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RESEARCH PAPER · Chemistry - A European Journal · 2022

Renaissance of Topotactic Ion‐Exchange for Functional Solids with Close Packed Structures

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Renaissance of Topotactic Ion‐Exchange for Functional Solids with Close Packed StructuresOriginalCircumventing thermodynamics to synthesize highly metastable perovskites: nano eggshells of SnHfO 36Kinetic Stabilization of the First Sn(II)-Perovskite Oxide as a Nanoshell0Prediction and Kinetic Stabilization of Sn(II)-Perovskite Oxide Nanoshells8Pulsed laser deposition of β-NaGaO2: significant dependence of sodium fraction, morphology, and phases of the film on deposition position in the plume2Synthesis and Structure of an Ion‐Exchanged SrTiO3 Photocatalyst with Improved Reactivity for Hydrogen Evolution9Switching Lead for Tin in PbHfO3: Noncubic Structure of SnHfO3**1Switching Lead for Tin in PbHfO3: Noncubic Structure of SnHfO3**5Cation exchange route to a Eu(II)-containing tantalum oxide1Solid-State Synthesis of Niobium Carbide Electrocatalyst in the Presence of Vanadium as Suppressor of Energy Input and Greenhouse Gas Emission3Designing Topotactic Ion-Exchange Reactions in Solid-State Oxides Through First-Principles Calculations4Synthesis and large crystal growth of a family of mixed-anionic methanesulfonate salts by anionic site-substitution: Na 5 (SO 3 CH 3 ) 4 (X) (X = BF 4 − , ClO 4 − , PF 6 − , I − )9Unconventional and Powerful Ion Sources for Solid-State Ion Exchange, Cu2SO4 and Cu3PO4: Exemplified by the Synthesis of Metastable β-CuGaO2 from Stable β-LiGaO21Ion Exchange Synthesizes a Metastable Layered Polymorph of MgZrN2 and MgHfN2 Semiconductors2Influence of Al‐doped SrTiO 3 cores on hydrogen evolution from SrTiO 3 /TiO 2 core‒shell catalysts3Nonreciprocal Charge Transport in an Iron‐Based Superconductor with Broken Inversion Symmetry Engineered by a Hydrogen‐Concentration Gradient0A Synthetic Perspective of Strategies for Accessing Metastable Polymorphs: Lessons Learned from Hafnium(IV) Oxide0Metastable Inorganic Materials through Reactive Molten-Salt Ion Exchange0

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  1. Circumventing thermodynamics to synthesize highly metastable perovskites: nano eggshells of SnHfO 3

    Nanoscale Advances · 2022-01-01

    Eric A. Gabilondo, Ryan J. Newell, Jessica Chestnut, James Weng, Jacob L. Jones, Paul A. Maggard

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  2. Kinetic Stabilization of the First Sn(II)-Perovskite Oxide as a Nanoshell

    ChemRxiv · 2022-07-18

    Shaun O’Donnell, David J. Osborn, Gowri Krishnan, Theresa Block, Aylin Koldemir, Thomas D. Small, Rachel Broughton, Jacob L. Jones, Rainer Pöttgen, Gunther G. Andersson, Gregory F. Metha, Paul A. Maggard

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  3. Prediction and Kinetic Stabilization of Sn(II)-Perovskite Oxide Nanoshells

    Chemistry of Materials · 2022-08-30

    Shaun O’Donnell, David J. Osborn, Gowri Krishnan, Theresa Block, Aylin Koldemir, Thomas D. Small, Rachel Broughton, Jacob L. Jones, Rainer Pöttgen, Gunther G. Andersson, Gregory F. Metha, Paul A. Maggard

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  4. Pulsed laser deposition of β-NaGaO2: significant dependence of sodium fraction, morphology, and phases of the film on deposition position in the plume

    Japanese Journal of Applied Physics · 2023-02-14

    Shunichi Suzuki, Issei Suzuki, Takahisa Omata

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  5. Synthesis and Structure of an Ion‐Exchanged SrTiO3 Photocatalyst with Improved Reactivity for Hydrogen Evolution

    Advanced Materials Interfaces · 2023-03-03

    Mingyi Zhang, Eric M. Lopato, Nnamdi N. Ene, Stephen D. Funni, Tianxiang Du, Kunyao Jiang, Stefan Bernhard, Paul A. Salvador, Gregory S. Rohrer

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  6. Switching Lead for Tin in PbHfO3: Noncubic Structure of SnHfO3**

    Angewandte Chemie · 2023-09-12

    Eric A. Gabilondo, Ryan J. Newell, Rachel Broughton, Aylin Koldemir, Rainer Pöttgen, Jacob L. Jones, Paul A. Maggard

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  7. Switching Lead for Tin in PbHfO3: Noncubic Structure of SnHfO3**

    Angewandte Chemie International Edition · 2023-09-12

    Eric A. Gabilondo, Ryan J. Newell, Rachel Broughton, Aylin Koldemir, Rainer Pöttgen, Jacob L. Jones, Paul A. Maggard

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  8. Cation exchange route to a Eu(II)-containing tantalum oxide

    Journal of Solid State Chemistry · 2023-09-20

    Shaun O’Donnell, Eric A. Gabilondo, Subhendu Jana, Aylin Koldemir, Theresa Block, Myung‐Hwan Whangbo, Reinhard Karl Kremer, Rainer Pöttgen, Paul A. Maggard

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  9. Solid-State Synthesis of Niobium Carbide Electrocatalyst in the Presence of Vanadium as Suppressor of Energy Input and Greenhouse Gas Emission

    ACS Omega · 2024-01-31

    K. Saito, Takahiro Jinushi, Itsuki Soga

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  10. Designing Topotactic Ion-Exchange Reactions in Solid-State Oxides Through First-Principles Calculations

    Chemistry of Materials · 2024-04-17

    Issei Suzuki, Masao Kita, Takahisa Omata

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  11. Synthesis and large crystal growth of a family of mixed-anionic methanesulfonate salts by anionic site-substitution: Na 5 (SO 3 CH 3 ) 4 (X) (X = BF 4 − , ClO 4 − , PF 6 − , I − )

    Dalton Transactions · 2025-01-01

    Eric A. Gabilondo, P. Shiv Halasyamani

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  12. Unconventional and Powerful Ion Sources for Solid-State Ion Exchange, Cu2SO4 and Cu3PO4: Exemplified by the Synthesis of Metastable β-CuGaO2 from Stable β-LiGaO2

    Inorganic Chemistry · 2025-01-27

    Issei Suzuki, Kako Washizu, Daiki Motai, Masao Kita, Takahisa Omata

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  13. Ion Exchange Synthesizes a Metastable Layered Polymorph of MgZrN2 and MgHfN2 Semiconductors

    Chemistry of Materials · 2025-03-03

    Christopher L. Rom, Matthew Jankousky, Maxwell Q. Phan, Shaun O’Donnell, Corlyn E. Regier, James Richmond Neilson, Vladan Stevanović, Andriy Zakutayev

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  14. Influence of Al‐doped SrTiO 3 cores on hydrogen evolution from SrTiO 3 /TiO 2 core‒shell catalysts

    Journal of the American Ceramic Society · 2025-04-04

    Wenjia Song, Paul A. Salvador, Gregory S. Rohrer

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  15. Nonreciprocal Charge Transport in an Iron‐Based Superconductor with Broken Inversion Symmetry Engineered by a Hydrogen‐Concentration Gradient

    Advanced Science · 2026-02-15

    Takayuki Nagai, Yukito Nishio, Jumpei Matsumoto, Kota Hanzawa, Hidenori Hiramatsu, Hideo Hosono, Tsuyoshi Kimura

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  16. A Synthetic Perspective of Strategies for Accessing Metastable Polymorphs: Lessons Learned from Hafnium(IV) Oxide

    ACS Materials Letters · 2026-08-04

    S. Chakraborty, James Pérez-Vázquez, Guan-Wen Liu, Sarbajit Banerjee

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  17. Metastable Inorganic Materials through Reactive Molten-Salt Ion Exchange

    Chemistry of Materials · 2026-10-13

    Sarah L. Ko, Arne Sjöblom, Kent J. Griffith

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