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RESEARCH PAPER · Chemical Society Reviews · 2018

Soft chemistry of ion-exchangeable layered metal oxides

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Soft chemistry of ion-exchangeable layered metal oxidesOriginalLayered gadolinium hydroxides for simultaneous drug delivery and imaging44Microwave-assisted functionalization of the Aurivillius phase Bi 2 SrTa 2 O 9 : diol grafting and amine insertion vs. alcohol grafting16Expanding the I–II–V Phase Space: Soft Synthesis of Polytypic Ternary and Binary Zinc Antimonides28Two-Dimensional Metal Oxide Nanosheets as Building Blocks for Artificial Photosynthetic Assemblies192Tuning the organization of the interlayer organic moiety in a hybrid layered perovskite5K‐Birnessite Electrode Obtained by Ion Exchange for Potassium‐Ion Batteries: Insight into the Concerted Ionic Diffusion and K Storage Mechanism104Morphology controlled synthesis of low bandgap SnSe 2 with high photodetectivity45Synthesis, Characterization and Photocatalytic Activity of Nanocrystalline First Transition-Metal (Ti, Mn, Co, Ni and Zn) Oxisde Nanofibers by Electrospinning18Gamma-Bi 4 V 2 O 11 – a layered oxide material for ion exchange in aqueous media11Thickness biased capture of CO 2 on carbide MXenes69Оптические свойства нестехиометрического оксида кремния SiO-=SUB=-x-=/SUB=- (x<2)0Topotactic Ion Exchange in a Three-Dimensional Close-Packed Trirutile Structure with an Octahedral Network8Crumpled carbon nanonets derived from anthracene oil for high energy density supercapacitor51Formation of Mixed‐Metal Ceria Nanopeapod Composites within Scrolled Hexaniobate Nanosheets6Reconfigurable lateral anionic heterostructures in oxide thin films via lithographically defined topochemistry13Two-dimensional Acetate-based Light Lanthanide Fluoride Nanomaterials (F–Ln, Ln = La, Ce, Pr, and Nd): Morphology, Structure, Growth Mechanism, and Stability29Soft Chemical Synthesis of H x CrS 2 : An Antiferromagnetic Material with Alternating Amorphous and Crystalline Layers43Ultrathin WO3 Nanosheets Converted from Metallic WS2 Sheets by Spontaneous Formation and Deposition of PdO Nanoclusters for Visible Light-Driven C–C Coupling Reactions37Thermal Stability and Spectroscopic Assessment of Brönsted Sites in Solid Acid-Layered Niobates7Optical Properties of Nonstoichiometric Silicon Oxide SiOx (x < 2)8Synthesis and thermal stability of new inorganic-organic perovskite-like hybrids based on layered titanates HLnTiO4 (Ln = La, Nd)28In Situ Compositing CsPbBr3 with Exfoliated Layered-Perovskite CsCa2Ta3O10: Interfacial Interaction and Enhanced Stability12Synthesis, structure and optical properties of layered M4Nb6O17⋅nH2O (M = K, Rb, Cs) hexaniobates9Ultra-tough and highly ordered macroscopic fiber assembly from 2D functional metal oxide nanosheet liquid crystals and strong ionic interlayer bridging7Visible-light-driven HSr2Nb3O10/CdS heterojunctions for high hydrogen evolution activity19The versatile biomedical applications of bismuth-based nanoparticles and composites: therapeutic, diagnostic, biosensing, and regenerative properties523There's no place like real-space: elucidating size-dependent atomic structure of nanomaterials using pair distribution function analysis149Topochemical synthesis of low-dimensional nanomaterials11Yb 3+ /Er 3+ co-doped Dion–Jacobson niobium layered perovskites as NIR-to-green upconversion materials6Topochemical synthesis of two-dimensional molybdenum carbide (Mo2C) via Na2CO3-Assited carbothermal reduction of 2H–MoS213Plasma Generating—Chemical Looping Catalyst Synthesis by Microwave Plasma Shock for Nitrogen Fixation from Air and Hydrogen Production from Water for Agriculture and Energy Technologies in Global Warming Prevention31Synthesis and thermal stability studies of mixed A-site Dion-Jacobson triple-layered perovskites,A′LaNaNb3O10 (A′ = H, Li, Na, K, Rb, CuCl)6On Prediction of a Novel Chiral Material Y2H3O(OH): A Hydroxyhydride Holding Hydridic and Protonic Hydrogens4Structurally Ordered Catalyst-Amplified Chemiluminescence Signals37DALDIRMALI KAPLAMA SİSTEMİ İLE 2B MALZEMELERİN KAPLANMASI0Synthesis of Organic–Inorganic Hybrids Based on Perovskite-like Bismuth Titanate H2K0.5Bi2.5Ti4O13·H2O and n -Alkylamines11An Artificial Z-Scheme Constructed from Dye-Sensitized Metal Oxide Nanosheets for Visible Light-Driven Overall Water Splitting148Preparation of Porous Particles of Layered Perovskite-Like Titanate HLaTiO49Synergistic Influence of d0 (Nb5+) and d10 (Cd2+) Cations in Stabilizing Noncentrosymmetric Dion–Jacobson Layered Perovskites, A′Cd2Nb3O10 (A′ = Rb, Cs)12Dual-functional Janus Nanosheets with Cation Exchangeability and Thermo-responsiveness Prepared via Regioselective Modification of K4Nb6O17·3H2O4Specific Structure and Properties of Composite Membranes Based on the Torlon® (Polyamide-imide)/Layered Perovskite Oxide9Grafting reactions of perovskite-like bismuth titanate H2K0.5Bi2.5Ti4O13·H2O with n-alcohols3Light-Induced In Situ Oxidative Coupling Mediated by Triplet State Reactive Oxygen into Nanostructured Hexaniobate Photocatalyst0Design of new electrode materials by Soft Chemistry for multivalent ion batteries0Two-Dimensional Molecular Sheets of Transition Metal Oxides toward Wearable Energy Storage34Hydronium Ions Stabilized in a Titanate-Layered Structure with High Ionic Conductivity: Application to Aqueous Proton Batteries37Microwave-mechanochemistry-assisted synthesis of Z-scheme HSr2Nb3O10/WO3 heterojunctions for improved simulated sunlight driven photocatalytic activity11Fast Proton Insertion in Layered H2W2O7 via Selective Etching of an Aurivillius Phase33WO 3 Rich in Oxygen Vacancies Through Ion‐Exchange Reaction for Enhanced Electrocatalytic N 2 Reduction to NH 319Constructing perovskite-like oxide CsCa2Ta3O10: Yb, Er@Cs(PbxMn1-x)(ClyBr1-y)3 perovskite halide composites for five-dimensional anti-counterfeiting barcodes applications33Ce( iv )-centered charge-neutral perovskite layers topochemically derived from anionic [CeTa 2 O 7 ] − layers9Defect engineering of oxide perovskites for catalysis and energy storage: synthesis of chemistry and materials science337Honeycomb layered oxides: structure, energy storage, transport, topology and relevant insights94Intercalation–exfoliation processes during ionic exchange reactions from sodium lepidocrocite-type titanate toward a proton-based trititanate structure4Layered terbium hydroxides for simultaneous drug delivery and imaging18Low-temperature topotactic oxidation using the solid-state oxidant Zr-doped CeO 22Migration of cations in layered oxides for creating a highly active interface toward CO preferential oxidation36Selective kinetic growth and role of local coordination in forming Al 2 TiO 5 -based coatings at lower temperatures8Soft chemistry of metastable metal chalcogenide nanomaterials67Stepping toward the carbon circular economy (CCE): Integration of solar chemistry and biosystems for an effective CO2 conversion into added value chemicals and fuels13Structural and Electronic Properties of Metal Oxides and Their Applications in Solar Cells15Synthesis of Materials by Ion Exchange Process: A Mild Yet Very Versatile Tool2Topochemical synthesis of perovskite-type CuNb 2 O 6 with colossal dielectric constant6Analysis of Solid-State Reaction Mechanisms with Two-Dimensional Fourier Transform Infrared Correlation Spectroscopy11The properties and prospects of chemically exfoliated nanosheets for quantum materials in two dimensions25Topochemical Deintercalation of Li from Layered LiNiB: toward 2D MBene81Cs absorption capacity and selectivity of crystalline and amorphous Hf and Zr phosphates7Kinetic 2D Crystals via Topochemical Approach29Nanostructured covalent organic frameworks with elevated crystallization for (electro)photocatalysis and energy storage devices10Ultrathin 2D-oxides: A perspective on fabrication, structure, defect, transport, electron, and phonon properties26Exfoliation of Methylamine and n-Butylamine Derivatives of Layered Perovskite-Like Oxides HLnTiO4 and H2Ln2Ti3O10 (Ln = La, Nd) into Nanolayers11Protonated Forms of Layered Perovskite-Like Titanate NaNdTiO4: Neutron and X-ray Diffraction Structural Analysis8Synthesis of n-Alkoxy Derivatives of Layered Perovskite-Like Niobate HCa2Nb3O10 and Study of Their Photocatalytic Activity for Hydrogen Production from an Aqueous Solution of Methanol26Capturing Metastable Oxide Semiconductors for Applications in Solar Energy Conversion44Synthesis of cubic silver titanium oxide with a spinel-based structure7Fast and efficient shear-force assisted production of covalently functionalized oxide nanosheets6Environmental aspects of planarization processes6Kinetics and Evolution of Magnetism in Soft-Chemical Synthesis of CrSe 2 from KCrSe 227Structural and Compositional Characteristics of Ball-Milled Lepidocrocite Alkali Titanate and the Correlation to Its Surface Acidic–Basic Properties11Photocatalytic Activity of n-Alkylamine and n-Alkoxy Derivatives of Layered Perovskite-like Titanates H2Ln2Ti3O10 (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol22Atomically Thin Materials for Next-Generation Rechargeable Batteries169Combined Role of Biaxial Strain and Nonstoichiometry for the Electronic, Magnetic, and Redox Properties of Lithiated Metal-Oxide Films: The LiMn2O4 Case6Interlayer alkali ion governs robustness, reactivity, and dielectric properties of sintered lepidocrocite titanate8Vanadium oxides obtained by chimie douce reactions: The influences of transition metal species on crystal structures and electrochemical behaviors in zinc–ion batteries26Accessibility in Liquid Media: Cyclodehydration of Hexane‐2,5‐Diol for the Evaluation of Layered Catalysts2Inorganic-organic derivatives of layered perovskite-like titanates HLnTiO4 (Ln = La, Nd) with n-amines and n-alcohols: Synthesis, thermal, vacuum and hydrolytic stability9Post-synthetic particle size reduction of a layered cesium titanate (Cs2Ti5O11) for the improvement of photocatalytic H2 production6Dion–Jacobson A′M iii NaNb 3 O 10 (A′ = Rb, Cs; M( iii ) = Sm, Bi) and RbSmNa 2 Nb 4 O 13 layered perovskites and their luminescent function8Unconventional synthesis of novel borides: interplay between crystal structures, magnetic and catalytic properties0Designing new polar materials1Exfoliation of functionalized layered oxides : synthetic approaches and advanced characterizations : toward a non-electrostatic reassembly0Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies544Scission of 2D Inorganic Nanosheets via Physical Adsorption on a Nonflat Surface6Renaissance of Topotactic Ion‐Exchange for Functional Solids with Close Packed Structures18Fluorine-Free Fabrication of MXene via Photo-Fenton Approach for Advanced Lithium–Sulfur Batteries128Recent Advances in Layered Metal‐Oxide Cathodes for Application in Potassium‐Ion Batteries96Versatile Coating Platform for Metal Oxide Nanoparticles: Applications to Materials and Biological Science27Ordering of a Nanoconfined Water Network around Zinc Ions Induces High Proton Conductivity in Layered Titanate7Chemically exfoliated inorganic nanosheets for nanoelectronics41Path Less Traveled: A Contemporary Twist on Synthesis and Traditional Structure Solution of Metastable LiNi12B88Lepidocrocite-Type Layered Titanate Nanoparticles as Photocatalysts for H2 Production23Topochemical Synthesis of Ca3CrN3H Involving a Rotational Structural Transformation for Catalytic Ammonia Synthesis32Topochemical Synthesis of Ca3CrN3H Involving a Rotational Structural Transformation for Catalytic Ammonia Synthesis5Photocatalytic Hydrogen Production from Aqueous Solutions of Glucose and Xylose over Layered Perovskite-like Oxides HCa2Nb3O10, H2La2Ti3O10 and Their Inorganic-Organic Derivatives19Guidelines for Arranging 2D Nanosheets into Neatly Tiled Monolayer Films by a Spin-Coating Process16Band-Gap Engineering of Layered Perovskites by Cu Spacer Insertion as Photocatalysts for Depollution Reaction7Photocatalytic Hydrogen Generation from Aqueous Methanol Solution over n-Butylamine-Intercalated Layered Titanate H2La2Ti3O10: Activity and Stability of the Hybrid Photocatalyst11Nouveaux oxysulfures fonctionnels métastables obtenus par désintercalation topochimique du soufre0Multiscale structural control of thiostannate chalcogels with two-dimensional crystalline constituents24Deposition of silver nanoparticles on nanoscroll-supported inorganic solid using incompletely rolled-up kaolinite2Interlayer modification and single-layer exfoliation of the Ruddlesden–Popper perovskite oxynitride K 2 LaTa 2 O 6 N to improve photocatalytic H 2 evolution activity17Reversible Iodine Intercalation in Lanthanide Incorporated Quasi-2d Bi2o30Advanced growth of 2D MXene for electrochemical sensors97First-principles approach to the structural, physical, electronic, magnetic and optical properties of honeycomb ordered antimonates Na3Fe2SbO642D nanocrystals of metal oxides and hydroxides with nanosheet/nanoflake morphology in biomedicine, energy and chemistry15Influence of HB2Nb3O10-Based Nanosheet Photocatalysts (B = Ca, Sr) Preparation Method on Hydrogen Production Efficiency12Development of Two-Dimensional Functional Nanomaterials for Biosensor Applications: Opportunities, Challenges, and Future Prospects53Topotactic Transition: A Promising Opportunity for Creating New Oxides44Transformation of K2Sb8Q13 and KSb5Q8 Bulk Crystals to Sb2Q3 (Q = S, Se) Nanofibers by Acid–Base Solution Chemistry7Topochemical Anionic Subunit Insertion Reaction for Constructing Nanoparticles of Layered Oxychalcogenide Intergrowth Structures9Pre-intercalation: A valuable approach for the improvement of post-lithium battery materials87Ultralow thermal conductivity of robust vermiculite aerogels fabricated by fast trivalent cation induced nanosheet gelation19Facile Synthesis of CsPbBr3/K4–xNb6O17 Nanocomposites with Sandwich-like and Scroll-like Heterostructures2Highly Efficient Liquid-Phase Exfoliation of Layered Perovskite-like Titanates HLnTiO4 and H2Ln2Ti3O10 (Ln = La, Nd) into Nanosheets8Incorporation of Photo- and Thermoresponsive N-Salicylidene Aniline Derivatives into Cobalt and Zinc Layered Hydroxides5Designed functions of oxide/hydroxide nanosheets via elemental replacement/doping46Prospect of high-temperature superconductivity in layered metal borocarbides15Quasi-2D Bi 0.775 Ln 0.225 O 1.5 (Ln = La, Pr, Nd, Sm, Eu): reversible iodine intercalation and their evaluation as the anode in the lithium-ion battery system5Superior oxygen evolution reaction activities of highly crystalline Ni 1− x Fe x -LDH (0.20 ≤ x ≤ 0.51) synthesized using soft chemistry10A comprehensive review on synthesis, properties, and applications of quaternary transition metal oxychalcogenides19Construction of Hierarchical Films via Layer‐by‐Layer Assembly of Exfoliated Unilamellar Zeolite Nanosheets6Interlayer Engineering of Layered Materials for Efficient Ion Separation and Storage87Ion and Water Transport in 2D Nanofluidic Channels42Simple to Quadruple Perovskite Transformation by Coordination Switching upon Solid-State Ion Exchange of NaNbO33Hydrothermally Synthesized ZnCr- and NiCr-Layered Double Hydroxides as Hydrogen Evolution Photocatalysts16Highly Organized Monolayer Arrangement of 2D Materials and Its Applications18Layered rare-earth stabilized Bi2O3: Organic amines intercalation under ambient conditions and their role as a solid adsorbent for iodine0Tutorial on Describing, Classifying, and Visualizing Common Crystal Structures in Nanoscale Materials Systems20Realization of new n = 3 and n = 4 Dion-Jacobson layered perovskite series with interlayer K+ ions and perovskite blocks stabilized by Pr3+ ions6The Grafting of Hydroxyaromatic Organics within Layered Perovskites via a Microwave-Assisted Method4Challenges and Strategies toward Manganese Hexacyanoferrate for High‐Performance Sodium‐Ion Batteries38Strain-dependent electronic, mechanical and piezoelectric properties of ZrSiO3 2D monolayer: A first principle approach7Development of MXene-based flexible piezoresistive sensors1Cation-eutaxy-enabled III–V-derived van der Waals crystals as memristive semiconductors12Systematic Study on Swelling/Delamination of Layered Metal Oxides with Quaternary Ammonium Ions: Production of Well‐Shaped/Oversized Unilamellar Nanosheets5When van der Waals Met Kagome: A 2D Antimonide with a Vanadium-Kagome Network6La2O2MQ2 phases: Stability and synthetic challenges0Atomically Layered Bronze Nanoalloy Featuring Perpetual Aureolin Fluorescence Adept Microplastic Identification Less than 1 μm in Water32D Transition Metal Ditellurides: Synthesis, Properties, and Applications0Synthesis and large crystal growth of a family of mixed-anionic methanesulfonate salts by anionic site-substitution: Na 5 (SO 3 CH 3 ) 4 (X) (X = BF 4 − , ClO 4 − , PF 6 − , I − )9

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  1. Layered gadolinium hydroxides for simultaneous drug delivery and imaging

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  2. Microwave-assisted functionalization of the Aurivillius phase Bi 2 SrTa 2 O 9 : diol grafting and amine insertion vs. alcohol grafting

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  3. Expanding the I–II–V Phase Space: Soft Synthesis of Polytypic Ternary and Binary Zinc Antimonides

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  4. Two-Dimensional Metal Oxide Nanosheets as Building Blocks for Artificial Photosynthetic Assemblies

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  10. Thickness biased capture of CO 2 on carbide MXenes

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  11. Оптические свойства нестехиометрического оксида кремния SiO-=SUB=-x-=/SUB=- (x<2)

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  33. On Prediction of a Novel Chiral Material Y2H3O(OH): A Hydroxyhydride Holding Hydridic and Protonic Hydrogens

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  35. DALDIRMALI KAPLAMA SİSTEMİ İLE 2B MALZEMELERİN KAPLANMASI

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  38. Preparation of Porous Particles of Layered Perovskite-Like Titanate HLaTiO4

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