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RESEARCH PAPER · Inorganic Chemistry · 2005

Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)3

Richard E. Sykora, Zerihun Assefa, Richard Geoffrey Haire, Thomas E. Albrecht‐Schmitt

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Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)3OriginalSynthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)3.0First Structural Determination of a Trivalent Californium Compound with Oxygen Coordination45Scandium, yttrium, the lanthanides and the actinides9Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)244Synthesis and Characterization of f-Element Iodate Architectures with Variable Dimensionality, α- and β-Am(IO3)322Syntheses, structures, and vibrational spectroscopy of the two-dimensional iodates Ln(IO3)3 and Ln(IO3)3(H2O) (LnYb, Lu)21Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]18Synthesis and structure of In(IO3)3 and vibrational spectroscopy of M(IO3)3 (M=Al, Ga, In)31Actinide compounds with heavy oxoanions containing a stereochemically active lone-pair of electrons2The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution106The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution19New iodate materials as potential laser matrices. Preparation and characterisation of α-M(IO3)3 (M=Y, Dy) and β-M(IO3)3 (M=Y, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er). Structural evolution as a function of the Ln3+ cationic radius41Hydrothermal synthesis, structural, Raman, and luminescence studies of Am[M(CN)2]3·3H2O and Nd[M(CN)2]3·3H2O (M=Ag, Au): Bimetallic coordination polymers containing both trans-plutonium and transition metal elements43Hydrothermal syntheses, structural, Raman, and luminescence studies of Cm[M(CN)2]3·3H2O and Pr[M(CN)2]3·3H2O (M=Ag, Au)43Magnetism and Raman spectroscopy of the dimeric lanthanide iodates Ln(IO3)3 (Ln=Gd, Er) and magnetism of Yb(IO3)322Polarity and Chirality in Uranyl Borates: Insights into Understanding the Vitrification of Nuclear Waste and the Development of Nonlinear Optical Materials104A two-dimensional topological structure and a series of corresponding plate-like Ln(IO3)3(H2O)·H2O (Ln = Nd, Eu, Gd, Tb, Dy) nanomaterials: Syntheses, structures and properties14Bonding Changes in Plutonium(III) and Americium(III) Borates60Bonding Changes in Plutonium(III) and Americium(III) Borates12Syntheses, Structures, and Spectroscopic Properties of Plutonium and Americium Phosphites and the Redetermination of the Ionic Radii of Pu(III) and Am(III)89Dielectric behavior and low temperature phase transition in NH4IO36Sensitizing Curium Luminescence through an Antenna Protein To Investigate Biological Actinide Transport Mechanisms54Oxoanion systems containing trivalent actinides16In[IO3](OH)2 – New member of hydrous and anhydrous iodate family with indium6Chirality and Polarity in the f‐Block Borates M4[B16O26(OH)4(H2O)3Cl4] (M=Sm, Eu, Gd, Pu, Am, Cm, and Cf)30Highly Luminescent and Stable Hydroxypyridinonate Complexes: A Step Towards New Curium Decontamination Strategies45Raman scattering structural studies of nonlinear optical M ( IO 3)3( M = Fe , Ga , α- In ) and linear optical β- In ( IO 3)323Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes48Comparing the 2,2′‐Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium49Comparing the 2,2′‐Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium19Hexavalent Americium Recovery Using Copper(III) Periodate51Inorganic Synthesis of Actinides3Substitutional Disorder of SeO32–/IO3– in the Crystalline Solid Matrix: Insights into the Fate of Radionuclides 79Se and 129I in the Environment15Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds20Organic and Aqueous Redox Speciation of Cu(III) Periodate Oxidized Transuranium Actinides13Uncovering the Origin of Divergence in the CsM(CrO4)2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis20TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)9An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements28An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements11Structure and Characterization of an Americium Bis(O,O’-diethyl)dithiophosphate Complex28A Trivalent Americium Organic Framework with Decent Structural Stability against Self‐Irradiation14MOFs with 12-Coordinate 5f-Block Metal Centers41Curium( iii ) luminescence spectroscopy as a tool for species determination4Room temperature crystal field splitting of curium resolved by circularly polarized luminescence spectroscopy5Ionothermal Synthesis of Am 4 B 22 O 42 Cl 12 : A Chiral Cubic Americium Borate Cluster2Investigation of Americium-Containing Phosphates, Silicates, Borates, Molybdates, and Fluorides Synthesized via High-Temperature Flux Crystal Growth6Spectroscopic Properties of Americium(III) in Mineral Acid Media7Light Emission from Transuranic Elements0

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  1. Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)3.

    ChemInform · 2005-09-28

    Richard E. Sykora, Zerihun Assefa, Richard Geoffrey Haire

    Read original paper ↗ ·

  2. First Structural Determination of a Trivalent Californium Compound with Oxygen Coordination

    Inorganic Chemistry · 2005-12-14

    Richard E. Sykora, Zerihun Assefa, Richard Geoffrey Haire, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  3. Scandium, yttrium, the lanthanides and the actinides

    Annual Reports Section A (Inorganic Chemistry) · 2006-01-01

    S. A. Cotton

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  4. Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2

    Journal of Solid State Chemistry · 2006-02-08

    Tyler A. Sullens, Philip M. Almond, Jessica A. Byrd, James V. Beitz, Travis H. Bray, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  5. Synthesis and Characterization of f-Element Iodate Architectures with Variable Dimensionality, α- and β-Am(IO3)3

    Inorganic Chemistry · 2006-02-11

    Wolfgang Runde, Amanda C. Bean, Lia F. Brodnax, Brian L. Scott

    Read original paper ↗ ·

  6. Syntheses, structures, and vibrational spectroscopy of the two-dimensional iodates Ln(IO3)3 and Ln(IO3)3(H2O) (LnYb, Lu)

    Journal of Solid State Chemistry · 2006-08-07

    Zerihun Assefa, Jie Ling, Richard Geoffrey Haire, Thomas E. Albrecht‐Schmitt, Richard E. Sykora

    Read original paper ↗ ·

  7. Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]

    Inorganic Chemistry · 2006-08-19

    Travis H. Bray, James V. Beitz, Amanda C. Bean, Yaqin Yu, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  8. Synthesis and structure of In(IO3)3 and vibrational spectroscopy of M(IO3)3 (M=Al, Ga, In)

    Journal of Solid State Chemistry · 2006-08-31

    Nhan Ngo, Katrina Kalachnikova, Zerihun Assefa, Richard Geoffrey Haire, Richard E. Sykora

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  9. Actinide compounds with heavy oxoanions containing a stereochemically active lone-pair of electrons

    Elsevier eBooks · 2007-01-01

    Richard E. Sykora, Tatiana Y. Shvareva, Thomas E. Albrecht‐Schmitt

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  10. The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution

    Angewandte Chemie International Edition · 2007-01-03

    Patric Lindqvist‐Reis, Christos Apostolidis, Jean Rebizant, Alfred Morgenstern, Reinhardt Klenze, Olaf Walter, Thomas Fanghänel, Richard Geoffrey Haire

    Read original paper ↗ ·

  11. The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution

    Angewandte Chemie · 2007-01-03

    Patric Lindqvist‐Reis, Christos Apostolidis, Jean Rebizant, Alfred Morgenstern, Reinhardt Klenze, Olaf Walter, Thomas Fanghänel, Richard Geoffrey Haire

    Read original paper ↗ ·

  12. New iodate materials as potential laser matrices. Preparation and characterisation of α-M(IO3)3 (M=Y, Dy) and β-M(IO3)3 (M=Y, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er). Structural evolution as a function of the Ln3+ cationic radius

    Solid State Sciences · 2007-04-15

    Delphine Phanon, Alain Mosset, Isabelle Gautier‐Luneau

    Read original paper ↗ ·

  13. Hydrothermal synthesis, structural, Raman, and luminescence studies of Am[M(CN)2]3·3H2O and Nd[M(CN)2]3·3H2O (M=Ag, Au): Bimetallic coordination polymers containing both trans-plutonium and transition metal elements

    Journal of Solid State Chemistry · 2007-09-18

    Zerihun Assefa, Katrina Kalachnikova, Richard Geoffrey Haire, Richard E. Sykora

    Read original paper ↗ ·

  14. Hydrothermal syntheses, structural, Raman, and luminescence studies of Cm[M(CN)2]3·3H2O and Pr[M(CN)2]3·3H2O (M=Ag, Au)

    Journal of Solid State Chemistry · 2008-01-19

    Zerihun Assefa, Richard Geoffrey Haire, Richard E. Sykora

    Read original paper ↗ ·

  15. Magnetism and Raman spectroscopy of the dimeric lanthanide iodates Ln(IO3)3 (Ln=Gd, Er) and magnetism of Yb(IO3)3

    Journal of Solid State Chemistry · 2008-05-04

    Richard E. Sykora, Peter G. Khalifah, Zerihun Assefa, Thomas E. Albrecht‐Schmitt, Richard Geoffrey Haire

    Read original paper ↗ ·

  16. Polarity and Chirality in Uranyl Borates: Insights into Understanding the Vitrification of Nuclear Waste and the Development of Nonlinear Optical Materials

    Chemistry of Materials · 2010-02-04

    Shuao Wang, Evgeny V. Alekseev, Jie Ling, Guokui Liu, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  17. A two-dimensional topological structure and a series of corresponding plate-like Ln(IO3)3(H2O)·H2O (Ln = Nd, Eu, Gd, Tb, Dy) nanomaterials: Syntheses, structures and properties

    Solid State Sciences · 2010-09-18

    Wen‐Xiang Chai, Jian Lin, Li Song, Kangying Shu, Laishun Qin, Hongsheng Shi, Jiayu Guo

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  18. Bonding Changes in Plutonium(III) and Americium(III) Borates

    Angewandte Chemie International Edition · 2011-08-18

    Matthew J. Polinski, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  19. Bonding Changes in Plutonium(III) and Americium(III) Borates

    Angewandte Chemie · 2011-08-18

    Matthew J. Polinski, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  20. Syntheses, Structures, and Spectroscopic Properties of Plutonium and Americium Phosphites and the Redetermination of the Ionic Radii of Pu(III) and Am(III)

    Inorganic Chemistry · 2012-07-17

    Justin N. Cross, Eric M. Villa, Shuao Wang, Juan Diwu, Matthew J. Polinski, Thomas E. Albrecht‐Schmitt

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  21. Dielectric behavior and low temperature phase transition in NH4IO3

    Phase Transitions · 2012-09-14

    M.M. Abdel Kader, F. El‐Kabbany, H. M. Naguib, W. M. Gamal

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  22. Sensitizing Curium Luminescence through an Antenna Protein To Investigate Biological Actinide Transport Mechanisms

    Journal of the American Chemical Society · 2013-01-30

    Manuel Sturzbecher‐Hoehne, Christophe Goujon, Gauthier J.‐P. Deblonde, Anne B. Mason, Rebecca J. Abergel

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  23. Oxoanion systems containing trivalent actinides

    Coordination Chemistry Reviews · 2013-07-22

    Matthew J. Polinski, Eric M. Villa, Thomas E. Albrecht‐Schmitt

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  24. In[IO3](OH)2 – New member of hydrous and anhydrous iodate family with indium

    Solid State Sciences · 2014-06-12

    Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov

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  25. Chirality and Polarity in the f‐Block Borates M4[B16O26(OH)4(H2O)3Cl4] (M=Sm, Eu, Gd, Pu, Am, Cm, and Cf)

    Chemistry - A European Journal · 2014-07-07

    Matthew J. Polinski, Kristen A. Pace, Jared T. Stritzinger, Jian Hung Lin, Justin N. Cross, Samantha K. Cary, Shelley M. Van Cleve, Evgeny V. Alekseev, Thomas E. Albrecht‐Schmitt

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  26. Highly Luminescent and Stable Hydroxypyridinonate Complexes: A Step Towards New Curium Decontamination Strategies

    Chemistry - A European Journal · 2014-07-07

    Manuel Sturzbecher‐Hoehne, Birgitta Kullgren, Erin Jarvis, Dahlia D. An, Rebecca J. Abergel

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  27. Raman scattering structural studies of nonlinear optical M ( IO 3)3( M = Fe , Ga , α- In ) and linear optical β- In ( IO 3)3

    Journal of Nonlinear Optical Physics & Materials · 2014-09-01

    M. Junaid Bushiri, T. C. Kochuthresia, V. K. Vaidyan, Isabelle Gautier‐Luneau

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  28. Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes

    Inorganic Chemistry · 2015-11-12

    Samantha K. Cary, Mark A. Silver, Guokui Liu, Jamie C. Wang, Justin A. Bogart, Jared T. Stritzinger, Alexandra A. Arico, Kenneth Hanson, Eric J. Schelter, Thomas E. Albrecht‐Schmitt

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  29. Comparing the 2,2′‐Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium

    Angewandte Chemie International Edition · 2016-09-15

    Justin N. Cross, Joseph A. Macor, Jeffery A. Bertke, Maryline G. Ferrier, Gregory S. Girolami, Stosh A. Kozimor, Joel R. Maassen, Brian L. Scott, David K. Shuh, Benjamin William Stein, S. Chantal E. Stieber

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  30. Comparing the 2,2′‐Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium

    Angewandte Chemie · 2016-09-22

    Justin N. Cross, Joseph A. Macor, Jeffery A. Bertke, Maryline G. Ferrier, Gregory S. Girolami, Stosh A. Kozimor, Joel R. Maassen, Brian L. Scott, David K. Shuh, Benjamin William Stein, S. Chantal E. Stieber

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  31. Hexavalent Americium Recovery Using Copper(III) Periodate

    Inorganic Chemistry · 2016-10-31

    Kevin P. McCann, Derek M. Brigham, Samuel S. Morrison, Jenifer C. Shafer

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  32. Inorganic Synthesis of Actinides

    Elsevier eBooks · 2017-01-01

    Wei‐Qun Shi, L. Mei, Zhifang Chai

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  33. Substitutional Disorder of SeO32–/IO3– in the Crystalline Solid Matrix: Insights into the Fate of Radionuclides 79Se and 129I in the Environment

    Inorganic Chemistry · 2017-03-09

    Yaxing Wang, Yumin Wang, Linjuan Zhang, Lanhua Chen, Zhiyong Liu, Xuemiao Yin, Daopeng Sheng, Juan Diwu, Jian‐Qiang Wang, Ning Liu, Zhifang Chai, Shuao Wang

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  34. Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds

    Inorganic Chemistry · 2017-10-09

    Yaxing Wang, Tao Duan, Zhehui Weng, Jie Ling, Xuemiao Yin, Lanhua Chen, Daopeng Sheng, Juan Diwu, Zhifang Chai, Ning Liu, Shuao Wang

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  35. Organic and Aqueous Redox Speciation of Cu(III) Periodate Oxidized Transuranium Actinides

    Industrial & Engineering Chemistry Research · 2018-01-08

    Kevin P. McCann, Sergey I. Sinkov, Gregg J. Lumetta, Jenifer C. Shafer

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  36. Uncovering the Origin of Divergence in the CsM(CrO4)2 (M = La, Pr, Nd, Sm, Eu; Am) Family through Examination of the Chemical Bonding in a Molecular Cluster and by Band Structure Analysis

    Journal of the American Chemical Society · 2018-01-10

    Shane S. Galley, Alexandra A. Arico, Tsung-Han Lee, Xiaoyu Deng, Yongxin Yao, Joseph M. Sperling, Vanessa Proust, Julia S. Storbeck, V. Dobrosavljević, Jennifer Neu, Theo Siegrist, Ryan Baumbach, Thomas E. Albrecht‐Schmitt, Nikolas Kaltsoyannis, Nicola Lanatà

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  37. TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)

    Chinese Journal of Physics · 2019-02-22

    Soraya Belhadj, Brahim Lagoun, Mohamed B. Taouti, Salah Khenchoul, Ali Benghia, Djamel Benbertal

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  38. An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements

    Angewandte Chemie International Edition · 2019-09-19

    J. August Ridenour, Robert G. Surbella, Artem V. Gelis, Daniel Koury, Frédéric Poineau, Kenneth R. Czerwinski, Christopher L. Cahill

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  39. An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements

    Angewandte Chemie · 2019-09-19

    J. August Ridenour, Robert G. Surbella, Artem V. Gelis, Daniel Koury, Frédéric Poineau, Kenneth R. Czerwinski, Christopher L. Cahill

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  40. Structure and Characterization of an Americium Bis(O,O’-diethyl)dithiophosphate Complex

    Inorganic Chemistry · 2020-10-29

    R. D. M. Greer, Cristian Celis‐Barros, Joseph M. Sperling, Alyssa Gaiser, Cory J. Windorff, Thomas E. Albrecht-Schönzart

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  41. A Trivalent Americium Organic Framework with Decent Structural Stability against Self‐Irradiation

    Chinese Journal of Chemistry · 2021-11-26

    Yugang Zhang, Kai Li, Sida Zhang, Xia Wang, Hailong Zhang, Yanlong Wang, Yanlong Wang, Yaxing Wang, Yaxing Wang, Zhifang Chai, Shuao Wang

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  42. MOFs with 12-Coordinate 5f-Block Metal Centers

    Journal of the American Chemical Society · 2022-02-10

    Kai Lv, Christian Urbank, Michael Patzschke, Juliane März, Peter Kaden, Stephan Weiß, Moritz Schmidt

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  43. Curium( iii ) luminescence spectroscopy as a tool for species determination

    Chemical Society Reviews · 2025-01-01

    Moritz Schmidt, Andrej Skerencak-Frech, Petra J. Panak, Nina Huittinen

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  44. Room temperature crystal field splitting of curium resolved by circularly polarized luminescence spectroscopy

    Chemical Science · 2025-01-01

    Joshua J. Woods, Appie A. Peterson, Joseph A. Adewuyi, Rachael Lai, Jennifer N. Wacker, Rebecca J. Abergel, Gaël Ung

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  45. Ionothermal Synthesis of Am 4 B 22 O 42 Cl 12 : A Chiral Cubic Americium Borate Cluster

    Inorganic Chemistry · 2025-01-24

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  46. Investigation of Americium-Containing Phosphates, Silicates, Borates, Molybdates, and Fluorides Synthesized via High-Temperature Flux Crystal Growth

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  47. Spectroscopic Properties of Americium(III) in Mineral Acid Media

    Inorganic Chemistry · 2025-07-08

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  48. Light Emission from Transuranic Elements

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