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RESEARCH PAPER · Accounts of Chemical Research · 2017

Chemistry-Inspired Adaptable Framework Structures

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Chemistry-Inspired Adaptable Framework StructuresOriginalA broad-band orange-yellow-emitting Lu 2 Mg 2 Al 2 Si 2 O 12 : Ce 3+ phosphor for application in warm white light-emitting diodes57Composition design, optical gap and stability investigations of lead-free halide double perovskite Cs 2 AgInCl 6468Emerging La 2 O 2 CN 2 matrix with controllable 3D morphology for photoluminescence applications5Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds8Optical properties of Mn 2+ doped cesium lead halide perovskite nanocrystals via a cation–anion co-substitution exchange reaction86Unraveling the correlation between oxide-ion motion and upconversion luminescence in β-La 2 Mo 2 O 9 :Yb 3+ ,Er 3+ derivatives11Homologous Series of 2D Chalcogenides Cs–Ag–Bi–Q (Q = S, Se) with Ion-Exchange Properties27Semiconducting Pavonites CdMBi4Se8 (M = Sn and Pb) and Their Thermoelectric Properties25Luminescence properties of emission tunable single-phased phosphor La 7 O 6 (BO 3 )(PO 4 ) 2 : Ce 3+ , Tb 3+ , Eu 3+21New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials246Heterovalent B-Site Co-Alloying Approach for Halide Perovskite Bandgap Engineering55Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O7730Synthesis and tunable luminescence of Eu3+ and Eu2+ codoped LaSr2AlO5:Eu phosphors for LED application15Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials268Li 6 Na 3 Sr 14 Al 11 P 22 O 90 : an oxo-centered Al 3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers7A structural–electrical property correlation in A-site double substituted lanthanum aluminate24Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15Ba 3 B 10 O 17 Br 2 : a new barium borate halide with B–O layered structure4BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation26Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block19LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges10Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance30Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances32NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers9NH 4 B 11 O 16 (OH) 2 : a new ammonium borate with wavy-shaped polycyclic 2∞[B 11 O 16 (OH) 2 ] layers27Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures25Structural construction and photoluminescence tuning via energy transfer in apatite-type solid-state phosphors83Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials192Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials714From AgGaS2 to Li2ZnSiS4: Realizing Impressive High Laser Damage Threshold Together with Large Second-Harmonic Generation Response134Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System91LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20Pb8M(BO3)6 (M = Mg, Ca): Two new borates with large birefringence activated by the ∞[Pb8B6O18]2- double layers6Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)64Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses103Beyond the Compositional Threshold of Nanoparticle-Based Materials42Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe59Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics495Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics67Computer-Assisted Design of a Superior Be 2 BO 3 F Deep-Ultraviolet Nonlinear-Optical Material41New Eu3+-activated bismuthate tellurate LiSrBiTeO6 red-emitting phosphor for InGaN-based w-LEDs52Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system1Combination of d 10 -cations and fluorine anion as active participants to design novel borate/carbonate nonlinear optical materials24MIMIIP3O9 (MI = Rb, MII = Cd, Mg, Ca; MI = Cs, MII = Pb, Sr; MI = K, MII = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties35From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry33A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species56A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species5Red-Shifted Emission in Y3MgSiAl3O12:Ce3+ Garnet Phosphor for Blue Light-Pumped White Light-Emitting Diodes114Synthesis and optical properties of orange–red emitting Sm3+-activated Ca9LiGd2/3(PO4)7 phosphors3Approaches to design inorganic semiconductors while maintaining structural motifs2Advantageous Units in Antimony Sulfides: Exploration and Design of Infrared Nonlinear Optical Materials95Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates266Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Ba3Mg3(BO3)3F3 polymorphs with reversible phase transition and high performances as ultraviolet nonlinear optical materials471Learning from a Mineral Structure toward an Ultra‐Narrow‐Band Blue‐Emitting Silicate Phosphor RbNa3(Li3SiO4)4:Eu2+226Learning from a Mineral Structure toward an Ultra‐Narrow‐Band Blue‐Emitting Silicate Phosphor RbNa3(Li3SiO4)4:Eu2+129The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges16Next‐Generation Narrow‐Band Green‐Emitting RbLi(Li 3 SiO 4 ) 2 :Eu 2+ Phosphor for Backlight Display Application534Preparation and investigation of Dy3+-doped Ca9LiGd2/3(PO4)7 single-phase full-color phosphor44Dy3+ and Tm3+ doped YGa3(BO3)4 for near ultraviolet excited white phosphors25Exploration of bluish violet‐emitting phosphor Ca 3 Al 4 ZnO 10 :Ti 4+ with enhanced emission by Ca 2+ vacancies11Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances253Structure and Photoluminescence Properties of Sm3+ Ion-Doped LiSrBiTeO6 Phosphor9The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge17BaB2S4: An Efficient and Air-Stable Thioborate as Infrared Nonlinear Optical Material with High Laser Damage Threshold86Imaging and therapeutic applications of persistent luminescence nanomaterials316Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge4Theoretical design of multifunctional half-Heusler materials based on first-principles calculations7BaB8O12F2: a promising deep-UV birefringent material60A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23Changes of optical transition models caused by crystal structural changes in CaSe2O50Growth, Crystal Structures, and Characteristics of Li 5 ASrMB 12 O 24 (A = Zn, Mg; M = Al, Ga) with [MB 12 O 24 ] Frameworks12A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials78A thorough understanding of the nonlinear optical properties of BODIPY/carborane/diketopyrrolopyrrole hybrid chromophores: module contribution, linear combination, one-/two-dimensional difference and carborane's arrangement66ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences51Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction13An energy band engineering design to enlarge the band gap of KTiOPO 4 (KTP)-type sulfates via aliovalent substitution66An insight into the preferential substitution and structure repair in Eu 2+ -doped whitlockite-type phosphors based on the combined experimental and theoretical calculations21Ba 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement17Effect of polyhedral co-substitution on the crystal structure and luminescence color of Sr2(Al1–xMgx)(Al1–xSi1+x)O7: Eu2+1Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+90KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18Li 2 ZnGeS 4 : a promising diamond-like infrared nonlinear optical material with high laser damage threshold and outstanding second-harmonic generation response43LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68Metal-cation substitutions induced the enhancement of second harmonic generation in A 8 BS 6 (A = Cu, and Ag; B = Si, Ge, and Sn)14Mg(H 2 O) 6 B 4 O 5 (OH) 4 (H 2 O) 3 : a new hydrated borate with a short DUV cutoff edge9Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation23BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7Broadening Frontiers of Infrared Nonlinear Optical Materials with π-Conjugated Trigonal-Planar Groups67Synthesis and photoluminescence properties of BaGeTeO6:Eu3+ red-emitting phosphor for n-UV Light Emitting Diodes42Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties37Rational Design via Synergistic Combination Leads to an Outstanding Deep-Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5 Functional Gene284Ba4M(CO3)2(BO3)2 (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method29Versatile Molten Salt Synthesis of Manganite Perovskite Oxide Nanocrystals and Their Magnetic Properties13Targeting the Next Generation of Deep-Ultraviolet Nonlinear Optical Materials: Expanding from Borates to Borate Fluorides to Fluorooxoborates453CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure87CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)‐type Structure432Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution15NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14Module-Analysis-Assisted Design of Deep Ultraviolet Fluorooxoborates with Extremely Large Gap and High Structural Stability109Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)28Synthesis and optical properties of new red-emitting SrBi2Ta2O9:Eu3+ phosphor application for w-LEDs commercially based on InGaN65Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Luminescence properties of novel Eu 3+ ‐doped tantalate NaCaTiTaO 6 red‐emitting phosphors for solid‐state lighting27Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)33REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”97Prediction of Fluorooxoborates with Colossal Second Harmonic Generation (SHG) Coefficients and Extremely Wide Band Gaps: Towards Modulating Properties by Tuning the BO 3 /BO 3 F Ratio in Layers99Prediction of Fluorooxoborates with Colossal Second Harmonic Generation (SHG) Coefficients and Extremely Wide Band Gaps: Towards Modulating Properties by Tuning the BO3/BO3F Ratio in Layers24A novel green phosphor Sr8ZnY(PO4)7:Eu2+, Ln3+ (Ln = Pr, Tm, Yb) with broad emission band for high color rendering white-lighting-emitting diodes19Ba2M(C3N3O3)2 (M = Sr, Pb): Band Engineering from p−π Interaction via Homovalent Substitution in Metal Cyanurates Containing Planar π-Conjugated Groups39Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties21Preparation, characterization, and luminescence properties of BiLaWO6:Eu3+ red-emitting phosphors for w-LEDs24Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)17A solid-state chemist’s eye for the development of materials science in China5Histidinium‐Driven Chirality Control of Self‐Assembled Hybrid Molybdenum Oxyfluorides24Structural, magnetic and dielectric properties of reduced graphene oxide/ La0.9Bi0.1FeO3 nanocomposites58Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis36Sb3+ Doping-Induced Triplet Self-Trapped Excitons Emission in Lead-Free Cs2SnCl6 Nanocrystals282Realizing an impressive red-emitting Ca 9 MnNa(PO 4 ) 7 phosphor through a dual function based on disturbing structural confinement and energy transfer53Transformation of Optical Anisotropy Origins in Perovskite-Related Materials: A First-Principles Study23A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48Synthesis, structure, and third-harmonic generation measurements of a mixed alkali metal iodate, KLi2(IO3)323Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups12Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 1219(NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization31Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials28Large optical polarizability causing positive effects on the birefringence of planar-triangular BO 3 groups in ternary borates18Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design304Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer33The functionality of tetrahedral units in fluoroxoiodates: fluorine-modulating effects in iodates with lone pair electrons3Three diphosphates, α-Li 2 Na 2 P 2 O 7 , Li 8 Pb 3 Ba(P 2 O 7 ) 4 and Li 7 Rb(P 2 O 7 ) 2 : influences of co-substitution on the crystal structure9Tuning the Langasite, La 3 SbZn 3 Si 2 O 14 , towards white light emission: synthesis, structure, SHG and photoluminescence studies19Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design52Band-Gap Modulation of Nonlinear-Optical Fluorooxoborates by Controlling the F/B Ratios4Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff Edges26Effects of P2O7 clusters arrangement on second harmonic generation responses of pyrophosphates14Phase transition and fluorescence regulation of BaAl2Si2O8:Eu using Ba source18Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs2Ca2(SO4)320

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  2. Composition design, optical gap and stability investigations of lead-free halide double perovskite Cs 2 AgInCl 6

    Journal of Materials Chemistry A · 2017-01-01

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  3. Emerging La 2 O 2 CN 2 matrix with controllable 3D morphology for photoluminescence applications

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  4. Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds

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  5. Optical properties of Mn 2+ doped cesium lead halide perovskite nanocrystals via a cation–anion co-substitution exchange reaction

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  6. Unraveling the correlation between oxide-ion motion and upconversion luminescence in β-La 2 Mo 2 O 9 :Yb 3+ ,Er 3+ derivatives

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  11. Heterovalent B-Site Co-Alloying Approach for Halide Perovskite Bandgap Engineering

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  12. Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77

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  15. Li 6 Na 3 Sr 14 Al 11 P 22 O 90 : an oxo-centered Al 3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers

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  23. LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges

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  45. Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system

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