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RESEARCH PAPER · Advanced Optical Materials · 2025

Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence

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Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the BirefringenceOriginal[C(NH 2 ) 3 ] 2 [C 2 H 5 (C 2 O 4 )]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs5Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Realizing large birefringence via S-substitution and anisotropic arrangement optimization4Structural and optoelectrical properties of methylene blue hydrate/poly (vinyl alcohol) (C16H18CIN3S·xH2O)-PVA: A novel material for high-performance laser filters4Organic π-conjugated units as versatile building blocks for high-performance birefringent crystals6SnCl 2 [SC(NH 2 ) 2 ]: lone-pair and hydrogen-bonding triggered chromophore assembling for dual optical optimization0InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials5Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal5Exploring Hybrid Metal Halide Materials beyond Halide Perovskites7Cation-sulfur-driven dimensional reduction engineering for tailoring sulfonate birefringent crystals with enhanced anisotropy2From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals5

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  1. [C(NH 2 ) 3 ] 2 [C 2 H 5 (C 2 O 4 )]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs

    Chemical Communications · 2025-01-01

    Yu-Ming Pan, Xinyou An, Zhi Gang Fang

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  2. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  3. Realizing large birefringence via S-substitution and anisotropic arrangement optimization

    Inorganic Chemistry Frontiers · 2025-01-01

    Zhiwei Sun, Bingbing Wu, Zihao Yu, Qingran Ding, Yu‐Ling Wang, Ming Zhong, Sangen Zhao, Junhua Luo

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  4. Structural and optoelectrical properties of methylene blue hydrate/poly (vinyl alcohol) (C16H18CIN3S·xH2O)-PVA: A novel material for high-performance laser filters

    Optics and Lasers in Engineering · 2025-10-16

    Abdelfatteh Bouzidi, W. Jilani, Ibrahim Sayed Yahia, Mawaheb Al-Dossari

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  5. Organic π-conjugated units as versatile building blocks for high-performance birefringent crystals

    Chinese Journal of Structural Chemistry · 2025-11-19

    Zhenchao Bai, Sangen Zhao, Kang Min Ok, Junhua Luo

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  6. SnCl 2 [SC(NH 2 ) 2 ]: lone-pair and hydrogen-bonding triggered chromophore assembling for dual optical optimization

    Dalton Transactions · 2026-01-01

    Xing-Yu Bi, Yuting Gao, Chenyuan Ma, Zhi Gang Fang, Meihong Duan

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  7. InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials

    Science China Materials · 2026-01-04

    Dan-Dan Zhou, Chunli Hu, Bingxuan Li, Jianggao Mao, Fang Kong

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  8. Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal

    Angewandte Chemie · 2026-03-05

    Lin Qiu, Xing‐Yu Li, Bing-Wei Miao, Hongjian Yu, Wenlong Liu, Yifan Sun, Ru‐Ling Tang

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  9. Exploring Hybrid Metal Halide Materials beyond Halide Perovskites

    Chemistry of Materials · 2026-04-15

    Jiawei Lin, Yutong Lin, Lingling Mao

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  10. Cation-sulfur-driven dimensional reduction engineering for tailoring sulfonate birefringent crystals with enhanced anisotropy

    Chinese Journal of Structural Chemistry · 2026-05-02

    Hanjing Huang, Longyun Xu, Wenli Zhao, Huijian Zhao, Xianghao Kong, Ning Ye, Zhanggui Hu, Conggang Li

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  11. From Coplanarity to Coaxiality: A Linearity-Oriented Design Paradigm for Ultrahigh Ultraviolet Birefringent Inorganic Crystals

    Journal of the American Chemical Society · 2026-05-04

    Congcong Jin, Yang Li, Chong‐An Chen, Wei Zeng, S. D. Lee, Kang Min Ok

    Read original paper ↗ ·