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RESEARCH PAPER · Chemical Communications · 2014

Th(VO 3 ) 2 (SeO 3 ) and Ln(VO 3 ) 2 (IO 3 ) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution

Teresa M. Eaton, Jian Hung Lin, Justin N. Cross, Jared T. Stritzinger, Thomas E. Albrecht‐Schmitt

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Th(VO 3 ) 2 (SeO 3 ) and Ln(VO 3 ) 2 (IO 3 ) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitutionOriginalChemInform Abstract: Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): Unusual Cases of Aliovalent Substitution.0Dimensional and Coordination Number Reductions in a Large Family of Lanthanide Tellurite Sulfates21Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67LnV3Te3O15(OH)3·nH2O (Ln = Ce, Pr, Nd, Sm, Eu, Gd; n = 1–2): A New Series of Semiconductors with Mixed-Valent Tellurium (IV,VI) Oxoanions14Recent advances on second-order NLO materials based on metal iodates328[NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds18Insertion of Trivalent Lanthanides into Uranyl Vanadate Layers and Frameworks16Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism16BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations12A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron33Schiff-base coordination complexes with plutonium( iv ) and cerium( iv )41A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions26Facile and Efficient Decontamination of Thorium from Rare Earths Based on Selective Selenite Crystallization48A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials71Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66Insights into the new 3d–5f heterometallic quaternary fluorides: Synthesis, crystal structures, spectroscopic properties, and thermodynamic stability3A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions138A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties19Origins of the odd optical observables in plutonium and americium tungstates7Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO399LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO337A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates7Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22First chiral fluorinated lead vanadate selenite Pb 2 (V 2 O 4 F)(VO 2 )(SeO 3 ) 3 with five asymmetric motifs and large optical properties24Ultrasensitive fluorescence detection of antitumor drug methotrexate based on a terbium-doped silica dendritic probe15Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant0Hydrothermal Synthesis of New Iodates Ln2(IO3)3(IO4) (Ln = La, Nd, Pr) Containing the Tetraoxoiodate(V) Anion: Creation of Luminescence Properties by Doping with Eu, Dy, and Tb5Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1Halide-Induced Band Gap Enhancement from Ba2SnSe4 to KBa2SnSe4Cl2Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties14Rational Design of Novel Polar Nonlinear Optical Materials in Alkali Metal Rare Earth Iodates5Assisting the Effective Design of an SBBO-Like Vanadium-Iodate Crystal with Mixed Metal Cations2Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals0

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  1. ChemInform Abstract: Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): Unusual Cases of Aliovalent Substitution.

    ChemInform · 2014-06-05

    Teresa M. Eaton, Jian Hung Lin, Justin N. Cross, Jared T. Stritzinger, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  2. Dimensional and Coordination Number Reductions in a Large Family of Lanthanide Tellurite Sulfates

    Inorganic Chemistry · 2014-08-06

    Jian Hung Lin, Kariem Diefenbach, Naoki Kikugawa, Ryan Baumbach, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  3. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

    Inorganic Chemistry · 2014-08-07

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

    Read original paper ↗ ·

  4. LnV3Te3O15(OH)3·nH2O (Ln = Ce, Pr, Nd, Sm, Eu, Gd; n = 1–2): A New Series of Semiconductors with Mixed-Valent Tellurium (IV,VI) Oxoanions

    Inorganic Chemistry · 2014-08-21

    Jian Hung Lin, Kariem Diefenbach, Jingcheng Fu, Justin N. Cross, Ronald Jene Clark, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  5. Recent advances on second-order NLO materials based on metal iodates

    Coordination Chemistry Reviews · 2015-01-25

    Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  6. [NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds

    Zeitschrift für Kristallographie - Crystalline Materials · 2015-08-07

    Vadim M. Kovrugin, Sergey V. Krivovichev, Olivier Mentré, Marie Colmont

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  7. Insertion of Trivalent Lanthanides into Uranyl Vanadate Layers and Frameworks

    Inorganic Chemistry · 2015-08-20

    Yaxing Wang, Xuemiao Yin, Yanyan Zhao, Yang Gao, Lanhua Chen, Zhiyong Liu, Daopeng Sheng, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

    Read original paper ↗ ·

  8. Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism

    Crystal Growth & Design · 2016-03-15

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Sergey V. Krivovichev, Olivier Mentré

    Read original paper ↗ ·

  9. BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution

    Journal of the American Chemical Society · 2016-07-18

    Mingli Liang, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  10. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

    CrystEngComm · 2017-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Xiao-Ni Yao, Xian‐Ming Zhang

    Read original paper ↗ ·

  11. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie International Edition · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·

  12. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·

  13. Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion

    Inorganic Chemistry · 2017-11-09

    Fei‐Fei Mao, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  14. Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations

    Chinese Journal of Chemistry · 2017-11-17

    Fang Kong, Yun‐Xiang Ma, Jiang‐Gao Mao

    Read original paper ↗ ·

  15. A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron

    Dalton Transactions · 2017-12-18

    Mingli Liang, Yun‐Xiang Ma, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  16. Schiff-base coordination complexes with plutonium( iv ) and cerium( iv )

    Chemical Communications · 2018-01-01

    Bonnie E. Klamm, Cory J. Windorff, Matthew L. Marsh, David S. Meeker, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  17. A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions

    Inorganic Chemistry · 2018-01-18

    Meiying Qie, Jian Hung Lin, Fang Kong, Mark A. Silver, Zenghui Yue, Xiaomei Wang, Linjuan Zhang, Hongliang Bao, Thomas E. Albrecht‐Schmitt, Jian‐Qiang Wang

    Read original paper ↗ ·

  18. Facile and Efficient Decontamination of Thorium from Rare Earths Based on Selective Selenite Crystallization

    Inorganic Chemistry · 2018-02-02

    Yaxing Wang, Huangjie Lu, Xing Dai, Tao Duan, Xiaojing Bai, Yawen Cai, Xuemiao Yin, Lanhua Chen, Juan Diwu, Shiyu Du, Ruhong Zhou, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Ning Liu, Shuao Wang

    Read original paper ↗ ·

  19. A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials

    Chemistry of Materials · 2018-03-13

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Jiang‐Gao Mao

    Read original paper ↗ ·

  20. Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O

    Inorganic Chemistry · 2018-07-19

    Yahui Li, Hongping Wu, Bingbing Zhang, Zhihua Yang, Guopeng Han, Shilie Pan

    Read original paper ↗ ·

  21. Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response

    Chemistry - A European Journal · 2018-11-08

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  22. Insights into the new 3d–5f heterometallic quaternary fluorides: Synthesis, crystal structures, spectroscopic properties, and thermodynamic stability

    Inorganica Chimica Acta · 2018-12-26

    Qi Liu, Huiqin Yin, Hongliang Bao, Zenghui Yue, Kariem Diefenbach, Zhongfeng Tang, Jian Hung Lin, Jian‐Qiang Wang

    Read original paper ↗ ·

  23. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie International Edition · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

    Read original paper ↗ ·

  24. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

    Read original paper ↗ ·

  25. (H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer

    Chemical Communications · 2019-01-01

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Ru‐Ling Tang, Bao-Lin Wu, Jiang‐Gao Mao

    Read original paper ↗ ·

  26. Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties

    Dalton Transactions · 2019-01-01

    Jian Hung Lin, Qi Liu, Zenghui Yue, Kariem Diefenbach, Liwei Cheng, Yue‐Jian Lin, Jian‐Qiang Wang

    Read original paper ↗ ·

  27. Origins of the odd optical observables in plutonium and americium tungstates

    Chemical Science · 2019-01-01

    Justin N. Cross, Tsung-Han Lee, Chang‐Jong Kang, Yongxin Yao, Samantha K. Cary, Jared T. Stritzinger, Matthew J. Polinski, Carla D. McKinley, Thomas E. Albrecht‐Schmitt, Nicola Lanatà

    Read original paper ↗ ·

  28. Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites

    Chemistry - A European Journal · 2019-01-13

    Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  29. HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System

    Inorganic Chemistry · 2019-03-06

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Baolin Wu, Jiang‐Gao Mao

    Read original paper ↗ ·

  30. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie International Edition · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Minmin Liu, Xian‐Ming Zhang

    Read original paper ↗ ·

  31. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Min‐Min Liu, Xian‐Ming Zhang

    Read original paper ↗ ·

  32. A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates

    Dalton Transactions · 2020-01-01

    Jian‐Han Zhang, Qi Wu, Wen-Zhong Lai

    Read original paper ↗ ·

  33. Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance

    Inorganic Chemistry Frontiers · 2020-01-01

    Lin Lin, Longhua Li, Chao Wu, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·

  34. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie International Edition · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·

  35. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·

  36. First chiral fluorinated lead vanadate selenite Pb 2 (V 2 O 4 F)(VO 2 )(SeO 3 ) 3 with five asymmetric motifs and large optical properties

    Dalton Transactions · 2021-01-01

    Lin Lin, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  37. Ultrasensitive fluorescence detection of antitumor drug methotrexate based on a terbium-doped silica dendritic probe

    Analytical Methods · 2021-01-01

    Arezoo Mohammadzadeh, Abolghasem Jouyban, Mohammad Hasanzadeh, Vahid Shafiei‐Irannejad, Jafar Soleymani

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  38. Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant

    Polyhedron · 2021-04-18

    Colin N. Reedy, Eric M. Villa

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  39. Hydrothermal Synthesis of New Iodates Ln2(IO3)3(IO4) (Ln = La, Nd, Pr) Containing the Tetraoxoiodate(V) Anion: Creation of Luminescence Properties by Doping with Eu, Dy, and Tb

    Crystal Growth & Design · 2021-07-15

    Ceren Kütahyalı Aslani, Vladislav V. Klepov, Mahmoud A. A. Aslani, Hans‐Conrad zur Loye

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  40. Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph

    Journal of Solid State Chemistry · 2022-01-22

    Honggang Wang, Jian‐Han Zhang, Ming-Shui Lin, Tianyu Wang, Zhijian Zhang, Shufeng Yan, Shao‐Ming Ying

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  41. Halide-Induced Band Gap Enhancement from Ba2SnSe4 to KBa2SnSe4Cl

    Crystal Growth & Design · 2023-07-20

    Xianghe Meng, Jinlong Shi, Mengran Sun, Jiyong Yao

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  42. Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties

    Inorganic Chemistry · 2023-09-07

    Nan Ma, Yu Hong Huang, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

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  43. Rational Design of Novel Polar Nonlinear Optical Materials in Alkali Metal Rare Earth Iodates

    Inorganic Chemistry · 2024-10-23

    Lijuan Liu, Haotian Tian, Mingjun Xia, Xiaoyang Wang

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  44. Assisting the Effective Design of an SBBO-Like Vanadium-Iodate Crystal with Mixed Metal Cations

    Crystal Growth & Design · 2025-05-22

    Xia Hao, Xuan Liu, Ruijie Wang, Chensheng Lin, Min Luo, Guang Peng, Tao Yan, Ning Ye

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  45. Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals

    Chemistry - A European Journal · 2025-10-09

    Ying‐Jie Jia, Yi-Gang Chen, Bingbing Zhang, Yao Guo, Xian‐Ming Zhang

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