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RESEARCH PAPER · Chemical Science · 2026

From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulation

Zhixiang Wang, Chun-Li Hu, Chuan‐Fu Sun, Jiang‐Gao Mao, Fang Kong

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8 direct citing papers in this saved network. Explore the next layer with second-order citations.

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From centrosymmetric (C 4 H 8 N 5 )(SbF 4 ) to polar (C 4 H 7 N 4 O)(SbF 4 ): a new UV nonlinear optical material achieved by functional group modulationOriginalBiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0Supramolecular template modulation in chiral lead bromide hybrids toward enhanced second-harmonic generation0Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0Unlocking Nonlinear Optics and Photoluminescence with Simultaneous Enhancement of Bandgap and Birefringence in Hybrid Sb-Based Halides2Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence1Local Aromatic Overlap Microregulation Enables Birefringence Enhancement in Isocompositional Hybrid Antimony Halides1Theoretical insights into the electronic structure and NBO features driving nonlinear optical enhancement in the donor–π–acceptor system of OPPh3py0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution

    Chemical Communications · 2026-01-01

    Zheng-Yu Yang, C. Z. Chen, Bing-Wei Miao, Yi‐Lei Lv, Wenfeng Zhou, Ming‐Yang Cao, Ru‐Ling Tang

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  2. Supramolecular template modulation in chiral lead bromide hybrids toward enhanced second-harmonic generation

    Chemical Communications · 2026-01-01

    Juan Cheng, Ziyu Zhou, Yingjie Wang, Lindong Luan, Guohong Zou, Zhien Lin

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  3. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

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  4. Unlocking Nonlinear Optics and Photoluminescence with Simultaneous Enhancement of Bandgap and Birefringence in Hybrid Sb-Based Halides

    Inorganic Chemistry · 2026-06-19

    Yu‐Mei Zhang, Yuqi Xu, Wen‐Dong Yao, Qiu-Xia Tang, Liming Kong, Jiajing Wu

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  5. Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence

    Crystal Growth & Design · 2026-06-29

    Ying Long, Xuehua Dong, Lin Qi, Lindong Luan, Zichen Ren, Zhien Lin, Guohong Zou

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  6. Local Aromatic Overlap Microregulation Enables Birefringence Enhancement in Isocompositional Hybrid Antimony Halides

    Crystal Growth & Design · 2026-08-21

    Jia-Wei Li, Zi-Feng Cao, Jun-Pu Wang, Wen-Pei Jia, Zi-Lin Yang, Yongyan Xu, Kai Zhang, Song-Xue Luo, Hui-Li Zheng, Jian-Qiang Zhao

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  7. Theoretical insights into the electronic structure and NBO features driving nonlinear optical enhancement in the donor–π–acceptor system of OPPh3py

    Royal Society Open Science · 2026-09-02

    Ubeiden C. Samboni, Luis F. Berrio Velasco, Fernando Cuenú Cabezas, Alejandro García Ríos, Chris Lorenz, Alberto Lopez

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  8. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

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