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RESEARCH PAPER · Inorganic Chemistry · 2024

Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy

Zichang Wang, Jianyi Zuo, Qing‐Yu Liu, Xueling Hou, Minqiang Gai

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Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio StrategyOriginalDie ersten Antimon‐Borosulfate offenbaren das Baukastensystem M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )0The First Antimony Borosulfates Unveil a Modular System M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )7Synthesis and Crystal Structure of Rb[B(SO 4 ) 2 ]: A Borosulfate Obtained from a Reaction with Chlorosulfuric Acid0Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates0The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates4Research advances in rare-earth nonlinear optical crystalline materials in 20250

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  1. Die ersten Antimon‐Borosulfate offenbaren das Baukastensystem M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )

    Angewandte Chemie · 2025-02-12

    Erich Turgunbajew, Henning A. Höppe

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  2. The First Antimony Borosulfates Unveil a Modular System M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )

    Angewandte Chemie International Edition · 2025-02-12

    Erich Turgunbajew, Henning A. Höppe

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  3. Synthesis and Crystal Structure of Rb[B(SO 4 ) 2 ]: A Borosulfate Obtained from a Reaction with Chlorosulfuric Acid

    Zeitschrift für anorganische und allgemeine Chemie · 2025-10-11

    Jasper Nickelsen, Arthur Edelmann, Marios Symeonidis, Jörn Bruns

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  4. Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates

    Chemistry of Materials · 2026-03-04

    Luyong Zhang, Jianyi Zuo, Guangsheng Xu, Jinbin Fan, Xue Bai, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  5. The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates

    Advanced Functional Materials · 2026-03-16

    Qinghe Li, Lilin Yang, Hongyuan Sha, Dongling Yang, Zujian Wang, Xiaoming Yang, Rongbing Su, Bin Su, Chao He, Xifa Long

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  6. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

    Tiantian He, Dandan Zhou, Fang Kong, Jianggao Mao

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