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RESEARCH PAPER · Journal of Materials Chemistry C · 2020

Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture

Zhuang Li, Shengzi Zhang, Wenhao Xing, Yangwu Guo, Chunxiao Li, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architectureOriginalExperimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units15Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75From AgGaS 2 to AgHgPS 4 : vacancy defects and highly distorted HgS 4 tetrahedra double-induced remarkable second-harmonic generation response68Revisiting thiophosphate Pb 3 P 2 S 8 : a multifunctional material combining a nonlinear optical response and photocurrent response23Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides28Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units49A 2 Zn 3 P 4 S 13 (A = Rb and Cs): First Infrared Nonlinear Optical Materials with Mixed Thiophosphate Functional Motifs PS 4 and P 2 S 621Alkali metal partial substitution-induced improved second-harmonic generation and enhanced laser-induced damage threshold for Ag-based sulfides21Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response16The synthesis and structure–property relation analysis of metal chalcohalide crystals Cs 2 InPS 4 X 2 (X = Cl, Br) with mixed anions6Two Nonlinear Optical Thiophosphates Cu 5 Hg 0.5 P 2 S 8 and AgHg 3 PS 6 Activated by Their Tetrahedra-Stacking Architecture12Toward the Rational Design of Mid‐Infrared Nonlinear Optical Materials with Targeted Properties via a Multi‐Level Data‐Driven Approach111The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe232(Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold14Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS626Ag[SC(NH2)2]2F: A Laser Damage-Tolerant Infrared Nonlinear Optical Material9Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP2S7 and KCrP2S79Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials90Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response22Quaternary alkaline-earth metal thiophosphate SrAgPS 4 : syntheses, structures, and optical properties9Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response12SrCl2·6H2O: An Alkaline-Earth-Metal Chloride Hexahydrate as Deep-Ultraviolet Nonlinear-Optical Crystal with the {[Sr(H2O)6]2+}∞ Cationic Framework8C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties14Phase-Matching Second-Harmonic Generation and Enhanced Laser-Induced Damage Threshold Induced by Cs Substitution: Cu 3 PSe 4 vs Cs 2 CuP 3 S 94Chalcophosphates: A plentiful source of infrared nonlinear optical materials42Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate12Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties3Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties26From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide5AVP2S7 (A = K, Rb): Dual-Optimized Infrared Nonlinear Optical Thiophosphates via Heterovalent-Substitution-Driven Symmetry Breaking and Reinforced Interlayer Interactions0AgEuPS4: Unlocking the Centrosymmetric Shackle of Rare-Earth Thiophosphates via Microscopic Distortion Cascading for Enhanced Second-Harmonic Generation Response1NaGa2PS6: A Noncentrosymmetric Thiophosphate with Wide Band Gap and High Laser-Induced Damage Threshold0

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  1. Experimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units

    Dalton Transactions · 2020-01-01

    Peng Wang, Maierhaba Abudoureheman, Zhaohui Chen

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  2. Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2020-10-23

    Zhuang Li, Jiyong Yao, Yicheng Wu

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  3. From AgGaS 2 to AgHgPS 4 : vacancy defects and highly distorted HgS 4 tetrahedra double-induced remarkable second-harmonic generation response

    Journal of Materials Chemistry C · 2020-12-12

    Wenhao Xing, Naizheng Wang, Chunlan Tang, Chunxiao Li, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  4. Revisiting thiophosphate Pb 3 P 2 S 8 : a multifunctional material combining a nonlinear optical response and photocurrent response

    Physical Chemistry Chemical Physics · 2021-01-01

    Bingheng Ji, Elizabeth Guderjahn, Kui Wu, Tajamul Hussain Syed, Wei Wei, Bingbing Zhang, Jian Wang

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  5. Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides

    Inorganic Chemistry · 2021-07-27

    Wenfeng Zhou, Qingming Zhang, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  6. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

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  7. SnPQ3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ8 Units

    Inorganic Chemistry · 2021-08-31

    Zhi‐Hui Shi, Mei Yang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  8. A 2 Zn 3 P 4 S 13 (A = Rb and Cs): First Infrared Nonlinear Optical Materials with Mixed Thiophosphate Functional Motifs PS 4 and P 2 S 6

    Journal of Materials Chemistry C · 2022-01-01

    Mingze Li, Lin‐Tao Jiang, Shao‐Min Pei, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  9. Alkali metal partial substitution-induced improved second-harmonic generation and enhanced laser-induced damage threshold for Ag-based sulfides

    Inorganic Chemistry Frontiers · 2022-01-01

    Wenfeng Zhou, Ming Geng, Mei Yan, Nian‐Tzu Suen, Wenlong Liu, Sheng‐Ping Guo

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  10. Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response

    Journal of Materials Chemistry C · 2022-01-01

    Yang Wang, Ruiqi Wang, Xiangli Che, Fei Liang, Min Luo, Yufeng Tang, Yunzhen Cao, Fuqiang Huang

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  11. The synthesis and structure–property relation analysis of metal chalcohalide crystals Cs 2 InPS 4 X 2 (X = Cl, Br) with mixed anions

    Dalton Transactions · 2022-01-01

    Chunlan Tang, Wenhao Xing, Naizheng Wang, Jian Tang, Zheshuai Lin, Jieyun Wu, Wenlong Yin, Bin Kang

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  12. Two Nonlinear Optical Thiophosphates Cu 5 Hg 0.5 P 2 S 8 and AgHg 3 PS 6 Activated by Their Tetrahedra-Stacking Architecture

    Inorganic Chemistry · 2022-01-11

    Yang Wang, Yuqiang Fang, Yunzhen Cao, Fuqiang Huang

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  13. Toward the Rational Design of Mid‐Infrared Nonlinear Optical Materials with Targeted Properties via a Multi‐Level Data‐Driven Approach

    Advanced Functional Materials · 2022-03-03

    Wenbing Cai, Ailijiang Abudurusuli, Congwei Xie, Evgenii Tikhonov, Junjie Li, Shilie Pan, Zhihua Yang

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  14. The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe2

    Journal of Alloys and Compounds · 2022-05-13

    Daniel J. Clark, Jian‐Han Zhang, Andrew J. Craig, Ashley Weiland, Jacilynn A. Brant, Jeong Bin Cho, Yong Soo Kim, Joon Ik Jang, Jennifer A. Aitken

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  15. (Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold

    Chemistry - A European Journal · 2022-08-10

    Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  16. Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS6

    Inorganic Chemistry · 2022-10-20

    Nan Zhang, Qian-Ting Xu, Zhi‐Hui Shi, Mei Yang, Sheng‐Ping Guo

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  17. Ag[SC(NH2)2]2F: A Laser Damage-Tolerant Infrared Nonlinear Optical Material

    Chemistry of Materials · 2022-10-21

    Mengya Ji, Chun‐Li Hu, Yilin Li, Bingxuan Li, Jiang‐Gao Mao

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  18. Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP2S7 and KCrP2S7

    Crystals · 2022-10-22

    Craig Cropek, Vivian Nguyen, Santosh Karki Chhetri, Jin Hu, Sheng‐Ping Guo, Jian Wang

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  19. Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2022-11-26

    Wenfeng Zhou, Jiajing Wu, Wenlong Liu, Sheng‐Ping Guo

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  20. Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response

    Inorganic Chemistry Frontiers · 2023-01-01

    Chenyao Zhao, Bingbing Zhang, Xinyu Tian, Guoqiang Zhou, Jingjing Xu, Kui Wu

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  21. Quaternary alkaline-earth metal thiophosphate SrAgPS 4 : syntheses, structures, and optical properties

    Dalton Transactions · 2023-01-01

    Wenhao Xing, Jian Tang, Fei Liang, Chunlan Tang, Jieyun Wu, Wenlong Yin, Bin Kang, Jianguo Deng

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  22. Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response

    CrystEngComm · 2023-01-01

    Craig Cropek, Bingheng Ji, Arka Sarkar, Fei Wang, Tajamul Hussain Syed, Wei Wei, Sheng‐Ping Guo, Jian Wang

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  23. SrCl2·6H2O: An Alkaline-Earth-Metal Chloride Hexahydrate as Deep-Ultraviolet Nonlinear-Optical Crystal with the {[Sr(H2O)6]2+}∞ Cationic Framework

    Inorganic Chemistry · 2023-06-23

    Wei Xu, Ru‐Ling Tang, Yu-Long Wei, Jinming Wang, Yu-Qing Zhang, Wenlong Liu, Sheng‐Ping Guo

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  24. C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties

    Inorganic Chemistry · 2023-12-19

    Wei Xu, Liang Ma, Yi‐Lei Lv, Siyu Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  25. Phase-Matching Second-Harmonic Generation and Enhanced Laser-Induced Damage Threshold Induced by Cs Substitution: Cu 3 PSe 4 vs Cs 2 CuP 3 S 9

    Inorganic Chemistry · 2024-09-19

    Mingyang Li, Chen‐Yi Zhao, Haiping Xu, Wenfeng Zhou, Wenlong Liu, Jing Zhu, Sheng‐Ping Guo

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  26. Chalcophosphates: A plentiful source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2025-02-26

    Yingying Kong, Guansong Zheng, Yi Du, Junjie Li, Shilie Pan

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  27. Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate

    Small · 2025-03-27

    Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Jian Tang, Wenwen Jiang, Nian‐Tzu Suen, Wenlong Yin, Sheng‐Ping Guo

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  28. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

    Angewandte Chemie · 2025-04-28

    Jia-Xiang Zhang, Sheng‐Hua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  29. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2025-04-28

    Jia-Xiang Zhang, Sheng‐Hua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  30. From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide

    Inorganic Chemistry · 2025-07-09

    Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Chunlan Tang, Wenwen Jiang, Sheng‐Ping Guo, Wenlong Yin

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  31. AVP2S7 (A = K, Rb): Dual-Optimized Infrared Nonlinear Optical Thiophosphates via Heterovalent-Substitution-Driven Symmetry Breaking and Reinforced Interlayer Interactions

    Inorganic Chemistry · 2026-08-11

    Shao-Peng Gui, Zi-Nan Chen, Wei-Hua Yan, Yu‐Xuan Zhang, Mao‐Yin Ran, Sheng‐Ping Guo

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  32. AgEuPS4: Unlocking the Centrosymmetric Shackle of Rare-Earth Thiophosphates via Microscopic Distortion Cascading for Enhanced Second-Harmonic Generation Response

    Chemistry of Materials · 2026-08-13

    Ao Guo, Si Yang, Yang Chi, Yu‐Xuan Zhang, Tianwei He, Mao‐Yin Ran, Sheng‐Ping Guo

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  33. NaGa2PS6: A Noncentrosymmetric Thiophosphate with Wide Band Gap and High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2026-09-15

    Jiaze Sun, Aoya He, Hongbo Zhang, Yali Cao, Guangmao Li

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