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RESEARCH PAPER · Small · 2023

Three‐in‐One Strategy Constructing the First High‐Performance Nonlinear Optical Sulfide Crystallizing with the P43 Space Group

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Three‐in‐One Strategy Constructing the First High‐Performance Nonlinear Optical Sulfide Crystallizing with the P43 Space GroupOriginalA new infrared nonlinear optical material BaZnGeS 4 with a wide band gap and large nonlinear optical response34Zn 2 HgP 2 S 8 : A Wide Bandgap Hg‐Based Infrared Nonlinear Optical Material with Large Second‐Harmonic Generation Response75KHg4Ga3S9: A Hg-Based Sulfide with Nonlinear-Optical Activity in the A–MII–MIII–Q (A = Alkali Metal; MII = d10 Metal; MIII = Ga, In; Q = S, Se) System17Three-in-One Tetrahedral Functional Units Constructing Diamondlike Ag2In2SiS3.06Se2.94 with High-Performance Nonlinear-Optical Activity4Double alkaline earth metals sulfide SrMgGeS4 with high laser-induced damage threshold and strong second-harmonic generation29Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances157Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction26Polysubstitution Induced Centrosymmetric-to-Noncentrosymmetric Structural Transformation and Nonlinear-Optical Behavior: The Case of Na0.45Ag0.55Ga3Se52[Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response21Design of Pentanary Mixed-Chalcogenides Ag2In2SiS6–xSex (x = 1, 2) Based on the Bucket Effect: Local Structural Difference and High-Performance Nonlinear-Optical Properties Realized by Partial Congener Substitution5Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups15Machine Learning Guided Discovery of Non‐Linear Optical Materials14K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4AgGaS2 and Derivatives: Design, Synthesis, and Optical Properties10Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations4Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations29Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate12Relativistic Effect Engineered Ag 2 Hg 1– x Cd x I 4 Crystals: Achieving Optimal Balance between Bandgap and Nonlinear Optical Performance2Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps5ANb 2 (PS 4 )(S 2 ) 3 (A = K, Rb, Cs): the first Nb-based NLO thiophosphates with [NbS 2 (S 2 ) 3 ] and [Nb 2 PS 6 (S 2 ) 4 ] units exhibiting tri-state structural transformation and high performance6Rare-Earth Selenophosphates Cs 2 YP 2 Se 7 and KYP 2 Se 6 Synthesized by the RFMOBQ Routine: Structural Evolution and Nonlinear Optical Activity2KHg 4 Ga 5 S 12 : A Diamond-like Tetrahedral Chalcogenide Exhibiting Giant Phase-Matching Second Harmonic Generation6{[Ge 2 S 7 ] 6– } ∞ Chains-Mediated Framework Reorganization Triggers Dimensional Upgrade and Infrared Nonlinear Optical Response3From KBa 4 Ge 3 S 10 Cl to ABa 3 EuGe 3 S 11 (A = Na, K) Synthesized by Reactive Flux Assisted Metal Oxide-Boron-Chalcogen (MOBQ) Method: Effect of Cation/Anion Cosubstitution on Crystal Structure and Nonlinear Optical Properties0A 3 Zr 2 (PS 4 )(P 2 S 7 ) 2 (A = K, Rb, Cs) Synthesized by the Metal Oxide-Boron-Chalcogen Routine: A Series of Zirconium-Based Thiophosphate Nonlinear Optical Crystals Featuring PS 4 Tetrahedron and P 2 S 7 Dimer0Nonlinear Optical-Active NaAlP 2 S 6 Synthesized by the MOBQ Method: Synthesis, Structure, and Optical Properties0Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)0

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27 direct citing papers saved.

  1. A new infrared nonlinear optical material BaZnGeS 4 with a wide band gap and large nonlinear optical response

    Inorganic Chemistry Frontiers · 2023-01-01

    Hongshan Wang, Xueting Pan, Wang Zhao, Yu Chu, Junjie Li

    Read original paper ↗ ·
  2. Zn 2 HgP 2 S 8 : A Wide Bandgap Hg‐Based Infrared Nonlinear Optical Material with Large Second‐Harmonic Generation Response

    Small · 2023-07-20

    Yu Chu, Hongshan Wang, Tudi Abutukadi, Zhi Li, Miriding Mutailipu, Xin Su, Zhihua Yang, Junjie Li, Shilie Pan

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  3. KHg4Ga3S9: A Hg-Based Sulfide with Nonlinear-Optical Activity in the A–MII–MIII–Q (A = Alkali Metal; MII = d10 Metal; MIII = Ga, In; Q = S, Se) System

    Inorganic Chemistry · 2023-08-03

    Wen‐Dong Yao, Xiao Fen Huang, Mei Yan, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·
  4. Three-in-One Tetrahedral Functional Units Constructing Diamondlike Ag2In2SiS3.06Se2.94 with High-Performance Nonlinear-Optical Activity

    Inorganic Chemistry · 2023-08-10

    Jun Li, Wenfeng Zhou, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  5. Double alkaline earth metals sulfide SrMgGeS4 with high laser-induced damage threshold and strong second-harmonic generation

    Materials Today Physics · 2023-09-29

    Hongshan Wang, Yu Chu, Xueting Pan, Zhihua Yang, Shilie Pan, Junjie Li

    Read original paper ↗ ·
  6. Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances

    Accounts of Chemical Research · 2024-02-01

    Wenfeng Zhou, Sheng‐Ping Guo

    Read original paper ↗ ·
  7. Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction

    Inorganic Chemistry · 2024-02-16

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao, Fang Kong

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  8. Polysubstitution Induced Centrosymmetric-to-Noncentrosymmetric Structural Transformation and Nonlinear-Optical Behavior: The Case of Na0.45Ag0.55Ga3Se5

    Inorganic Chemistry · 2024-03-22

    Jun Li, Jia-Nuo Li, Liyun Hu, Jun-Jie Ni, Wen‐Dong Yao, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  9. [Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response

    Chemistry of Materials · 2024-03-27

    Zixuan Wu, Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

    Read original paper ↗ ·
  10. Design of Pentanary Mixed-Chalcogenides Ag2In2SiS6–xSex (x = 1, 2) Based on the Bucket Effect: Local Structural Difference and High-Performance Nonlinear-Optical Properties Realized by Partial Congener Substitution

    Inorganic Chemistry · 2024-04-16

    Mingyang Li, Jun Li, Wen‐Dong Yao, Nan Zhang, Haiping Xu, Wenfeng Zhou, Sheng‐Ping Guo

    Read original paper ↗ ·
  11. Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups

    Inorganic Chemistry · 2024-04-23

    Wencong Li, Junbo Wang, Lili Liu, Chunmei Huang, Yanyan Ding, Mengmeng Zhu, Jindan Tian, Hai-Xin Qi, Yaoqing Chu, Jiayue Xu

    Read original paper ↗ ·
  12. Machine Learning Guided Discovery of Non‐Linear Optical Materials

    Advanced Theory and Simulations · 2024-11-27

    Sownyak Mondal, Raheel Hammad

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  13. K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

    Inorganic Chemistry · 2024-12-19

    Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu

    Read original paper ↗ ·
  14. AgGaS2 and Derivatives: Design, Synthesis, and Optical Properties

    Nanomaterials · 2025-01-20

    Guansheng Xing, Bing Chen

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  15. Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations

    Angewandte Chemie · 2025-03-18

    Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  16. Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations

    Angewandte Chemie International Edition · 2025-03-18

    Shao‐Min Pei, Xiaoming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  17. Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate

    Small · 2025-03-27

    Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Jian Tang, Wenwen Jiang, Nian‐Tzu Suen, Wenlong Yin, Sheng‐Ping Guo

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  18. Relativistic Effect Engineered Ag 2 Hg 1– x Cd x I 4 Crystals: Achieving Optimal Balance between Bandgap and Nonlinear Optical Performance

    ACS Applied Optical Materials · 2025-05-14

    Hongyan Cui, Liangcheng Song, Sheng Lv, Yanling Xu, Chongqiang Zhu, Chunhui Yang

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  19. Reactive flux assisted metal oxide–boron–sulfur routine for syntheses of CsRESiS 4 (RE = Sm, Gd–Ho): featuring nonlinear optical activity and wide band gaps

    Inorganic Chemistry Frontiers · 2025-11-05

    Zhen-Cheng Wu, Fang-Xu Tian, Rui Xiao, Mao-Yin Ran, Wenlong Liu, Wen-Tong Chen, Sheng-Ping Guo

    Read original paper ↗ ·
  20. ANb 2 (PS 4 )(S 2 ) 3 (A = K, Rb, Cs): the first Nb-based NLO thiophosphates with [NbS 2 (S 2 ) 3 ] and [Nb 2 PS 6 (S 2 ) 4 ] units exhibiting tri-state structural transformation and high performance

    Inorganic Chemistry Frontiers · 2025-12-09

    Zong-Ze Li, Yang Chi, Yu-Xuan Zhang, Ao Guo, Hui-Zhi Gao, Zheng-Ren Chen, Mao-Yin Ran, Wenlong Liu, Sheng-Ping Guo

    Read original paper ↗ ·
  21. Rare-Earth Selenophosphates Cs 2 YP 2 Se 7 and KYP 2 Se 6 Synthesized by the RFMOBQ Routine: Structural Evolution and Nonlinear Optical Activity

    Inorganic Chemistry · 2026-01-14

    Zong-Ze Li, Ming-Yang Li, Ning Wang, Mao‐Yin Ran, Sheng‐Ping Guo

    Read original paper ↗ ·
  22. KHg 4 Ga 5 S 12 : A Diamond-like Tetrahedral Chalcogenide Exhibiting Giant Phase-Matching Second Harmonic Generation

    Chemistry of Materials · 2026-02-03

    Weiping Guo, Chao Yang, Bingxuan Li, Hong‐Hua Cui, Lingyun Li, Yan Yu, Zhong‐Zhen Luo, Zhigang Zou

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  23. {[Ge 2 S 7 ] 6– } ∞ Chains-Mediated Framework Reorganization Triggers Dimensional Upgrade and Infrared Nonlinear Optical Response

    Chemistry of Materials · 2026-03-19

    Wen-Rui Zhou, Zhen-Cheng Wu, Yong-han WU Xue-jiao LIU, Mao‐Yin Ran, Sheng‐Ping Guo

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  24. From KBa 4 Ge 3 S 10 Cl to ABa 3 EuGe 3 S 11 (A = Na, K) Synthesized by Reactive Flux Assisted Metal Oxide-Boron-Chalcogen (MOBQ) Method: Effect of Cation/Anion Cosubstitution on Crystal Structure and Nonlinear Optical Properties

    Inorganic Chemistry · 2026-06-12

    Qiu-Yang Du, Ming-Yang Li, Nan Zhang, Wenfeng Zhou, Ru‐Ling Tang, Sheng‐Ping Guo

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  25. A 3 Zr 2 (PS 4 )(P 2 S 7 ) 2 (A = K, Rb, Cs) Synthesized by the Metal Oxide-Boron-Chalcogen Routine: A Series of Zirconium-Based Thiophosphate Nonlinear Optical Crystals Featuring PS 4 Tetrahedron and P 2 S 7 Dimer

    Inorganic Chemistry · 2026-07-01

    Zi-Nan Chen, Zong-Ze Li, Ning Wang, Jian Cheng, Zhen‐Cheng Wu, Feng Qiu, Mao‐Yin Ran, Sheng‐Ping Guo

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  26. Nonlinear Optical-Active NaAlP 2 S 6 Synthesized by the MOBQ Method: Synthesis, Structure, and Optical Properties

    Inorganic Chemistry · 2026-07-04

    Zong-Ze Li, Zi-Nan Chen, Sheng‐Ping Guo

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  27. Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)

    Inorganic Chemistry · 2026-09-28

    Xiangtian Liu, Bingchen Xiao, Lei Hou, Wencong Li, Wenlong Zhao, Kaixin Yin, Haonan Pei, Xiaonan Li, Zhuangzhuang Dong, Lili Liu

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