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RESEARCH PAPER · Inorganic Chemistry · 2017

Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building Blocks

Miriding Mutailipu, Min Zhang, Xin Su, Zhihua Yang, Shilie Pan

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Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building BlocksOriginalStructural Insights into Borates with an Anion‐Templated Open‐Framework Configuration: Asymmetric K2BaB16O26 versus Centrosymmetric K3CsB20O32 and Na2M2NB18O30 (M=Rb, Cs; N=Ba, Pb)26Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O7730Syntheses, crystal structure and luminescent properties of polyborates PbLnB7O13 (Ln = Gd, Sm) with a 2D [B7O13]∞ framework13Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials267LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges10NH 4 B 11 O 16 (OH) 2 : a new ammonium borate with wavy-shaped polycyclic 2∞[B 11 O 16 (OH) 2 ] layers27A new luminescent host material K3GdB6O12: synthesis, crystal structure and luminescent properties activated by Sm3+7Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates42LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges16The structure and classification of complex borates43Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge4Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores14Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions98Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties37LiK[B5O8(OH)]·1.5H2O: A novel lithium borate with nonlinear optical property11β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound6Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196Borates: A Rich Source for Optical Materials1089Synthesis, crystal structure and theoretical calculations of two rare-earth borates with DUV cut-off edges6Second-order nonlinear optical and photoelectric properties of Zn4B6O12S20Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer11Phase Relations in the CaO-B2O3-Sc2O3 Ternary System1Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups8Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains5Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals33Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6K3Y3(BO3)4: A Potential UV Nonlinear-Optical Crystal Designed by a Chemical Substitution Strategy14K0.9Rb2.1B8PO16: Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal with Balanced Performance Derived from π-Conjugated and Non-π-Conjugated Groups11Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8Two alkali metal borates built by {Li@B 14 } and {B 15 } cluster units1Cd3Sc(BO3)3: a novel orthoborate with pseudo-1D ∞[ScB6O18] chains0A Lithium Calcium Borate Nonlinear Optical Crystal with Deep-UV Cutoff Edge and Moderate Second-Harmonic Generation Response1FBB-directed open framework evolution in alkali metal borates: Synthesis and structure property relationships of NaRb2B9O150

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  1. Structural Insights into Borates with an Anion‐Templated Open‐Framework Configuration: Asymmetric K2BaB16O26 versus Centrosymmetric K3CsB20O32 and Na2M2NB18O30 (M=Rb, Cs; N=Ba, Pb)

    Chemistry - A European Journal · 2017-07-21

    Miriding Mutailipu, Min Zhang, Xin Su, Zhihua Yang, Yanna Chen, Shilie Pan

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  2. Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77

    Inorganic Chemistry · 2017-10-09

    Maierhaba Abudoureheman, Shujuan Han, Ying Wang, Qiong Liu, Zhihua Yang, Shilie Pan

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  3. Syntheses, crystal structure and luminescent properties of polyborates PbLnB7O13 (Ln = Gd, Sm) with a 2D [B7O13]∞ framework

    Journal of Luminescence · 2017-10-12

    Dan Zhao, Fa‐Xue Ma, Baozhong Liu, Mingjie Ma, Peigao Duan, Lina Zhang, Weilong Zhang

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  4. Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials

    Journal of the American Chemical Society · 2017-11-22

    Miriding Mutailipu, Zhiqing Xie, Xin Su, Min Zhang, Ying Wang, Zhihua Yang, Muhammad Ramzan Saeed Ashraf Janjua, Shilie Pan

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  5. LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges

    Dalton Transactions · 2018-01-01

    Ruru Ma, Yun Mo Yang, Cong Hu, Xiaoyu Dong, Zhihua Yang, Shilie Pan

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  6. NH 4 B 11 O 16 (OH) 2 : a new ammonium borate with wavy-shaped polycyclic 2∞[B 11 O 16 (OH) 2 ] layers

    New Journal of Chemistry · 2018-01-01

    Chunmei Huang, Fangfang Zhang, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  7. A new luminescent host material K3GdB6O12: synthesis, crystal structure and luminescent properties activated by Sm3+

    Zeitschrift für Kristallographie - Crystalline Materials · 2018-01-24

    Dan Zhao, Cong-Kui Nie, Ye Tian, Baozhong Liu, Yun-Chang Fan, Ji Zhao

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  8. Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates

    Inorganic Chemistry · 2018-01-25

    Shao-Chen Zhi, Yuelin Wang, Li Quan Sun, Jian‐Wen Cheng, Guo‐Yu Yang

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  9. LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge

    Inorganic Chemistry · 2018-02-14

    Yun Mo Yang, Qingrong Kong, Zhihua Yang, Shilie Pan

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  10. The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges

    Chemistry - A European Journal · 2018-08-07

    Ruru Ma, Yun Mo Yang, Cong Hu, Zhihua Yang, Shilie Pan

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  11. The structure and classification of complex borates

    Russian Chemical Reviews · 2018-10-25

    Anastasiya P. Topnikova, Elena L. Belokoneva

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  12. Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge

    Solid State Sciences · 2018-12-01

    Kun Chai, Hongyi Li, Mingyuan Zhu, Bin Dai

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  13. Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores

    Journal of Solid State Chemistry · 2019-01-11

    Soyon Lee, Hongil Jo, Kang Min Ok

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  14. Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

    Inorganic Chemistry · 2019-01-14

    Jianhao Huang, Congcong Jin, Pei-Li Xu, Pifu Gong, Zheshuai Lin, Jian‐Wen Cheng, Guo‐Yu Yang

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  15. Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties

    Inorganic Chemistry · 2019-01-16

    Eun Jeong Cho, Seung‐Jin Oh, Hongil Jo, Junsu Lee, Tae‐Soo You, Kang Min Ok

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  16. LiK[B5O8(OH)]·1.5H2O: A novel lithium borate with nonlinear optical property

    Inorganic Chemistry Communications · 2019-02-23

    Xuyan Li, Guo‐Yu Yang

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  17. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

    Chemistry - A European Journal · 2019-06-18

    Shujuan Han, Chunmei Huang, Abudukadi Tudi, Shuaishuai Hu, Zhihua Yang, Shilie Pan

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  18. K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound

    ChemistrySelect · 2019-09-17

    Shuzhao Huang, Chen Zhou, Shichao Cheng, Feng Yu

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  19. Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 19

    New Journal of Chemistry · 2020-01-01

    Xiaowen Niu, Li Wang

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  20. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  21. Synthesis, crystal structure and theoretical calculations of two rare-earth borates with DUV cut-off edges

    New Journal of Chemistry · 2021-01-01

    Qin Ma, Tinghao Tong, Zhi Su

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  22. Second-order nonlinear optical and photoelectric properties of Zn4B6O12S

    Journal of Alloys and Compounds · 2021-02-03

    Wenfeng Zhou, Wen‐Dong Yao, Ru‐Ling Tang, Huaiguo Xue, Sheng‐Ping Guo

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  23. Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer

    Dalton Transactions · 2021-12-01

    Chengfa Wu, Zilong Chen, Jianbang Chen, Zhihua Yang, Fangfang Zhang, Hongsheng Shi, Shilie Pan

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  24. Phase Relations in the CaO-B2O3-Sc2O3 Ternary System

    Journal of Phase Equilibria and Diffusion · 2022-02-01

    Wenke Zhi, Xiaoyi Chen, Fei Wang, Yang Tian, Yongnian Dai, Bin Yang

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  25. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

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  26. Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups

    ACS Omega · 2023-06-02

    Yu Dang, Jingdong Yan, Xueling Hou, Hongsheng Shi

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  27. Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains

    Inorganic Chemistry · 2023-06-12

    Ru‐Ling Tang, Lei Huai, Wenlong Liu

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  28. Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals

    Chemical Science · 2024-01-01

    Yang Li, Kang Min Ok

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  29. Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions

    New Journal of Chemistry · 2024-01-01

    Lei Huai, Wenlong Liu, Beibei Zhang, Ru‐Ling Tang, Yi‐Lei Lv, Yue‐Qi Wei, Sheng‐Ping Guo

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  30. K3Y3(BO3)4: A Potential UV Nonlinear-Optical Crystal Designed by a Chemical Substitution Strategy

    Inorganic Chemistry · 2024-09-12

    Chao Yang Feng, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  31. K0.9Rb2.1B8PO16: Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal with Balanced Performance Derived from π-Conjugated and Non-π-Conjugated Groups

    Inorganic Chemistry · 2024-09-22

    Wenyu He, Xianchao Zhu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  32. Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework

    Inorganic Chemistry · 2024-12-31

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  33. Two alkali metal borates built by {Li@B 14 } and {B 15 } cluster units

    Dalton Transactions · 2025-01-01

    Mian Li, Dan Qin, Juan Chen, Qi Wei, Guo‐Yu Yang

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  34. Cd3Sc(BO3)3: a novel orthoborate with pseudo-1D ∞[ScB6O18] chains

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    Runqing Liu, Yuntian Zhao, Jiming Huang, Shibo Guan, Senlin Leng

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  35. A Lithium Calcium Borate Nonlinear Optical Crystal with Deep-UV Cutoff Edge and Moderate Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-05-18

    Xianghao Kong, Zherui Yu, Ning Jia, Ning Ye, Zhanggui Hu, Conggang Li

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  36. FBB-directed open framework evolution in alkali metal borates: Synthesis and structure property relationships of NaRb2B9O15

    Journal of Molecular Structure · 2026-10-03

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