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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range

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Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission rangeOriginalGiant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks6Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks33(CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units10Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum7Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering4Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5Advanced Optoelectronic Properties of Sb(III) based Metal Halides: Opportunities and Challenges25CsICl 2 : A Record-Birefringent Inorganic Crystal with Ultrawide Infrared Transparency Enabled by Linear Interhalogen ICl 2 – Units38Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals5Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence3BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0立体化学活性孤对电子与极性基元协同构筑高性能紫外非线性光学晶体(NH4)2Sb3F9SeO4(特邀)0Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals12Defect Diamond‐Like d 10 Metal Indium Selenium With Strong Second‐Harmonic Generation and Enhanced Laser‐Induced Damage Threshold3Enhanced Birefringence in Organic–Inorganic Hybrid Antimony Halides via Partial Halogen Substitution1Molecular Dipole Engineering in Layered Perovskite Ferroelectrics Enables Large Rashba-Dresselhaus Spin Splitting and Persistent Spin Texture for UV Circularly Polarized Light Detection6Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0Local Aromatic Overlap Microregulation Enables Birefringence Enhancement in Isocompositional Hybrid Antimony Halides1Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks

    Angewandte Chemie · 2025-04-16

    Chong‐An Chen, Yang Li, Hongbo Huang, Congcong Jin, Bingbing Zhang, Kang Min Ok

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  2. Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks

    Angewandte Chemie International Edition · 2025-04-16

    Chong‐An Chen, Yang Li, Hongbo Huang, Congcong Jin, Bingbing Zhang, Kang Min Ok

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  3. (CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units

    Inorganic Chemistry · 2025-05-20

    Ru‐Ling Tang, Yue‐Qi Wei, Yi‐Lei Lv, Bing-Wei Miao, Cheng Chen, Wenlong Liu

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  4. Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum

    Advanced Optical Materials · 2025-06-03

    Yi‐Lei Lv, Ru‐Ling Tang, Cheng Chen, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  5. Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering

    Crystal Growth & Design · 2025-06-24

    Xiang Mao, Yu Yan, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  6. Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions

    Inorganic Chemistry · 2025-06-30

    Lei Geng, Baozhu Zhu, You‐Zhao Lan, Chang‐Yu Meng, Qi Wu

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  7. Advanced Optoelectronic Properties of Sb(III) based Metal Halides: Opportunities and Challenges

    Advanced Functional Materials · 2025-07-06

    Tao Huang, Hui Peng, Ruosheng Zeng, Bingsuo Zou

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  8. CsICl 2 : A Record-Birefringent Inorganic Crystal with Ultrawide Infrared Transparency Enabled by Linear Interhalogen ICl 2 – Units

    Journal of the American Chemical Society · 2025-07-21

    Chong‐An Chen, Yang Li, Congcong Jin, Kang Min Ok

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  9. Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals

    Inorganic Chemistry · 2025-08-05

    Tingyu Wang, Dan Wang, Bailiang Li, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  10. Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence

    Crystal Growth & Design · 2025-12-25

    Han Bing Luo, Siyu Chen, Bailiang Li, Liling Cao, Xuehua Dong, Ling Huang, Guohong Zou

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  11. BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution

    Chemical Communications · 2026-01-01

    Zheng-Yu Yang, C. Z. Chen, Bing-Wei Miao, Yi‐Lei Lv, Wenfeng Zhou, Ming‐Yang Cao, Ru‐Ling Tang

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  12. 立体化学活性孤对电子与极性基元协同构筑高性能紫外非线性光学晶体(NH4)2Sb3F9SeO4(特邀)

    Chinese Journal of Lasers · 2026-01-01

    鄢雨欣 Yan Yuxin, 董雪华 Dong Xuehua, 黄玲 Huang Ling, Zou Guohong

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  13. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

    Journal of the American Chemical Society · 2026-03-05

    Chong‐An Chen, Yang Li, Congcong Jin, S. D. Lee, Zhihua Yang, Kang Min Ok

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  14. Defect Diamond‐Like d 10 Metal Indium Selenium With Strong Second‐Harmonic Generation and Enhanced Laser‐Induced Damage Threshold

    Small · 2026-05-17

    Muhammad Zeeshan, Zhiyong Bai, Kaijie Xie, Jin Zhou, Ji Qi, Muhammad Arsalan, Liangmeng Zhu, Weiqi Huang, Junhua Luo, Sangen Zhao

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  15. Enhanced Birefringence in Organic–Inorganic Hybrid Antimony Halides via Partial Halogen Substitution

    Crystal Growth & Design · 2026-05-25

    Qin Zhang, Luli Wang, Xuemei Lan, Liling Cao, Xuehua Dong, Ling Huang, Guohong Zou

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  16. Molecular Dipole Engineering in Layered Perovskite Ferroelectrics Enables Large Rashba-Dresselhaus Spin Splitting and Persistent Spin Texture for UV Circularly Polarized Light Detection

    Journal of the American Chemical Society · 2026-06-26

    Jia-Hang Wu, Cheng‐Ao Ji, Na Wang, Qiang-Qiang Bi, Yue Zhao, Hao-Nan Huang, Shuo Tan, Le‐Ping Miao, Xiaobin Fu, Xue‐Zeng Lu, Wen Zhang

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  17. Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization

    Coordination Chemistry Reviews · 2026-08-14

    Dan-Dan Zhou, Tian-Tian He, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  18. Local Aromatic Overlap Microregulation Enables Birefringence Enhancement in Isocompositional Hybrid Antimony Halides

    Crystal Growth & Design · 2026-08-21

    Jia-Wei Li, Zi-Feng Cao, Jun-Pu Wang, Wen-Pei Jia, Zi-Lin Yang, Yongyan Xu, Kai Zhang, Song-Xue Luo, Hui-Li Zheng, Jian-Qiang Zhao

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  19. Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation

    Chinese Chemical Letters · 2026-09-01

    Xiangyuan Li, Wei Liu, Xuehua Dong, Ling Huang, Liling Cao, Guohong Zou

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  20. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

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