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RESEARCH PAPER · Inorganic Chemistry · 2016

La2SrCr2O7F2: A Ruddlesden–Popper Oxyfluoride Containing Octahedrally Coordinated Cr4+ Centers

Ronghuan Zhang, Gareth Read, Franz Lang, Tom Lancaster, Stephen J. Blundell, Michael A. Hayward

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La2SrCr2O7F2: A Ruddlesden–Popper Oxyfluoride Containing Octahedrally Coordinated Cr4+ CentersOriginalChemInform Abstract: La2SrCr2O7F2: A Ruddlesden—Popper Oxyfluoride Containing Octahedrally Coordinated Cr4+ Centers.0La 2 SrCr 2 O 7 : Controlling the Tilting Distortions of n = 2 Ruddlesden–Popper Phases through A-Site Cation Order32Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior57Structural Modification of the Cation-Ordered Ruddlesden–Popper Phase YSr2Mn2O7 by Cation Exchange and Anion Insertion19Possible high- Tc superconductivity due to incipient narrow bands originating from hidden ladders in Ruddlesden-Popper compounds24Soft chemistry of ion-exchangeable layered metal oxides183Structural Diversity from Anion Order in Heteroanionic Materials55Topochemical Fluorination of La2NiO4+d: Unprecedented Ordering of Oxide and Fluoride Ions in La2NiO3F257Sr3Ir2O7F2 : Topochemical conversion of a relativistic Mott state into a spin-orbit driven band insulator3Possible High- $T_c$ T c Superconductivity in “Hidden Ladder” Materials0Stepwise topochemical fluorination of SrCrO 3 perovskite via a super-structured oxide6Heteroanionic Materials by Design: Progress Toward Targeted Properties237Fluorination and reduction of CaCrO 3 by topochemical methods5Electronic properties of perovskite strontium chromium oxyfluoride epitaxial thin films fabricated via low-temperature topotactic reaction11Bond length fluctuation in perovskite chromate SrCrO38Synergistic Influence of d0 (Nb5+) and d10 (Cd2+) Cations in Stabilizing Noncentrosymmetric Dion–Jacobson Layered Perovskites, A′Cd2Nb3O10 (A′ = Rb, Cs)12Unraveling the Suppression of Oxygen Octahedra Rotations in A3B2O7 Ruddlesden-Popper Compounds: Engineering Multiferroicity and Beyond53Interplay between Oxo and Fluoro in Vanadium Oxyfluorides for Centrosymmetric and Non-Centrosymmetric Structure Formation4Microstructural Activation of a Topochemical Reduction Reaction8Low Temperature Synthesis of Oxyfluoride Csti2o2.85f3.15 from a Layered Oxide Cs0.68ti1.83o41Designing new polar materials1Low temperature synthesis of oxyfluoride CsTi2O2.85F3.15 from a layered oxide Cs0.68Ti1.83O43Mixed anion materials0Cuprate Oxyfluorides La2Cu0.8Ni0.2O3F2 and La2CuO3F2 with “Channel-like” Anion Ordering20Advancing Near-Infrared Light Sources: Enhancing Chromium Emission through Cation Substitution in Ultra-Broadband Near-Infrared Phosphors48Double-Layered Perovskite Oxyfluoride Cathodes with High Capacity Involving O–O Bond Formation for Fluoride-Ion Batteries52Broadband near-infrared mechanoluminescence in Cr3+ doped Mg3Ga2GeO839PVDF fluorination of La4Co3O10: Synthesis, structure and physical properties of La4Co3O10F25Structure and Magnetic Properties of the n = 3 Ruddlesden–Popper Oxyfluoride La 0.5 Sr 3.5 Fe 3 O 7.5 F 2.611Structure, magnetism and thermal stability of the n = 3 Ruddlesden–Popper oxyfluoride La 4 Ni 3 O 8.4 F 3.54Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy25Controlling the Regioselectivity of Topochemical Reduction Reactions Through Sequential Anion Insertion and Extraction2Controlling the Regioselectivity of Topochemical Reduction Reactions Through Sequential Anion Insertion and Extraction0Topochemical Fluorination Yields Long-Range Superlattice in Epitaxial La 2 NiO 4 Thin Films0Redox-Neutral Interstitial Hydride Incorporation in Ruddlesden–Popper Oxides0

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  1. ChemInform Abstract: La2SrCr2O7F2: A Ruddlesden—Popper Oxyfluoride Containing Octahedrally Coordinated Cr4+ Centers.

    ChemInform · 2016-05-01

    Ronghuan Zhang, Gareth Read, Franz Lang, Tom Lancaster, Stephen J. Blundell, Michael A. Hayward

    Read original paper ↗ ·

  2. La 2 SrCr 2 O 7 : Controlling the Tilting Distortions of n = 2 Ruddlesden–Popper Phases through A-Site Cation Order

    Inorganic Chemistry · 2016-08-09

    Ronghuan Zhang, Brian M. Abbett, Gareth Read, Franz Lang, Tom Lancaster, T. Thao Tran, P. Shiv Halasyamani, Stephen J. Blundell, Nicole A. Benedek, Michael A. Hayward

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  3. Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior

    Chemistry of Materials · 2016-10-28

    Ronghuan Zhang, Mark S. Senn, Michael A. Hayward

    Read original paper ↗ ·

  4. Structural Modification of the Cation-Ordered Ruddlesden–Popper Phase YSr2Mn2O7 by Cation Exchange and Anion Insertion

    Inorganic Chemistry · 2017-08-04

    Ronghuan Zhang, Alexandra S. Gibbs, Weiguo Zhang, P. Shiv Halasyamani, Michael A. Hayward

    Read original paper ↗ ·

  5. Possible high- Tc superconductivity due to incipient narrow bands originating from hidden ladders in Ruddlesden-Popper compounds

    Physical review. B./Physical review. B · 2017-11-14

    Daisuke Ogura, Hideo Aoki, Kazuhiko Kuroki

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  6. Soft chemistry of ion-exchangeable layered metal oxides

    Chemical Society Reviews · 2018-01-01

    Ritesh Uppuluri, Arnab Sen Gupta, Alyssa S. Rosas, Thomas E. Mallouk

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  7. Structural Diversity from Anion Order in Heteroanionic Materials

    Chemistry of Materials · 2018-04-30

    Nenian Charles, Richard J. Saballos, James M. Rondinelli

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  8. Topochemical Fluorination of La2NiO4+d: Unprecedented Ordering of Oxide and Fluoride Ions in La2NiO3F2

    Inorganic Chemistry · 2018-05-11

    Kerstin Wissel, Jonas Heldt, Pedro B. Groszewicz, Supratik Dasgupta, Hergen Breitzke, Manuel Donzelli, Aamir Iqbal Waidha, Andrew Dominic Fortes, Jochen Rohrer, Peter Raymond Slater, Gerd Buntkowsky, Oliver Clemens

    Read original paper ↗ ·

  9. Sr3Ir2O7F2 : Topochemical conversion of a relativistic Mott state into a spin-orbit driven band insulator

    Physical review. B./Physical review. B · 2018-10-16

    Christi Peterson, Michael W. Swift, Zach Porter, Raphaële J. Clément, Guang Xin Wu, Gihyeon Ahn, S. J. Moon, Bryan C. Chakoumakos, Jacob P. C. Ruff, Huibo B. Cao, Chris G. Van de Walle, Stephen D. Wilson

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  10. Possible High- $$T_c$$ T c Superconductivity in “Hidden Ladder” Materials

    Springer theses · 2019-01-01

    Daisuke Ogura

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  11. Stepwise topochemical fluorination of SrCrO 3 perovskite via a super-structured oxide

    Chemical Communications · 2019-01-01

    Yu Su, Yoshihiro Tsujimoto, Kotaro Fujii, Yuji Masubuchi, Hirohito Ohata, Hideo Iwai, Masatomo Yashima, Kazunari Yamaura

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  12. Heteroanionic Materials by Design: Progress Toward Targeted Properties

    Advanced Materials · 2019-03-12

    Jaye K. Harada, Nenian Charles, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  13. Fluorination and reduction of CaCrO 3 by topochemical methods

    Dalton Transactions · 2020-01-01

    Christian A. Juillerat, Yoshihiro Tsujimoto, Akira Chikamatsu, Yuji Masubuchi, Tetsuya Hasegawa, Kazunari Yamaura

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  14. Electronic properties of perovskite strontium chromium oxyfluoride epitaxial thin films fabricated via low-temperature topotactic reaction

    Physical Review Materials · 2020-02-18

    Akira Chikamatsu, Takahiro Maruyama, Tsukasa Katayama, Yu Su, Yoshihiro Tsujimoto, Kazunari Yamaura, Miho Kitamura, Koji Horiba, Hiroshi Kumigashira, Tetsuya Hasegawa

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  15. Bond length fluctuation in perovskite chromate SrCrO3

    Journal of Applied Physics · 2020-02-19

    Yifan Ding, Lipeng Cao, Weipeng Wang, Boyu Jing, Xi Shen, Yuan Yao, Lifang Xu, Junjie Li, Changqing Jin, Richeng Yu

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  16. Synergistic Influence of d0 (Nb5+) and d10 (Cd2+) Cations in Stabilizing Noncentrosymmetric Dion–Jacobson Layered Perovskites, A′Cd2Nb3O10 (A′ = Rb, Cs)

    Inorganic Chemistry · 2020-05-28

    Shalu Atri, Meenakshi Pokhriyal, S. Uma

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  17. Unraveling the Suppression of Oxygen Octahedra Rotations in A3B2O7 Ruddlesden-Popper Compounds: Engineering Multiferroicity and Beyond

    Physical Review Letters · 2020-10-08

    Yajun Zhang, Jie Wang, Philippe Ghosez

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  18. Interplay between Oxo and Fluoro in Vanadium Oxyfluorides for Centrosymmetric and Non-Centrosymmetric Structure Formation

    Molecules · 2021-01-24

    Prashanth Sandineni, Hooman Yaghoobnejad Asl, Weiguo Zhang, P. Shiv Halasyamani, K. Ghosh, Amitava Choudhury

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  19. Microstructural Activation of a Topochemical Reduction Reaction

    ACS Organic & Inorganic Au · 2021-11-15

    Zhilin Liang, Midori Amano Patiño, Mylène Hendrickx, Joke Hadermann, Michael A. Hayward

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  20. Low Temperature Synthesis of Oxyfluoride Csti2o2.85f3.15 from a Layered Oxide Cs0.68ti1.83o4

    SSRN Electronic Journal · 2022-01-01

    Ya Nan Tang, Qinshang Xu, Yu Su, Zihan Wang, Lanlu Lu, Liang Tang

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  21. Designing new polar materials

    Elsevier eBooks · 2022-01-28

    Emma E. McCabe

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  22. Low temperature synthesis of oxyfluoride CsTi2O2.85F3.15 from a layered oxide Cs0.68Ti1.83O4

    Journal of Solid State Chemistry · 2022-06-30

    Qinshang Xu, Yu Su, Ya Nan Tang, Zihan Wang, Lanlu Lu, Liang Tang

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  23. Mixed anion materials

    Elsevier eBooks · 2022-08-24

    Tong Zhu, Daichi Kato, Shenghan Gao, Hiroshi Kageyama

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  24. Cuprate Oxyfluorides La2Cu0.8Ni0.2O3F2 and La2CuO3F2 with “Channel-like” Anion Ordering

    Inorganic Chemistry · 2022-10-18

    Jonas Jacobs, James Hester, Stefan G. Ebbinghaus

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  25. Advancing Near-Infrared Light Sources: Enhancing Chromium Emission through Cation Substitution in Ultra-Broadband Near-Infrared Phosphors

    Chemistry of Materials · 2023-11-17

    Natalia Majewska, Yi‐Ting Tsai, Xiang-Yun Zeng, Mu‐Huai Fang, Sebastian Mahlik

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  26. Double-Layered Perovskite Oxyfluoride Cathodes with High Capacity Involving O–O Bond Formation for Fluoride-Ion Batteries

    Journal of the American Chemical Society · 2024-01-09

    Hidenori Miki, Kentaro Yamamoto, Hiroyuki Nakaki, Takahiro Yoshinari, Koji Nakanishi, Shinji Nakanishi, Hideki Iba, Jun Miyawaki, Yoshihisa Harada, Akihide Kuwabara, Yanchang Wang, Toshiki Watanabe, Toshiyuki Matsunaga, Kazuhiko Maeda, Hiroshi Kageyama, Yoshiharu Uchimoto

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  27. Broadband near-infrared mechanoluminescence in Cr3+ doped Mg3Ga2GeO8

    Chemical Engineering Journal · 2024-08-22

    Binli Xiao, Sheng Wu, Puxian Xiong, Yao Xiao, Peishan Shao, Zhiyao Zhou, Yinzhen Wang, Feifei Wang

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  28. PVDF fluorination of La4Co3O10: Synthesis, structure and physical properties of La4Co3O10F2

    Scripta Materialia · 2024-09-19

    Bruno Gonano, Øystein S. Fjellvåg, Gwladys Steciuk, Kenneth P. Marshall, Helmer Fjellvåg, Martin Valldor

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  29. Structure and Magnetic Properties of the n = 3 Ruddlesden–Popper Oxyfluoride La 0.5 Sr 3.5 Fe 3 O 7.5 F 2.6

    Inorganic Chemistry · 2024-10-18

    Andy Bivour, Jonas Jacobs, Florian Daumann, Gerald Hörner, Birgit Weber, C. Ritter, Stefan G. Ebbinghaus

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  30. Structure, magnetism and thermal stability of the n = 3 Ruddlesden–Popper oxyfluoride La 4 Ni 3 O 8.4 F 3.5

    Dalton Transactions · 2025-01-01

    Jakob Geßner, Stefan G. Ebbinghaus, Jonas Jacobs

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  31. Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy

    Chemical Reviews · 2025-03-31

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  32. Controlling the Regioselectivity of Topochemical Reduction Reactions Through Sequential Anion Insertion and Extraction

    Angewandte Chemie International Edition · 2025-09-09

    Romain Wernert, Bodoo Batnaran, Michael A. Hayward

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  33. Controlling the Regioselectivity of Topochemical Reduction Reactions Through Sequential Anion Insertion and Extraction

    Angewandte Chemie · 2025-09-09

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  34. Topochemical Fluorination Yields Long-Range Superlattice in Epitaxial La 2 NiO 4 Thin Films

    ACS Nano · 2026-06-08

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  35. Redox-Neutral Interstitial Hydride Incorporation in Ruddlesden–Popper Oxides

    Inorganic Chemistry · 2026-06-23

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