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RESEARCH PAPER · Inorganic Chemistry · 2010

Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η8-C8H8)2] and Uranyl [UO2X2] Compounds

J.‐C. Berthet, P. Thuéry, M. Ephritikhine

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Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η8-C8H8)2] and Uranyl [UO2X2] CompoundsOriginalLanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2000136The actinides2Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds135Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters78Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters22New polynuclear U( iv )–U( v ) complexes from U( iv ) mediated uranyl( v ) disproportionation71Periodic Trends in Hexanuclear Actinide Clusters42Uranyl Heteropolyoxometalate: Synthesis, Structure, and Spectroscopic Properties37Relativistic Density Functional Study on Uranium(IV) and Thorium(IV) Oxide Clusters of Zonohedral Geometry13Coordination of 1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline and 2,4,6-tris(2-pyridyl)-1,3,5-triazine to MX3 (M=Ce, U; X=I, OSO2CF3) in pyridine and acetonitrile9Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 201017Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges344Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products372Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes323New Reactivity of the Uranyl(VI) Ion116Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71Time-Resolved Assembly of Chiral Uranyl Peroxo Cage Clusters Containing Belts of Polyhedra35Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 201238Thorocene adducts of the neutral 2,2′-bipyridine and its radical anion. Synthesis and crystal structures of [Th(η8-C8H8)2(κ2-bipy)] and [Th(μ-η8:η5-C8H8)2(κ2-bipy)K(py)2]∞25Comparison of uranium(VI) and thorium(IV) coordination polymers with p-toluenesulfonic acid16Oxo Clusters of 5f Elements24Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Coordination of Tetravalent Actinides (An=ThIV, UIV, NpIV, PuIV) with DOTA: From Dimers to Hexamers72Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides36Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides7Tetrametallic Thorium Compounds with Th 4 E 4 (E = S, Se) Cubane Cores7Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters16Redox Properties of Monocyclooctatetraenyl Uranium(IV) and (V) Complexes: Experimental and Relativistic DFT Studies12In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect16Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl439Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl46Breaking C–O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes40Structural properties of ultra-small thorium and uranium dioxide nanoparticles embedded in a covalent organic framework45Ferrocene‐Based Actinide Clusters: Synthesis, Crystal Structures, and Characterization3Synthesis and Characterization of Cerium-Oxo Clusters Capped by Acetylacetonate11Crystallographic Evidence for Formation of M 6 O 8 /M 6 O 9 f-Element Clusters in Hydrolysis Reactions6Uranyl Clusters Based on 1,10-Phenanthroline Derivative Ligands: Synthesis, Crystal Structures, and Iodine Capture1M6O8 metal oxo clusters: A key structural motif across the periodic table8

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  1. Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2000

    Coordination Chemistry Reviews · 2005-04-21

    Ji‐Young Hyeon, J. Gottfriedsen, Frank Thomas Edelmann

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  2. The actinides

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  3. Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds

    Journal of the American Chemical Society · 2011-03-31

    J.-C. Tourneux, J.‐C. Berthet, Thibault Cantat, P. Thuéry, Nicolas Mézailles, M. Ephritikhine

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  4. Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters

    Angewandte Chemie International Edition · 2011-05-12

    Biplab Biswas, Victor Mougel, Jacques Pécaut, Marinella Mazzanti

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  5. Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters

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    Biplab Biswas, Victor Mougel, Jacques Pécaut, Marinella Mazzanti

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  6. New polynuclear U( iv )–U( v ) complexes from U( iv ) mediated uranyl( v ) disproportionation

    Chemical Communications · 2011-11-18

    Victor Mougel, Jacques Pécaut, Marinella Mazzanti

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  7. Periodic Trends in Hexanuclear Actinide Clusters

    Inorganic Chemistry · 2012-03-21

    Juan Diwu, Shuao Wang, Thomas E. Albrecht‐Schmitt

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  8. Uranyl Heteropolyoxometalate: Synthesis, Structure, and Spectroscopic Properties

    Inorganic Chemistry · 2012-04-20

    Pius O. Adelani, Allen G. Oliver, Thomas E. Albrecht‐Schmitt

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  9. Relativistic Density Functional Study on Uranium(IV) and Thorium(IV) Oxide Clusters of Zonohedral Geometry

    Inorganic Chemistry · 2012-06-01

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  10. Coordination of 1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline and 2,4,6-tris(2-pyridyl)-1,3,5-triazine to MX3 (M=Ce, U; X=I, OSO2CF3) in pyridine and acetonitrile

    Polyhedron · 2012-07-23

    J.‐C. Berthet, J.-M. Onno, Florence Gupta, Christelle Rivière, P. Thuéry, M. Nierlich, Charles Madic, M. Ephritikhine

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  11. Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2010

    Coordination Chemistry Reviews · 2012-09-12

    Frank Thomas Edelmann

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  12. Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges

    Chemical Reviews · 2012-10-24

    Jie Qiu, Peter Carman Burns

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  13. Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products

    Chemical Reviews · 2012-10-29

    Karah E. Knope, L. Soderholm

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  14. Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes

    Chemical Reviews · 2012-11-07

    M.B. Jones, Andrew J. Gaunt

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  15. New Reactivity of the Uranyl(VI) Ion

    Chemistry - A European Journal · 2012-11-14

    Robert J. Baker

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  16. Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate

    Inorganic Chemistry · 2012-12-07

    P. Thuéry

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  17. Time-Resolved Assembly of Chiral Uranyl Peroxo Cage Clusters Containing Belts of Polyhedra

    Inorganic Chemistry · 2012-12-11

    Jie Qiu, Kévin Nguyen, Laurent J. Jouffret, Jennifer E. S. Szymanowski, Peter Carman Burns

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  18. Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2012

    Coordination Chemistry Reviews · 2013-11-21

    Frank Thomas Edelmann

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  19. Thorocene adducts of the neutral 2,2′-bipyridine and its radical anion. Synthesis and crystal structures of [Th(η8-C8H8)2(κ2-bipy)] and [Th(μ-η8:η5-C8H8)2(κ2-bipy)K(py)2]∞

    Comptes Rendus Chimie · 2013-12-14

    J.‐C. Berthet, P. Thuéry, M. Ephritikhine

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  20. Comparison of uranium(VI) and thorium(IV) coordination polymers with p-toluenesulfonic acid

    Polyhedron · 2015-03-10

    Yingjie Zhang, Jason Roy Price, Inna Karatchevtseva, Kim Lu, Bongho Yoon, Fatima Kadi, Gregory R. Lumpkin, Feng Li

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  21. Oxo Clusters of 5f Elements

    Structure and bonding · 2016-01-01

    Sarah Hickam, Peter Carman Burns

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  22. Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs

    Journal of Solid State Chemistry · 2016-07-28

    Lingling Liang, Ronglan Zhang, Jianshe Zhao, Chiyang Liu, Ng Seik Weng

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  23. Coordination of Tetravalent Actinides (An=ThIV, UIV, NpIV, PuIV) with DOTA: From Dimers to Hexamers

    Chemistry - A European Journal · 2017-03-10

    Christelle Tamain, Thomas Dumas, Christoph Hennig, Philippe Guilbaud

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  24. Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides

    Angewandte Chemie International Edition · 2017-07-07

    Polly Louise Arnold, Bradley E. Cowie, Markéta Suvova, Markus Zegke, Nicola Magnani, Éric Colineau, Jean‐Christophe Griveau, R. Caciuffo, Jason B. Love

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  25. Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides

    Angewandte Chemie · 2017-07-07

    Polly Louise Arnold, Bradley E. Cowie, Markéta Suvova, Markus Zegke, Nicola Magnani, Éric Colineau, Jean‐Christophe Griveau, R. Caciuffo, Jason B. Love

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  26. Tetrametallic Thorium Compounds with Th 4 E 4 (E = S, Se) Cubane Cores

    Inorganic Chemistry · 2017-08-23

    Matthew A. Stuber, Anna Y. Kornienko, Thomas J. Emge, John G. Brennan

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  27. Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters

    Crystal Growth & Design · 2017-08-31

    Ralph A. Zehnder, James M. Boncella, Justin N. Cross, Stosh A. Kozimor, Marisa J. Monreal, Henry S. La Pierre, Brian L. Scott, Aaron M. Tondreau, Mat­thias Zeller

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  28. Redox Properties of Monocyclooctatetraenyl Uranium(IV) and (V) Complexes: Experimental and Relativistic DFT Studies

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  29. In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect

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  30. Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl4

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  31. Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl4

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  32. Breaking C–O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes

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  33. Structural properties of ultra-small thorium and uranium dioxide nanoparticles embedded in a covalent organic framework

    Chemical Science · 2020-01-01

    Liane M. Moreau, Alexandre Hervé, Mark D. Straub, Dominic R. Russo, Rebecca J. Abergel, Selim Alayoǧlu, John Arnold, Augustin Braun, Gauthier J.‐P. Deblonde, Yangdongling Liu, Trevor D. Lohrey, Daniel T. Olive, Yusen Qiao, Julian A. Rees, David K. Shuh, Simon J. Teat, Corwin H. Booth, Stefan G. Minasian

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  34. Ferrocene‐Based Actinide Clusters: Synthesis, Crystal Structures, and Characterization

    European Journal of Inorganic Chemistry · 2023-03-18

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  35. Synthesis and Characterization of Cerium-Oxo Clusters Capped by Acetylacetonate

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  36. Crystallographic Evidence for Formation of M 6 O 8 /M 6 O 9 f-Element Clusters in Hydrolysis Reactions

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  37. Uranyl Clusters Based on 1,10-Phenanthroline Derivative Ligands: Synthesis, Crystal Structures, and Iodine Capture

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  38. M6O8 metal oxo clusters: A key structural motif across the periodic table

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