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RESEARCH PAPER · Physical Chemistry Chemical Physics · 2016

The mechanism of large second harmonic generation enhancement activated by Zn 2+ substitution

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The mechanism of large second harmonic generation enhancement activated by Zn 2+ substitutionOriginalA new phase-matchable nonlinear optical silicate: Rb 2 ZnSi 3 O 825Li 6 Zn 3 (BO 3 ) 4 : a new zincoborate featuring vertex-, edge- and face-sharing LiO 4 tetrahedra and exhibiting reversible phase transitions18Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building Blocks36Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions3Na2ZnSn2S6: A mixed-metal thiostannate with large second-harmonic generation response activated by penta-tetrahedral [ZnSn4S14]10− clusters10Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29Computational assessment of promising mid-infrared nonlinear optical materials Mg–IV–V2 (IV = Si, Ge, Sn; V = P, As): a first-principles study16Mild hydrothermal synthesis of the two compounds [SrZn2(SeO3)3] and [SrZn0.68Cu0.32(SeO3)2]: Structural characterization, spectroscopic and magnetic studies4LiGeBO 4 : a nonlinear optical material with a balance between deep-ultraviolet cut-off edge and large SHG response induced by hand-in-hand tetrahedra21Two alkali calcium borates exhibiting second harmonic generation and deep-UV cutoff edges3Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Development of Eu-doped Sr2MgSi2O7 single crystalline scintillators10Effects of dopant concentration in Eu-doped Ca2MgSi2O7 single crystalline scintillators16From silicates to oxonitridosilicates: improving optical anisotropy for phase-matching as ultraviolet nonlinear optical materials47Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 311The Balance of Deep-Ultraviolet Transparency and Large Second Harmonic Generation Response in a Silicate Crystal0Rational design of a promising oxychalcogenide infrared nonlinear optical crystal60Balance of Deep-Ultraviolet Transparency and Large Second Harmonic Generation Response in a Silicate Crystal9Enhanced Second-Harmonic-Generation Efficiency and Birefringence in Melillite Oxychalcogenides Sr2MGe2OS6 (M = Mn, Zn, and Cd)97Effect of film thickness of ZnO as the electron transport layer on the performance of organic photodetectors15Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups35Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials181Searching for silicate nonlinear optical materials by combining calculation and experiment17Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals21Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li 3 (OH)PbSiO 463Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units3LiASi2O5 (A = K, Rb): Effects of cations on crystal structure and optical properties1Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units0K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response10Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response1LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response2Broadband infrared-transparent crystals enabled by heterologous isomorphic substitution0

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  1. A new phase-matchable nonlinear optical silicate: Rb 2 ZnSi 3 O 8

    Journal of Materials Chemistry C · 2017-01-01

    Bingqing Zhao, Yi Jin Yang, Sangen Zhao, Yaoguo Shen, Xianfeng Li, Lina Li, Chengmin Ji, Zheshuai Lin, Junhua Luo

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  2. Li 6 Zn 3 (BO 3 ) 4 : a new zincoborate featuring vertex-, edge- and face-sharing LiO 4 tetrahedra and exhibiting reversible phase transitions

    Inorganic Chemistry Frontiers · 2017-01-01

    Yanna Chen, Donghai An, Min Zhang, Cong Hu, Miriding Mutailipu, Zhihua Yang, Xiaoquan Lu, Shilie Pan

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  3. Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building Blocks

    Inorganic Chemistry · 2017-04-24

    Miriding Mutailipu, Min Zhang, Xin Su, Zhihua Yang, Shilie Pan

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  4. Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions

    Journal of Solid State Chemistry · 2017-05-04

    Hoyong Jung, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  5. Na2ZnSn2S6: A mixed-metal thiostannate with large second-harmonic generation response activated by penta-tetrahedral [ZnSn4S14]10− clusters

    Science China Technological Sciences · 2017-05-12

    Guangmao Li, Kui Wu, Qiong Liu, Zhihua Yang, Shilie Pan

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  6. Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations

    Inorganic Chemistry Frontiers · 2018-01-01

    Yanna Chen, Min Zhang, Cong Hu, Zhihua Yang, Shilie Pan

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  7. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

    Dalton Transactions · 2018-01-01

    Ruijiao Chen, Xiaowen Wu, Zhi Su

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  8. The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies

    Dalton Transactions · 2018-01-01

    Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  9. Computational assessment of promising mid-infrared nonlinear optical materials Mg–IV–V2 (IV = Si, Ge, Sn; V = P, As): a first-principles study

    Materials Research Express · 2018-03-12

    Jianping Xiao, Shifu Zhu, Beijun Zhao, Baojun Chen, Hui Liu, Z. Y. He

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  10. Mild hydrothermal synthesis of the two compounds [SrZn2(SeO3)3] and [SrZn0.68Cu0.32(SeO3)2]: Structural characterization, spectroscopic and magnetic studies

    Journal of Saudi Chemical Society · 2018-03-19

    Sana Koubaa, A. Kabadou, Lotfi Bessais

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  11. LiGeBO 4 : a nonlinear optical material with a balance between deep-ultraviolet cut-off edge and large SHG response induced by hand-in-hand tetrahedra

    Inorganic Chemistry Frontiers · 2019-01-01

    Qiong Liu, Cong Hu, Xin Su, Maierhaba Abudoureheman, Shilie Pan, Zhihua Yang

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  12. Two alkali calcium borates exhibiting second harmonic generation and deep-UV cutoff edges

    New Journal of Chemistry · 2019-01-01

    Peng Rong Ren, Yun Mo Yang, Hao Li, Zhihua Yang, Shilie Pan

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  13. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

    Molecules · 2019-07-30

    Yanna Chen, Min Zhang, Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  14. Development of Eu-doped Sr2MgSi2O7 single crystalline scintillators

    Optical Materials · 2020-08-18

    Kenta Igashira, Daisuke Nakauchi, Taiki Ogawa, Takumi Kato, Noriaki Kawaguchi, Takayuki Yanagida

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  15. Effects of dopant concentration in Eu-doped Ca2MgSi2O7 single crystalline scintillators

    Materials Research Bulletin · 2020-12-01

    Kenta Igashira, Daisuke Nakauchi, Taiki Ogawa, Takumi Kato, Noriaki Kawaguchi, Takayuki Yanagida

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  16. From silicates to oxonitridosilicates: improving optical anisotropy for phase-matching as ultraviolet nonlinear optical materials

    Chemical Communications · 2020-12-10

    Xiaodong Zhang, Lichao Guo, Bingbing Zhang, Jin Yu, Ying Wang, Kui Wu, Haijun Wang, Ming‐Hsien Lee

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  17. Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 3

    Dalton Transactions · 2021-01-01

    Hongbo Gao, Ruijiao Chen, Kewang Zhang, Ailijiang Abudurusuli, Kangrong Lai, Junjie Li

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  18. The Balance of Deep-Ultraviolet Transparency and Large Second Harmonic Generation Response in a Silicate Crystal

    SSRN Electronic Journal · 2021-01-01

    Zheyao Xiong, Hongyuan Sha, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  19. Rational design of a promising oxychalcogenide infrared nonlinear optical crystal

    Chemical Science · 2022-01-01

    Yansong Cheng, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  20. Balance of Deep-Ultraviolet Transparency and Large Second Harmonic Generation Response in a Silicate Crystal

    Crystal Growth & Design · 2022-04-04

    Zheyao Xiong, Jing Xu, Haotian Tian, Hongyuan Sha, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  21. Enhanced Second-Harmonic-Generation Efficiency and Birefringence in Melillite Oxychalcogenides Sr2MGe2OS6 (M = Mn, Zn, and Cd)

    Chemistry of Materials · 2022-04-07

    Mao‐Yin Ran, Shenghua Zhou, Bingxuan Li, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  22. Effect of film thickness of ZnO as the electron transport layer on the performance of organic photodetectors

    Optical Materials · 2022-05-10

    Xianwen Yan, Jin Li

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  23. Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups

    Chemistry - A European Journal · 2022-12-16

    Yu-Jie Zhang, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  24. Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials

    Chemical Society Reviews · 2023-01-01

    Xin Liu, Yi‐Chang Yang, Mengyue Li, Ling Chen, Li‐Ming Wu

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  25. Searching for silicate nonlinear optical materials by combining calculation and experiment

    Inorganic Chemistry Frontiers · 2023-01-01

    Jingjing Zhang, Ruqing Wei, Daqing Yang, Ying Wang, Bingbing Zhang

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  26. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

    Coordination Chemistry Reviews · 2023-02-08

    Mao‐Yin Ran, A-Yang Wang, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  27. The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals

    Advanced Optical Materials · 2023-07-09

    Hongyuan Sha, Yanran Shang, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  28. Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li 3 (OH)PbSiO 4

    Journal of the American Chemical Society · 2023-10-09

    Yuanyu Yang, Yan Xiao, Bingxuan Li, Yi-Gang Chen, Penghui Guo, Bingbing Zhang, Xian‐Ming Zhang

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  29. Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units

    New Journal of Chemistry · 2024-01-01

    Aihaimaitijiang Ababaikeri, Xueting Pan, Gulimeikereyi Tuniyazi, Xiangzhan Jiang, Yanhui Zhang, Dilnur Malik

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  30. LiASi2O5 (A = K, Rb): Effects of cations on crystal structure and optical properties

    Optical Materials · 2024-01-08

    Jun Sun, Bo Ran, Ping Hu, Zhaofeng Wu, Ming‐Hsien Lee, Haiming Duan

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  31. Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units

    Zeitschrift für anorganische und allgemeine Chemie · 2024-06-19

    Aihaimaitijiang Ababaikeri, Gulimeikereyi Tuniyazi, Yanhui Zhang, Dilnur Malik

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  32. K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response

    Inorganic Chemistry · 2024-12-07

    Fanlu Bu, Xiaorong Liu, Hongwei Yu, Runqing Liu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  33. Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-01-04

    Meihui Chen, Wei Wei, Jiawei Zhao, Juanjuan Lu, Donghai An, Yanna Chen

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  34. LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-12-11

    Mingyue Gu, Hu Liu, Xianchao Zhu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  35. Broadband infrared-transparent crystals enabled by heterologous isomorphic substitution

    Dalton Transactions · 2026-01-01

    B Yang, Ziqi Chen, Zhenjiang Lu, Juanjuan Lu

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