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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

A new infrared nonlinear optical material BaZnGeS 4 with a wide band gap and large nonlinear optical response

Hongshan Wang, Xueting Pan, Wang Zhao, Yu Chu, Junjie Li

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A new infrared nonlinear optical material BaZnGeS 4 with a wide band gap and large nonlinear optical responseOriginalBa 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units8KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6Synthesis, structure and characterization of Cd 2 TeO 3 Cl 2 with unprecedented [Cd 2 O 6 Cl 4 ] octahedral dimers5Chemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement16Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals9Pb 3.5 GeS 4 Br 3 : the first phase-matching thiogermanate halide infrared nonlinear optical material12Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap2Rare-earth oxychalcogenide Eu 2 ZnGe 2 OS 6 : a phase-matching infrared nonlinear optical material with [GeOS 3 ] units7Wide band gap selenide infrared nonlinear optical materials A II Mg 6 Ga 6 Se 16 with strong SHG responses and high laser-induced damage thresholds31β -CsHg 2 I 5 , a compound with rare [Hg 2 I 5 ] dimers and large optical anisotropy2Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Computer‐Aided Development of New Nonlinear Optical Materials38Computer‐Aided Development of New Nonlinear Optical Materials14Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17A wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units2Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds5Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties4Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11Prismatic crystal field stabilized divalent rare-earth chalcogenide REIIBII6CIII6QVI16 with bifunctionality30Blue LD pumped passively Q-switched Pr:YLF lasers generation using 2D germanene nanosheets1Chalcophosphates: A plentiful source of infrared nonlinear optical materials42A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property5SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold4[HgX 2 ] Linear Group Enabled Ultraviolet Birefringent Crystal RbHg 5 Br 11 with Strong Optical Anisotropy and Wide Bandgap12BaAl2MS6 (M = Si and Ge): the rational construction of diamond-like structures with ultrawide band gap by group-optimization approach6Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）0Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering0高性能硫属化物红外非线性光学材料构效关系（特邀）0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0From Centrosymmetric Mg 2 GeS 4 to Noncentrosymmetric CdMg 3 Ge 2 S 8 : Cation-Mixing-Driven Symmetry Reduction4Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry1Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study0AlGaS3: a wide band gap ternary diamond-like infrared nonlinear optical material with high laser-induced damage threshold1

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34 direct citing papers saved.

  1. Ba 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Linan Wang, Hongshan Wang, Ling Luo, Junjie Li, Feng Yu

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  2. KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge

    Dalton Transactions · 2023-01-01

    Zhiyuan Zhang, Die Xu, Zhencheng Wu, Mei Hu, Xin Su, Yineng Huang

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  3. Synthesis, structure and characterization of Cd 2 TeO 3 Cl 2 with unprecedented [Cd 2 O 6 Cl 4 ] octahedral dimers

    Dalton Transactions · 2023-01-01

    Linan Wang, Chen Bai, Yingying Kong, Maqsood Iqbal, Yu Chu, Junjie Li

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  4. Chemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement

    Inorganic Chemistry Frontiers · 2024-01-01

    Hongshan Wang, Xueting Pan, Shilie Pan, Junjie Li

    Read original paper ↗ ·

  5. Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals

    Inorganic Chemistry Frontiers · 2024-01-01

    Shengzi Zhang, Linfeng Dong, Bohui Xu, Huige Chen, Hao Huo, Fei Liang, Rui Fen Wu, Pifu Gong, Zheshuai Lin

    Read original paper ↗ ·

  6. Pb 3.5 GeS 4 Br 3 : the first phase-matching thiogermanate halide infrared nonlinear optical material

    Inorganic Chemistry Frontiers · 2024-01-01

    Jiazheng Zhou, Hongshan Wang, Junjie Liu, Xin Su, Yu Chu, Jiale Qu, Xiangzhan Jiang

    Read original paper ↗ ·

  7. Pb 6 Ba 3 Si 2 S 8 I 10 : a new thiohalide with a quasi-two-dimensional structure and wide band gap

    Dalton Transactions · 2024-01-01

    Zhao Wang, Jiazheng Zhou, Linan Wang, Wenqi Jin, Yingying Kong, Yu Chu, Junjie Li

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  8. Rare-earth oxychalcogenide Eu 2 ZnGe 2 OS 6 : a phase-matching infrared nonlinear optical material with [GeOS 3 ] units

    CrystEngComm · 2024-01-01

    G F Wang, Wentian Wu, Chunxiao Li, Jiyong Yao

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  9. Wide band gap selenide infrared nonlinear optical materials A II Mg 6 Ga 6 Se 16 with strong SHG responses and high laser-induced damage thresholds

    Chemical Science · 2024-01-01

    Linan Wang, Dongdong Chu, Zhihua Yang, Junjie Li, Shilie Pan

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  10. β -CsHg 2 I 5 , a compound with rare [Hg 2 I 5 ] dimers and large optical anisotropy

    Dalton Transactions · 2024-01-01

    Yingying Kong, Hongshan Wang, Wang Zhao, Qi Sun, Junjie Li, Shilie Pan

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  11. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  12. Computer‐Aided Development of New Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-12-05

    Hongshan Wang, Miriding Mutailipu, Zhihua Yang, Shilie Pan, Junjie Li

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  13. Computer‐Aided Development of New Nonlinear Optical Materials

    Angewandte Chemie · 2024-12-05

    Hongshan Wang, Miriding Mutailipu, Zhihua Yang, Shilie Pan, Junjie Li

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  14. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

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  15. A wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units

    Dalton Transactions · 2025-01-01

    Guansong Zheng, Wang Zhao, Xiaoyu Wu, Hongshan Wang, Yi Du, Juanjuan Lu, Xiaodong Zhou, Junjie Li

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  16. Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds

    Dalton Transactions · 2025-01-01

    Guili Wang, Bohui Xu, Chunxiao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao

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  17. Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties

    Dalton Transactions · 2025-01-01

    Maqsood Iqbal, Jiazheng Zhou, Hongshan Wang, Juanjuan Lu, Shilie Pan, Junjie Li

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  18. Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

    Inorganic Chemistry Frontiers · 2025-01-01

    Ping Feng, Shenghua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  19. Prismatic crystal field stabilized divalent rare-earth chalcogenide REIIBII6CIII6QVI16 with bifunctionality

    The Innovation Materials · 2025-01-01

    Linan Wang, Hongshan Wang, Qi Sun, Zuxin Chen, Fei Tang, Shilie Pan, Junjie Li, Miriding Mutailipu

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  20. Blue LD pumped passively Q-switched Pr:YLF lasers generation using 2D germanene nanosheets

    Optics Communications · 2025-01-23

    Junjie Yuan, Houwen Yang, Guowei Liu, Chuanrui Zhao, Zhengping Wang, Wenyong Cheng

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  21. Chalcophosphates: A plentiful source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2025-02-26

    Yingying Kong, Guansong Zheng, Yi Du, Junjie Li, Shilie Pan

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  22. A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property

    Chinese Journal of Structural Chemistry · 2025-03-24

    Qi Sun, Hongshan Wang, Linlin Liu, Zuxin Chen, Junjie Li, Shilie Pan

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  23. SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold

    Optics Express · 2025-03-27

    Hongshan Wang, Ran An, Yi Du, Shilie Pan, Junjie Li

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  24. [HgX 2 ] Linear Group Enabled Ultraviolet Birefringent Crystal RbHg 5 Br 11 with Strong Optical Anisotropy and Wide Bandgap

    Advanced Science · 2025-09-09

    Yingtai Du, Wangfei Che, Yunfei Shi, Juanjuan Lu, Xiaodong Zhou, Ting Liu, Shilie Pan, Junjie Li

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  25. BaAl2MS6 (M = Si and Ge): the rational construction of diamond-like structures with ultrawide band gap by group-optimization approach

    Materials Today Chemistry · 2025-10-25

    Puxuan Wang, Deman Kong, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  26. Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties

    Coordination Chemistry Reviews · 2025-11-19

    Wei Huang, Chi Wang, Guohong Tang, Kexin Huang, Baojun Chen, Z. Y. He, Z. Y. He

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  27. ABCQ4型硫属化物红外非线性光学材料的构效关系（特邀）

    Chinese Journal of Lasers · 2026-01-01

    王硕 Wang Shuo, 张成龙 Zhang Chenglong, 黄君本 Huang Junben, Ailijiang Abudurusuli, 吐沙姑·阿不都吾甫 Abudouwufu Tushagu

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  28. Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering

    Chemical Communications · 2026-01-01

    Xinyao Qi, Haonan Liu, Yu-Jie Zhang, Shihui Ma, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  29. 高性能硫属化物红外非线性光学材料构效关系（特邀）

    Chinese Journal of Lasers · 2026-01-01

    张成龙 Zhang Chenglong, 王硕 Wang Shuo, Ailijiang Abudurusuli, 黄君本 Huang Junben

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  30. SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice

    Inorganic Chemistry · 2026-01-21

    Chenyao Zhao, Yanhong Wang, Yun Lv, SeungGyum Jung, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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  31. From Centrosymmetric Mg 2 GeS 4 to Noncentrosymmetric CdMg 3 Ge 2 S 8 : Cation-Mixing-Driven Symmetry Reduction

    Chemistry of Materials · 2026-04-07

    Chonglei Xu, Eric A. Gabilondo, Michael J. Waters, Yunseung Kuk, James M. Rondinelli, P. Shiv Halasyamani

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  32. Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry

    Advanced Optical Materials · 2026-04-21

    Guili Wang, Siyang Luo, Ming‐Hsien Lee, Jiyong Yao

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  33. Cation-substitution-driven electronic, nonlinear optical, elastic, and thermal transport properties of layered AeHgGeSe4 (Ae = Ba, Sr): A first-principles study

    Computational Condensed Matter · 2026-08-12

    Saravana Karthikeyan SKS, Shaik Gouse Peera, Chang Yi Kong

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  34. AlGaS3: a wide band gap ternary diamond-like infrared nonlinear optical material with high laser-induced damage threshold

    Science China Materials · 2026-09-04

    Yunfei Shi, Hongshan Wang, Yu Chu, Xin Su, Zhenglong Li, Juanjuan Lu, Ailijiang Abudurusuli, Junjie Li, Shilie Pan

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