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RESEARCH PAPER · Inorganic Chemistry · 2002

Steric Control of Substituted Phenoxide Ligands on Product Structures of Uranyl Aryloxide Complexes

Marianne P. Wilkerson, Carol J. Burns, David E. Morris, Robert T. Paine, Brian L. Scott

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Steric Control of Substituted Phenoxide Ligands on Product Structures of Uranyl Aryloxide ComplexesOriginal17 Scandium, yttrium, the lanthanides and the actinides3Calixarenes as aryloxides: oligonuclear europium(iii) derivatives45The Actinides34Synthesis of Group 1 Metal 2,6-Diphenylphenoxide Complexes [M(OC6H3Ph2-2,6)] (M = Li, Na, K, Rb, Cs) and Structures of the Solvent-Free Complexes [Rb(OC6H3Ph2-2,6)]x and [Cs(OC6H3Ph2-2,6)]x: One-Dimensional Extended Arrays of Metal Aryloxides312D Chiral Uranyl( VI ) Coordination Polymers with Second‐Harmonic Generation Response and Ferroelectric Properties7818 Scandium, yttrium, the lanthanides and the actinides11Distorted Equatorial Coordination Environments and Weakening of UO Bonds in Uranyl Complexes Containing NCN and NPN Ligands83Mono‐, Di‐ and Trinuclear Dioxo Complexes of Uranium Containing Hydrazonato and Azomethine Ligands28Dimethylsuphoxide and its roles in the coordination chemistry of the uranyl ion26Versatile new uranyl(vi) dihalide complexes supported by tunable organic amide ligands19Separation of actinides and lanthanides: Synthesis and molecular structure of a new di-μ-phenoxo-bridged dinuclear bis(dioxouranium(VI)) complex33Combinatorial Multinuclear NMR and X-ray Diffraction Studies of Uranium(VI)-Nucleotide Complexes41Uranyl ion complexes with aminoalcoholbis(phenolate) [O,N,O,O′] donor ligands44Synthesis and Structural Characterization of a Uranyl(VI) Complex Possessing Unsupported Unidentate Thiolate Ligands13An entry route into non-aqueous plutonyl coordination chemistry32Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine8Highlights in Uranium Coordination Chemistry59Near-Infrared Photoluminescence from a Plutonyl Ion16Synthesis, molecular and supramolecular structure, spectroscopy and electrochemistry of a dialkoxo-bridged diuranyl(VI) compound8Syntheses, structures, and electrochemistry of a dinuclear compound and a mononuclear–mononuclear cocrystalline compound of uranyl(VI)13Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U–I bond22Uranium(VI) Bis(imido) Chalcogenate Complexes: Synthesis and Density Functional Theory Analysis79Cation–Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(N t Bu) 2 ] +148Cation–Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(NtBu)2]+39Oxo ligand functionalization in the uranyl ion (UO22+)335Coordination of N-Donor Ligands to a Uranyl(V) β-Diketiminate Complex45Oxidative Addition to U(V)−U(V) Dimers: Facile Routes to Uranium(VI) Bis(imido) Complexes89Di-2-pyridyl ketone in actinide chemistry: Dinuclear uranyl complexes16Hexadentate Terephthalamide(bis-hydroxypyridinone) Ligands for Uranyl Chelation: Structural and Thermodynamic Consequences of Ligand Variation46New reactivity of the uranyl ion: ring opening polymerisation of epoxides38Ring-Opening Polymerization of Epoxides Catalyzed by Uranyl Complexes: An Experimental and Theoretical Study of the Reaction Mechanism272.13 Product Class 13: Organometallic Complexes of the Actinides2New Mechanism for the Ring-Opening Polymerization of Lactones? Uranyl Aryloxide-Induced Intermolecular Catalysis50Uranium(III) Complexes with Bulky Aryloxide Ligands Featuring Metal–Arene Interactions and Their Reactivity Toward Nitrous Oxide67Arene-ligated heteroleptic terphenolate complexes of thorium31Synthesis, X-ray structure, electrochemical behaviour and fluorescence studies of mononuclear dioxouranium complexes with oxygen donor ligands4Coordination Chemistry of Metal Phenolates—General Aspects2Highly Valence-Diversified Binuclear Uranium Complexes of a Schiff-Base Polypyrrolic Macrocycle: Prediction of Unusual Structures, Electronic Properties, and Formation Reactions19Why Is Uranyl Formohydroxamate Red?25Perturbation of the O–U–O Angle in Uranyl by Coordination to a 12-Membered Macrocycle32Coordination Characteristics of Uranyl BBP Complexes: Insights from an Electronic Structure Analysis6Elucidating bonding preferences in tetrakis(imido)uranate(VI) dianions70Carbon Dioxide Activation by a Uranium(III) Complex Derived from a Chelating Bis(aryloxide) Ligand49Understanding the origins of O yl –U–O yl bending in the uranyl (UO 2 2+ ) ion56Dehydration of the Uranyl Peroxide Studtite, [UO2(η2-O2)(H2O)2]·2H2O, Affords a Drastic Change in the Electronic Structure: A Combined X-ray Spectroscopic and Theoretical Analysis51How to Bend the Uranyl Cation via Crystal Engineering28Uranyl-tri-bis(silyl)amide Alkali Metal Contact and Separated Ion Pair Complexes17Coordination aspects in Schiff bases cocrystals44Hexadentate β-Dicarbonyl(bis-catecholamine) Ligands for Efficient Uranyl Cation Decorporation: Thermodynamic and Antioxidant Activity Studies12Experimental and Computational Study of a Tetraazamacrocycle Bis(aryloxide) Uranyl Complex and of the Analogues {E═U═NR}2+ (E = O and NR)13Novel Heteroleptic Uranyl(VI) Complexes Incorporating Tetradentate and Bidentate Chelating Ligands: Deviation from the O yl ‐U‐O yl Linearity5Reactions of Np(VI) and Pu(VI) with Phenanthroline Result in Bending the Np(VI)O₂²⁺ Unit and a Reduced Pu(V) Species1Reactions of Np(VI) and Pu(VI) with Phenanthroline Result in Bending the [Np VI O 2 ] 2+ Unit and a Reduced Pu(V) Species3Soft N-donor and CHON ligands for minor actinide separation: From 4f/5f bonding principles to process design0

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  1. 17 Scandium, yttrium, the lanthanides and the actinides

    Annual Reports Section A (Inorganic Chemistry) · 2003-01-01

    S. A. Cotton

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  2. Calixarenes as aryloxides: oligonuclear europium(iii) derivatives

    Dalton Transactions · 2003-01-01

    Sean D. Fleming, Carl David Gutsche, Jack McB. Harrowfield, Mark I. Ogden, Brian W. Skelton, Donald F. Stewart, ALLAN HENRY WHITE

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  3. The Actinides

    Elsevier eBooks · 2003-01-01

    Carol J. Burns, Mary P. Neu, Hakim Boukhalfa, Keith E. Gutowski, Nicholas J. Bridges, Robin Don Rogers

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  4. Synthesis of Group 1 Metal 2,6-Diphenylphenoxide Complexes [M(OC6H3Ph2-2,6)] (M = Li, Na, K, Rb, Cs) and Structures of the Solvent-Free Complexes [Rb(OC6H3Ph2-2,6)]x and [Cs(OC6H3Ph2-2,6)]x: One-Dimensional Extended Arrays of Metal Aryloxides

    Inorganic Chemistry · 2003-08-29

    Charles S. Weinert, Phillip Edward Fanwick, Ian P. Rothwell

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  5. 2D Chiral Uranyl( VI ) Coordination Polymers with Second‐Harmonic Generation Response and Ferroelectric Properties

    European Journal of Inorganic Chemistry · 2003-10-01

    Yong‐Rong Xie, Hong Lin Zhao, Xisen Wang, Zhi‐Rong Qu, Ren‐Gen Xiong, Xiang Xue, Zi‐Ling Xue, Xiao‐Zeng You

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  6. 18 Scandium, yttrium, the lanthanides and the actinides

    Annual Reports Section A (Inorganic Chemistry) · 2004-01-01

    S. A. Cotton

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  7. Distorted Equatorial Coordination Environments and Weakening of UO Bonds in Uranyl Complexes Containing NCN and NPN Ligands

    Inorganic Chemistry · 2004-04-22

    Mark J. Sarsfield, M. Helliwell, James Raftery

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  8. Mono‐, Di‐ and Trinuclear Dioxo Complexes of Uranium Containing Hydrazonato and Azomethine Ligands

    Zeitschrift für anorganische und allgemeine Chemie · 2004-07-27

    Claudia C. Gatto, Ernesto Schulz Lang, A. Kupfer, Adelheid Hagenbach, Ulrich Abram

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  9. Dimethylsuphoxide and its roles in the coordination chemistry of the uranyl ion

    Comptes Rendus Chimie · 2004-12-24

    Jack McB. Harrowfield, Brian W. Skelton, ALLAN HENRY WHITE

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  10. Versatile new uranyl(vi) dihalide complexes supported by tunable organic amide ligands

    Chemical Communications · 2005-01-01

    Shanmugaperumal Kannan, Charles Leslie Barnes, Paul B. Duval

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  11. Separation of actinides and lanthanides: Synthesis and molecular structure of a new di-μ-phenoxo-bridged dinuclear bis(dioxouranium(VI)) complex

    Inorganica Chimica Acta · 2005-09-28

    R. Kannappan, Duncan M. Tooke, Anton L. Spek, Jan Reedijk

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  12. Combinatorial Multinuclear NMR and X-ray Diffraction Studies of Uranium(VI)-Nucleotide Complexes

    Journal of the American Chemical Society · 2005-10-08

    Zoltán Szabó, István Furó, I. Csöregh

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  13. Uranyl ion complexes with aminoalcoholbis(phenolate) [O,N,O,O′] donor ligands

    Polyhedron · 2005-10-18

    H. Sopo, J. Sviili, Arto Valkonen, Reijo Sillanpää

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  14. Synthesis and Structural Characterization of a Uranyl(VI) Complex Possessing Unsupported Unidentate Thiolate Ligands

    Inorganic Chemistry · 2005-11-08

    Shanmugaperumal Kannan, Charles Leslie Barnes, Paul B. Duval

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  15. An entry route into non-aqueous plutonyl coordination chemistry

    Chemical Communications · 2007-01-01

    Andrew J. Gaunt, Sean D. Reilly, Trevor W. Hayton, Brian L. Scott, Mary P. Neu

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  16. Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine

    Dalton Transactions · 2007-01-01

    Jeffery A. Bertke, S.D. Bunge

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  17. Highlights in Uranium Coordination Chemistry

    Structure and bonding · 2008-01-01

    Suzanne C. Bart, Karsten Meyer

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  18. Near-Infrared Photoluminescence from a Plutonyl Ion

    The Journal of Physical Chemistry A · 2008-03-01

    Marianne P. Wilkerson, John M. Berg

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  19. Synthesis, molecular and supramolecular structure, spectroscopy and electrochemistry of a dialkoxo-bridged diuranyl(VI) compound

    Polyhedron · 2008-03-15

    Susanta Hazra, Samit Majumder, Μ. Fleck, Sasankasekhar Mohanta

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  20. Syntheses, structures, and electrochemistry of a dinuclear compound and a mononuclear–mononuclear cocrystalline compound of uranyl(VI)

    Crystal Research and Technology · 2008-10-20

    Μ. Fleck, Susanta Hazra, S. Majumder, Sasankasekhar Mohanta

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  21. Reactivity of UI4(OEt2)2 with phenols: probing the chemistry of the U–I bond

    Dalton Transactions · 2009-01-01

    David D. Schnaars, Guang Xin Wu, Trevor W. Hayton

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  22. Uranium(VI) Bis(imido) Chalcogenate Complexes: Synthesis and Density Functional Theory Analysis

    Inorganic Chemistry · 2009-02-13

    L.P. Spencer, Ping Xiong Yang, Brian L. Scott, Enrique R. Batista, James M. Boncella

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  23. Cation–Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(N t Bu) 2 ] +

    Angewandte Chemie International Edition · 2009-04-19

    L.P. Spencer, Eric J. Schelter, Ping Xiong Yang, Robyn L. Gdula, Brian L. Scott, Joe D. Thompson, Jaqueline L. Kiplinger, Enrique R. Batista, James M. Boncella

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  24. Cation–Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(NtBu)2]+

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    L.P. Spencer, Eric J. Schelter, Ping Xiong Yang, Robyn L. Gdula, Brian L. Scott, Joe D. Thompson, Jaqueline L. Kiplinger, Enrique R. Batista, James M. Boncella

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  25. Oxo ligand functionalization in the uranyl ion (UO22+)

    Coordination Chemistry Reviews · 2009-06-22

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  26. Coordination of N-Donor Ligands to a Uranyl(V) β-Diketiminate Complex

    Inorganic Chemistry · 2009-11-30

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  27. Oxidative Addition to U(V)−U(V) Dimers: Facile Routes to Uranium(VI) Bis(imido) Complexes

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    L.P. Spencer, Ping Xiong Yang, Brian L. Scott, Enrique R. Batista, James M. Boncella

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  28. Di-2-pyridyl ketone in actinide chemistry: Dinuclear uranyl complexes

    Polyhedron · 2010-02-03

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  29. Hexadentate Terephthalamide(bis-hydroxypyridinone) Ligands for Uranyl Chelation: Structural and Thermodynamic Consequences of Ligand Variation

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  30. New reactivity of the uranyl ion: ring opening polymerisation of epoxides

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  31. Ring-Opening Polymerization of Epoxides Catalyzed by Uranyl Complexes: An Experimental and Theoretical Study of the Reaction Mechanism

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  32. 2.13 Product Class 13: Organometallic Complexes of the Actinides

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  33. New Mechanism for the Ring-Opening Polymerization of Lactones? Uranyl Aryloxide-Induced Intermolecular Catalysis

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  34. Uranium(III) Complexes with Bulky Aryloxide Ligands Featuring Metal–Arene Interactions and Their Reactivity Toward Nitrous Oxide

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    Sebastian M. Franke, Ba L. Tran, Frank W. Heinemann, Wolfgang Hieringer, Daniel J. Mindiola, Karsten Meyer

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  35. Arene-ligated heteroleptic terphenolate complexes of thorium

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  36. Synthesis, X-ray structure, electrochemical behaviour and fluorescence studies of mononuclear dioxouranium complexes with oxygen donor ligands

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  37. Coordination Chemistry of Metal Phenolates—General Aspects

    Patai's chemistry of functional groups · 2014-04-29

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  38. Highly Valence-Diversified Binuclear Uranium Complexes of a Schiff-Base Polypyrrolic Macrocycle: Prediction of Unusual Structures, Electronic Properties, and Formation Reactions

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  39. Why Is Uranyl Formohydroxamate Red?

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    Mark A. Silver, Walter L. Dorfner, Samantha K. Cary, Justin N. Cross, Jian Hung Lin, Eric J. Schelter, Thomas E. Albrecht‐Schmitt

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  40. Perturbation of the O–U–O Angle in Uranyl by Coordination to a 12-Membered Macrocycle

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  41. Coordination Characteristics of Uranyl BBP Complexes: Insights from an Electronic Structure Analysis

    ACS Omega · 2017-03-21

    C. D. Pemmaraju, Roy Copping, Danil E. Smiles, David K. Shuh, Niels Grønbech‐Jensen, David Prendergast, Andrew Canning

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  42. Elucidating bonding preferences in tetrakis(imido)uranate(VI) dianions

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  43. Carbon Dioxide Activation by a Uranium(III) Complex Derived from a Chelating Bis(aryloxide) Ligand

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  44. Understanding the origins of O yl –U–O yl bending in the uranyl (UO 2 2+ ) ion

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  45. Dehydration of the Uranyl Peroxide Studtite, [UO2(η2-O2)(H2O)2]·2H2O, Affords a Drastic Change in the Electronic Structure: A Combined X-ray Spectroscopic and Theoretical Analysis

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  46. How to Bend the Uranyl Cation via Crystal Engineering

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  47. Uranyl-tri-bis(silyl)amide Alkali Metal Contact and Separated Ion Pair Complexes

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  48. Coordination aspects in Schiff bases cocrystals

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  49. Hexadentate β-Dicarbonyl(bis-catecholamine) Ligands for Efficient Uranyl Cation Decorporation: Thermodynamic and Antioxidant Activity Studies

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  50. Experimental and Computational Study of a Tetraazamacrocycle Bis(aryloxide) Uranyl Complex and of the Analogues {E═U═NR}2+ (E = O and NR)

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