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RESEARCH PAPER · Angewandte Chemie International Edition · 2015

Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge

Sangen Zhao, Pifu Gong, Siyang Luo, Lei Bai, Zheshuai Lin, Yuan‐Yuan Tang, Yuelan Zhou, Maochun Hong, Junhua Luo

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Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption EdgeOriginalChemInform Abstract: Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge.0“XA 6 ” octahedra influencing the arrangement of anionic groups and optical properties in inverse-perovskite [B 6 O 10 ]XA 3 (X = Cl, Br; A = alkali metal)19AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups59KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold124KMg6(P2O7)2P3O10: A novel phosphate with two distinct anions22Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem256Synthesis and structure of a new halophosphate Sr 3 P 3 O 10 Cl with the flexible [P 3 O 10 ] 5− anions9Crystal growth and optical characteristics of beryllium-free polyphosphate, KLa(PO3)4, a possible deep-ultraviolet nonlinear optical crystal101Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba3(ZnB5O10)PO442A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups49Application of the Dimensional Reduction Formalism to Pb12[Li2(P2O7)2(P4O13)2](P4O13): a Phosphate Containing Three Types of Isolated P–O Groups21A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response384Deep Ultraviolet Nonlinear Optical Materials644A new congruent-melting double phosphate PbCd(PO3)4 with photocatalytic activity10Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Growth, Properties, and Theoretical Analysis of KBa2(PO3)5 Single Crystal51Deep-Ultraviolet Transparent Cs 2 LiPO 4 Exhibits an Unprecedented Second Harmonic Generation160Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge69LiRb 2 PO 4 : a new deep-ultraviolet nonlinear optical phosphate with a large SHG response95Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2113Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)220Application of the dimensional reduction formalism to Pb 9−x Ba x [Li 2 (P 2 O 7 ) 2 (P 4 O 13 ) 2 ] (x = 0, 2, 6, 7): a series of phosphates with two types of isolated polyphosphate groups13Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups237Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units16Theoretical investigation on the balance between large band gap and strong SHG response in BMO 4 (M = P and As) crystals22Two Phosphates: Noncentrosymmetric Cs6Mg6(PO3)18 and Centrosymmetric Cs2MgZn2(P2O7)255M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications238Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth893Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth99A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures36Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5Synthesis and characterization of a new beryllium-free deep-ultraviolet nonlinear optical material: Na2GdCO3F331Linear-to-λ-Shape P–O–P Bond Transmutation in Polyphosphates with Infinite (PO3)∞ Chain15Rational Design of Deep-Ultraviolet Nonlinear Optical Materials in Fluorooxoborates: Toward Optimal Planar Configuration157The Power of Heterometalation through Lithium for Helix Chain-Based Noncentrosymmetric Metal–Organic Frameworks with Tunable Second-Harmonic Generation Effects19LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point56Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups9K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups31An optoelectronic duple bistable phosphate with ultrahigh thermal stability7A 36-Membered Ring Metal Chalcogenide with a Very Low Framework Density26Crystal Growth and Optical Properties of Beryllium-Free Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F35A beryllium-free deep-UV nonlinear optical material CsNaMgP 2 O 7 with honeycomb-like topological layers53Evaluating the component contribution to nonlinear optical performances using stable [Ni 4 O 4 ] cuboidal clusters as models13First principle study of nonlinear optical crystals15K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure26Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholds76A Joint Strategy To Evaluate the Microscopic Origin of the Second-Harmonic-Generation Response in Nonpolar ABCO3F Compounds32Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation239Synthesis, crystal structure and characterizations of a new diphosphate Rb2CaP2O719Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals258Deep-ultraviolet nonlinear optical materials: Development trend and innovative exploration16Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications18The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation14Synthesis, structure and electronic structure calculation of a new perovskite-type phosphate fluoride K2BaPO4F9Exploring Potential Beryllium-free, Deep-Ultraviolet Optical Crystals in the Rare Earth Fluoride Carbonate–Water System34Rational Design of the First Lead/Tin Fluorooxoborates MB2O3F2 (M = Pb, Sn), Containing Flexible Two-Dimensional [B6O12F6]∞ Single Layers with Widely Divergent Second Harmonic Generation Effects212MIMIIP3O9 (MI = Rb, MII = Cd, Mg, Ca; MI = Cs, MII = Pb, Sr; MI = K, MII = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties35Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge14Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates265Two noncentrosymmetric polyphosphates featuring infinite one-dimensional (PO3)∞ chain, LiMP2O6 (M = Rb, Cs): Synthesis, structure and optical properties8Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials195Removal of A-Site Alkali and Alkaline Earth Metal Cations in KBe2BO3F2-Type Layered Structures To Enhance the Deep-Ultraviolet Nonlinear Optical Capability47ALiZnP2O7 (A = Rb, Cs): Two Mixed Alkali Zinc Pyrophosphates Featuring a [Li2Zn2P4O20]14– Anionic Skeleton34A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)336Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure245The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation26BaPO3Cl: a Metal Phosphate Chloride with Infinite [PO3]∞ Chains25Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)36Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction13Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response13An alkali metal phosphate RbPbBi 2 (PO 4 ) 3 with three kinds of disorder: the effect of isolated soft cation units on the crystal structure7Chloride carbodiimide K 12 Pb 51 (CN 2 ) 30 Cl 54 with an unprecedented 45 Å unit cell axis and a large birefringence7Growth and theoretical study on the deep-ultraviolet transparent β-CsBa 2 (PO 3 ) 5 nonlinear optical crystal10Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba 11 [Al(PO 4 ) 4 ](P 2 O 7 )(PO 4 ) 3 with balanced overall performance and parsimony-forbidden structure23Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal79Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 611BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7Abrupt Structural Transformation in Asymmetric ABPO4F (A = K, Rb, Cs)21A New Cadmium‐Based Pb2Cd3(PO4)2(P2O7) with Two Types of Isolated P–O Groups18Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties26Lone‐Pair Enhanced Birefringence in an Alkaline‐Earth Metal Tin(II) Phosphate BaSn 2 (PO 4 ) 2130Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates268Targeting the Next Generation of Deep-Ultraviolet Nonlinear Optical Materials: Expanding from Borates to Borate Fluorides to Fluorooxoborates450Four new deep ultraviolet borates with isolated B12O24 groups: Synthesis, structure, and optical properties9Module-Analysis-Assisted Design of Deep Ultraviolet Fluorooxoborates with Extremely Large Gap and High Structural Stability109Cs2Zn5(PO4)4 and Cs3La(PO4)2: Two Cs‐Containing Phosphates with Three‐Dimensional Frameworks14Synthesis, structure and characterization of a new triphosphate: CsMg2P3O102Highly Polarizable Hg2+ Induced a Strong Second Harmonic Generation Signal and Large Birefringence in LiHgPO4265Syntheses, crystal structures, and characterizations of three new pyrophosphates CsNaZnP2O7, RbNaZnP2O7, and RbLiMgP2O710Rb10Zn4Sn4S17: A Chalcogenide with Large Laser Damage Threshold Improved from the Mn-Based Analogue28LiCsPbP2O7: A new alkali metal lead pyrophosphate featuring two dimensional [LiP2O7]∞ layer2KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 483A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups53Syntheses, characterization, and theoretical calculation of Rb2Mg3(P2O7)2 polymorphs with deep-ultraviolet cutoff edges18Highly porous aluminophosphates with unique three dimensional open framework structures from mild hydrothermal syntheses16Large nonlinear optical effect in tungsten bronze structures via Li/Na cross-substitutions4M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework9Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence49Polar polymorphism: α- and β-KCsWP 2 O 9 nonlinear optical materials with a strong second harmonic generation response25Similarities and differences between Mn( ii ) and Zn( ii ) coordination polymers supported by porphyrin-based ligands: synthesis, structures and nonlinear optical properties24Syntheses, structures and characterization of non-centrosymmetric Rb 2 Zn 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 M 3 (P 2 O 7 ) 2 (M = Zn and Mg)26Tellurium–oxygen group enhanced birefringence in tellurium phosphates: a first-principles investigation4The functionality of tetrahedral units in fluoroxoiodates: fluorine-modulating effects in iodates with lone pair electrons3Three diphosphates, α-Li 2 Na 2 P 2 O 7 , Li 8 Pb 3 Ba(P 2 O 7 ) 4 and Li 7 Rb(P 2 O 7 ) 2 : influences of co-substitution on the crystal structure9Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response23Two new ammonium/alkali-rare earth metal difluorophosphates ALa(PO 2 F 2 ) 4 (A = NH 4 and K) with moderate birefringence and short cutoff edges26Band-Gap Modulation of Nonlinear-Optical Fluorooxoborates by Controlling the F/B Ratios4Ultraviolet nonlinear optical crystal: (NH4)ZnPO47The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement8Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO3)2F290Noncentrosymmetric Orthophosphate YM3(PO4)3 (M = Sr, Ba) Crystals: Single Crystal Growth, Structure, and Properties34Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra147Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra43Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials55Designing a Deep-UV Nonlinear Optical Fluorooxosilicophosphate127Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates10Syntheses, characterization and calculations of LimAnM6O15 (A=Rb, Cs; M=Si, Ge; m+n=6)18Two Copper-Rich Open-Framework Chalcogenides Built from Unusual [Cu5(SnxM1–x)Se10] Clusters and [(SnxM1–x)2Se6] Dimeric Linkers (M = In and Ga)4Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials137Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials29Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials131CsZn2BO3X2 (X2=F2, Cl2, and FCl): A Series of Beryllium‐Free Deep‐Ultraviolet Nonlinear‐Optical Crystals with Excellent Properties143CsZn2BO3X2 (X2=F2, Cl2, and FCl): A Series of Beryllium‐Free Deep‐Ultraviolet Nonlinear‐Optical Crystals with Excellent Properties29A2BBi2(PO4)2(P2O7) (A = K, Rb, B = Pb, Cd): the Effect of Cation Sizes on Structural Evolution10K8Cd21Pb7(P2O7)16 and KCd2P3O10: Two new phosphates featuring special structure configurations2Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence92Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence13Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62Ba 3 [Al(PO 4 ) 3 ]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO 4 ) 4 ] 9− units16ACs 5 Bi 4 (PO 4 ) 2 (P 2 O 7 ) 3 (A = K, Rb and Cs) with two kinds of isolated P–O groups designed by dimensional reduction theory6Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials41Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization28K 2 ZnMoP 2 O 10 : a novel nonlinear optical molybdophosphate with a strong second harmonic generation response and moderate birefringence24RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers9To improve the key properties of nonlinear optical crystals assembled with tetrahedral functional building units46Ultraviolet nonlinear optical crystals A 3 SrBi(P 2 O 7 ) 2 (A = K, Rb) with large second harmonic generation responses15A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups106M(NH 2 SO 3 ) 2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence142M(NH 2 SO 3 ) 2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence27UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate196UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate28BaYOBO3: A deep-ultraviolet rare-earth oxy-borate with a large second harmonic generation response45KCs2[Pb2Br5(HCOO)2]: A Polar 3D Lead‐Bromide Framework Exhibiting Strong Second‐Harmonic Generation Response10The application and development of the first principles calculation in nonlinear optical materials1

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  1. ChemInform Abstract: Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge.

    ChemInform · 2015-05-27

    Sangen Zhao, Pifu Gong, Siyang Luo, Lei Bai, Zheshuai Lin, Yuan‐Yuan Tang, Yuelan Zhou, Maochun Hong, Junhua Luo

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  2. “XA 6 ” octahedra influencing the arrangement of anionic groups and optical properties in inverse-perovskite [B 6 O 10 ]XA 3 (X = Cl, Br; A = alkali metal)

    Physical Chemistry Chemical Physics · 2016-01-01

    Zhihua Yang, Bing‐Hua Lei, Bin Yang, Shilie Pan

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  3. AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups

    Journal of Materials Chemistry C · 2016-01-01

    Yuqiao Zhou, Liling Cao, Chensheng Lin, Min Luo, Tao Yan, Ning Ye, Wendan Cheng

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  4. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge

    Journal of Materials Chemistry C · 2016-01-01

    Maierhaba Abudoureheman, Shujuan Han, Bing‐Hua Lei, Zhihua Yang, Xifa Long, Shilie Pan

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  5. RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold

    Chemistry of Materials · 2016-02-02

    Qi Wu, Hongming Liu, Fangchao Jiang, Lei Kang, Lei Yang, Zheshuai Lin, Zhanggui Hu, Xingguo Chen, Xiang‐Gao Meng, Jingui Qin

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  6. KMg6(P2O7)2P3O10: A novel phosphate with two distinct anions

    Inorganic Chemistry Communications · 2016-02-08

    Yaoguo Shen, Siyuan Zeng, Yingying Xu, Sijie Liu, Sasa Wang, Zhenyue Wu, Sangen Zhao, Junhua Luo

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  7. Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem

    Journal of the American Chemical Society · 2016-02-18

    Sangen Zhao, Lei Kang, Yaoguo Shen, Xiaodong Wang, Muhammad Adnan Asghar, Zheshuai Lin, Yingying Xu, Siyuan Zeng, Maochun Hong, Junhua Luo

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  8. Synthesis and structure of a new halophosphate Sr 3 P 3 O 10 Cl with the flexible [P 3 O 10 ] 5− anions

    Solid State Sciences · 2016-03-21

    Jianhua Gao, Xi Liu, Limei Song, Xunshan Sha, Pan Zhao, Ping Guo

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  9. Crystal growth and optical characteristics of beryllium-free polyphosphate, KLa(PO3)4, a possible deep-ultraviolet nonlinear optical crystal

    Scientific Reports · 2016-04-29

    Pai Shan, Tongqing Sun, Hong Chen, Hongde Liu, Shaolin Chen, Xuanwen Liu, Yongfa Kong, Jingjun Xu

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  10. Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba3(ZnB5O10)PO4

    Crystal Growth & Design · 2016-05-23

    Hongwei Yu, Jacqueline Cantwell, Hongping Wu, Weiguo Zhang, Kenneth Reinhard Poeppelmeier, P. Shiv Halasyamani

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  11. A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups

    Chemistry of Materials · 2016-06-02

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  12. Application of the Dimensional Reduction Formalism to Pb12[Li2(P2O7)2(P4O13)2](P4O13): a Phosphate Containing Three Types of Isolated P–O Groups

    Inorganic Chemistry · 2016-07-11

    Xiangyu Zhang, Hongping Wu, Ying Wang, Xiaoyu Dong, Shujuan Han, Shilie Pan

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  13. A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response

    Journal of the American Chemical Society · 2016-07-12

    Lin Li, Ying Wang, Bing‐Hua Lei, Shujuan Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  14. Deep Ultraviolet Nonlinear Optical Materials

    Chemistry of Materials · 2016-07-12

    T. Thao Tran, Hongwei Yu, James M. Rondinelli, Kenneth Reinhard Poeppelmeier, P. Shiv Halasyamani

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  15. A new congruent-melting double phosphate PbCd(PO3)4 with photocatalytic activity

    Journal of Alloys and Compounds · 2016-08-04

    Molin Zhou, Xingxing Jiang, Mingjun Xia, Hongwei Huang, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  16. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie International Edition · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  17. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  18. Growth, Properties, and Theoretical Analysis of KBa2(PO3)5 Single Crystal

    Crystal Growth & Design · 2016-09-07

    Pai Shan, Tongqing Sun, Hongde Liu, Shiguo Liu, Shaolin Chen, Xuanwen Liu, Yongfa Kong, Jingjun Xu

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  19. Deep-Ultraviolet Transparent Cs 2 LiPO 4 Exhibits an Unprecedented Second Harmonic Generation

    Chemistry of Materials · 2016-09-13

    Yaoguo Shen, Yi Jin Yang, Sangen Zhao, Bingqing Zhao, Zheshuai Lin, Chengmin Ji, Lina Li, Ping Fu, Maochun Hong, Junhua Luo

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  20. Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge

    Inorganic Chemistry · 2016-10-31

    Yaoguo Shen, Sangen Zhao, Bingqing Zhao, Chengmin Ji, Lina Li, Zhihua Sun, Maochun Hong, Junhua Luo

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  21. LiRb 2 PO 4 : a new deep-ultraviolet nonlinear optical phosphate with a large SHG response

    Journal of Materials Chemistry C · 2016-11-21

    Lin Li, Ying Wang, Bing‐Hua Lei, Shujuan Han, Zhihua Yang, Hongyi Li, Shilie Pan

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  22. Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2

    Angewandte Chemie International Edition · 2016-11-30

    Sangen Zhao, Yi Jin Yang, Yaoguo Shen, Bingqing Zhao, Lina Li, Chengmin Ji, Zhenyue Wu, Daqiang Yuan, Zheshuai Lin, Maochun Hong, Junhua Luo

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  23. Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2

    Angewandte Chemie · 2016-11-30

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  24. Application of the dimensional reduction formalism to Pb 9−x Ba x [Li 2 (P 2 O 7 ) 2 (P 4 O 13 ) 2 ] (x = 0, 2, 6, 7): a series of phosphates with two types of isolated polyphosphate groups

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  25. Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups

    Chemical Communications · 2017-01-01

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  26. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response

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    Chao Wu, Longhua Li, Gang Yang, Jun‐Ling Song, Bing Yan, Mark Graeme Humphrey, Long Zhang, Jianda Shao, Chi Zhang

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  27. Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units

    New Journal of Chemistry · 2017-01-01

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  28. Theoretical investigation on the balance between large band gap and strong SHG response in BMO 4 (M = P and As) crystals

    RSC Advances · 2017-01-01

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  29. Two Phosphates: Noncentrosymmetric Cs6Mg6(PO3)18 and Centrosymmetric Cs2MgZn2(P2O7)2

    Inorganic Chemistry · 2017-01-03

    Yi-Gang Chen, Meiling Xing, Pengfei Liu, Yao Guo, Nan Qing Yang, Xian‐Ming Zhang

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  30. M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications

    Chemistry of Materials · 2017-01-30

    Hongwei Yu, Joshua Young, Hongping Wu, Weiguo Zhang, James M. Rondinelli, P. Shiv Halasyamani

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  31. Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth

    Angewandte Chemie International Edition · 2017-03-02

    Bingbing Zhang, Guoqiang Q. Shi, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  32. Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth

    Angewandte Chemie · 2017-03-02

    Bingbing Zhang, Guoqiang Q. Shi, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  33. A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures

    Inorganic Chemistry · 2017-03-15

    Maierhaba Abudoureheman, Shujuan Han, Ying Wang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  34. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

    Crystals · 2017-04-12

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  35. Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials

    Inorganic Chemistry · 2017-06-02

    Bing‐Ping Yang, Chun‐Li Hu, Fei‐Fei Mao, Xiang Xu, Jiang‐Gao Mao

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  36. Synthesis and characterization of a new beryllium-free deep-ultraviolet nonlinear optical material: Na2GdCO3F3

    Journal of Alloys and Compounds · 2017-07-12

    Ling Huang, Qian Wang, Chensheng Lin, Guohong Zou, Daojiang Gao, Jian Bi, Ning Ye

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  37. Linear-to-λ-Shape P–O–P Bond Transmutation in Polyphosphates with Infinite (PO3)∞ Chain

    Inorganic Chemistry · 2017-08-15

    Ying Wang, Lin Li, Shujuan Han, Bing‐Hua Lei, Maierhaba Abudoureheman, Zhihua Yang, Shilie Pan

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  38. Rational Design of Deep-Ultraviolet Nonlinear Optical Materials in Fluorooxoborates: Toward Optimal Planar Configuration

    Chemistry of Materials · 2017-08-18

    Fei Liang, Lei Kang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  39. The Power of Heterometalation through Lithium for Helix Chain-Based Noncentrosymmetric Metal–Organic Frameworks with Tunable Second-Harmonic Generation Effects

    Crystal Growth & Design · 2017-10-13

    Yongpeng Li, Xingxia Wang, Shu-Ni Li, Huaming Sun, Yu‐Cheng Jiang, Man‐Cheng Hu, Quan‐Guo Zhai

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  40. LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point

    Inorganic Chemistry · 2017-10-19

    Dajiang Mei, Shiyan Zhang, Fei Liang, Sangen Zhao, Jian‐Qiao Jiang, Junbo Zhong, Zheshuai Lin, Yuandong Wu

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  41. Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups

    Inorganic Chemistry Communications · 2017-11-07

    Yuan Fang, Zhaohui Chen, Yunjing Shi, Wenyao Zhang, Xiaoyu Dong

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  42. K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups

    Journal of Alloys and Compounds · 2017-11-16

    Qian Wang, Chensheng Lin, Guohong Zou, Mengjiao Liu, Daojiang Gao, Jian Bi, Ling Huang

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  43. An optoelectronic duple bistable phosphate with ultrahigh thermal stability

    Journal of Materials Chemistry C · 2017-11-23

    Yaoguo Shen, Sangen Zhao, Chenxi Wang, Zujian Wang, Jianghe Feng, Maochun Hong, Junhua Luo

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  44. A 36-Membered Ring Metal Chalcogenide with a Very Low Framework Density

    Inorganic Chemistry · 2017-11-27

    Wei Wang, Huajun Yang, Min Luo, Yeshuang Zhong, Dingguo Xu, Tao Wu, Zhien Lin

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  45. Crystal Growth and Optical Properties of Beryllium-Free Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F

    Crystal Growth & Design · 2017-12-28

    Bingqing Zhao, Lei Bai, Bingxuan Li, Sangen Zhao, Yaoguo Shen, Xianfeng Li, Qingran Ding, Chengmin Ji, Zheshuai Lin, Junhua Luo

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  46. A beryllium-free deep-UV nonlinear optical material CsNaMgP 2 O 7 with honeycomb-like topological layers

    Journal of Materials Chemistry C · 2018-01-01

    Sangen Zhao, Yi Jin Yang, Yaoguo Shen, Xiaodong Wang, Qingran Ding, Xianfeng Li, Yanqiang Li, Lina Li, Zheshuai Lin, Junhua Luo

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  47. Evaluating the component contribution to nonlinear optical performances using stable [Ni 4 O 4 ] cuboidal clusters as models

    Dalton Transactions · 2018-01-01

    Zhi-Min Hao, Meng‐Yao Chao, Yan Liu, Yinglin Song, Junyi Yang, Lifeng Ding, Wen‐Hua Zhang, Jian‐Ping Lang

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  48. First principle study of nonlinear optical crystals

    Acta Physica Sinica · 2018-01-01

    Fei Liang, Lin Zhe-Shuai, Yicheng Wu

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  49. K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure

    Dalton Transactions · 2018-01-01

    Ming Wen, Cong Hu, Zhihua Yang, Xiaohong Wu, Shilie Pan

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  50. Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholds

    Journal of Materials Chemistry C · 2018-01-01

    Zhihua Yang, Cong Hu, Miriding Mutailipu, Yanzhou Sun, Kui Wu, Min Zhang, Shilie Pan

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