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RESEARCH PAPER · Journal of the American Chemical Society · 2025

Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal

Haonan Liu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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25 direct citing papers in this saved network. Explore the next layer with second-order citations.

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Rational Design of a Deep-Ultraviolet Nonlinear Optical CrystalOriginalHg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Growth and Characterization of Novel SrB2O4 Crystals0Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3KGdSiSe4 and KGdGeSe4: Two Rare Earth Metal-Based Selenides with Wide Bandgaps and Large Nonlinear Optical Responses0The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4氢键组装的新型紫外非线性光学晶体（R/S‑DACH）Mal·H2O的设计及性能研究（特邀）0Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances3Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances32Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates0Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal0From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals4F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance0Entropy‐Driven Structural Modulation Enables High‐Efficiency Nonlinear Optical Performance in Defective Wurtzite Selenides2K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals1When Octahedra Learn to Be Prisms: Unlocking a Record Deep‑UV NLO Crystal0When Octahedra Learn to Be Prisms: Unlocking a Record Deep‑UV NLO Crystal0Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates0A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages0A Two‐Dimensional Organic Salt With a Deep‐Ultraviolet Cutoff Edge and Strong Second‐Harmonic Generation0A Two‐Dimensional Organic Salt With a Deep‐Ultraviolet Cutoff Edge and Strong Second‐Harmonic Generation0Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges0The Parallel Coplanar Alignment of Planar Non‐π‐Conjugated [Pb 3 Br 3 ] Rings for a Stable Ultraviolet Nonlinear Optical Crystal0Unlocking Hidden Potential via Reprogrammed Mineral Structures: How Anionic Transformation Achieves Ultraviolet Nonlinear Optical Performance0Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides0MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence0

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  1. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  2. Growth and Characterization of Novel SrB2O4 Crystals

    Crystals · 2025-10-25

    Magdalena Angelova, Rusi Rusew, Rositsa Nikolova, Boris Lubomirov Shivachev

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  3. Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties

    The Journal of Physical Chemistry Letters · 2025-12-26

    Zi-Xuan Zhao, Wei Chen, Hui‐Yan Zhao, Mengjiao Xu, Chao He, Qi Wei, Guo-Ming Wang

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  4. KGdSiSe4 and KGdGeSe4: Two Rare Earth Metal-Based Selenides with Wide Bandgaps and Large Nonlinear Optical Responses

    SSRN Electronic Journal · 2026-01-01

    Zhenlong Li, Guansong Zheng, Chen Bai, Leyan Nian, Shilie Pan, Junjie Li

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  5. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

    Hangwei Jia, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  6. 氢键组装的新型紫外非线性光学晶体（R/S‑DACH）Mal·H2O的设计及性能研究（特邀）

    Chinese Journal of Lasers · 2026-01-01

    阚子钧 Kan Zijun, 李雷鸣 Li Leiming, 吴红萍 Wu Hongping, 张玉杰 ZHANG Yujie, 俞洪伟 Yu Hongwei, 吴以成 Wu Yicheng

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  7. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  8. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie International Edition · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  9. Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates

    Chemistry of Materials · 2026-03-04

    Luyong Zhang, Jianyi Zuo, Guangsheng Xu, Jinbin Fan, Xue Bai, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  10. Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal

    Advanced Optical Materials · 2026-05-01

    Wenbin Zhang, Wenqi Jin, X. Ma, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

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  11. From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals

    Journal of the American Chemical Society · 2026-05-04

    Congcong Jin, Yang Li, Chong‐An Chen, Wei Zeng, S. D. Lee, Kang Min Ok

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  12. F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance

    Materials Today Chemistry · 2026-05-06

    Dahong Peng, Hongkang Su, Ziting Yan, chenxu li, Shilie Pan, Min Zhang

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  13. Entropy‐Driven Structural Modulation Enables High‐Efficiency Nonlinear Optical Performance in Defective Wurtzite Selenides

    Laser & Photonics Review · 2026-05-07

    Jian Cheng, Mao‐Yin Ran, Zi-Nan Chen, Sheng‐Ping Guo

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  14. K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-07-02

    Jingjing Xu, Huili Zhang, Xuemei Shi, Xin Wen, Jingyao Lu, Jindong Chen, Chensheng Lin, Ning Ye, Guang Peng

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  15. When Octahedra Learn to Be Prisms: Unlocking a Record Deep‑UV NLO Crystal

    Angewandte Chemie International Edition · 2026-07-11

    Qi Gao, Hongping Wu, Hu Z, Jiyang Wang, Yizhi Wu, Hongwei Yu

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  16. When Octahedra Learn to Be Prisms: Unlocking a Record Deep‑UV NLO Crystal

    Angewandte Chemie · 2026-07-11

    Qi Gao, Hongping Wu, Hu Z, Jiyang Wang, Yizhi Wu, Hongwei Yu

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  17. Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates

    Inorganic Chemistry · 2026-08-04

    Xiuying Zhang, Yebiao Wu, Qiya Huang, Lehui Liu, Peican Chen, Hongming Liu

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  18. A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages

    Inorganic Chemistry · 2026-08-08

    Hanjing Huang, Huijian Zhao, Wenli Zhao, Xianchao Zhu, Ning Ye, Zhanggui Hu, Conggang Li

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  19. A Two‐Dimensional Organic Salt With a Deep‐Ultraviolet Cutoff Edge and Strong Second‐Harmonic Generation

    Angewandte Chemie · 2026-08-20

    Xiaotian Zhang, Xingxing Jiang, Shaohua Xiao, Wenzhi Song, Chao Wu, Zheshuai Lin, Zhipeng Huang, Jinhu Yang, Mark Graeme Humphrey, Chi Zhang

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  20. A Two‐Dimensional Organic Salt With a Deep‐Ultraviolet Cutoff Edge and Strong Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2026-08-20

    Xiaotian Zhang, Xingxing Jiang, Shaohua Xiao, Wenzhi Song, Chao Wu, Zheshuai Lin, Zhipeng Huang, Jinhu Yang, Mark Graeme Humphrey, Chi Zhang

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  21. Multidimensional Cation Modulation toward Phase-Matchable Nonlinear Optical Fluorides with Short UV Cutoff Edges

    Inorganic Chemistry · 2026-08-22

    Ling Wang, Mei Yan, Bing-Wei Miao, Guo-Ren Zhu, Min Li, Wenfeng Zhou, Ru‐Ling Tang

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  22. The Parallel Coplanar Alignment of Planar Non‐π‐Conjugated [Pb 3 Br 3 ] Rings for a Stable Ultraviolet Nonlinear Optical Crystal

    Advanced Optical Materials · 2026-08-27

    Xiaofan Tong, Zuju Ma, Yulu Wu, Ruibiao Fu, Wenjing Yang, Jiacheng Chen, Qian Zeng

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  23. Unlocking Hidden Potential via Reprogrammed Mineral Structures: How Anionic Transformation Achieves Ultraviolet Nonlinear Optical Performance

    Journal of the American Chemical Society · 2026-09-11

    Wenbin Zhang, Ruonan Zhang, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

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  24. Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides

    Coordination Chemistry Reviews · 2026-09-22

    Zichang Wang, Dajiang Mei, Ximeng Lv, Shuchang Wu, Yang Liu, Jingdong Yan, Xiangran Kong, Hongwei Leng, Zuotao Lei, Chunhui Yang

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  25. MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence

    Crystal Growth & Design · 2026-10-02

    Yaozu Li, Chao Wei, Wenjing Zhang, Huiyi Zhang, Bo Zhao, Bingbing Zhang, Ying Wang

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