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RESEARCH PAPER · Science China Chemistry · 2026

Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence

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Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringenceOriginalAnionic configuration extension induced birefringence enhancement in vanadium iodate oxyfluorides0Cation-dominated second-harmonic generation in chiral tetrahydro-1-naphthylammonium halides0Chiral calcium thiocyanate hybrids: amino acid-enabled structural diversity and second-harmonic generation0Counterion engineering in open-framework crystals: dual enhancement of birefringence and UV transparency in Cd–oxalate framework via cation substitution0Diamond-like Ag x Cu 3− x PS 4 ( x = 1 and 2) synthesized by the metal oxide–boron–chalcogen (MOBQ) routine: local high-entropy engineering for balanced infrared nonlinear optical performance1无金属钙钛矿及其非线性光学特性与器件研究进展(特邀)1Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects3Chirality-driven polar lattice engineering for high-performance organic nonlinear optical crystals3Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Halogen-Mediated Dimensionality Reduction in Bismuth Oxychlorides: Trade-off between Birefringence and Band Gap0Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates0Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides0Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides0Proton-transfer-induced supramolecular assembly of 4-Aminopyridinium hydrogen maleate: Synthesis, structure-property correlation toward nonlinear optical (NLO) applications0Fluorinated substituent engineering in naphthyl chalcone crystals for enhanced second-order nonlinear optical responses and measurable terahertz emission0Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)0An investigation of the role of defects and band gap shrinkage in third-order nonlinear optics and enhanced optical limiting of ZnO-CeO2-rGO heterostructures0Influence of the Cation Size on Symmetry Breaking and Optical Performances in Ae2Mg3(BO3)2F4 (Ae = Sr, Ba)0

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  1. Anionic configuration extension induced birefringence enhancement in vanadium iodate oxyfluorides

    Chemical Communications · 2026-01-01

    Bo Yu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  2. Cation-dominated second-harmonic generation in chiral tetrahydro-1-naphthylammonium halides

    Dalton Transactions · 2026-01-01

    Youpei Zhang, Junjie Guan, Junhua Zhang, X Q Li, J Z Zhao, Yimin Yang, Yongshen Zheng, Jialiang Xu

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  3. Chiral calcium thiocyanate hybrids: amino acid-enabled structural diversity and second-harmonic generation

    Chemical Communications · 2026-01-01

    Xuemei Wen, Yingjie Wang, Guohong Zou, Zhien Lin, Kang Min Ok

    Read original paper ↗ ·
  4. Counterion engineering in open-framework crystals: dual enhancement of birefringence and UV transparency in Cd–oxalate framework via cation substitution

    CrystEngComm · 2026-01-01

    Chenyuan Ma, Jingyi Xie, Zhi Fang, Meihong Duan

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  5. Diamond-like Ag x Cu 3− x PS 4 ( x = 1 and 2) synthesized by the metal oxide–boron–chalcogen (MOBQ) routine: local high-entropy engineering for balanced infrared nonlinear optical performance

    Inorganic Chemistry Frontiers · 2026-01-01

    Ao Guo, Rong-Ling Zhu, Zi-Nan Chen, Zhi Deng, Zong-Ze Li, Shao-Peng Gui, Mao‐Yin Ran, Sheng‐Ping Guo

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  6. 无金属钙钛矿及其非线性光学特性与器件研究进展(特邀)

    Chinese Journal of Lasers · 2026-01-01

    Qingyue Cui, Huaiqiang Xun, PANG Xuan, 黄春梅 Huang Chunmei

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  7. Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects

    Inorganic Chemistry · 2026-03-09

    Zheng-Yu Yang, Ming-Yang Cao, Liang Ma, Bing-Wei Miao, Xing-Yu Li, Wenfeng Zhou, Ru‐Ling Tang

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  8. Chirality-driven polar lattice engineering for high-performance organic nonlinear optical crystals

    Science China Materials · 2026-04-07

    Bo Liu, Jiali Chen, Yu-Peng Han, Qiaohong Li, Shangda Li, Fusong Wang, Jian Zhang

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  9. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  10. Halogen-Mediated Dimensionality Reduction in Bismuth Oxychlorides: Trade-off between Birefringence and Band Gap

    Journal of Molecular Structure · 2026-08-03

    Huaiqiang Xun, Shumei Cao, Qingyue Cui, Yi Feng, Rui Wu, Chunmei Huang, Leyan Nian

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  11. Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates

    Inorganic Chemistry · 2026-08-04

    Xiuying Zhang, Yebiao Wu, Qiya Huang, Lehui Liu, Peican Chen, Hongming Liu

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  12. Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides

    Angewandte Chemie International Edition · 2026-09-03

    S. D. Lee, Wei Zeng, Congcong Jin, Chong‐An Chen, Kang Min Ok

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  13. Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides

    Angewandte Chemie · 2026-09-03

    S. D. Lee, Wei Zeng, Congcong Jin, Chong‐An Chen, Kang Min Ok

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  14. Proton-transfer-induced supramolecular assembly of 4-Aminopyridinium hydrogen maleate: Synthesis, structure-property correlation toward nonlinear optical (NLO) applications

    Materials Science and Engineering B · 2026-09-08

    S. Balaji, B. Sahaya Infant Lasalle, Muthu Senthil Pandian, K. Anitha

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  15. Fluorinated substituent engineering in naphthyl chalcone crystals for enhanced second-order nonlinear optical responses and measurable terahertz emission

    Journal of Molecular Structure · 2026-09-09

    Qi Chu, Fanghao Xuan, Shoubo Wang, Jinkang Ma, Weiting Wang, Yukang Liang, Dongwei Zhai, Lifeng Cao, Bing Teng

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  16. Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)

    Inorganic Chemistry · 2026-09-28

    Xiangtian Liu, Bingchen Xiao, Lei Hou, Wencong Li, Wenlong Zhao, Kaixin Yin, Haonan Pei, Xiaonan Li, Zhuangzhuang Dong, Lili Liu

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  17. An investigation of the role of defects and band gap shrinkage in third-order nonlinear optics and enhanced optical limiting of ZnO-CeO2-rGO heterostructures

    Materials Science and Engineering B · 2026-10-02

    R. Anjana, W. Aswathy, Jibi Kunjumon, Neelamma Basayya Gummagol, Javeesh Alex, R. Jolly Bose, Roshan Jose, R. S. Rimal Isaac, P. S. Patil, Davidson Sajan

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  18. Influence of the Cation Size on Symmetry Breaking and Optical Performances in Ae2Mg3(BO3)2F4 (Ae = Sr, Ba)

    Inorganic Chemistry · 2026-10-05

    Yu Qiu, Haonan Liu, Yujie Zhang, Hongping Wu, Hongwei Yu

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