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RESEARCH PAPER · Journal of the American Chemical Society · 2017

Two-Step Design of a Single-Doped White Phosphor with High Color Rendering

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Two-Step Design of a Single-Doped White Phosphor with High Color RenderingOriginalSite occupancy and luminescence properties of Ca 3 Ln(AlO) 3 (BO 3 ) 4 :Ce 3+ ,Tb 3+ ,Mn 2+ (Ln = Y, Gd)45Tunable white light emitting Sr 2 V 2 O 7 :Bi 3+ phosphors: Role of bismuth ion54Site Occupancy Preference and Antithermal Quenching of the Bi2+ Deep Red Emission in β-Ca2P2O7:Bi2+62Novel single-phase full-color emitting Ba9Lu2Si6O24:Ce3+/Mn2+/Tb3+ phosphors for white LED applications37Giant Enhancement of Luminescence from Phosphors through Oxygen‐Vacancy‐Mediated Chemical Pressure Relaxation26Ca-α-SiAlON:Eu Phosphors: Oxidation States, Energy Transfer, and Emission Enhancement by Incorporation-Aimed Surface Engineering6Single-Phase White Light-Emitting Ca x Ba(9– x )Lu2Si6O24:Eu2+/Mn2+ Phosphors40Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials267A helical chain-like organic–inorganic hybrid arsenotungstate with color-tunable photoluminescence44A strategy for realizing tunable luminescence and full-color emission in Sr 3 Gd 2 (Si 3 O 9 ) 2 :Eu phosphors by introducing dual functional Mn 2+18Broad color tuning of Bi 3+ /Eu 3+ -doped (Ba,Sr) 3 Sc 4 O 9 solid solution compounds via crystal field modulation and energy transfer107Broad-band emission of A 3 B′B′′ 2 O 9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder14Controllable two-dimensional luminescence tuning in Eu 2+ ,Mn 2+ doped (Ca,Sr) 9 Sc(PO 4 ) 7 based on crystal field regulation and energy transfer61Preparation and photoluminescence properties of red-emitting phosphor ZnAl2O4:Eu3+with an intense5D0→7F2transition24Tunable luminescence properties and energy transfer of single-phase Ca4(PO4)2O: Dy3+, Eu2+ multi-color phosphors for warm white light21Photoluminescence properties and efficient energy transfer of Ce3+/Eu2+ activated K2Ba7Si16O40 phosphors15Reduction of Eu3+ to Eu2+ in α-Y2Si2O7 and X1-Y2SiO5 and their luminescent properties8White Light Emission and Enhanced Color Stability in a Single-Component Host161Photoluminescence and tunable emissions of La2(GeO4)O:Bi3+, Eu3+ phosphor for ultraviolet converted light emitting diodes38Construction of Eu2+ doped H3Sr6(PO4)5·2H2O with novel cruciate multilayer microarchitectures: facile hydrothermal synthesis, growth mechanism, and luminescence properties3Tb3+, Eu3+ Co-doped CsPbBr3 QDs Glass with Highly Stable and Luminous Adjustable for White LEDs191BaWO4:Ln3+ Nanocrystals: Controllable Synthesis, Theoretical Investigation on the Substitution Site, and Bright Upconversion Luminescence as a Sensor for Glucose Detection16Single-phased white-emitting Ca3Y(GaO)3(BO3)4:Ce3+,Tb3+,Sm3+ phosphors with high-efficiency: Photoluminescence, energy transfer and application in near-UV-pumped white LEDs63Structural Confinement toward Giant Enhancement of Red Emission in Mn2+‐Based Phosphors165Synthesis and photoluminescence properties of a novel BaGe4O9:Eu3+ red emitting phosphor for warm white LEDs62White-light-emitting from single-phased (Ca,Eu,Mn)9Al(PO4)7 phosphor with blue-white-yellow tunable luminescence properties for UV-based LEDs16Layered Structure Produced Nonconcentration Quenching in a Novel Eu3+-Doped Phosphor185Remarkable photoluminescence of europium( ii )-doped phosphate cyan@red-emitting phosphors with highly dispersed luminescence centers11A rate equation model for the energy transfer mechanism of a novel multi-color-emissive phosphor, Ca 1.624 Sr 0.376 Si 5 O 3 N 6 :Eu 2+12Calcium-based efficient cathode-ray scintillating metal–organic frameworks constructed from π-conjugated luminescent motifs24Crystal structure and photoluminescence tuning of novel single-phase Ca 8 ZnLu(PO 4 ) 7 :Eu 2+ ,Mn 2+ phosphors for near-UV converted white light-emitting diodes61Eu 3+ -Activated Sr 3 ZnTa 2 O 9 single-component white light phosphors: emission intensity enhancement and color rendering improvement80Full spectrum core–shell phosphors under ultraviolet excitation7Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes71Luminescence color tuning and energy transfer properties in (Sr,Ba) 2 LaGaO 5 :Bi 3+ ,Eu 3+ solid solution phosphors: realization of single-phased white emission for WLEDs107Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuning34Multi-quantum-well quantum dots with stable dual emission6Multichannel photoluminescence tuning in Eu-doped apatite phosphors via coexisting cation substitution, energy transfer and valence mixing54Multicolor properties and applications of Ln 3+ doped hierarchical NaY(WO 4 ) 2 via a facile solvothermal process4Significant enhancement of cathode-ray scintillation for a conductive Bi-SMOF via in situ partial rare earth ion replacement34Suppression of Back Energy Transfer by Energy Transfer Between Terbium Ions1Dehydrogenation-driven to synthesize high-performance Lu2Si4N6C:Ce3+- a broad green-emitting phosphor for full-spectrum lighting18Ba3P4O13:Eu3+ phosphors with high thermal stability and high internal quantum efficiency for near-ultraviolet white light-emitting diodes13Energy transfer and luminescence properties of Dy3+/Eu3+ doped silicoaluminate phosphors46Impact of process parameters on luminescence properties and nanostructure of YVO4:Eu phosphor32Tunable emission and applications of Ln3+ doped NaGd(WO4)2 nanocrystals via a facile solvothermal process10Data-Driven Discovery of Full-Visible-Spectrum Phosphor133Engineering of K3YSi2O7To Tune Photoluminescence with Selected Activators and Site Occupancy117Composition-driven anionic disorder-order transformations triggered single-Eu2+-converted high-color-rendering white-light phosphors50New physical insight into crystal structure, luminescence and optical properties of YPO4:Dy3+∖Eu3+∖Tb3+ single-phase white-light-emitting phosphors87Influence of dopants oxidation states control on the photoluminescence properties of inorganic phospors0Controllable Eu valence based on linear structural evolution in single-phased Sr3-La1+(PO4)3-(SiO4) phosphors to realize tunable/white light emissions7Mesoporous Crystalline Silver-Chalcogenolate Cluster-Assembled Material with Tailored Photoluminescence Properties57Bi3+ induced broad NUV-excitation band in Eu3+-doped red phosphor with scheelite-related structure19Structural modulation induced intensity enhancement of full color spectra: a case of Ba 3 ZnTa 2−x Nb x O 9 :Eu 3+ phosphors19Ca 8 Mg 7 Si 9 N 22 :Ce 3+ —A Yellow-Emitting Nitride Phosphor for White Light Emitting Diodes46Theoretical design and characterization of high efficient Sr9Ln(PO4)7: Eu2+ phosphors19Double sites occupancy of Mn4+ in Cs2NaAlF6 with enhanced photoluminescence for white light-emitting diodes37Tuning the oxidation states of dopants in Li2SrSiO4:Eu,Ce and control of the photoemission color8Violet-light-excitable super-narrow band green emitting phosphor for high-quality white LEDs9The crucial impact of cerium reduction on photoluminescence16Two single-phase ZnWO4: RE3+, Li+ (RE = Sm, Eu) white phosphors with high luminous intensity synthesized by solid-state reaction14Eu3+, Sm3+ Deep‐Red Phosphors as Novel Materials for White Light‐Emitting Diodes and Simultaneous Performance Enhancement of Organic–Inorganic Perovskite Solar Cells84A novel narrow-band blue-emitting phosphor of Bi3+-activated Sr3Lu2Ge3O12 based on a highly symmetrical crystal structure used for WLEDs and FEDs183Site occupation and energy transfer of Ce3+-Activated oxynitride Lu4SiAlO8N with broad-cyan-light-emitting property used for WLEDs5Tuning the Oxidation States of Dopants: A Strategy for the Modulation of Material Photoluminescence Properties11Confinement and antenna effect for ultrasmall Y2O3:Eu3+ nanocrystals supported by MOF with enhanced near-UV light absorption thereby enhanced luminescence and excellently multifunctional applications41Observation of energy transfer from Eu2+ to Eu3+ and tunable luminescence in phosphors YF3:Eu prepared by hydrothermal method38Broad band white-light-emitting Y5Si3O12N:Ce3+/Dy3+ oxonitridosilicate phosphors for solid state lighting applications38Highly dispersed Eu2+ activated Ca10(PO4)6Cl2 phosphor with enhanced blue emitting through deposition-precipitation process6Efficient Regulation of Energy Transfer in a Multicomponent Dye-Loaded MOF for White-Light Emission Tuning74AB 11 O 16 (OH) 2 (A = K and Cs): interpenetrating 2D layers with large birefringence7A novel broad-band cyan light-emitting oxynitride based phosphor used for realizing the full-visible-spectrum lighting of WLEDs21Design of a Bismuth-Activated Narrow-Band Cyan Phosphor for Use in White Light Emitting Diodes and Field Emission Displays100A data-driven approach to predicting band gap, excitation, and emission energies for Eu 2+ -activated phosphors28A solid-solution modulation strategy in trivalent bismuth-doped gallate phosphors for single substrate tunable emission5Enhanced luminescence and tunable color in [Eu 2+ , Si 4+ ]/Mn 2+ doped K 2 BaCa(PO 4 ) 2 based on charge compensation and energy transfer5Modern aspects of strategies for developing single-phase broadly tunable white light-emitting phosphors60Novel narrow-band blue light-emitting phosphor of Eu 2+ -activated silicate used for WLEDs19Phosphor-in-glass with full-visible-spectrum emission based on ultra-low melting Sn-F-P-O glass pumped by NUV LED chips24Synthesis, structure and photoluminescence properties of Ca2YTaO6:Bi3+\Eu3+ double perovskite white light emitting phosphors49Spontaneous-reduction and photoluminescence tuning in singly-doped Ba5-Ca (PO4)3Cl:Eu2+/Eu3+ phosphors23Effect of lattice distortion induced by Li+ doping on white light CaWO4: Dy3+ phosphors: Phase, photoluminescence and electronic structure15High-performance red@green core-shell emitting nitride phosphor with monodisperse Eu2+ luminescence centers for solid state lighting10Pink-emitting RbBaBP2O8:Sm phosphor with diamondoid structure and high thermostability47Tb3+ and Sm3+ co-doped CaWO4 white light phosphors for plant lamp synthesized via solid state method: Phase, photoluminescence and electronic structure27Single phase multi color emitting Ca 2 LuTaO 6 : Dy 3+ /Eu 3+ double perovskite oxide phosphors31Bi3+ occupancy rearrangement in K2-xAxMgGeO4 phosphor to achieve ultra-broad-band white emission based on alkali metal substitution engineering38Designing a Thermally Robust Green-Emitting Phosphor Rb2HfSi2O7: Eu2+ by an Atomic Chain Vibration Model and Its White Light-Emitting Diode Application16Design, synthesis and control of the optical properties of phosphors for white light emitting diodes0Fabrication and photoluminescence characteristics of novel red-emitting Ba2LuNbO6:Eu3+ double-perovskite phosphors on near UV WLEDs44MMCT-induced high-bright yellow light-emitting phosphor Bi3+-activated Ba2YGaO5 used for WLED124Machine Learning Guided Design of Single–Phase Hybrid Lead Halide White Phosphors25Toward white light emission from plasmonic‐luminescent hybrid nanostructures5Machine learning identification of experimental conditions for the synthesis of single-phase white phosphors19Síntesis y caracterización de silicatos de itrio codopados con Eu³⁺ y Eu²⁺ con posible aplicación a diodos emisores de luz blanca0A green emitting (Ba,Ca)ScO 2 F:Bi 3+ ,K + perovskite phosphor with high efficiency and good thermal stability for LED backlight displays6Ultra-stable narrowband green-emitting CsPbBr 3 quantum dot-embedded glass ceramics for wide color gamut backlit displays27Tendentious multiple sites occupation towards white light emission in single-phase Ba2(1-/3)Ca(1-/3)Sr B2Si4O14:Eu2+ phosphors16Green-emitting Bi3+-doped La2SrSc2O7 phosphor for pc-WLED lighting: Luminescent properties and energy transfer strategy50Ultra-narrowband emitting and highly stable CsPbX3@glass@PDMS (X3=Br3, Br1.5I1.5) monolithic composite film for backlit displays14Tailoring red-NIR luminescence in rare earth doped lead-free layered double perovskites by bivalent manganese energy bridge0Energy transfer mediated single-phased white light emission in Bi3+-Eu3+ codoped Ba3YGa2O7.5 for WLED33Enabling Wide-Gamut Human-Centric Display Lighting0Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Design of K2SrCa(PO4)2-x(BO3)x:Eu2+ phosphors with full-visible spectrum by crystal structure modification12Compositional tuning and site engineering of Sr-alloyed Ca3(PO4)2:Mn2+, Eu2+ towards multicenter-activated single-component white light emitter6Tuning the Red Emission to Instigate Intrinsic White‐Light Emission in Single‐Phase Phosphor with Excellent Color Rendering Index9Enhanced cyan emission via competitive site occupancy engineering in Sr2SiO4:Eu2+ phosphor for achieving full-spectrum LED lighting19Versatile phosphor-in-glass based on Sn–F–P–O matrix with ultra-high color rendering for white LEDs/LDs10A metal-to-metal charge transfer induced green-yellow phosphor CsAlGe 2 O 6 :Bi 3+ for full-spectrum LED devices13Ba 3 LuGa 2 O 7.5 :Bi 3+ phosphors with potential application in full-spectrum WLEDs and temperature sensing73Highly emissive Sb 3+ -doped Rb 2 InCl 5 ·H 2 O perovskites: cost-effective synthesis, luminescence, and its application11Non-concentration quenching and energy transfer enhanced green emission in Ca 8 SrGd(PO 4 ) 7 :Eu 2+ ,Tb 3+ for near-UV white LEDs with a high color rendering index20Preparation and luminescent properties of Ba 3 Na 0.32 Nb 6 O 12 (Si 2 O 7 ) 2 :Eu 3+ red phosphors with high color purity4Ultrahighly Efficient Narrowband Red Luminescence of Uniquely Distorted Mn 4+ Octahedron in the Feldspar‐Type LED Phosphor47Site‐Engineering for Controlling Multiple‐Excitation and Emission in Eu2+‐Activated CaSrSiO4 Phosphors in Marine Fisheries21Realizing multicolor tunable photoluminescence in La2MgTiO6: Tb3+, Eu3+ phosphors via energy transfer and application for white light-emitting diodes23Novel high-brightness yellow light-emitting phosphor Ba2GdGaO5: Bi3+ for NUV-pumped WLED application9Multi-type electronic transitions induced multi-color light emitting of bismuth in tantalate used for WLED4Ultrastable quantum dot composites with dense barrier layer for wide color gamut display7Narrow-band cyan and green dual-peak emission Rb2KNa(Li3SiO4)4: Eu2+ phosphor for full-spectrum w-LED: Synthesis, structure, and spectrum regulation9Cationic substitution engineering induced Multi-Color light emitting of bismuth in Tantalate used for WLED12Unlocking color-tunable emission of Eu 2+ -activated phosphors through doping-free exploration of hidden sites3Advancements of Lanthanide-doped Phosphors in Solid-state Lighting Applications27Less is more: An oxyfluoride garnet broadband cyan-green phosphor towards highly efficient full-spectrum WLEDs22Thermally Induced Morphological and Structural Transformations on Eu2+/Eu3+-Coactivated Calcium Silicate Nanophosphors8Eu2+ doping and Mg2+-coupled Zn2+, Ca2+ and Sr2+ cations induce tunable orange-blue luminescence in cordierite3A novel SrLaScO4:Bi layered perovskite phosphor with broad-band green emission: Multi-cationic sites engineering, and application in high color rendering pc-WLED9Investigations of structural, photoluminescence, colorimetric, lifetime, and luminous efficiency of Tb3+ and Sm3+ co-doped calcium tungstate for WLEDs6Achieving Ultra‐Broadband Sunlight‐Like Emission in Single‐Phase Phosphors: The Interplay of Structure and Luminescence44Broadband spectral cyan emission phosphor for full-spectrum LED caused by interstitial site occupation2An efficient violet-excited and cyan-green/near-infrared dual emitting phosphor for full-spectrum lighting14Development of Mg2TiO4:Mn4+ phosphors for enhanced red LED emission and forensic fingerprint analysis21Oxidation states, optical and electronic properties of Eu and Tb doped nano-fluorapatite phosphor by self-propagating combustible approach8Research on the preparation of glass ceramics from yellow phosphorus slag doped with Tb3+ versus co-doped with Tb3+-Eu3+ and its luminescent properties11Modulating optical properties through cation substitution: composition-property relationships in MI3M III P 3 O 9 N:Eu 2+ (M I = Na, K; M III = Al, Ga, In)2Luminescence enhancement and color regulation of Sr2LiAlO4-1.5N : Eu2+ phosphor for high color rendering index white LED applications4Single‐Grain High‐Efficiency Full‐Visible‐Spectrum White Emitters17Single‐Grain High‐Efficiency Full‐Visible‐Spectrum White Emitters3Investigation into the great enhancement of luminescence intensity through K/Na substitution in Nepheline structure for WLED1Recent Advances in CsPbX 3 (X = Cl, Br, I) Perovskite NCs@Glass: Structures, Characterizations, and Applications20Novel ultra-broadband cyan phosphor with excellent thermal stability for full-spectrum WLED7Defect-engineered photoluminescence in Ba6Y2Ga4O15: Synergistic cation and atmosphere regulation for ultraviolet-driven WLEDs18Aqueous synthesis of stable Pb(OH)Br:Cu red phosphor with DFT insights into its luminescence mechanism1Unlocking novel halogen germanate phosphors for full-spectrum lighting and ultra-sensitive temperature sensing7Ultra‐Pure 531 nm Green‐Emitting CsPbBr 3 @Glass With a High Quantum Efficiency for Rec. 2020 Backlit Display3K 7 MgY 2 (B 5 O 10 ) 3 : a novel ultraviolet nonlinear optical crystal based on the [B 5 O 10 ] functional unit2Dy3 + -doped Sr2GdTaO6 double perovskite phosphors for white LEDs: photoluminescence, thermal stability, and optical transitions3Broadband‐Emitting NaGdSiO 4 :Eu 2+/3+ Phosphor for White Light‐Emitting Diodes0

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  2. Tunable white light emitting Sr 2 V 2 O 7 :Bi 3+ phosphors: Role of bismuth ion

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  4. Novel single-phase full-color emitting Ba9Lu2Si6O24:Ce3+/Mn2+/Tb3+ phosphors for white LED applications

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  32. Eu 3+ -Activated Sr 3 ZnTa 2 O 9 single-component white light phosphors: emission intensity enhancement and color rendering improvement

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