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RESEARCH PAPER · Angewandte Chemie International Edition · 2025

A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure Design

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A Promising Deep Ultraviolet Nonlinear Optical Crystal Activated by the Ordered Structure DesignOriginalA wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units2Hydrogen Bond Chemistry Enabled Key Materials for High-Energy-Density Lithium Batteries0KNa 2 Y 2 B 2 O 6 F 3 : a beryllium free deep-UV nonlinear optical crystal with well-balanced properties2Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups3Halide Ion-Directed Symmetry Control in π-Conjugated Molecular Crystals6Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties35Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties6Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains22Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains8Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes10Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates4Strongly Polar [H2PO3]− Induced π-Conjugated Group Arrangement for Balanced UV Nonlinear Optical Performance3Lewis Acidity‐Governed Ion Exchange and Record Birefringence in A′[Ag 3 (PO 3 F) 2 ]11Lewis Acidity‐Governed Ion Exchange and Record Birefringence in A′[Ag 3 (PO 3 F) 2 ]2Synergistic Design of UV Nonlinear Optical Crystals: Harnessing Flexible π-Conjugated Anions and Guanidinium Cations for Enhanced Performance4Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal25Research on Nonlinear Optical Materials Based on BO 3 and BO 4 Hydroxy Tetraborates4Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals5Shape‐Topology‐Driven Design of Deep Ultraviolet Nonlinear Optical Crystals: Engineering [CH 3 PO 3 ]–Metal‐Oxo Layered Frameworks for Enhanced SHG, DUV Transparency3Asymmetry-driven organic–inorganic hybrid strategy for constructing structures with exceptional organofunctionalized B–O units2Counterion engineering in open-framework crystals: dual enhancement of birefringence and UV transparency in Cd–oxalate framework via cation substitution0From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulation8Two scandium borate UV NLO crystals designed through chemical element substitution1Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence18(C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence0RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2(C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts13Ultrawide Bandgap and Record-High Birefringence in a Covalent Beryllium-Organic Framework7Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal0From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals4Heterovalent Coexistence‐Driven Symmetry Breaking and Dimensional Evolution: Designing Polar Heart‐Shaped Channels for Exceptional MFIR Nonlinear Optics5Breaking Layered Limitations via Electrostatic-to-Covalent Conversion toward Three-Dimensional T2-Cluster-Based Chalcogenides7Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking1(CN 4 H 7 )(NH 2 SO 3 ): A Solar‐Blind Ultraviolet Nonlinear Optical Crystal With Short UV Cutoff Edge and Full‐Wavelength Phase‐Matching0K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals1Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates2When Octahedra Learn to Be Prisms: Unlocking a Record Deep‑UV NLO Crystal0Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs0A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages0Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges0

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  2. Hydrogen Bond Chemistry Enabled Key Materials for High-Energy-Density Lithium Batteries

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  3. KNa 2 Y 2 B 2 O 6 F 3 : a beryllium free deep-UV nonlinear optical crystal with well-balanced properties

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  4. Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups

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  5. Halide Ion-Directed Symmetry Control in π-Conjugated Molecular Crystals

    Inorganic Chemistry · 2025-06-17

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  6. Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2025-06-20

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  7. Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties

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  8. Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains

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  10. Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes

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  11. Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates

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  12. Strongly Polar [H2PO3]− Induced π-Conjugated Group Arrangement for Balanced UV Nonlinear Optical Performance

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    Xin Wen, Guang Peng, Jingyao Lu, Yuchen Yan, Huili Zhang, Huili Zhang, Dequan Kong, Haohai Yu, Huaijin Zhang, Huaijin Zhang, Ning Ye

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  13. Lewis Acidity‐Governed Ion Exchange and Record Birefringence in A′[Ag 3 (PO 3 F) 2 ]

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  14. Lewis Acidity‐Governed Ion Exchange and Record Birefringence in A′[Ag 3 (PO 3 F) 2 ]

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  15. Synergistic Design of UV Nonlinear Optical Crystals: Harnessing Flexible π-Conjugated Anions and Guanidinium Cations for Enhanced Performance

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    Cheng Hu, Yujie Fan, Chensheng Lin, Yunxia Song, Chao Wang, Tao Yan, Min Luo

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  16. Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal

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  17. Research on Nonlinear Optical Materials Based on BO 3 and BO 4 Hydroxy Tetraborates

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    Shuai An, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  18. Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals

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    Hangwei Jia, Xiangrong Song, Muhammad Arif, Yaqi Jin, Feng Yu, Xueling Hou

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  19. Shape‐Topology‐Driven Design of Deep Ultraviolet Nonlinear Optical Crystals: Engineering [CH 3 PO 3 ]–Metal‐Oxo Layered Frameworks for Enhanced SHG, DUV Transparency

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  20. Asymmetry-driven organic–inorganic hybrid strategy for constructing structures with exceptional organofunctionalized B–O units

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  21. Counterion engineering in open-framework crystals: dual enhancement of birefringence and UV transparency in Cd–oxalate framework via cation substitution

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  22. From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulation

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  23. Two scandium borate UV NLO crystals designed through chemical element substitution

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  24. Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence

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  29. Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal

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  31. Heterovalent Coexistence‐Driven Symmetry Breaking and Dimensional Evolution: Designing Polar Heart‐Shaped Channels for Exceptional MFIR Nonlinear Optics

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  35. K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals

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