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RESEARCH PAPER · Inorganic Chemistry · 2003

Cation−Cation Interactions in Neptunyl(V) Compounds: Hydrothermal Preparation and Structural Characterization of NpO2(IO3) and α- and β-AgNpO2(SeO3)

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Cation−Cation Interactions in Neptunyl(V) Compounds: Hydrothermal Preparation and Structural Characterization of NpO2(IO3) and α- and β-AgNpO2(SeO3)OriginalDo Secondary and Tertiary Ammonium Cations Act as Structure-Directing Agents in the Formation of Layered Uranyl Selenites?48Cation—Cation Interactions in Neptunyl(V) Compounds: Hydrothermal Preparation and Structural Characterization of NpO2(IO3) and α‐ and β‐AgNpO2(SeO3).0New one-dimensional uranyl and neptunyl iodates: crystal structures of K3[(UO2)2(IO3)6](IO3)·H2O and K[NpO2(IO3)3]·1.5H2O22Hydrothermal synthesis and structure of K6[(UO2)4(CrO4)7]·6H2O: A layered uranyl chromate with a new uranyl sheet topology3018 Scandium, yttrium, the lanthanides and the actinides11Hydrothermal Synthesis, Structure, and Magnetic Properties of the Mixed-Valent Np(IV)/Np(V) Selenite Np(NpO2)2(SeO3)355Hydrothermal synthesis, structure, and catalytic properties of UO2Sb2O425Cation−Cation Interactions between Uranyl Cations in a Polar Open-Framework Uranyl Periodate136Hydrothermal synthesis and crystal structure of a three-dimensional metal selenite containing double helical chains: Fe3(H2O)(SeO3)313Ethylenediammonium decafluorodineptunate(IV)4Magnetism and electron spin resonance in single crystalline β-AgNpO2(SeO3)18Structural Variability in Neptunium(V) Oxalate Compounds: Synthesis and Structural Characterization of Na2NpO2(C2O4)OH·H2O23Hydrothermal synthesis, structure, Raman spectroscopy, and self-irradiation studies of 248Cm(IO3)342Crystal chemistry and ion-exchange properties of the layered uranyl iodate K[UO2(IO3)3]40Similarities between the Coordination of Actinide Ions in Solution and the Structures of their Related Crystalline Phases1Synthesis and structure of a novel three-dimensional metal selenite containing multidirectional intersecting double helical chains: [Fe2(H2O)4(SeO3)2]8Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)348Study of Hg22+ and Complexes of NpO2+ and UO22+ in Solution. Examples of Cation−Cation Interactions38Hydrothermal Synthesis and Structure of Neptunium(V) Oxide2Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)244Silver(I) Coordination Polymers Based on A Nano-Sized Bent Bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole Ligand: The Role of Ligand Isomerism and the Templating Effect of Polyatomic Anions and Solvent Intermediates87Vibrational Spectroscopy of Mass-Selected [UO2(ligand)n]2+Complexes in the Gas Phase: Comparison with Theory105Syntheses, structures, and vibrational spectroscopy of the two-dimensional iodates Ln(IO3)3 and Ln(IO3)3(H2O) (LnYb, Lu)21Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]18Development and characterization of nanocomposite materials36Na2Li8[(UO2)11O12(WO5)2]: Three Different Uranyl‐Ion Coordination Geometries and Cation–Cation Interactions71Na2Li8[(UO2)11O12(WO5)2]: Three Different Uranyl‐Ion Coordination Geometries and Cation–Cation Interactions17Product evolution in the Np(IV) fluorophosphate system15The role of cation–cation interactions in a neptunyl chloride hydrate and topological aspects of neptunyl structural units30Cation−Cation Interactions and Antiferromagnetism in Na[Np(V)O2(OH)2]: Synthesis, Structure, and Magnetic Properties49Molecular magnetism in neptunyl (+1, +2) complexes: 237Np-Mössbauer and magnetic study4Actinide compounds with heavy oxoanions containing a stereochemically active lone-pair of electrons2Synthesis, crystal and band structures, and optical properties of a new mixed-framework mercury selenide diselenite, (Hg3Se2)(Se2O5)9Syntheses, structures, and properties of Ag4(Mo2O5)(SeO4)2(SeO3) and Ag2(MoO3)3SeO337Selenium Oxoanion Compounds of Palladium(II)25A Theoretical Study of the Inner-Sphere Disproportionation Reaction Mechanism of the Pentavalent Actinyl Ions134One-Dimensional Array of Two- and Three-Center Cation−Cation Bonds in the Structure of Li4[(UO2)10O10(Mo2O8)]63Synthesis, Structure, and Infrared Spectroscopy of the First Np5+ Neptunyl Silicates, Li6(NpO2)4(H2Si2O7)(HSiO4)2(H2O)4 and K3(NpO2)3(Si2O7)19Hydrothermal synthesis and structure characterization of the first organically templated metal iodates2A Comparison of Neptunyl(V) and Neptunyl(VI) Solution Coordination: The Stability of Cation−Cation Interactions71Hydrothermal Synthesis and Crystal Structure of Polar and Nonpolar Compounds in Indium Iodate Family31Hydrothermal Synthesis and X‐ray Crystal Structure of Four Inorganic‐Organic Hybrid Compounds in Vanadium /Copper Iodate Family0Electrochemical and Complexation Behavior of Neptunium in Aqueous Perchlorate and Nitrate Solutions115Synthesis, structure determination, and infrared spectroscopy of (NpO2)2(SO4)(H2O)4: Prevalence of cation–cation interactions and cationic nets in neptunyl sulfate compounds21NEPTUNYL COMPOUNDS: POLYHEDRON GEOMETRIES, BOND-VALENCE PARAMETERS, AND STRUCTURAL HIERARCHY77Synthesis and crystal structure of pentavalent uranyl complexes. The remarkable stability of UO2X (X = I, SO3CF3) in non-aqueous solutions95Oxo ligand functionalization in the uranyl ion (UO22+)335Quaternary Neptunium Compounds: Syntheses and Characterization of KCuNpS3, RbCuNpS3, CsCuNpS3, KAgNpS3, and CsAgNpS322Does Iodate Incorporate into Layered Uranyl Phosphates Under Hydrothermal Conditions?18Further insights into intermediate- and mixed-valency in neptunium oxoanion compounds: structure and absorption spectroscopy of K2[(NpO2)3B10O16(OH)2(NO3)2]52Hydrothermal Synthesis and Crystal Structures of Actinide Compounds2Plutonium30Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9− and their supramolecular pairing in the solid state52Binuclear Uranium(VI) Complexes with a “Pacman” Expanded Porphyrin: Computational Evidence for Highly Unusual Bis‐Actinyl Structures45Crystal and Electronic Structure of a Mixed-Valent Np(IV)−Np(V) Compound: [BuMeIm]5[Np(NpO2)3(H2O)6Cl12]30Polarity and Chirality in Uranyl Borates: Insights into Understanding the Vitrification of Nuclear Waste and the Development of Nonlinear Optical Materials104Binuclear Hexa- and Pentavalent Uranium Complexes with a Polypyrrolic Ligand: A Density Functional Study of Water- and Hydronium-Induced Reactions44Theoretical predictions of cofacial bis(actinyl) complexes of a stretched Schiff-base calixpyrrole ligand46Role of Anions and Reaction Conditions in the Preparation of Uranium(VI), Neptunium(VI), and Plutonium(VI) Borates56Two New Neptunyl(V) Selenites: A Novel Cation–Cation Interaction Framework in (NpO2)3(OH)(SeO3)(H2O)2·H2O and a Uranophane-Type Sheet in Na(NpO2)(SeO3)(H2O)29Synthesis, Structural Characterization, and Magnetic Properties of the Heteroleptic Dinuclear Nickel Selenite Complex [{Ni(TMEDA)SeO3}2]6Three-Dimensional Hybrid Framework Containing U2O13 Dimers Connected via Cation–Cation Interactions48Theoretical exploration of uranyl complexes of a designed polypyrrolic macrocycle: structure/property effects of hinge size on Pacman-shaped complexes31Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks30One-Dimensional Uranyl-2,2′-bipyridine Coordination Polymer with Cation–Cation Interactions: (UO2)2(2,2′-bpy)(CH3CO2)(O)(OH)44The First Uranyl Arsonates Featuring Heterometallic Cation–Cation Interactions with UVI═O–ZnII Bonding40Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges344Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies36Uranium minerals and their relevance to long term storage of nuclear fuels116Expansion of the Rich Structures and Magnetic Properties of Neptunium Selenites: Soft Ferromagnetism in Np(SeO3)213The structure hierarchy hypothesis44Synthesis and structure of crystalline complexes of Np(V) with isophthalic acid. Cation-cation interaction in the compounds [(NpO2)2(C6H4(COO)2)(H2O)]·H2O and M[(NpO2)(C6H4(COO)2)]·2.5H2O, M = [H3O], [NH4], and [C(NH2)3]6Atypical temperature-dependence of symmetry transformation observed in a uranyl phosphonate25Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium34Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds20Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité0Unexpected Behavior of Np in Oxo-selenate/Oxo-selenite Systems9Electron-Transfer-Enhanced Cation–Cation Interactions in Homo- and Heterobimetallic Actinide Complexes: A Relativistic Density Functional Theory Study7Role of Bis(triphenylphosphine)iminium Cation [PNP]+ on the Crystal Packing of [PNP]+[HSeO3]− Solvate Salt2Actinides: Crystallography0Accessibility of Uranyl–Plutonium Complex Supported by a Polypyrrolic Macrocycle: An Implication for Experimental Synthesis5Mixed-valent neptunium oligomer complexes based on cation–cation interactions4The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds41Secondary Role of Aliphatic and Heterocyclic Amines in the Formation of Low-Temperature Amine-Bearing U, Np, and Pu(VI) Chromates2Dinuclear Complexes of Uranyl, Neptunyl, and Plutonyl: Structures and Oxidation States Revealed by Experiment and Theory5Exploring the Valence Diversity of Uranium by Flux Growth of Uranium Silicate under Inert Atmosphere6Cation–Cation Interactions in Neptunium(V,VI)-diglycolamide System0

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  1. Do Secondary and Tertiary Ammonium Cations Act as Structure-Directing Agents in the Formation of Layered Uranyl Selenites?

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  2. Cation—Cation Interactions in Neptunyl(V) Compounds: Hydrothermal Preparation and Structural Characterization of NpO2(IO3) and α‐ and β‐AgNpO2(SeO3).

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  3. New one-dimensional uranyl and neptunyl iodates: crystal structures of K3[(UO2)2(IO3)6](IO3)·H2O and K[NpO2(IO3)3]·1.5H2O

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  4. Hydrothermal synthesis and structure of K6[(UO2)4(CrO4)7]·6H2O: A layered uranyl chromate with a new uranyl sheet topology

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  5. 18 Scandium, yttrium, the lanthanides and the actinides

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  6. Hydrothermal Synthesis, Structure, and Magnetic Properties of the Mixed-Valent Np(IV)/Np(V) Selenite Np(NpO2)2(SeO3)3

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  7. Hydrothermal synthesis, structure, and catalytic properties of UO2Sb2O4

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  8. Cation−Cation Interactions between Uranyl Cations in a Polar Open-Framework Uranyl Periodate

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  9. Hydrothermal synthesis and crystal structure of a three-dimensional metal selenite containing double helical chains: Fe3(H2O)(SeO3)3

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  10. Ethylenediammonium decafluorodineptunate(IV)

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  11. Magnetism and electron spin resonance in single crystalline β-AgNpO2(SeO3)

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  12. Structural Variability in Neptunium(V) Oxalate Compounds: Synthesis and Structural Characterization of Na2NpO2(C2O4)OH·H2O

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  13. Hydrothermal synthesis, structure, Raman spectroscopy, and self-irradiation studies of 248Cm(IO3)3

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  14. Crystal chemistry and ion-exchange properties of the layered uranyl iodate K[UO2(IO3)3]

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  15. Similarities between the Coordination of Actinide Ions in Solution and the Structures of their Related Crystalline Phases

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  16. Synthesis and structure of a novel three-dimensional metal selenite containing multidirectional intersecting double helical chains: [Fe2(H2O)4(SeO3)2]

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  17. Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)3

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  18. Study of Hg22+ and Complexes of NpO2+ and UO22+ in Solution. Examples of Cation−Cation Interactions

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  19. Hydrothermal Synthesis and Structure of Neptunium(V) Oxide

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  20. Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2

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  21. Silver(I) Coordination Polymers Based on A Nano-Sized Bent Bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole Ligand: The Role of Ligand Isomerism and the Templating Effect of Polyatomic Anions and Solvent Intermediates

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  22. Vibrational Spectroscopy of Mass-Selected [UO2(ligand)n]2+Complexes in the Gas Phase: Comparison with Theory

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  23. Syntheses, structures, and vibrational spectroscopy of the two-dimensional iodates Ln(IO3)3 and Ln(IO3)3(H2O) (LnYb, Lu)

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  24. Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]

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  25. Development and characterization of nanocomposite materials

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  26. Na2Li8[(UO2)11O12(WO5)2]: Three Different Uranyl‐Ion Coordination Geometries and Cation–Cation Interactions

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  28. Product evolution in the Np(IV) fluorophosphate system

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  29. The role of cation–cation interactions in a neptunyl chloride hydrate and topological aspects of neptunyl structural units

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  30. Cation−Cation Interactions and Antiferromagnetism in Na[Np(V)O2(OH)2]: Synthesis, Structure, and Magnetic Properties

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  31. Molecular magnetism in neptunyl (+1, +2) complexes: 237Np-Mössbauer and magnetic study

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  32. Actinide compounds with heavy oxoanions containing a stereochemically active lone-pair of electrons

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    Richard E. Sykora, Tatiana Y. Shvareva, Thomas E. Albrecht‐Schmitt

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  33. Synthesis, crystal and band structures, and optical properties of a new mixed-framework mercury selenide diselenite, (Hg3Se2)(Se2O5)

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  34. Syntheses, structures, and properties of Ag4(Mo2O5)(SeO4)2(SeO3) and Ag2(MoO3)3SeO3

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  35. Selenium Oxoanion Compounds of Palladium(II)

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  36. A Theoretical Study of the Inner-Sphere Disproportionation Reaction Mechanism of the Pentavalent Actinyl Ions

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  37. One-Dimensional Array of Two- and Three-Center Cation−Cation Bonds in the Structure of Li4[(UO2)10O10(Mo2O8)]

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  38. Synthesis, Structure, and Infrared Spectroscopy of the First Np5+ Neptunyl Silicates, Li6(NpO2)4(H2Si2O7)(HSiO4)2(H2O)4 and K3(NpO2)3(Si2O7)

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  39. Hydrothermal synthesis and structure characterization of the first organically templated metal iodates

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  40. A Comparison of Neptunyl(V) and Neptunyl(VI) Solution Coordination: The Stability of Cation−Cation Interactions

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  41. Hydrothermal Synthesis and Crystal Structure of Polar and Nonpolar Compounds in Indium Iodate Family

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  42. Hydrothermal Synthesis and X‐ray Crystal Structure of Four Inorganic‐Organic Hybrid Compounds in Vanadium /Copper Iodate Family

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  43. Electrochemical and Complexation Behavior of Neptunium in Aqueous Perchlorate and Nitrate Solutions

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  44. Synthesis, structure determination, and infrared spectroscopy of (NpO2)2(SO4)(H2O)4: Prevalence of cation–cation interactions and cationic nets in neptunyl sulfate compounds

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  45. NEPTUNYL COMPOUNDS: POLYHEDRON GEOMETRIES, BOND-VALENCE PARAMETERS, AND STRUCTURAL HIERARCHY

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  46. Synthesis and crystal structure of pentavalent uranyl complexes. The remarkable stability of UO2X (X = I, SO3CF3) in non-aqueous solutions

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  47. Oxo ligand functionalization in the uranyl ion (UO22+)

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  48. Quaternary Neptunium Compounds: Syntheses and Characterization of KCuNpS3, RbCuNpS3, CsCuNpS3, KAgNpS3, and CsAgNpS3

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  49. Does Iodate Incorporate into Layered Uranyl Phosphates Under Hydrothermal Conditions?

    Inorganic Chemistry · 2009-10-30

    Jie Ling, Shijun Wu, Fanrong Chen, Antonio Simonetti, J. T. Shafer, Thomas E. Albrecht‐Schmitt

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  50. Further insights into intermediate- and mixed-valency in neptunium oxoanion compounds: structure and absorption spectroscopy of K2[(NpO2)3B10O16(OH)2(NO3)2]

    Chemical Communications · 2010-01-01

    Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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