high color rendering index0Manipulating Persistent Luminescence via Chemical Unit Cosubstitution in Gallate Spinel Li 1– x Mg 2 x Ga 5– x O 8 :Cr 3+ Solid Solution2Broad visible emission from a blue-light-excitable single-phase NaLaS 2 :Bi 3+ phosphor for high-CRI white LEDs0Red/near-infrared emitting phosphors based on Bi 3+ ions: recent advances, materials design, and applications3Towards a universal ansatz for heat-induced emission peak shifts: insights from M 2 SiO 4 :Eu 2+ (M = Sr, Ba, Ca) phosphors2Recent advances on zinc- and/or sulfur-containing mechanoluminescent materials and their spectroscopic properties toward diverse applications1Locking Broadband Bi 3+ Luminescence Color From 6 to 423 K0

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