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RESEARCH PAPER · Inorganic Chemistry · 2000

Basicity of Uranyl Oxo Ligands upon Coordination of Alkoxides

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Basicity of Uranyl Oxo Ligands upon Coordination of AlkoxidesOriginalUranyl ion complexation by medium and large homooxacalixarenes: from mono- to poly-uranate complexes28Coordination Trends in Alkali Metal Crown Ether Uranyl Halide Complexes: The Series [A(Crown)]2[UO2X4] Where A = Li, Na, K and X = Cl, Br89Reaction of the Uranyl(VI) Ion (UO22+) with a Triamidoamine Ligand: Preparation and Structural Characterization of a Mixed-Valent Uranium(V/VI) Oxo−Imido Dimer91Synthesis and Structural Characterization of the First Uranium Cluster Containing an Isopolyoxometalate Core0Synthesis and Structural Characterization of the First Uranium Cluster Containing an Isopolyoxometalate Core121Uranyl ions as supramolecular linkers in a bis(hexahomotrioxacalix[6]arene) hexa-uranate complex18The first uranyl–methine carbon bond; a complex with out-of-plane uranyl equatorial coordination59Steric Control of Substituted Phenoxide Ligands on Product Structures of Uranyl Aryloxide Complexes54Synthesis and crystal structure of 1:2 mixed uranyl/alkali metal ions (Li + , Na + , K + , Cs + ) complexes of p-tert-butyltetrahomodioxacalix[4]arene49The Actinides34Uranyl bis-iminophosphorane complexes with in- and out-of-plane equatorial coordinationElectronic supplementary information (ESI) available: Variable temperature 1H NMR spectra; Raman spectra; solid state diffuse reflectance electronic absorption spectra; luminescence spectra; interatomic distances of the optimised structures of 1* and 2* from molecular modelling calculations. See http://www.rsc.org/suppdata/dt/b3/b304602h/6218 Scandium, yttrium, the lanthanides and the actinides11Oxygen and nitrogen Lewis base adducts of [UO2(OTf)2]. Crystal structures of polypyridine complexes with out-of-plane uranyl equatorial coordination81Synthesis of the stable UO2I2, the last of the uranyl dihalides. X-Ray crystal structure of [UO2I2(py)3]Electronic supplementary information (ESI) available: full experimental details. See http://www.rsc.org/suppdata/cc/b4/b400717d/52Extending the Chemistry of the Uranyl Ion: Lewis Acid Coordination to a UO Oxygen163Distorted Equatorial Coordination Environments and Weakening of UO Bonds in Uranyl Complexes Containing NCN and NPN Ligands83Mono‐, Di‐ and Trinuclear Dioxo Complexes of Uranium Containing Hydrazonato and Azomethine Ligands28Selective complexation of uranium( iii ) over lanthanide( iii ) triflates by 2,2′:6′,2″-terpyridine. X-Ray crystal structures of [M(OTf) 3 (terpy) 2 ] and [M(OTf) 2 (terpy) 2 (py)][OTf] (M = Nd, Ce, U) and of polynuclear µ-oxo uranium( iv ) complexes resulting from hydrolysis42Complexation of the uranyl ion (UO2)2+ with a tetraphenylimidodiphosphinate ligand: the first trinuclear uranyl complex comprising a double μ2-oxo (UO2) bridge11Unprecedented reduction of the uranyl ion [UO2]2+ into a polyoxo uranium(iv) cluster: Synthesis and crystal structure of the first f-element oxide with a M6(µ3-O)8 core73Uranyl complexes with the pyridine-2,6-dicarboxylato ligand: new dinuclear species with μ-η2,η2-peroxide, μ2-hydroxide or μ2-methoxide bridges89Actinides: Inorganic & Coordination ChemistryBased in part on the article Actinides: Inorganic & Coordination Chemistry by Grigorii L. Soloveichik which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .1Actinides: Inorganic & Coordination ChemistryBased in part on the article Actinides: Inorganic & Coordination Chemistry by Grigorii L. Soloveichik which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .0Bridging a Gap in Actinide Chemistry37Combinatorial Multinuclear NMR and X-ray Diffraction Studies of Uranium(VI)-Nucleotide Complexes41Uranyl ion complexes with aminoalcoholbis(phenolate) [O,N,O,O′] donor ligands44Synthesis and Structural Characterization of a Uranyl(VI) Complex Possessing Unsupported Unidentate Thiolate Ligands13Polynuclear uranium(IV) compounds with (μ3-oxo)U3 or (μ4-oxo)U4 cores and compartmental Schiff base ligands31Easy access to stable pentavalent uranyl complexes98Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations136Uranyl ion complexes with long chain aminoalcoholbis(phenolate) [O,N,O,O′] donor ligands12Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine8Reactivity of the “yl”-Bond in Uranyl(VI) Complexes. 1. Rates and Mechanisms for the Exchange between thetrans-dioxo Oxygen Atoms in (UO2)2(OH)22+and Mononuclear UO2(OH)n2-nComplexes with Solvent Water41Structural and Functional Evolution of Metallacrowns504Synthesis and Characterization of Three Homoleptic Alkoxides of Uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UV(OtBu)6], and UVI(OtBu)650First 5f-element complexes with the tetradentate BTBP ligand. Synthesis and crystal structure of uranyl(VI) compounds with CyMe4BTBP28Sterically Congested Uranyl Complexes with Seven-Coordination of the UO2 Unit: the Peculiar Ligation Mode of Nitrate in [UO2(NO3)2(Rbtp)] Complexes65A DFT study of the single electron reduction and silylation of the U–O bond of the uranyl dication in a macrocyclic environment37Synthesis and crystal structure of pentavalent uranyl complexes. The remarkable stability of UO2X (X = I, SO3CF3) in non-aqueous solutions95Synthesis and Redox Chemistry of High-Valent Uranium Aryloxides30Pentavalent uranyl complexes243Two uranyl–organic frameworks with pyridinecarboxylate ligands. A novel heterometallic uranyl–copper(II) complex with a cation–cation interaction57Oxo ligand functionalization in the uranyl ion (UO22+)335Actinide Structural Chemistry4Isolation of a uranyl amide by “ate” complex formation14Binuclear Uranium(VI) Complexes with a “Pacman” Expanded Porphyrin: Computational Evidence for Highly Unusual Bis‐Actinyl Structures45Binuclear Hexa- and Pentavalent Uranium Complexes with a Polypyrrolic Ligand: A Density Functional Study of Water- and Hydronium-Induced Reactions44Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η8-C8H8)2] and Uranyl [UO2X2] Compounds38Comparison of the Redox Chemistry of Primary and Secondary Amides of U(IV): Isolation of a U(VI) Bis(imido) Complex or a Homoleptic U(VI) Amido Complex60Probing the local coordination environment and nuclearity of uranyl(vi) complexes in non-aqueous media by emission spectroscopy109Role of the Uranyl Oxo Group as a Hydrogen Bond Acceptor29Uranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol67Oxo Group Protonation and Silylation of Pentavalent Uranyl Pacman Complexes57Oxo Group Protonation and Silylation of Pentavalent Uranyl Pacman Complexes7Syntheses and structures of two uranyl complexes with DMPU4Magnetic communication and reactivity of a stable homometallic cation–cation trimer of pentavalent uranyl73Theoretical exploration of uranyl complexes of a designed polypyrrolic macrocycle: structure/property effects of hinge size on Pacman-shaped complexes31Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation174Developments in the photophysics and photochemistry of actinide ions and their coordination compounds233NMR Spectroscopic Evidence of Lewis Acid–Lewis Base Complex Formation of Perfluoroborane with Uranyl β-Diketonato Complexes2Ring-Opening Polymerization of Epoxides Catalyzed by Uranyl Complexes: An Experimental and Theoretical Study of the Reaction Mechanism27Bisactinyl halogenated complexes: relativistic density functional theory calculation and experimental synthesis9New Reactivity of the Uranyl(VI) Ion116Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors37Causes of uranyl ion nonlinearity in crystal structures46Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies36Cation-cation interactions between uranyl(VI) ions31Reductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage44Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Highly Valence-Diversified Binuclear Uranium Complexes of a Schiff-Base Polypyrrolic Macrocycle: Prediction of Unusual Structures, Electronic Properties, and Formation Reactions19Relativistic DFT and experimental studies of mono- and bis-actinyl complexes of an expanded Schiff-base polypyrrole macrocycle19Metal Substitution into Metal Organic Nanotubes: Impacts on Solvent Uptake and Stability18Facile Reductive Silylation of UO22+ to Uranium(IV) Chloride38Facile Reductive Silylation of UO22+ to Uranium(IV) Chloride11Infrared vibrational spectra, electronic structures, and formation reactions of polypyrrolic mono‐ and bis‐actinyl complexes: A relativistic DFT study3Uranyl-tri-bis(silyl)amide Alkali Metal Contact and Separated Ion Pair Complexes17Accessibility of Uranyl–Plutonium Complex Supported by a Polypyrrolic Macrocycle: An Implication for Experimental Synthesis5High-Pressure Studies of Cesium Uranyl Chloride7Multi-colour uranyl emission efficiently tuned by hexacyanidometallates within hybrid coordination frameworks37Uranyl Oxo Silylation Promoted by Silsesquioxane Coordination19Multinuclear NMR Studies on Lewis Acid–Lewis Base Interactions between Bis(pentafluorophenyl)borinic Acid and Uranyl β-Diketonato Complexes in Toluene4Relativistic DFT Probe for Reaction Energies and Electronic/Bonding Properties of Polypyrrolic Hetero-Bimetallic Actinide Complexes: Effects of Uranylendo-Oxo Functionalization10Uranyl(VI) Triflate as Catalyst for the Meerwein–Ponndorf–Verley Reaction8Synthesis of Transition Metal-sulfur Complexes by Si-S Bond Cleavage1Luminescence properties of the actinides and actinyls4Méthodes catalytiques innovantes de réduction de liaisons carbone-oxygène appliquées à la dépolymérisation réductrice des plastiques oxygénés0Molecular and environmental facets of pentavalent uranium chemistry3Identification and Quantification of Multiphase U(VI) Speciation on Gibbsite with pH Using TRLFS and PARAFAC of Excitation Emission Matrices11Uranyl (VI) complexes from hydrazone based Schiff bases derived from the condensation of benzene-1,3-di- or benzene-1,3,5-tricarbohydrazide and hydroxyaromatic aldehydes1Photoluminescence of a Uranium(IV) Alkoxide Complex3Cation–Cation Interactions in Neptunium(V,VI)-diglycolamide System0

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  1. Uranyl ion complexation by medium and large homooxacalixarenes: from mono- to poly-uranate complexes

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  2. Coordination Trends in Alkali Metal Crown Ether Uranyl Halide Complexes: The Series [A(Crown)]2[UO2X4] Where A = Li, Na, K and X = Cl, Br

    Inorganic Chemistry · 2001-05-26

    Janet A. Danis, Mavis R. Lin, Brian L. Scott, Bryan W. Eichhorn, Wolfgang H. Runde

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  3. Reaction of the Uranyl(VI) Ion (UO22+) with a Triamidoamine Ligand: Preparation and Structural Characterization of a Mixed-Valent Uranium(V/VI) Oxo−Imido Dimer

    Inorganic Chemistry · 2001-09-06

    Paul B. Duval, Carol J. Burns, Wayne E. Buschmann, David L. Clark, David E. Morris, Brian L. Scott

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  4. Synthesis and Structural Characterization of the First Uranium Cluster Containing an Isopolyoxometalate Core

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  5. Synthesis and Structural Characterization of the First Uranium Cluster Containing an Isopolyoxometalate Core

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  6. Uranyl ions as supramolecular linkers in a bis(hexahomotrioxacalix[6]arene) hexa-uranate complex

    Journal of the Chemical Society Dalton Transactions · 2001-11-08

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  7. The first uranyl–methine carbon bond; a complex with out-of-plane uranyl equatorial coordination

    Chemical Communications · 2002-01-01

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  8. Steric Control of Substituted Phenoxide Ligands on Product Structures of Uranyl Aryloxide Complexes

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  9. Synthesis and crystal structure of 1:2 mixed uranyl/alkali metal ions (Li + , Na + , K + , Cs + ) complexes of p-tert-butyltetrahomodioxacalix[4]arene

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  10. The Actinides

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  11. Uranyl bis-iminophosphorane complexes with in- and out-of-plane equatorial coordinationElectronic supplementary information (ESI) available: Variable temperature 1H NMR spectra; Raman spectra; solid state diffuse reflectance electronic absorption spectra; luminescence spectra; interatomic distances of the optimised structures of 1* and 2* from molecular modelling calculations. See http://www.rsc.org/suppdata/dt/b3/b304602h/

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  12. 18 Scandium, yttrium, the lanthanides and the actinides

    Annual Reports Section A (Inorganic Chemistry) · 2004-01-01

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  13. Oxygen and nitrogen Lewis base adducts of [UO2(OTf)2]. Crystal structures of polypyridine complexes with out-of-plane uranyl equatorial coordination

    Dalton Transactions · 2004-01-01

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  14. Synthesis of the stable UO2I2, the last of the uranyl dihalides. X-Ray crystal structure of [UO2I2(py)3]Electronic supplementary information (ESI) available: full experimental details. See http://www.rsc.org/suppdata/cc/b4/b400717d/

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  15. Extending the Chemistry of the Uranyl Ion: Lewis Acid Coordination to a UO Oxygen

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  16. Distorted Equatorial Coordination Environments and Weakening of UO Bonds in Uranyl Complexes Containing NCN and NPN Ligands

    Inorganic Chemistry · 2004-04-22

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  17. Mono‐, Di‐ and Trinuclear Dioxo Complexes of Uranium Containing Hydrazonato and Azomethine Ligands

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  18. Selective complexation of uranium( iii ) over lanthanide( iii ) triflates by 2,2′:6′,2″-terpyridine. X-Ray crystal structures of [M(OTf) 3 (terpy) 2 ] and [M(OTf) 2 (terpy) 2 (py)][OTf] (M = Nd, Ce, U) and of polynuclear µ-oxo uranium( iv ) complexes resulting from hydrolysis

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  19. Complexation of the uranyl ion (UO2)2+ with a tetraphenylimidodiphosphinate ligand: the first trinuclear uranyl complex comprising a double μ2-oxo (UO2) bridge

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  20. Unprecedented reduction of the uranyl ion [UO2]2+ into a polyoxo uranium(iv) cluster: Synthesis and crystal structure of the first f-element oxide with a M6(µ3-O)8 core

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  21. Uranyl complexes with the pyridine-2,6-dicarboxylato ligand: new dinuclear species with μ-η2,η2-peroxide, μ2-hydroxide or μ2-methoxide bridges

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  22. Actinides: Inorganic & Coordination ChemistryBased in part on the article Actinides: Inorganic & Coordination Chemistry by Grigorii L. Soloveichik which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .

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  24. Bridging a Gap in Actinide Chemistry

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  25. Combinatorial Multinuclear NMR and X-ray Diffraction Studies of Uranium(VI)-Nucleotide Complexes

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  26. Uranyl ion complexes with aminoalcoholbis(phenolate) [O,N,O,O′] donor ligands

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  27. Synthesis and Structural Characterization of a Uranyl(VI) Complex Possessing Unsupported Unidentate Thiolate Ligands

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  28. Polynuclear uranium(IV) compounds with (μ3-oxo)U3 or (μ4-oxo)U4 cores and compartmental Schiff base ligands

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  29. Easy access to stable pentavalent uranyl complexes

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  30. Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations

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  31. Uranyl ion complexes with long chain aminoalcoholbis(phenolate) [O,N,O,O′] donor ligands

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  32. Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine

    Dalton Transactions · 2007-01-01

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  33. Reactivity of the “yl”-Bond in Uranyl(VI) Complexes. 1. Rates and Mechanisms for the Exchange between thetrans-dioxo Oxygen Atoms in (UO2)2(OH)22+and Mononuclear UO2(OH)n2-nComplexes with Solvent Water

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  34. Structural and Functional Evolution of Metallacrowns

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  35. Synthesis and Characterization of Three Homoleptic Alkoxides of Uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UV(OtBu)6], and UVI(OtBu)6

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  36. First 5f-element complexes with the tetradentate BTBP ligand. Synthesis and crystal structure of uranyl(VI) compounds with CyMe4BTBP

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  37. Sterically Congested Uranyl Complexes with Seven-Coordination of the UO2 Unit: the Peculiar Ligation Mode of Nitrate in [UO2(NO3)2(Rbtp)] Complexes

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  38. A DFT study of the single electron reduction and silylation of the U–O bond of the uranyl dication in a macrocyclic environment

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  39. Synthesis and crystal structure of pentavalent uranyl complexes. The remarkable stability of UO2X (X = I, SO3CF3) in non-aqueous solutions

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  40. Synthesis and Redox Chemistry of High-Valent Uranium Aryloxides

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  41. Pentavalent uranyl complexes

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  42. Two uranyl–organic frameworks with pyridinecarboxylate ligands. A novel heterometallic uranyl–copper(II) complex with a cation–cation interaction

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  43. Oxo ligand functionalization in the uranyl ion (UO22+)

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  44. Actinide Structural Chemistry

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  45. Isolation of a uranyl amide by “ate” complex formation

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  46. Binuclear Uranium(VI) Complexes with a “Pacman” Expanded Porphyrin: Computational Evidence for Highly Unusual Bis‐Actinyl Structures

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  47. Binuclear Hexa- and Pentavalent Uranium Complexes with a Polypyrrolic Ligand: A Density Functional Study of Water- and Hydronium-Induced Reactions

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  48. Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η8-C8H8)2] and Uranyl [UO2X2] Compounds

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  49. Comparison of the Redox Chemistry of Primary and Secondary Amides of U(IV): Isolation of a U(VI) Bis(imido) Complex or a Homoleptic U(VI) Amido Complex

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  50. Probing the local coordination environment and nuclearity of uranyl(vi) complexes in non-aqueous media by emission spectroscopy

    Dalton Transactions · 2011-01-01

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