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RESEARCH PAPER · Semiconductor Science and Technology · 2014

Topochemical reactions of layered transition-metal oxides

Michael A. Hayward

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Topochemical reactions of layered transition-metal oxidesOriginalCrystal and magnetic structures of the brownmillerite Ca 2 Cr 2 O 518Stabilization of cubic Sr 2 FeMoO 6 through topochemical reduction9Size dependence of structural, magnetic, and electrical properties in corundum-type Ti2O3 nanoparticles showing insulator–metal transition31Topochemical Oxidation of Perovskite KCoF3 to a K2PtCl6 Structure-Type Oxyfluoride10Towards new materials by hierarchical topotactic syntheses1Creation of near-infrared luminescent phosphors enabled by topotactic reduction of bismuth-activated red-emitting crystals31La2SrCr2O7F2: A Ruddlesden–Popper Oxyfluoride Containing Octahedrally Coordinated Cr4+ Centers35Unconventional Luminescent Centers in Metastable Phases Created by Topochemical Reduction Reactions34Unconventional Luminescent Centers in Metastable Phases Created by Topochemical Reduction Reactions7Hard–soft chemistry of Sr 1−x Ca x CrO 3–δ solid solutions5Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior57Topochemical Approach for Transition-Metal Exchange Assisted by Copper Extrusion: from Cu2FeBO5 to Fe3BO510Topotactic Reduction toward a Noncentrosymmetric Deficient Perovskite Tb0.50Ca0.50Mn0.96O2.37 with Ordered Mn Vacancies and Piezoelectric Behavior8Developing intercalation based anode materials for fluoride-ion batteries: topochemical reduction of Sr 2 TiO 3 F 2 via a hydride based defluorination process42Small-moment paramagnetism and extensive twinning in the topochemically reduced phase Sr 2 ReLiO 5.51Soft chemistry of ion-exchangeable layered metal oxides183Multiferroism in Iron-Based Oxyfluoride Perovskites20Hydride Reduction of BaTiO3 − Oxyhydride Versus O Vacancy Formation35Composés inorganiques innovants par manipulation et diversification du sous-réseau anionique0Topotactic Ion Exchange in a Three-Dimensional Close-Packed Trirutile Structure with an Octahedral Network8Complex structural ordering of the oxygen deficiency in La0.5Ca2.5Mn2O7−δRuddlesden–Popper phases0Trigonal-Planar Low-Spin Co2+ in a Layered Mixed-Polyhedral Network from Topotactic Reduction7Trapping of different stages of BaTiO 3 reduction with LiH12On Prediction of a Novel Chiral Material Y2H3O(OH): A Hydroxyhydride Holding Hydridic and Protonic Hydrogens4Raman Spectroscopy of Iron-Oxide Core-Corona Nanoparticles: Effect of Synthesis Temperature8Topochemical synthesis of perovskite-type CuNb 2 O 6 with colossal dielectric constant6Tri-α-PbO2-Type Fe–Sb Tungstate by Topotactic Ion Exchange of LiSbWO66Barium Titanium Oxynitride from Ammonia-Free Nitridation of Reduced BaTiO38Hole and Electron Doping of Topochemically Reduced Ni(I)/Ru(II) Insulating Ferromagnetic Oxides12The Formation of Metal–Oxide Heterostructures at Low-Temperature Oxidation of Alloys Based on the Fe–18Cr System7Unintended consequence of topochemical reduction of SrFeO3 to SrFeO2 : Design of infinite layered oxides6Renaissance of Topotactic Ion‐Exchange for Functional Solids with Close Packed Structures18Hydrogen Atom Doping—A Versatile Method for Modulated Interface Resistive Switching7Topochemical Synthesis of Ca3CrN3H Involving a Rotational Structural Transformation for Catalytic Ammonia Synthesis32Topochemical Synthesis of Ca3CrN3H Involving a Rotational Structural Transformation for Catalytic Ammonia Synthesis5Electrostatic gating and intercalation in 2D materials226Topotactic Transition: A Promising Opportunity for Creating New Oxides44Nickelate superconductors get ‘hotter’3Evidence of filamentary superconductivity in pressurized La3Ni2O7-delta single crystals3Selective Synthesis of Defect-Rich LaMnO3 by Low-Temperature Anion Cometathesis7Topological Conversion of Nickel Foams to Monolithic Single‐Atom Catalysts24Valence-Ordered Thin-Film Nickelate with Tri-component Nickel Coordination Prepared by Topochemical Reduction10Simple to Quadruple Perovskite Transformation by Coordination Switching upon Solid-State Ion Exchange of NaNbO33Competition between Anion-Deficient Oxide and Oxyhydride Phases during the Topochemical Reduction of LaSrCoRuO64Reviewing the dynamic modeling aspects of chemical looping hydrogen production17Absence of hydrogen insertion into highly crystalline superconducting infinite layer nickelates14New Mn and V-rich Phosphate Fluoride Obtained by Topochemical Reaction for Na-ion Batteries Positive Electrode4La2O2MQ2 phases: Stability and synthetic challenges0Exploring the electronic and structural properties of tantalates and infinite-layer nickelates via electron microscopy and x-ray spectroscopy approaches0Covalent Stabilization of the Iridium-Containing Oxyhydrides Sr2Mn0.5Ir0.5O3.25H0.75 and Sr2Mn0.5Ir0.5O2.66H1.334Structure and magnetism of La x Sr 2− x Co 0.5 Ir 0.5 O 4− y H y (0 < x < 1) iridium-containing oxyhydride phases2Investigations of key issues on the reproducibility of high-T c superconductivity emerging from compressed La3Ni2O783Octahedral Rotation Change in the Ruddlesden–Popper Compound Gd3Ba2Fe4O12.5 by Topotactically Introduced Oxide Ions0Mesoporous titanium niobate nanosheets with oxygen defects via topology reduction enhancing efficient lithium storage6Changes in the crystal structure of layered perovskite compounds A3B2O9 (A = Ba, Sr; B = W, Re)1Enhanced superconductivity and mixed-dimensional behaviour in infinite-layer samarium nickelate thin films4Reduction Pathway and Temperature-Dependent Decomposition of Epitaxial BiFeO3 Thin Films Under CaH2 Treatment0

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  1. Crystal and magnetic structures of the brownmillerite Ca 2 Cr 2 O 5

    Dalton Transactions · 2015-01-01

    Ángel M. Arévalo‐López, John Paul Attfield

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  2. Stabilization of cubic Sr 2 FeMoO 6 through topochemical reduction

    Chemical Communications · 2015-01-01

    Daniel D. Taylor, Nathaniel J. Schreiber, Craig M. Brown, Ángel M. Arévalo‐López, Efrain E. Rodriguez

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  3. Size dependence of structural, magnetic, and electrical properties in corundum-type Ti2O3 nanoparticles showing insulator–metal transition

    Journal of Asian Ceramic Societies · 2015-07-17

    Yoshihiro Tsujimoto, Yoshitaka Matsushita, Shan Yu, Kazunari Yamaura, Tetsuo Uchikoshi

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  4. Topochemical Oxidation of Perovskite KCoF3 to a K2PtCl6 Structure-Type Oxyfluoride

    Inorganic Chemistry · 2015-10-19

    R. Nagarajan, Shahzad Ahmad, Poonam Singh

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  5. Towards new materials by hierarchical topotactic syntheses

    Unknown journal · 2015-11-13

    Ignacio Blazquez Alcover

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  6. Creation of near-infrared luminescent phosphors enabled by topotactic reduction of bismuth-activated red-emitting crystals

    Journal of Materials Chemistry C · 2016-01-01

    Bo-Mei Liu, Zi-Jun Yong, Yang Zhou, Dan-Dan Zhou, Lirong Zheng, Li-Na Li, Hui-Mei Yu, Hong-Tao Sun

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  7. La2SrCr2O7F2: A Ruddlesden–Popper Oxyfluoride Containing Octahedrally Coordinated Cr4+ Centers

    Inorganic Chemistry · 2016-03-09

    Ronghuan Zhang, Gareth Read, Franz Lang, Tom Lancaster, Stephen J. Blundell, Michael A. Hayward

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  8. Unconventional Luminescent Centers in Metastable Phases Created by Topochemical Reduction Reactions

    Angewandte Chemie International Edition · 2016-03-11

    Bo‐Mei Liu, Zhigang Zhang, Kai Zhang, Yoshihiro Kuroiwa, Chikako Moriyoshi, Huimei Yu, Chao Li, Lirong Zheng, Lina Li, Guang Yang, Yang Zhou, Yongzheng Fang, Jingshan Hou, Yoshitaka Matsushita, Hong‐Tao Sun

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  9. Unconventional Luminescent Centers in Metastable Phases Created by Topochemical Reduction Reactions

    Angewandte Chemie · 2016-03-11

    Bo‐Mei Liu, Zhigang Zhang, Kai Zhang, Yoshihiro Kuroiwa, Chikako Moriyoshi, Huimei Yu, Chao Li, Lirong Zheng, Lina Li, Guang Yang, Yang Zhou, Yongzheng Fang, Jingshan Hou, Yoshitaka Matsushita, Hong‐Tao Sun

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  10. Hard–soft chemistry of Sr 1−x Ca x CrO 3–δ solid solutions

    Materials Chemistry Frontiers · 2016-09-30

    Ángel M. Arévalo‐López, Alagar K. Srinath, John Paul Attfield

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  11. Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior

    Chemistry of Materials · 2016-10-28

    Ronghuan Zhang, Mark S. Senn, Michael A. Hayward

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  12. Topochemical Approach for Transition-Metal Exchange Assisted by Copper Extrusion: from Cu2FeBO5 to Fe3BO5

    Inorganic Chemistry · 2017-02-17

    C. Martin, Antoine Maignan, Anne Guesdon, Fabien Laine, Oleg I. Lebedev

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  13. Topotactic Reduction toward a Noncentrosymmetric Deficient Perovskite Tb0.50Ca0.50Mn0.96O2.37 with Ordered Mn Vacancies and Piezoelectric Behavior

    Chemistry of Materials · 2017-10-30

    Hao Zhang, Song Wei Gao, Qinghua Zhang, Jingen Wu, Jie Liang, Cheng Dong, Lin Gu, Shuxiang Dong, Junliang Sun, Fuhui Liao, Jianhua Lin, Ruqiang Zou, Guobao Li

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  14. Developing intercalation based anode materials for fluoride-ion batteries: topochemical reduction of Sr 2 TiO 3 F 2 via a hydride based defluorination process

    Journal of Materials Chemistry A · 2018-01-01

    Kerstin Wissel, Supratik Dasgupta, Alexander Benes, Roland Schoch, Matthias Bauer, Ralf Witte, Andrew Dominic Fortes, Emre Erdem, Jochen Rohrer, Oliver Clemens

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  15. Small-moment paramagnetism and extensive twinning in the topochemically reduced phase Sr 2 ReLiO 5.5

    Dalton Transactions · 2018-01-01

    Nijat Hasanli, Nicolas Gauquelin, Johan Verbeeck, Joke Hadermann, Michael A. Hayward

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  16. Soft chemistry of ion-exchangeable layered metal oxides

    Chemical Society Reviews · 2018-01-01

    Ritesh Uppuluri, Arnab Sen Gupta, Alyssa S. Rosas, Thomas E. Mallouk

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  17. Multiferroism in Iron-Based Oxyfluoride Perovskites

    Inorganic Chemistry · 2018-08-14

    Steven Hartman, Sung June Cho, Rohan Mishra

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  18. Hydride Reduction of BaTiO3 − Oxyhydride Versus O Vacancy Formation

    ACS Omega · 2018-09-19

    Reji Nedumkandathil, Aleksander Jaworski, Jêkabs Grîns, Diana Bernin, Maths Karlsson, Carin Eklöf-Österberg, Alexandra Maria Neagu, Cheuk‐Wai Tai, Andrew J. Pell, Ulrich Häußermann

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  19. Composés inorganiques innovants par manipulation et diversification du sous-réseau anionique

    Unknown journal · 2018-12-14

    Sarah Nicoud

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  20. Topotactic Ion Exchange in a Three-Dimensional Close-Packed Trirutile Structure with an Octahedral Network

    Inorganic Chemistry · 2019-02-20

    Vandana Meena, Tapas Kumar Mandal

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  21. Complex structural ordering of the oxygen deficiency in La0.5Ca2.5Mn2O7−δRuddlesden–Popper phases

    Acta Crystallographica Section A Foundations and Advances · 2019-06-26

    Daniel González‐Merchante, Raquel Cortés‐Gil, José M. Alonso, Emilio Matesanz, José Luis Martínez, A. Rivera, Jacobo Santamaria, M. Luisa Ruiz‐González, José María González-Calbet

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  22. Trigonal-Planar Low-Spin Co2+ in a Layered Mixed-Polyhedral Network from Topotactic Reduction

    Inorganic Chemistry · 2019-10-04

    Lijia Zhou, Yifeng Han, Congling Yin, Yanhui Wang, Xiaoyan Yang, Mathieu M. B. Allix, Qingzhen Huang, Jin Xiong, Bing‐Wu Wang, Guobao Li, Xiaojun Kuang, Xianran Xing

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  23. Trapping of different stages of BaTiO 3 reduction with LiH

    RSC Advances · 2020-01-01

    Hua Guo, Aleksander Jaworski, Zili Ma, Adam Slabon, Zoltán Bacsik, Reji Nedumkandathil, Ulrich Häußermann

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  24. On Prediction of a Novel Chiral Material Y2H3O(OH): A Hydroxyhydride Holding Hydridic and Protonic Hydrogens

    Materials · 2020-02-22

    Aleksandr Pishtshev, Evgenii Strugovshchikov, Smagul Zh. Karazhanov

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  25. Raman Spectroscopy of Iron-Oxide Core-Corona Nanoparticles: Effect of Synthesis Temperature

    Protection of Metals and Physical Chemistry of Surfaces · 2020-11-01

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  26. Topochemical synthesis of perovskite-type CuNb 2 O 6 with colossal dielectric constant

    Journal of Materials Chemistry C · 2021-01-01

    Masayuki Fukuda, Ikuya Yamada, Hajime Hojo, Chihiro Takahashi, Yuya Yoshida, Katsuhisa Tanaka, Masaki Azuma, Koji Fujita

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  27. Tri-α-PbO2-Type Fe–Sb Tungstate by Topotactic Ion Exchange of LiSbWO6

    ACS Applied Electronic Materials · 2021-05-26

    Vandana Meena, Jaideep Malik, Tapas Kumar Mandal

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  28. Barium Titanium Oxynitride from Ammonia-Free Nitridation of Reduced BaTiO3

    Inorganics · 2021-08-05

    Hua Guo, Aleksander Jaworski, Zheng Chen, Can Lu, Adam Slabon, Ulrich Häußermann

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  29. Hole and Electron Doping of Topochemically Reduced Ni(I)/Ru(II) Insulating Ferromagnetic Oxides

    Inorganic Chemistry · 2021-09-13

    Zheying Xu, Lun Jin, Julius-Konstantin Backhaus, Felicity Green, Michael A. Hayward

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  30. The Formation of Metal–Oxide Heterostructures at Low-Temperature Oxidation of Alloys Based on the Fe–18Cr System

    Protection of Metals and Physical Chemistry of Surfaces · 2021-11-01

    Vladimir A. Kotenev

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  31. Unintended consequence of topochemical reduction of SrFeO3 to SrFeO2 : Design of infinite layered oxides

    Physical Review Materials · 2021-12-29

    Timothy Ferreira, Shree Ram Acharya, Ying Wai Li, David Parker, Athena S. Sefat, Valentino R. Cooper

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  32. Renaissance of Topotactic Ion‐Exchange for Functional Solids with Close Packed Structures

    Chemistry - A European Journal · 2022-04-07

    Eric A. Gabilondo, Shaun O’Donnell, Ryan J. Newell, Rachel Broughton, Marcelo Mateus, Jacob L. Jones, Paul A. Maggard

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  33. Hydrogen Atom Doping—A Versatile Method for Modulated Interface Resistive Switching

    Advanced Electronic Materials · 2022-06-25

    Srinivas Vanka, Hyungki Shin, B. A. Davidson, Chong Liu, Ke Zou

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  34. Topochemical Synthesis of Ca3CrN3H Involving a Rotational Structural Transformation for Catalytic Ammonia Synthesis

    Angewandte Chemie International Edition · 2022-08-05

    Yu Cao, Maria A. Kirsanova, Masayuki Ochi, Walid Al Maksoud, Tong Zhu, Rohit Kumar Rai, Shenghan Gao, Tatsuya Tsumori, Shintaro Kobayashi, Shogo Kawaguchi, Edy Abou‐Hamad, Kazuhiko Kuroki, Cédric Tassel, Artem M. Abakumov, Yoji Kobayashi, Hiroshi Kageyama

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  35. Topochemical Synthesis of Ca3CrN3H Involving a Rotational Structural Transformation for Catalytic Ammonia Synthesis

    Angewandte Chemie · 2022-08-05

    Yu Cao, Maria A. Kirsanova, Masayuki Ochi, Walid Al Maksoud, Tong Zhu, Rohit Kumar Rai, Shenghan Gao, Tatsuya Tsumori, Shintaro Kobayashi, Shogo Kawaguchi, Edy Abou‐Hamad, Kazuhiko Kuroki, Cédric Tassel, Artem M. Abakumov, Yoji Kobayashi, Hiroshi Kageyama

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  36. Electrostatic gating and intercalation in 2D materials

    Nature Reviews Materials · 2022-08-31

    Yecun Wu, Danfeng Li, Chun-Lan Wu, Harold Y. Hwang, Yi Ping Cui

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  37. Topotactic Transition: A Promising Opportunity for Creating New Oxides

    Advanced Functional Materials · 2023-06-15

    Ziang Meng, Han Yan, Peixin Qin, Xiaorong Zhou, Xiaoning Wang, Hongyu Chen, Li Liu, Zhiqi Liu

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  38. Nickelate superconductors get ‘hotter’

    Science China Materials · 2023-08-03

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  39. Evidence of filamentary superconductivity in pressurized La3Ni2O7-delta single crystals

    Research Square · 2023-11-30

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  40. Selective Synthesis of Defect-Rich LaMnO3 by Low-Temperature Anion Cometathesis

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  41. Topological Conversion of Nickel Foams to Monolithic Single‐Atom Catalysts

    Advanced Functional Materials · 2024-01-04

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  42. Valence-Ordered Thin-Film Nickelate with Tri-component Nickel Coordination Prepared by Topochemical Reduction

    ACS Nano · 2024-01-25

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  43. Simple to Quadruple Perovskite Transformation by Coordination Switching upon Solid-State Ion Exchange of NaNbO3

    Inorganic Chemistry · 2024-03-24

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  44. Competition between Anion-Deficient Oxide and Oxyhydride Phases during the Topochemical Reduction of LaSrCoRuO6

    Inorganic Chemistry · 2024-06-28

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  45. Reviewing the dynamic modeling aspects of chemical looping hydrogen production

    International Journal of Hydrogen Energy · 2024-08-08

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  46. Absence of hydrogen insertion into highly crystalline superconducting infinite layer nickelates

    Physical Review Materials · 2024-08-12

    M. Gonzalez, Anton V. Ievlev, Kyuho Lee, W. Kim, Yijun Yu, Jennifer Fowlie, Harold Y. Hwang

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  47. New Mn and V-rich Phosphate Fluoride Obtained by Topochemical Reaction for Na-ion Batteries Positive Electrode

    Chemistry of Materials · 2024-10-04

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  48. La2O2MQ2 phases: Stability and synthetic challenges

    Solid State Sciences · 2024-10-09

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  49. Exploring the electronic and structural properties of tantalates and infinite-layer nickelates via electron microscopy and x-ray spectroscopy approaches

    Unknown journal · 2024-10-22

    Aravind Raji

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  50. Covalent Stabilization of the Iridium-Containing Oxyhydrides Sr2Mn0.5Ir0.5O3.25H0.75 and Sr2Mn0.5Ir0.5O2.66H1.33

    Inorganic Chemistry · 2024-11-05

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